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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [5-(4-methylsulfanylphenyl)-3-(trifluoromethyl)-1,2-oxazol-4-yl]methanamine —— C12H11F3N2OS
    [5-(4-methylsulfanylphenyl)-3-(trifluoromethyl)-1,2-oxazol-4-yl]methanamine
    —— (1R,2R)-2-(2,2-dimethoxyethyl)-1-[(E)-1-phenylsulfanyl-3-tri(propan-2-yl)silyloxyprop-1-enyl]cyclohexan-1-ol —— C28H48O4SSi
    (1R,2R)-2-(2,2-dimethoxyethyl)-1-[(E)-1-phenylsulfanyl-3-tri(propan-2-yl)silyloxyprop-1-enyl]cyclohexan-1-ol
    —— 4-[(Z)-(5-butylsulfanylimidazo[5,1-e]tetrazol-7-ylidene)methyl]-N,N-dimethylaniline —— C16H20N6S
    4-[(Z)-(5-butylsulfanylimidazo[5,1-e]tetrazol-7-ylidene)methyl]-N,N-dimethylaniline
    —— (Z,Z,Z,Z)-1,2,5,6,9,10,13,14-octathiacyclohexadeca-3,7,11,15-tetraene —— C8H8S8
    (Z,Z,Z,Z)-1,2,5,6,9,10,13,14-octathiacyclohexadeca-3,7,11,15-tetraene
    —— 4-(4-cyclopentylsulfanylphenyl)-6-methyl-1,3,5-triazin-2-amine —— C15H18N4S
    4-(4-cyclopentylsulfanylphenyl)-6-methyl-1,3,5-triazin-2-amine
    —— (7Z)-5-ethylsulfanyl-7-(2-furylmethylene)imidazo[5,1-c][1,2,4]triazole —— C11H10N4OS
    (7Z)-5-ethylsulfanyl-7-(2-furylmethylene)imidazo[5,1-c][1,2,4]triazole
    —— (3'S,10'Z)-3'-phenylsulfanylspiro[1,3-dioxolane-2,4'-2,3,3a,5,6,7,8,9-octahydro-1H-cyclopenta[9]annulene] —— C20H26O2S
    (3'S,10'Z)-3'-phenylsulfanylspiro[1,3-dioxolane-2,4'-2,3,3a,5,6,7,8,9-octahydro-1H-cyclopenta[9]annulene]
    —— N-[(1Z)-3,4,4-trichloro-2-nitro-1-phenylsulfanylbuta-1,3-dienyl]aniline —— C16H11Cl3N2O2S
    N-[(1Z)-3,4,4-trichloro-2-nitro-1-phenylsulfanylbuta-1,3-dienyl]aniline
    —— [3-(4-cyclopentylsulfanylphenyl)pyrazin-2-yl]methanamine —— C16H19N3S
    [3-(4-cyclopentylsulfanylphenyl)pyrazin-2-yl]methanamine
    —— 5,5'-Bis-benzylmercapto-[2,2'-azo-1,3,4-thiadiazol] —— C18H14N6S4
    5,5'-Bis-benzylmercapto-[2,2'-azo-1,3,4-thiadiazol]
    —— 2-amino-4-(4-cyclopentylsulfanylphenyl)furan-3-carbonitrile —— C16H16N2OS
    2-amino-4-(4-cyclopentylsulfanylphenyl)furan-3-carbonitrile
    —— methyl (2S)-2-chloro-2-(4-cyclopentylsulfanylphenyl)acetate —— C14H17ClO2S
    methyl (2S)-2-chloro-2-(4-cyclopentylsulfanylphenyl)acetate
    —— [(Z)-[2-(3,4-dimethoxyphenyl)sulfanylphenyl]methylideneamino]urea —— C16H17N3O3S
    [(Z)-[2-(3,4-dimethoxyphenyl)sulfanylphenyl]methylideneamino]urea
    —— 4-methoxy-N-[(Z)-(5-quinolin-8-ylsulfanylfuran-2-yl)methylideneamino]benzamide —— C22H17N3O3S
    4-methoxy-N-[(Z)-(5-quinolin-8-ylsulfanylfuran-2-yl)methylideneamino]benzamide
    —— 1-[(2S)-2-(4-ethylsulfanylphenyl)-2-hydroxyethyl]piperidin-4-ol —— C15H23NO2S
    1-[(2S)-2-(4-ethylsulfanylphenyl)-2-hydroxyethyl]piperidin-4-ol
    —— 1-[(2R)-2-(4-ethylsulfanylphenyl)-2-hydroxyethyl]piperidin-4-ol —— C15H23NO2S
    1-[(2R)-2-(4-ethylsulfanylphenyl)-2-hydroxyethyl]piperidin-4-ol
    —— (1R)-1-(4-cyclopentylsulfanylphenyl)pentane-1,5-diol —— C16H24O2S
    (1R)-1-(4-cyclopentylsulfanylphenyl)pentane-1,5-diol
    —— 2-(2-methylphenoxy)-N'-{(Z)-[5-(pyridin-2-ylsulfanyl)furan-2-yl]methylidene}acetohydrazide —— C19H17N3O3S
    2-(2-methylphenoxy)-N'-{(Z)-[5-(pyridin-2-ylsulfanyl)furan-2-yl]methylidene}acetohydrazide
    —— (2R)-2-[[5-[(3-chloroanilino)methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-1-(4-methylphenyl)ethylideneamino]propanamide —— C22H25ClN6OS
    (2R)-2-[[5-[(3-chloroanilino)methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-1-(4-methylphenyl)ethylideneamino]propanamide
    —— 2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(E)-1-phenylethylideneamino]acetamide —— C23H26N6OS
    2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(E)-1-phenylethylideneamino]acetamide
    —— (1S)-1-(4-cyclopentylsulfanylphenyl)pentane-1,5-diol —— C16H24O2S
    (1S)-1-(4-cyclopentylsulfanylphenyl)pentane-1,5-diol
    —— (2R)-N-[(Z)-(2-fluorophenyl)methylideneamino]-2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C23H25FN6OS
    (2R)-N-[(Z)-(2-fluorophenyl)methylideneamino]-2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— 2-[5-(4-propan-2-ylsulfanylphenyl)-1,3,4-thiadiazol-2-yl]ethanamine —— C13H17N3S2
    2-[5-(4-propan-2-ylsulfanylphenyl)-1,3,4-thiadiazol-2-yl]ethanamine
    —— 2-[4-[(1R)-1-(4-methylsulfanylphenyl)ethyl]piperazin-1-yl]ethanamine —— C15H25N3S
    2-[4-[(1R)-1-(4-methylsulfanylphenyl)ethyl]piperazin-1-yl]ethanamine
    —— 2-[4-[(1S)-1-(4-methylsulfanylphenyl)ethyl]piperazin-1-yl]ethanamine —— C15H25N3S
    2-[4-[(1S)-1-(4-methylsulfanylphenyl)ethyl]piperazin-1-yl]ethanamine
    —— (3R)-3-(4-ethylsulfanylphenyl)-3-piperidin-4-ylpropan-1-ol —— C16H25NOS
    (3R)-3-(4-ethylsulfanylphenyl)-3-piperidin-4-ylpropan-1-ol
    —— (2S)-N-[(Z)-benzylideneamino]-2-phenylsulfanylpropanamide —— C16H16N2OS
    (2S)-N-[(Z)-benzylideneamino]-2-phenylsulfanylpropanamide
    —— 3-[2-(4-Methylsulfanylphenyl)-1,3-thiazol-4-yl]propanoic acid —— C13H13NO2S2
    3-[2-(4-Methylsulfanylphenyl)-1,3-thiazol-4-yl]propanoic acid
    —— 2-[2-(4-Ethylsulfanylphenyl)-1,3-thiazol-4-yl]acetic acid —— C13H13NO2S2
    2-[2-(4-Ethylsulfanylphenyl)-1,3-thiazol-4-yl]acetic acid
    —— 3-[3-(4-methylsulfanylphenyl)-1,2-thiazol-5-yl]propanoic acid —— C13H13NO2S2
    3-[3-(4-methylsulfanylphenyl)-1,2-thiazol-5-yl]propanoic acid
    —— (2Z)-2-[(morpholin-4-ylamino)methylidene]-1-benzothiophen-3-one —— C13H14N2O2S
    (2Z)-2-[(morpholin-4-ylamino)methylidene]-1-benzothiophen-3-one
    —— 2-[2-(4-propan-2-ylsulfanylphenyl)-1,3-thiazol-4-yl]ethanamine —— C14H18N2S2
    2-[2-(4-propan-2-ylsulfanylphenyl)-1,3-thiazol-4-yl]ethanamine
    —— 3-[4-(4-ethylsulfanylphenyl)-1,3-thiazol-2-yl]propan-1-amine —— C14H18N2S2
    3-[4-(4-ethylsulfanylphenyl)-1,3-thiazol-2-yl]propan-1-amine
    —— (2S)-2-cyclopentyl-2-(4-propan-2-ylsulfanylphenyl)acetic acid —— C16H22O2S
    (2S)-2-cyclopentyl-2-(4-propan-2-ylsulfanylphenyl)acetic acid
    —— N-[(Z)-(4-bromophenyl)methylideneamino]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C11H10BrN5OS
    N-[(Z)-(4-bromophenyl)methylideneamino]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— (2Z)-2-[1-(2-chloroanilino)ethylidene]-1-benzothiophen-3-one —— C16H12ClNOS
    (2Z)-2-[1-(2-chloroanilino)ethylidene]-1-benzothiophen-3-one
    —— 2-[3-(4-propan-2-ylsulfanylphenyl)-1,2-thiazol-5-yl]ethanamine —— C14H18N2S2
    2-[3-(4-propan-2-ylsulfanylphenyl)-1,2-thiazol-5-yl]ethanamine
    —— (2E)-2-{1-[4-(phenylsulfanyl)phenyl]ethylidene}hydrazinecarbothioamide —— C15H15N3S2
    (2E)-2-{1-[4-(phenylsulfanyl)phenyl]ethylidene}hydrazinecarbothioamide
    —— 1-[2-methyl-4-(4-methylsulfanylphenyl)butan-2-yl]piperazine —— C16H26N2S
    1-[2-methyl-4-(4-methylsulfanylphenyl)butan-2-yl]piperazine
    —— (2R)-2-cyclopentyl-2-(4-propan-2-ylsulfanylphenyl)acetic acid —— C16H22O2S
    (2R)-2-cyclopentyl-2-(4-propan-2-ylsulfanylphenyl)acetic acid
    —— 5-Amino-4-(4-propan-2-ylsulfanylphenyl)-1,2-oxazole-3-carboxylic acid —— C13H14N2O3S
    5-Amino-4-(4-propan-2-ylsulfanylphenyl)-1,2-oxazole-3-carboxylic acid
    —— 3-[5-(4-ethylsulfanylphenyl)-1,3,4-oxadiazol-2-yl]propanoic acid —— C13H14N2O3S
    3-[5-(4-ethylsulfanylphenyl)-1,3,4-oxadiazol-2-yl]propanoic acid
    —— methyl 5-amino-3-(4-ethylsulfanylphenyl)-1,2-oxazole-4-carboxylate —— C13H14N2O3S
    methyl 5-amino-3-(4-ethylsulfanylphenyl)-1,2-oxazole-4-carboxylate
    —— 3-Tert-butyl-N'-[(Z)-[4-(methylsulfanyl)phenyl]methylidene]-1H-pyrazole-5-carbohydrazide —— C16H20N4OS
    3-Tert-butyl-N'-[(Z)-[4-(methylsulfanyl)phenyl]methylidene]-1H-pyrazole-5-carbohydrazide
    —— (NZ)-N-[[2-(4-methoxyphenyl)sulfanylphenyl]methylidene]hydroxylamine —— C14H13NO2S
    (NZ)-N-[[2-(4-methoxyphenyl)sulfanylphenyl]methylidene]hydroxylamine
    —— [5-Methyl-4-(4-propan-2-ylsulfanylphenyl)thiophen-3-yl]methanamine —— C15H19NS2
    [5-Methyl-4-(4-propan-2-ylsulfanylphenyl)thiophen-3-yl]methanamine
    —— 5-methyl-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1H-pyrazole-3-carboxamide —— C13H14N4OS
    5-methyl-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1H-pyrazole-3-carboxamide
    —— 2-[5-(4-ethylsulfanylphenyl)-3-methyl-1,2-oxazol-4-yl]acetic acid —— C14H15NO3S
    2-[5-(4-ethylsulfanylphenyl)-3-methyl-1,2-oxazol-4-yl]acetic acid
    —— N-[(1R)-2,2,2-trichloro-1-(4-chlorophenyl)sulfanylethyl]acetamide —— C10H9Cl4NOS
    N-[(1R)-2,2,2-trichloro-1-(4-chlorophenyl)sulfanylethyl]acetamide
    —— 3-[3-methyl-5-(4-methylsulfanylphenyl)-1,2-oxazol-4-yl]propanoic acid —— C14H15NO3S
    3-[3-methyl-5-(4-methylsulfanylphenyl)-1,2-oxazol-4-yl]propanoic acid