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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-N-[(1R,2S)-2-methylcyclohexyl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C16H22N4OS2
    (2R)-N-[(1R,2S)-2-methylcyclohexyl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— N-[(1R)-1-(4-ethylphenyl)ethyl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H20N4OS2
    N-[(1R)-1-(4-ethylphenyl)ethyl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 6-Amino-1-cyclopropyl-5-[2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetyl]pyrimidine-2,4-dione —— C13H14N4O3S2
    6-Amino-1-cyclopropyl-5-[2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetyl]pyrimidine-2,4-dione
    —— 6-Amino-5-[2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetyl]-1-cyclopropylpyrimidine-2,4-dione —— C18H17N5O4S
    6-Amino-5-[2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetyl]-1-cyclopropylpyrimidine-2,4-dione
    —— 2-(4-chlorophenyl)-5-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3,4-oxadiazole —— C15H10ClN5OS2
    2-(4-chlorophenyl)-5-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3,4-oxadiazole
    —— N-[2-(4-methoxyphenoxy)ethyl]-N-methyl-2-phenylsulfanylpyridine-3-carboxamide —— C22H22N2O3S
    N-[2-(4-methoxyphenoxy)ethyl]-N-methyl-2-phenylsulfanylpyridine-3-carboxamide
    —— 3-[(3-fluorophenyl)methylsulfanyl]-5-thiophen-2-yl-1H-1,2,4-triazole —— C13H10FN3S2
    3-[(3-fluorophenyl)methylsulfanyl]-5-thiophen-2-yl-1H-1,2,4-triazole
    —— N-[(1S)-1-(4-ethylphenyl)ethyl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H20N4OS2
    N-[(1S)-1-(4-ethylphenyl)ethyl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-[(1-Cyclopentyltetrazol-5-yl)sulfanylmethyl]-5-(3-methylphenyl)-1,3,4-oxadiazole —— C16H18N6OS
    2-[(1-Cyclopentyltetrazol-5-yl)sulfanylmethyl]-5-(3-methylphenyl)-1,3,4-oxadiazole
    —— N-[2-(cyclohexen-1-yl)ethyl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H20N4OS2
    N-[2-(cyclohexen-1-yl)ethyl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 1-(1-ethyl-2,5-dimethylpyrrol-3-yl)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C16H18N4OS2
    1-(1-ethyl-2,5-dimethylpyrrol-3-yl)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— 5-(3,4-Dimethoxyphenyl)-2-methyl-4-pyrimidin-2-ylsulfanylthieno[2,3-d]pyrimidine —— C19H16N4O2S2
    5-(3,4-Dimethoxyphenyl)-2-methyl-4-pyrimidin-2-ylsulfanylthieno[2,3-d]pyrimidine
    —— 5-(4-Chlorophenyl)-4-(1-cyclopropyltetrazol-5-yl)sulfanylthieno[2,3-d]pyrimidine —— C16H11ClN6S2
    5-(4-Chlorophenyl)-4-(1-cyclopropyltetrazol-5-yl)sulfanylthieno[2,3-d]pyrimidine
    —— 6-Amino-1-cyclopropyl-5-[2-(1-methylimidazol-2-yl)sulfanylacetyl]pyrimidine-2,4-dione —— C13H15N5O3S
    6-Amino-1-cyclopropyl-5-[2-(1-methylimidazol-2-yl)sulfanylacetyl]pyrimidine-2,4-dione
    —— 6-Amino-1-cyclopropyl-5-(2-pyrimidin-2-ylsulfanylacetyl)pyrimidine-2,4-dione —— C13H13N5O3S
    6-Amino-1-cyclopropyl-5-(2-pyrimidin-2-ylsulfanylacetyl)pyrimidine-2,4-dione
    —— 6-(2,3-Dihydro-1,4-benzodioxin-6-ylsulfanyl)pyridine-3-sulfonamide —— C13H12N2O4S2
    6-(2,3-Dihydro-1,4-benzodioxin-6-ylsulfanyl)pyridine-3-sulfonamide
    —— (4-methylsulfanylphenyl)methyl N'-propan-2-ylcarbamimidothioate —— C12H18N2S2
    (4-methylsulfanylphenyl)methyl N'-propan-2-ylcarbamimidothioate
    —— N-[2-(4-methylphenyl)sulfanylethyl]-2-(1-oxidopyridin-1-ium-2-yl)oxyacetamide —— C16H18N2O3S
    N-[2-(4-methylphenyl)sulfanylethyl]-2-(1-oxidopyridin-1-ium-2-yl)oxyacetamide
    —— N-[2-(4-chlorophenyl)sulfanylphenyl]-2-([1,2,4]triazolo[4,3-a]pyridin-3-yloxy)acetamide —— C20H15ClN4O2S
    N-[2-(4-chlorophenyl)sulfanylphenyl]-2-([1,2,4]triazolo[4,3-a]pyridin-3-yloxy)acetamide
    —— 1-[2-(4-Chlorophenyl)sulfanylethyl]-3,5-dimethyl-4-nitropyrazole —— C13H14ClN3O2S
    1-[2-(4-Chlorophenyl)sulfanylethyl]-3,5-dimethyl-4-nitropyrazole
    —— N-[2-(4-chlorophenyl)sulfanylphenyl]-2-(1-oxidopyridin-1-ium-2-yl)oxyacetamide —— C19H15ClN2O3S
    N-[2-(4-chlorophenyl)sulfanylphenyl]-2-(1-oxidopyridin-1-ium-2-yl)oxyacetamide
    —— (3S)-1-tert-butyl-5-oxo-N-(2-phenylsulfanylphenyl)pyrrolidine-3-carboxamide —— C21H24N2O2S
    (3S)-1-tert-butyl-5-oxo-N-(2-phenylsulfanylphenyl)pyrrolidine-3-carboxamide
    —— (3R)-1-tert-butyl-5-oxo-N-(2-phenylsulfanylphenyl)pyrrolidine-3-carboxamide —— C21H24N2O2S
    (3R)-1-tert-butyl-5-oxo-N-(2-phenylsulfanylphenyl)pyrrolidine-3-carboxamide
    —— 4-cyclopropyl-3-(2-methylprop-2-enylsulfanyl)-1H-1,2,4-triazol-5-one —— C9H13N3OS
    4-cyclopropyl-3-(2-methylprop-2-enylsulfanyl)-1H-1,2,4-triazol-5-one
    —— N-[(1R)-1-(furan-2-yl)ethyl]-2-pyridin-2-ylsulfanylacetamide —— C13H14N2O2S
    N-[(1R)-1-(furan-2-yl)ethyl]-2-pyridin-2-ylsulfanylacetamide
    —— 2-(5-Bromothiophen-2-yl)-5-(pyridin-2-ylsulfanylmethyl)-1,3,4-oxadiazole —— C12H8BrN3OS2
    2-(5-Bromothiophen-2-yl)-5-(pyridin-2-ylsulfanylmethyl)-1,3,4-oxadiazole
    —— N-benzyl-N-[(3S)-1,1-dioxo-2,3-dihydrothiophen-3-yl]-2-pyridin-2-ylsulfanylacetamide —— C18H18N2O3S2
    N-benzyl-N-[(3S)-1,1-dioxo-2,3-dihydrothiophen-3-yl]-2-pyridin-2-ylsulfanylacetamide
    —— N-[(2-fluorophenyl)methyl]-2-pyridin-2-ylsulfanylacetamide —— C14H13FN2OS
    N-[(2-fluorophenyl)methyl]-2-pyridin-2-ylsulfanylacetamide
    —— 4-cyclopropyl-3-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one —— C12H11N5O3S
    4-cyclopropyl-3-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one
    —— 1-(4-Benzylsulfonylpiperazin-1-yl)-2-pyridin-2-ylsulfanylethanone —— C18H21N3O3S2
    1-(4-Benzylsulfonylpiperazin-1-yl)-2-pyridin-2-ylsulfanylethanone
    —— 4-cyclopropyl-3-[[2-(4-methylanilino)-1,3-thiazol-4-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one —— C16H17N5OS2
    4-cyclopropyl-3-[[2-(4-methylanilino)-1,3-thiazol-4-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one
    —— 4-cyclopropyl-3-[(4-methylphenyl)methylsulfanyl]-1H-1,2,4-triazol-5-one —— C13H15N3OS
    4-cyclopropyl-3-[(4-methylphenyl)methylsulfanyl]-1H-1,2,4-triazol-5-one
    —— N-(6-amino-1-butyl-2,4-dioxopyrimidin-5-yl)-N-cyclopentyl-2-pyridin-2-ylsulfanylacetamide —— C20H27N5O3S
    N-(6-amino-1-butyl-2,4-dioxopyrimidin-5-yl)-N-cyclopentyl-2-pyridin-2-ylsulfanylacetamide
    —— 4-cyclopropyl-3-[(2-phenyl-1,3-thiazol-4-yl)methylsulfanyl]-1H-1,2,4-triazol-5-one —— C15H14N4OS2
    4-cyclopropyl-3-[(2-phenyl-1,3-thiazol-4-yl)methylsulfanyl]-1H-1,2,4-triazol-5-one
    —— 4-cyclopropyl-3-[2-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl]sulfanyl-1H-1,2,4-triazol-5-one —— C13H20N4O3S
    4-cyclopropyl-3-[2-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl]sulfanyl-1H-1,2,4-triazol-5-one
    —— 4-cyclopropyl-3-[2-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl]sulfanyl-1H-1,2,4-triazol-5-one —— C13H20N4O3S
    4-cyclopropyl-3-[2-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl]sulfanyl-1H-1,2,4-triazol-5-one
    —— 4-Cyclopropyl-5-((2-oxo-2-(thiophen-2-yl)ethyl)thio)-2,4-dihydro-3h-1,2,4-triazol-3-one —— C11H11N3O2S2
    4-Cyclopropyl-5-((2-oxo-2-(thiophen-2-yl)ethyl)thio)-2,4-dihydro-3h-1,2,4-triazol-3-one
    —— N-(6-amino-1-butyl-2,4-dioxopyrimidin-5-yl)-N-ethyl-2-pyridin-2-ylsulfanylacetamide —— C17H23N5O3S
    N-(6-amino-1-butyl-2,4-dioxopyrimidin-5-yl)-N-ethyl-2-pyridin-2-ylsulfanylacetamide
    —— N-[[5-(4-chlorophenyl)furan-2-yl]methyl]-N-methyl-2-pyridin-2-ylsulfanylacetamide —— C19H17ClN2O2S
    N-[[5-(4-chlorophenyl)furan-2-yl]methyl]-N-methyl-2-pyridin-2-ylsulfanylacetamide
    —— N-[(1S)-1-(furan-2-yl)ethyl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C17H17N3O3S
    N-[(1S)-1-(furan-2-yl)ethyl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 4-cyclopropyl-3-(2-hydroxyethylsulfanyl)-1H-1,2,4-triazol-5-one —— C7H11N3O2S
    4-cyclopropyl-3-(2-hydroxyethylsulfanyl)-1H-1,2,4-triazol-5-one
    —— N-[(2R)-heptan-2-yl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C18H25N3O2S
    N-[(2R)-heptan-2-yl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[(1R)-1-(furan-2-yl)ethyl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C17H17N3O3S
    N-[(1R)-1-(furan-2-yl)ethyl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[(2R)-5-methylhexan-2-yl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C18H25N3O2S
    N-[(2R)-5-methylhexan-2-yl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[(2S)-6-methylheptan-2-yl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C19H27N3O2S
    N-[(2S)-6-methylheptan-2-yl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[(1R)-1-cyclopropylethyl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C16H19N3O2S
    N-[(1R)-1-cyclopropylethyl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 4-cyclopropyl-3-(2-ethoxyethylsulfanyl)-1H-1,2,4-triazol-5-one —— C9H15N3O2S
    4-cyclopropyl-3-(2-ethoxyethylsulfanyl)-1H-1,2,4-triazol-5-one
    —— 2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-octan-2-yl]acetamide —— C19H27N3O2S
    2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-octan-2-yl]acetamide
    —— 2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-pentylacetamide —— C16H21N3O2S
    2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-pentylacetamide
    —— N-methyl-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3-methylthiophen-2-yl)methyl]acetamide —— C18H19N3O2S2
    N-methyl-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3-methylthiophen-2-yl)methyl]acetamide