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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 6-ethyl-2-((pyridin-3-ylmethyl)thio)pyrimidin-4(3H)-one —— C12H13N3OS
    6-ethyl-2-((pyridin-3-ylmethyl)thio)pyrimidin-4(3H)-one
    —— 2-butylsulfanyl-4,5-dimethyl-1H-pyrimidin-6-one —— C10H16N2OS
    2-butylsulfanyl-4,5-dimethyl-1H-pyrimidin-6-one
    —— ethyl (2R)-2-[(4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-3-oxobutanoate —— C12H16N2O4S
    ethyl (2R)-2-[(4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-3-oxobutanoate
    —— (2R)-N,N-dimethyl-3-oxo-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]butanamide —— C13H19N3O3S
    (2R)-N,N-dimethyl-3-oxo-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]butanamide
    —— 2-[(1R)-1-phenylethyl]sulfanyl-4-propyl-1H-pyrimidin-6-one —— C15H18N2OS
    2-[(1R)-1-phenylethyl]sulfanyl-4-propyl-1H-pyrimidin-6-one
    —— 4-ethyl-2-(2-oxopropylsulfanyl)-1H-pyrimidin-6-one —— C9H12N2O2S
    4-ethyl-2-(2-oxopropylsulfanyl)-1H-pyrimidin-6-one
    —— N-[(4-methylphenyl)methyl]-2-[[6-oxo-4-(trifluoromethyl)-1H-pyrimidin-2-yl]sulfanyl]acetamide —— C15H14F3N3O2S
    N-[(4-methylphenyl)methyl]-2-[[6-oxo-4-(trifluoromethyl)-1H-pyrimidin-2-yl]sulfanyl]acetamide
    —— 2-[(4,5-dimethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetonitrile —— C8H9N3OS
    2-[(4,5-dimethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetonitrile
    —— 2-[2-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl]sulfanyl-4-ethyl-1H-pyrimidin-6-one —— C14H21N3O3S
    2-[2-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl]sulfanyl-4-ethyl-1H-pyrimidin-6-one
    —— Methyl 2-((4-ethyl-6-oxo-1,6-dihydropyrimidin-2-yl)thio)acetate —— C9H12N2O3S
    Methyl 2-((4-ethyl-6-oxo-1,6-dihydropyrimidin-2-yl)thio)acetate
    —— N-(2-chlorobenzyl)-2-((4,5-dimethyl-6-oxo-1,6-dihydropyrimidin-2-yl)thio)acetamide —— C15H16ClN3O2S
    N-(2-chlorobenzyl)-2-((4,5-dimethyl-6-oxo-1,6-dihydropyrimidin-2-yl)thio)acetamide
    —— ethyl (2R)-2-[(5-ethyl-4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoate —— C12H18N2O3S
    ethyl (2R)-2-[(5-ethyl-4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoate
    —— ethyl 2-[(5-ethyl-4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-2-methylpropanoate —— C13H20N2O3S
    ethyl 2-[(5-ethyl-4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-2-methylpropanoate
    —— ethyl (2R)-2-[[6-oxo-4-(trifluoromethyl)-1H-pyrimidin-2-yl]sulfanyl]butanoate —— C11H13F3N2O3S
    ethyl (2R)-2-[[6-oxo-4-(trifluoromethyl)-1H-pyrimidin-2-yl]sulfanyl]butanoate
    —— 2-[(4-chlorophenyl)methylsulfanyl]-4,5-dimethyl-1H-pyrimidin-6-one —— C13H13ClN2OS
    2-[(4-chlorophenyl)methylsulfanyl]-4,5-dimethyl-1H-pyrimidin-6-one
    —— 2-allylthio-5-ethyl-6-methyl-4(3H)-pyrimidinone —— C10H14N2OS
    2-allylthio-5-ethyl-6-methyl-4(3H)-pyrimidinone
    —— 2-((3-chlorobenzyl)thio)-6-(trifluoromethyl)pyrimidin-4(3H)-one —— C12H8ClF3N2OS
    2-((3-chlorobenzyl)thio)-6-(trifluoromethyl)pyrimidin-4(3H)-one
    —— methyl (2S)-2-[[6-oxo-4-(trifluoromethyl)-1H-pyrimidin-2-yl]sulfanyl]butanoate —— C10H11F3N2O3S
    methyl (2S)-2-[[6-oxo-4-(trifluoromethyl)-1H-pyrimidin-2-yl]sulfanyl]butanoate
    —— 5-ethyl-4-methyl-2-[(1R)-1-phenylethyl]sulfanyl-1H-pyrimidin-6-one —— C15H18N2OS
    5-ethyl-4-methyl-2-[(1R)-1-phenylethyl]sulfanyl-1H-pyrimidin-6-one
    —— N-(furan-2-ylmethyl)-2-((6-oxo-4-(trifluoromethyl)-1,6-dihydropyrimidin-2-yl)thio)acetamide —— C12H10F3N3O3S
    N-(furan-2-ylmethyl)-2-((6-oxo-4-(trifluoromethyl)-1,6-dihydropyrimidin-2-yl)thio)acetamide
    —— ethyl (2S)-2-[(4,5-dimethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]butanoate —— C12H18N2O3S
    ethyl (2S)-2-[(4,5-dimethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]butanoate
    —— methyl (2S)-2-[(4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]butanoate —— C11H16N2O3S
    methyl (2S)-2-[(4-ethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]butanoate
    —— methyl (2S)-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]butanoate —— C12H18N2O3S
    methyl (2S)-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]butanoate
    —— ethyl (2S)-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]butanoate —— C13H20N2O3S
    ethyl (2S)-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]butanoate
    —— 2-((2-oxo-2,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-4-yl)thio)acetonitrile —— C9H9N3OS
    2-((2-oxo-2,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-4-yl)thio)acetonitrile
    —— 6-n-Propyl-2-allylthiouracil 62459-11-4 C10H14N2OS
    6-n-Propyl-2-allylthiouracil
    —— 2-[[2-[(1S)-1-ethoxyethyl]-1,3-thiazol-4-yl]methylsulfanyl]-5-pyridin-3-yl-1,3,4-oxadiazole —— C15H16N4O2S2
    2-[[2-[(1S)-1-ethoxyethyl]-1,3-thiazol-4-yl]methylsulfanyl]-5-pyridin-3-yl-1,3,4-oxadiazole
    —— (3R)-3-(6-chloropyridazin-3-yl)sulfanyl-1-(1-methylpyrazol-4-yl)piperidin-2-one —— C13H14ClN5OS
    (3R)-3-(6-chloropyridazin-3-yl)sulfanyl-1-(1-methylpyrazol-4-yl)piperidin-2-one
    —— (3S)-3-(6-chloropyridazin-3-yl)sulfanyl-1-(1-methylpyrazol-4-yl)piperidin-2-one —— C13H14ClN5OS
    (3S)-3-(6-chloropyridazin-3-yl)sulfanyl-1-(1-methylpyrazol-4-yl)piperidin-2-one
    —— 4-[(6-chloropyridazin-3-yl)sulfanylmethyl]-2-[(1R)-1-ethoxyethyl]-1,3-thiazole —— C12H14ClN3OS2
    4-[(6-chloropyridazin-3-yl)sulfanylmethyl]-2-[(1R)-1-ethoxyethyl]-1,3-thiazole
    —— 4-[(6-chloropyridazin-3-yl)sulfanylmethyl]-2-[(1S)-1-ethoxyethyl]-1,3-thiazole —— C12H14ClN3OS2
    4-[(6-chloropyridazin-3-yl)sulfanylmethyl]-2-[(1S)-1-ethoxyethyl]-1,3-thiazole
    —— 2-[[2-[(1R)-1-ethoxyethyl]-1,3-thiazol-4-yl]methylsulfanyl]-5-pyridin-3-yl-1,3,4-oxadiazole —— C15H16N4O2S2
    2-[[2-[(1R)-1-ethoxyethyl]-1,3-thiazol-4-yl]methylsulfanyl]-5-pyridin-3-yl-1,3,4-oxadiazole
    —— 2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide —— C14H19N5OS
    2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide
    —— 2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide —— C22H25N3O2S
    2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide
    —— 2-(3-Bromophenyl)-5-[(3-methylphenyl)methylsulfanyl]-1,3,4-oxadiazole —— C16H13BrN2OS
    2-(3-Bromophenyl)-5-[(3-methylphenyl)methylsulfanyl]-1,3,4-oxadiazole
    —— N-[(1R)-1-phenylbutyl]-2-(2,3,5,6-tetramethylphenyl)sulfanylacetamide —— C22H29NOS
    N-[(1R)-1-phenylbutyl]-2-(2,3,5,6-tetramethylphenyl)sulfanylacetamide
    —— 2-(3-bromophenyl)-5-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-1,3,4-oxadiazole —— C16H12BrFN2OS
    2-(3-bromophenyl)-5-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-1,3,4-oxadiazole
    —— [2-oxo-2-[[(1S)-1-phenylbutyl]amino]ethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C22H27NO3S
    [2-oxo-2-[[(1S)-1-phenylbutyl]amino]ethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— (2R)-2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile —— C11H8BrN3OS
    (2R)-2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanenitrile
    —— 6-benzyl-3-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one —— C17H13N5O2S2
    6-benzyl-3-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one
    —— N-cycloheptyl-2-[[6-(4-fluorophenyl)-7-oxo-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-3-yl]sulfanyl]acetamide —— C19H21FN6O2S
    N-cycloheptyl-2-[[6-(4-fluorophenyl)-7-oxo-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-3-yl]sulfanyl]acetamide
    —— 3-(4-Methylphenyl)-7-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C17H12N4O2S3
    3-(4-Methylphenyl)-7-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— 2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide —— C16H22N4OS
    2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide
    —— N-cyclopentyl-2-[(4-oxo-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl)sulfanyl]acetamide —— C11H13N5O2S2
    N-cyclopentyl-2-[(4-oxo-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl)sulfanyl]acetamide
    —— 3-(2-oxopropylsulfanyl)-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one —— C7H7N5O2S
    3-(2-oxopropylsulfanyl)-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one
    —— 3-Methyl-7-(2-oxopropylsulfanyl)-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C8H8N4O2S2
    3-Methyl-7-(2-oxopropylsulfanyl)-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— 2-[[6-(4-chlorophenyl)-7-oxo-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-3-yl]sulfanyl]-N-cyclohexylacetamide —— C18H19ClN6O2S
    2-[[6-(4-chlorophenyl)-7-oxo-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-3-yl]sulfanyl]-N-cyclohexylacetamide
    —— N-cycloheptyl-2-[(7-oxo-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-3-yl)sulfanyl]acetamide —— C13H18N6O2S
    N-cycloheptyl-2-[(7-oxo-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-3-yl)sulfanyl]acetamide
    —— 2-[(3-tert-butyl-4-oxo-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl)sulfanyl]-N-cycloheptylacetamide —— C17H25N5O2S2
    2-[(3-tert-butyl-4-oxo-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-7-yl)sulfanyl]-N-cycloheptylacetamide
    —— 3-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one —— C10H7N5O2S2
    3-(2-oxo-2-thiophen-2-ylethyl)sulfanyl-8H-[1,2,4]triazolo[4,3-b][1,2,4]triazin-7-one