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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-[(4-Chlorobenzyl)sulfanyl][1,2,4]triazino[5,6-d][3,1]benzoxazepine —— C17H11ClN4OS
    3-[(4-Chlorobenzyl)sulfanyl][1,2,4]triazino[5,6-d][3,1]benzoxazepine
    —— 3-(Benzylsulfanyl)-5-(2-(((4-fluorobenzyl)oxy)amino)vinyl)-6-methyl-1,2,4-triazine —— C20H19FN4OS
    3-(Benzylsulfanyl)-5-(2-(((4-fluorobenzyl)oxy)amino)vinyl)-6-methyl-1,2,4-triazine
    —— 2-{6-[(4-Chlorophenyl)sulfanyl]-3-pyridazinyl}-2-phenylacetonitrile —— C18H12ClN3S
    2-{6-[(4-Chlorophenyl)sulfanyl]-3-pyridazinyl}-2-phenylacetonitrile
    —— 4-Nitro-5-{[5-(prop-2-EN-1-YL)-5H-[1,2,4]triazino[5,6-B]indol-3-YL]sulfanyl}-2,1,3-benzothiadiazole —— C18H11N7O2S2
    4-Nitro-5-{[5-(prop-2-EN-1-YL)-5H-[1,2,4]triazino[5,6-B]indol-3-YL]sulfanyl}-2,1,3-benzothiadiazole
    —— 3-((4-Chlorobenzyl)sulfanyl)-5-(2-(methoxyamino)vinyl)-6-methyl-1,2,4-triazine —— C14H15ClN4OS
    3-((4-Chlorobenzyl)sulfanyl)-5-(2-(methoxyamino)vinyl)-6-methyl-1,2,4-triazine
    —— (1R,2S,5S,6S)-2,6-bis[(4-methylphenyl)sulfanylmethyl]bicyclo[3.3.1]nonane —— C25H32S2
    (1R,2S,5S,6S)-2,6-bis[(4-methylphenyl)sulfanylmethyl]bicyclo[3.3.1]nonane
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[(4-chlorophenyl)methyl]acetamide —— C26H23ClN4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[(4-chlorophenyl)methyl]acetamide
    —— 2-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]acetonitrile —— C19H16N4S
    2-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]acetonitrile
    —— 2-(2,4-Dichlorophenyl)-2-[6-(phenylsulfanyl)-3-pyridazinyl]acetonitrile 339026-28-7 C18H11Cl2N3S
    2-(2,4-Dichlorophenyl)-2-[6-(phenylsulfanyl)-3-pyridazinyl]acetonitrile
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[(4-methylphenyl)methyl]acetamide —— C25H22N4OS
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[(4-methylphenyl)methyl]acetamide
    —— 10-Bromo-3-(butylsulfanyl)[1,2,4]triazino[5,6-d][3,1]benzoxazepine —— C14H13BrN4OS
    10-Bromo-3-(butylsulfanyl)[1,2,4]triazino[5,6-d][3,1]benzoxazepine
    —— 3-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]oxolan-2-one —— C19H15N3O2S
    3-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]oxolan-2-one
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[(2S)-3-methylbutan-2-yl]acetamide —— C24H28N4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[(2S)-3-methylbutan-2-yl]acetamide
    —— 5-(4-Chloro-benzylsulfanyl)-8,11,11-trimethyl-3,4,6-triaza-tricyclo[6.2.1.0*2,7*]undeca-2,4,6-triene —— C18H20ClN3S
    5-(4-Chloro-benzylsulfanyl)-8,11,11-trimethyl-3,4,6-triaza-tricyclo[6.2.1.0*2,7*]undeca-2,4,6-triene
    —— 6-Amino-5-[2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetyl]-1,3-dimethylpyrimidine-2,4-dione —— C23H20N6O3S
    6-Amino-5-[2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetyl]-1,3-dimethylpyrimidine-2,4-dione
    —— 5-(4-Chlorophenyl)sulfanyl-6-(4-methylphenyl)-3-phenyl-1,2,4-triazine —— C22H16ClN3S
    5-(4-Chlorophenyl)sulfanyl-6-(4-methylphenyl)-3-phenyl-1,2,4-triazine
    —— 3-[[(2R)-oxan-2-yl]methylsulfanyl]-5,6-diphenyl-1,2,4-triazine —— C21H21N3OS
    3-[[(2R)-oxan-2-yl]methylsulfanyl]-5,6-diphenyl-1,2,4-triazine
    —— 3,6-Bis(4-fluorophenyl)-5-phenylsulfanyl-1,2,4-triazine —— C21H13F2N3S
    3,6-Bis(4-fluorophenyl)-5-phenylsulfanyl-1,2,4-triazine
    —— 2-{[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl}-N-tert-butylacetamide —— C23H26N4OS
    2-{[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl}-N-tert-butylacetamide
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]ethanone —— C25H28N4O2S
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]ethanone
    —— (2R)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]propanamide —— C23H24N4O2S
    (2R)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]propanamide
    —— 3-(2-Fluorophenyl)-6-phenyl-5-phenylsulfanyl-1,2,4-triazine —— C21H14FN3S
    3-(2-Fluorophenyl)-6-phenyl-5-phenylsulfanyl-1,2,4-triazine
    —— 5-(Methylsulfanyl)-1H-1,2,3-triazole-4-carbohydrazide —— C4H7N5OS
    5-(Methylsulfanyl)-1H-1,2,3-triazole-4-carbohydrazide
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-cyclopropylacetamide —— C22H22N4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-cyclopropylacetamide
    —— 2-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-1-morpholin-4-ylethanone —— C23H24N4O2S
    2-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-1-morpholin-4-ylethanone
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[(2R)-pentan-2-yl]acetamide —— C22H24N4OS
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[(2R)-pentan-2-yl]acetamide
    —— 2-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethanone —— C25H17N5O2S
    2-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethanone
    —— 1-[(6-Chloropyridazin-3-yl)amino]-3-[4-(difluoromethylsulfanyl)phenyl]thiourea —— C12H10ClF2N5S2
    1-[(6-Chloropyridazin-3-yl)amino]-3-[4-(difluoromethylsulfanyl)phenyl]thiourea
    —— (2S)-N-cyclopentyl-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]propanamide —— C23H24N4OS
    (2S)-N-cyclopentyl-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]propanamide
    —— Ethyl 5-[(4-bromophenyl)sulfanyl]-3-phenyl-1,2,4-triazine-6-carboxylate —— C18H14BrN3O2S
    Ethyl 5-[(4-bromophenyl)sulfanyl]-3-phenyl-1,2,4-triazine-6-carboxylate
    —— (2R)-2-(4-chlorophenyl)-2-[6-(4-chlorophenyl)sulfanylpyridazin-3-yl]acetonitrile —— C18H11Cl2N3S
    (2R)-2-(4-chlorophenyl)-2-[6-(4-chlorophenyl)sulfanylpyridazin-3-yl]acetonitrile
    —— 5-(Benzylsulfanyl)-3-phenyl-6-(trifluoromethyl)-1,2,4-triazine —— C17H12F3N3S
    5-(Benzylsulfanyl)-3-phenyl-6-(trifluoromethyl)-1,2,4-triazine
    —— (1S,8R)-5-[(2-fluorophenyl)methylsulfanyl]-8,11,11-trimethyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene —— C18H20FN3S
    (1S,8R)-5-[(2-fluorophenyl)methylsulfanyl]-8,11,11-trimethyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene
    —— (E)-2-(3-benzylsulfanyl-6-methyl-1,2,4-triazin-5-yl)-N,N-dimethylethenamine —— C15H18N4S
    (E)-2-(3-benzylsulfanyl-6-methyl-1,2,4-triazin-5-yl)-N,N-dimethylethenamine
    —— 4-Chlorobenzyl 5,6-dimethyl-1,2,4-triazin-3-yl sulfide —— C12H12ClN3S
    4-Chlorobenzyl 5,6-dimethyl-1,2,4-triazin-3-yl sulfide
    —— Ethyl 5-[(4-fluorophenyl)sulfanyl]-3-phenyl-1,2,4-triazine-6-carboxylate —— C18H14FN3O2S
    Ethyl 5-[(4-fluorophenyl)sulfanyl]-3-phenyl-1,2,4-triazine-6-carboxylate
    —— Methyl 4-{[6-methyl-3-(4-methylphenyl)-1,2,4-triazin-5-yl]sulfanyl}phenyl ether —— C18H17N3OS
    Methyl 4-{[6-methyl-3-(4-methylphenyl)-1,2,4-triazin-5-yl]sulfanyl}phenyl ether
    —— ethyl (2S)-2-[[5,6-bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]propanoate —— C16H15N3O4S
    ethyl (2S)-2-[[5,6-bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]propanoate
    —— {2-[(6-chloro-3-pyridazinyl)sulfanyl]-1-methyl-1H-imidazol-4-yl}methanol —— C9H9ClN4OS
    {2-[(6-chloro-3-pyridazinyl)sulfanyl]-1-methyl-1H-imidazol-4-yl}methanol
    —— 2-[(5,6-diethyl-1,2,4-triazin-3-yl)sulfanyl]-N-(thiophen-2-ylmethyl)acetamide —— C14H18N4OS2
    2-[(5,6-diethyl-1,2,4-triazin-3-yl)sulfanyl]-N-(thiophen-2-ylmethyl)acetamide
    —— 5,6-Bis(furan-2-yl)-3-(2-methylpropylsulfanyl)-1,2,4-triazine —— C15H15N3O2S
    5,6-Bis(furan-2-yl)-3-(2-methylpropylsulfanyl)-1,2,4-triazine
    —— (3E)-3-hydroxyimino-1-benzothiophen-2-one —— C8H5NO2S
    (3E)-3-hydroxyimino-1-benzothiophen-2-one
    —— 1-ethyl-3-[(6-methoxy-1H-pyrazin-2-ylidene)-nitrosomethyl]thiourea —— C9H13N5O2S
    1-ethyl-3-[(6-methoxy-1H-pyrazin-2-ylidene)-nitrosomethyl]thiourea
    —— Butenthiolen —— C4H6S
    Butenthiolen
    —— 1-ethyl-3-[nitroso(1H-pyrazin-2-ylidene)methyl]thiourea —— C8H11N5OS
    1-ethyl-3-[nitroso(1H-pyrazin-2-ylidene)methyl]thiourea
    —— (1R,5S)-2,6-bis(phenylsulfanyl)bicyclo[3.3.1]nona-2,6-diene —— C21H20S2
    (1R,5S)-2,6-bis(phenylsulfanyl)bicyclo[3.3.1]nona-2,6-diene
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-4-phenylbutan-2-ylideneamino]triazole-4-carboxamide —— C22H21ClN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-4-phenylbutan-2-ylideneamino]triazole-4-carboxamide
    —— N-[2-[(5E)-5-[(4-fluorophenyl)methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]ethyl]-2-(4-methylphenyl)sulfanylacetamide —— C21H19FN2O3S2
    N-[2-[(5E)-5-[(4-fluorophenyl)methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]ethyl]-2-(4-methylphenyl)sulfanylacetamide
    —— (7E)-3-[chloro(difluoro)methyl]-7-[(1,5-dimethyl-1H-pyrazol-4-yl)methylidene]-6-methyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C12H11ClF2N6S
    (7E)-3-[chloro(difluoro)methyl]-7-[(1,5-dimethyl-1H-pyrazol-4-yl)methylidene]-6-methyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (5E)-2-[2,2-dimethoxyethyl(methyl)amino]-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazol-4-one —— C16H20N2O3S2
    (5E)-2-[2,2-dimethoxyethyl(methyl)amino]-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazol-4-one