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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-pyridyl pentafluoroethyl sulfide 107146-03-2 C7H4F5NS
    2-pyridyl pentafluoroethyl sulfide
    —— 5-methyl-5-(2-pyridinethiyl)-1,1,1,2,2,3,3-heptafluorooctane 107146-08-7 C14H16F7NS
    5-methyl-5-(2-pyridinethiyl)-1,1,1,2,2,3,3-heptafluorooctane
    —— (1S,5R,7aS)-1-{(1S)-1-(hydroxymethyl)ethyl-2-[(4S)-2,2,5,5-tetramethyl-1,3-dioxolan-4-yl]}-7a-methyl-4-phenylthio-2,3,5,6,7,7a-hexahydro-1H-inden-5-ol 681180-39-2 C26H38O4S
    (1S,5R,7aS)-1-{(1S)-1-(hydroxymethyl)ethyl-2-[(4S)-2,2,5,5-tetramethyl-1,3-dioxolan-4-yl]}-7a-methyl-4-phenylthio-2,3,5,6,7,7a-hexahydro-1H-inden-5-ol
    —— 1-ethenesulfonyl-2-iodo-ethane 856060-30-5 C4H7IO2S
    1-ethenesulfonyl-2-iodo-ethane
    —— (Diethoxy-phosphorylsulfanyl)-o-tolylsulfanyl-acetic acid ethyl ester 28053-92-1 C15H23O5PS2
    (Diethoxy-phosphorylsulfanyl)-o-tolylsulfanyl-acetic acid ethyl ester
    —— 30752-46-6 C16H16N2OS2
    —— 2-<(5-Nitro-2-thiazolyl)thio>-4-picolin-1-oxid 53976-57-1 C9H7N3O3S2
    2-<(5-Nitro-2-thiazolyl)thio>-4-picolin-1-oxid
    —— 2-Propylthio-4-cyclohexylimidazol 56659-45-1 C12H20N2S
    2-Propylthio-4-cyclohexylimidazol
    —— (2S,3R)-1-(2-{(E)-(1R,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-5-[2-((1R,3S)-1,3-dimethyl-pent-4-ynyl)-[1,3]dithian-2-yl]-1,3-dimethyl-pent-2-enyl}-[1,3]dithian-2-yl)-4-((1S,3R,4R)-3-methoxy-4-triisopropylsilanyloxy-cyclohexyl)-3-methyl-butan-2-ol 164592-84-1 C49H92O4S4Si2
    (2S,3R)-1-(2-{(E)-(1R,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-5-[2-((1R,3S)-1,3-dimethyl-pent-4-ynyl)-[1,3]dithian-2-yl]-1,3-dimethyl-pent-2-enyl}-[1,3]dithian-2-yl)-4-((1S,3R,4R)-3-methoxy-4-triisopropylsilanyloxy-cyclohexyl)-3-methyl-butan-2-ol
    —— 83292-96-0 C12H20Cl2O8Os2
    —— (tert-butoxymethyl)(4-chlorophenyl)sulfane 1616956-14-9 C11H15ClOS
    (tert-butoxymethyl)(4-chlorophenyl)sulfane
    —— (2-tert-butylsulfanylphenyl)methyl-diphenylphosphane;palladium(2+);dichloride 862162-82-1 C23H25Cl2PPdS
    (2-tert-butylsulfanylphenyl)methyl-diphenylphosphane;palladium(2+);dichloride
    —— YbI(C5(CH3)4Si(CH3)2(1,4-diisopropyl-1,4,7-triazacyclononane) 467429-99-8 C23H44IN3SiYb
    YbI(C5(CH3)4Si(CH3)2(1,4-diisopropyl-1,4,7-triazacyclononane)
    —— (3aS,5aR,8S,9aR)-3a,5a,6-Trimethyl-1-phenylsulfanyl-8-(tetrahydro-pyran-2-yloxy)-3a,4,5a,8,9,9a-hexahydro-3H-cyclopenta[a]naphthalene-2,5-dione 80114-34-7 C27H32O4S
    (3aS,5aR,8S,9aR)-3a,5a,6-Trimethyl-1-phenylsulfanyl-8-(tetrahydro-pyran-2-yloxy)-3a,4,5a,8,9,9a-hexahydro-3H-cyclopenta[a]naphthalene-2,5-dione
    —— 4-Hydroxy-5-(hydroxymethyl)-2-(benzylthio)pyrimidine 93185-34-3 C12H12N2O2S
    4-Hydroxy-5-(hydroxymethyl)-2-(benzylthio)pyrimidine
    —— 1-Phenylthio-2-chloraethylsulfon 66754-28-7 C15H15ClO2S2
    1-Phenylthio-2-chloraethylsulfon
    —— 2-hydroxy-4-(2-nitro-phenylsulfanyl)-benzoic acid 99847-55-9 C13H9NO5S
    2-hydroxy-4-(2-nitro-phenylsulfanyl)-benzoic acid
    —— 1-(1-Imidazolyl)-3-p-(p-bromphenylthio)-phenyl-propan-3-ol 69964-70-1 C18H17BrN2OS
    1-(1-Imidazolyl)-3-p-(p-bromphenylthio)-phenyl-propan-3-ol
    —— 1-methyl-8-(thiophen-2-ylmethylsulfanyl)-1,2,3,4-tetrahydropyrimido[1,6-a]pyrimidin-6-one 1420368-79-1 C13H15N3OS2
    1-methyl-8-(thiophen-2-ylmethylsulfanyl)-1,2,3,4-tetrahydropyrimido[1,6-a]pyrimidin-6-one
    —— 2,3,4,5-Tetrafluoro-6-(2,3,6-trifluoro-phenylsulfanyl)-phenylamine 13645-94-8 C12H4F7NS
    2,3,4,5-Tetrafluoro-6-(2,3,6-trifluoro-phenylsulfanyl)-phenylamine
    —— 117532-25-9 C8H8N3S*F6P
    —— Prop-2-inyl-xanthogensaeure-butylester 22118-17-8 C8H12OS2
    Prop-2-inyl-xanthogensaeure-butylester
    —— 1,2-O-thiocarbonylxylitol 142832-59-5 C6H10O5S
    1,2-O-thiocarbonylxylitol
    —— 3-nitro-4-nitroxymethyl-1,3-oxazolidine 1043044-40-1 C4H7N3O6
    3-nitro-4-nitroxymethyl-1,3-oxazolidine
    —— Isopropyl-dithiocarbamic acid p-tolyl ester 51098-16-9 C11H15NS2
    Isopropyl-dithiocarbamic acid p-tolyl ester
    —— N,N-dimethyl-2-(phenylthio)-(Z)-2-heptenamide 1294896-77-7 C15H21NOS
    N,N-dimethyl-2-(phenylthio)-(Z)-2-heptenamide
    —— tert-butyl ((3-(methyl(pyridin-4-yl)amino)propanamido)(methylthio)methylene)carbamate 1365267-06-6 C16H24N4O3S
    tert-butyl ((3-(methyl(pyridin-4-yl)amino)propanamido)(methylthio)methylene)carbamate
    —— (E)-1-(phenylthio)-1-(trimethylsilyl)-1-octene 87514-04-3 C17H28SSi
    (E)-1-(phenylthio)-1-(trimethylsilyl)-1-octene
    —— Dichloro-(3-methanesulfonyl-2-methyl-propyl)-methyl-silane 24429-98-9 C6H14Cl2O2SSi
    Dichloro-(3-methanesulfonyl-2-methyl-propyl)-methyl-silane
    —— 1-Chloro-4-phenylsulfanylmethylsulfanylmethyl-benzene 93718-35-5 C14H13ClS2
    1-Chloro-4-phenylsulfanylmethylsulfanylmethyl-benzene
    —— 2,6-Dichloro-4-(4-fluoro-benzylsulfanyl)-pyridine-3,5-dicarbonitrile 21937-76-8 C14H6Cl2FN3S
    2,6-Dichloro-4-(4-fluoro-benzylsulfanyl)-pyridine-3,5-dicarbonitrile
    —— (E)-1,3-Bis-butylsulfanyl-but-1-ene 97030-46-1 C12H24S2
    (E)-1,3-Bis-butylsulfanyl-but-1-ene
    —— 1-<(5-Cyanopentyl)thio>acetaldehyd-O-(methylcarbamoyl)oxim 26649-48-9 C10H17N3O2S
    1-<(5-Cyanopentyl)thio>acetaldehyd-O-(methylcarbamoyl)oxim
    —— [(E)-hex-3-enyl] pyridin-2-ylsulfanylformate 129667-30-7 C12H15NO2S
    [(E)-hex-3-enyl] pyridin-2-ylsulfanylformate
    —— 2-(4-Bromo-phenylsulfanyl)-2-methyl-butyric acid 91335-48-7 C11H13BrO2S
    2-(4-Bromo-phenylsulfanyl)-2-methyl-butyric acid
    —— 3-(2,3-Dihydroxypropyl)-2-methyl-6-(methylthio)-4(3H)-pyrimidinone 767320-10-5 C9H14N2O3S
    3-(2,3-Dihydroxypropyl)-2-methyl-6-(methylthio)-4(3H)-pyrimidinone
    —— 1-[bis(phenylsulfanyl)methyl]-2-ethylbenzene 65597-78-6 C21H20S2
    1-[bis(phenylsulfanyl)methyl]-2-ethylbenzene
    —— 1-Chlor-4-<4-methylphenylmercapto>-butan 14633-32-0 C11H15ClS
    1-Chlor-4-<4-methylphenylmercapto>-butan
    —— ethyl-phenyl-(5-phenylsulfanyl-pentyl)-amine 857597-11-6 C19H25NS
    ethyl-phenyl-(5-phenylsulfanyl-pentyl)-amine
    —— 5-Dodecyl-3-(5-dodecylthieno[3,2-b]thiophen-3-yl)sulfanylthieno[3,2-b]thiophene 1440337-18-7 C36H54S5
    5-Dodecyl-3-(5-dodecylthieno[3,2-b]thiophen-3-yl)sulfanylthieno[3,2-b]thiophene
    —— Cu(norbornene)CH3SO3 86689-31-8 CH3O3S*C7H10*Cu
    Cu(norbornene)CH3SO3
    —— 2-(4-Chloro-phenyl)-2-phenylsulfanyl-propionitrile 54835-34-6 C15H12ClNS
    2-(4-Chloro-phenyl)-2-phenylsulfanyl-propionitrile
    —— 3-(4-chloro-2-methylphenylthio)-1-[4-(2-hydroxy-2-methylpropoxy)-3-methoxyphenyl]pyrazine-2(1H)-one 1099661-85-4 C22H23ClN2O4S
    3-(4-chloro-2-methylphenylthio)-1-[4-(2-hydroxy-2-methylpropoxy)-3-methoxyphenyl]pyrazine-2(1H)-one
    —— 14043-15-3 C7H13N3S3
    —— 58609-70-4 C15H11BrOS
    —— 5-(4-Phenylmercapto-phenoxy)-1-pentin 58609-51-1 C17H16OS
    5-(4-Phenylmercapto-phenoxy)-1-pentin
    —— 6-N-benzyl-4-N-(3-fluoro-4-pyridin-4-ylsulfanylphenyl)pyrimidine-2,4,6-triamine 637039-32-8 C22H19FN6S
    6-N-benzyl-4-N-(3-fluoro-4-pyridin-4-ylsulfanylphenyl)pyrimidine-2,4,6-triamine
    —— 2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-cyclopropylpropanamide 923710-30-9 C16H20N4OS
    2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-cyclopropylpropanamide
    —— [2,5-Dichloro-4-(4-fluoro-phenylsulfanylthiocarbonylamino)-phenyl]-dithiocarbamic acid 4-fluoro-phenyl ester 21552-36-3 C20H12Cl2F2N2S4
    [2,5-Dichloro-4-(4-fluoro-phenylsulfanylthiocarbonylamino)-phenyl]-dithiocarbamic acid 4-fluoro-phenyl ester
    —— 1309789-32-9 C16H18F2S