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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— ethyl 2-[2-[2-oxo-2-[[(1S)-1-thiophen-2-ylethyl]amino]ethyl]sulfanyl-1,3-thiazol-4-yl]acetate —— C15H18N2O3S3
    ethyl 2-[2-[2-oxo-2-[[(1S)-1-thiophen-2-ylethyl]amino]ethyl]sulfanyl-1,3-thiazol-4-yl]acetate
    —— 2-(2-Phenylquinazolin-4-yl)sulfanyl-1,3-benzothiazole —— C21H13N3S2
    2-(2-Phenylquinazolin-4-yl)sulfanyl-1,3-benzothiazole
    —— (2R)-N-[(1-methylpiperidin-1-ium-4-ylidene)amino]-2-phenylsulfanylpropanamide —— C15H22N3OS+
    (2R)-N-[(1-methylpiperidin-1-ium-4-ylidene)amino]-2-phenylsulfanylpropanamide
    —— N-[[(2S)-oxolan-2-yl]methyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C11H15N3O3S
    N-[[(2S)-oxolan-2-yl]methyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— 2-[(1R)-1-(2-chlorophenyl)ethyl]sulfanyl-5-(2-fluorophenyl)-1,3,4-oxadiazole —— C16H12ClFN2OS
    2-[(1R)-1-(2-chlorophenyl)ethyl]sulfanyl-5-(2-fluorophenyl)-1,3,4-oxadiazole
    —— (5-Benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)methyl-cyclohexylazanium —— C17H25N4S+
    (5-Benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)methyl-cyclohexylazanium
    —— (3R)-3-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)piperidine —— C10H18N4S
    (3R)-3-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)piperidine
    —— (3S)-3-(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)-1-(4-methylcyclohexyl)piperidine —— C17H30N4S
    (3S)-3-(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)-1-(4-methylcyclohexyl)piperidine
    —— (3S)-3-[4-ethyl-5-(2-pyrrolidin-1-ium-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]-1-methylsulfonylpiperidine —— C16H30N5O2S2+
    (3S)-3-[4-ethyl-5-(2-pyrrolidin-1-ium-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]-1-methylsulfonylpiperidine
    —— 3-benzylsulfanyl-4-methyl-5-[(2S)-1-methylsulfonylpyrrolidin-2-yl]-1,2,4-triazole —— C15H20N4O2S2
    3-benzylsulfanyl-4-methyl-5-[(2S)-1-methylsulfonylpyrrolidin-2-yl]-1,2,4-triazole
    —— (4-methoxycyclohexyl)-[(2S)-2-[4-methyl-5-(2-pyrrolidin-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]pyrrolidin-1-yl]methanone —— C21H35N5O2S
    (4-methoxycyclohexyl)-[(2S)-2-[4-methyl-5-(2-pyrrolidin-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]pyrrolidin-1-yl]methanone
    —— 4-(5-Ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)-1-[[1-(2-phenylethyl)tetrazol-5-yl]methyl]piperidin-1-ium —— C20H29N8S+
    4-(5-Ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)-1-[[1-(2-phenylethyl)tetrazol-5-yl]methyl]piperidin-1-ium
    —— (3S)-3-(5-methylsulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl)piperidine —— C11H20N4S
    (3S)-3-(5-methylsulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl)piperidine
    —— (3S)-3-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)piperidine —— C10H18N4S
    (3S)-3-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)piperidine
    —— [(2S)-2-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)pyrrolidin-1-yl]-[(2S)-oxolan-2-yl]methanone —— C19H24N4O2S
    [(2S)-2-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)pyrrolidin-1-yl]-[(2S)-oxolan-2-yl]methanone
    —— 4-methyl-3-(2-pyrrolidin-1-ylethylsulfanyl)-5-[(2S)-1-(thiophen-2-ylmethyl)pyrrolidin-2-yl]-1,2,4-triazole —— C18H27N5S2
    4-methyl-3-(2-pyrrolidin-1-ylethylsulfanyl)-5-[(2S)-1-(thiophen-2-ylmethyl)pyrrolidin-2-yl]-1,2,4-triazole
    —— (3S)-3-(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)piperidine —— C10H18N4S
    (3S)-3-(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)piperidine
    —— (2S)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-cyclopropylpropanamide —— C15H18N4OS2
    (2S)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-cyclopropylpropanamide
    —— 2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S)-1-(2-chlorophenyl)ethyl]acetamide —— C19H19ClN4OS2
    2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S)-1-(2-chlorophenyl)ethyl]acetamide
    —— (2S)-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-benzylpropanamide —— C13H17N5OS
    (2S)-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-benzylpropanamide
    —— 2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3-chlorophenyl)methyl]acetamide —— C18H17ClN4OS2
    2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3-chlorophenyl)methyl]acetamide
    —— 3-(1-Methyltetrazol-5-yl)sulfanylpropyl-(thiophen-3-ylmethyl)azanium —— C10H16N5S2+
    3-(1-Methyltetrazol-5-yl)sulfanylpropyl-(thiophen-3-ylmethyl)azanium
    —— [5-(3-Chloro-2-methylphenyl)furan-2-yl]methyl-[3-(1-methyltetrazol-5-yl)sulfanylpropyl]azanium —— C17H21ClN5OS+
    [5-(3-Chloro-2-methylphenyl)furan-2-yl]methyl-[3-(1-methyltetrazol-5-yl)sulfanylpropyl]azanium
    —— [5-(4-Chlorophenyl)furan-2-yl]methyl-[3-(1-methyltetrazol-5-yl)sulfanylpropyl]azanium —— C16H19ClN5OS+
    [5-(4-Chlorophenyl)furan-2-yl]methyl-[3-(1-methyltetrazol-5-yl)sulfanylpropyl]azanium
    —— N-benzyl-N-tert-butyl-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C23H28N4O2S
    N-benzyl-N-tert-butyl-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylethyl]acetamide —— C18H16FN3O2S
    2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylethyl]acetamide
    —— 2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(4-methylcyclohexyl)acetamide —— C17H20FN3O2S
    2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(4-methylcyclohexyl)acetamide
    —— 2-[[5-(2-Fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetonitrile —— C10H6FN3OS
    2-[[5-(2-Fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetonitrile
    —— N-[(1R)-1-(2-chlorophenyl)ethyl]-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C18H15ClFN3O2S
    N-[(1R)-1-(2-chlorophenyl)ethyl]-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— (2S)-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-pyrrolidin-1-ylpropan-1-one —— C15H16FN3O2S
    (2S)-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-pyrrolidin-1-ylpropan-1-one
    —— 1-[2-[2-(4-Chlorophenyl)sulfanylethoxy]ethyl]piperazine-1,4-diium —— C14H23ClN2OS+2
    1-[2-[2-(4-Chlorophenyl)sulfanylethoxy]ethyl]piperazine-1,4-diium
    —— 2-(2-Fluorophenyl)-5-[(5-phenyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-oxadiazole —— C17H11FN4O2S
    2-(2-Fluorophenyl)-5-[(5-phenyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— (2S)-N-benzyl-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C18H16FN3O2S
    (2S)-N-benzyl-2-[[5-(2-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— [5-(3-Chloro-4-fluorophenyl)furan-2-yl]methyl-(3-pyrimidin-2-ylsulfanylpropyl)azanium —— C18H18ClFN3OS+
    [5-(3-Chloro-4-fluorophenyl)furan-2-yl]methyl-(3-pyrimidin-2-ylsulfanylpropyl)azanium
    —— 1-[3-(4-Chlorophenyl)sulfanylpropyl]piperazine-1,4-diium —— C13H21ClN2S+2
    1-[3-(4-Chlorophenyl)sulfanylpropyl]piperazine-1,4-diium
    —— 2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-(1-cyanocyclohexyl)acetamide —— C19H23N5OS
    2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-(1-cyanocyclohexyl)acetamide
    —— 2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylethyl)acetamide —— C20H22N4OS
    2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylethyl)acetamide
    —— 2-[(4-benzyl-5-cyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3-chlorophenyl)methyl]acetamide —— C21H21ClN4OS
    2-[(4-benzyl-5-cyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3-chlorophenyl)methyl]acetamide
    —— N-(1-adamantylmethyl)-2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C23H30N4OS
    N-(1-adamantylmethyl)-2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(1S)-1-(1-adamantyl)ethyl]-2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C24H32N4OS
    N-[(1S)-1-(1-adamantyl)ethyl]-2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— [5-(4-Chlorophenyl)furan-2-yl]methyl-(3-pyrimidin-2-ylsulfanylpropyl)azanium —— C18H19ClN3OS+
    [5-(4-Chlorophenyl)furan-2-yl]methyl-(3-pyrimidin-2-ylsulfanylpropyl)azanium
    —— [5-(3-Chloro-2-methylphenyl)furan-2-yl]methyl-(3-pyrimidin-2-ylsulfanylpropyl)azanium —— C19H21ClN3OS+
    [5-(3-Chloro-2-methylphenyl)furan-2-yl]methyl-(3-pyrimidin-2-ylsulfanylpropyl)azanium
    —— 2-[(4-Benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-(5-phenyl-3,4-dihydropyrazol-2-yl)ethanone —— C21H21N5OS
    2-[(4-Benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-(5-phenyl-3,4-dihydropyrazol-2-yl)ethanone
    —— 2-(2,5-dimethylphenyl)sulfanyl-N-[(1R,2R)-1-pyrrolidin-1-ium-1-yl-1-thiophen-2-ylpropan-2-yl]acetamide —— C21H29N2OS2+
    2-(2,5-dimethylphenyl)sulfanyl-N-[(1R,2R)-1-pyrrolidin-1-ium-1-yl-1-thiophen-2-ylpropan-2-yl]acetamide
    —— N-(cyclopropylmethyl)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-propylacetamide —— C24H26N4OS
    N-(cyclopropylmethyl)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-propylacetamide
    —— N-[(1R)-1-(1-adamantyl)ethyl]-2-[(5-ethyl-4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C21H31N3O2S
    N-[(1R)-1-(1-adamantyl)ethyl]-2-[(5-ethyl-4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— 1-[[5-Methyl-4-(2-morpholin-4-ium-4-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]propan-2-one —— C12H21N4O2S+
    1-[[5-Methyl-4-(2-morpholin-4-ium-4-ylethyl)-1,2,4-triazol-3-yl]sulfanyl]propan-2-one
    —— 4-benzyl-3-methyl-5-[[(2R)-oxolan-2-yl]methylsulfanyl]-1,2,4-triazole —— C15H19N3OS
    4-benzyl-3-methyl-5-[[(2R)-oxolan-2-yl]methylsulfanyl]-1,2,4-triazole
    —— 3-[(4-Methyl-5-pyrazin-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanoate —— C10H10N5O2S-
    3-[(4-Methyl-5-pyrazin-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanoate
    —— N-(2-adamantyl)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C20H26N4O2S
    N-(2-adamantyl)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide