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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (3R)-7-methyl-6-oxo-N-[(1R)-1-phenylethyl]-3,4-dihydro-2H-pyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C17H19N3O2S
    (3R)-7-methyl-6-oxo-N-[(1R)-1-phenylethyl]-3,4-dihydro-2H-pyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— (3R)-8-tert-butyl-N-(furan-2-ylmethyl)-6-oxo-3,4-dihydro-2H-pyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C17H21N3O3S
    (3R)-8-tert-butyl-N-(furan-2-ylmethyl)-6-oxo-3,4-dihydro-2H-pyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— (3R)-N-[2-(3,5-dimethylpyrazol-1-yl)ethyl]-6-oxo-3,4-dihydro-2H-pyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C15H19N5O2S
    (3R)-N-[2-(3,5-dimethylpyrazol-1-yl)ethyl]-6-oxo-3,4-dihydro-2H-pyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— (3S)-8-tert-butyl-6-oxo-N-(thiophen-2-ylmethyl)-3,4-dihydro-2H-pyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C17H21N3O2S2
    (3S)-8-tert-butyl-6-oxo-N-(thiophen-2-ylmethyl)-3,4-dihydro-2H-pyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— (3R)-8-tert-butyl-6-oxo-N-[[(2R)-oxolan-2-yl]methyl]-3,4-dihydro-2H-pyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C17H25N3O3S
    (3R)-8-tert-butyl-6-oxo-N-[[(2R)-oxolan-2-yl]methyl]-3,4-dihydro-2H-pyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— (3R)-8-tert-butyl-6-oxo-N-[[(2S)-oxolan-2-yl]methyl]-3,4-dihydro-2H-pyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C17H25N3O3S
    (3R)-8-tert-butyl-6-oxo-N-[[(2S)-oxolan-2-yl]methyl]-3,4-dihydro-2H-pyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— (2Z,5Z)-3-(2-methoxyethyl)-2-(phenylimino)-5-{[5-(phenylsulfanyl)furan-2-yl]methylidene}-1,3-thiazolidin-4-one —— C23H20N2O3S2
    (2Z,5Z)-3-(2-methoxyethyl)-2-(phenylimino)-5-{[5-(phenylsulfanyl)furan-2-yl]methylidene}-1,3-thiazolidin-4-one
    —— 1-[(2-hydroxyethoxy)methyl]-5-(2-phenylvinyl)-6-phenylthiouracil —— C21H20N2O4S
    1-[(2-hydroxyethoxy)methyl]-5-(2-phenylvinyl)-6-phenylthiouracil
    —— (E)-3-(tert-butylamino)-2-[2-(tert-butylamino)-1-[(E)-2-(tert-butylamino)-1-cyanoethenyl]sulfonylethenyl]sulfonylprop-2-enenitrile —— C20H33N5O4S2
    (E)-3-(tert-butylamino)-2-[2-(tert-butylamino)-1-[(E)-2-(tert-butylamino)-1-cyanoethenyl]sulfonylethenyl]sulfonylprop-2-enenitrile
    —— (5Z)-2-[(3,4-dimethylanilino)methoxy]-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazol-4-one —— C20H20N2O2S2
    (5Z)-2-[(3,4-dimethylanilino)methoxy]-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazol-4-one
    —— 6-({5-[(4-chlorophenyl)sulfanyl]-2-furyl}methylene)-5-imino-2-propyl-5,6-dihydro-7H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one —— C19H15ClN4O2S2
    6-({5-[(4-chlorophenyl)sulfanyl]-2-furyl}methylene)-5-imino-2-propyl-5,6-dihydro-7H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one
    —— (E)-3-amino-2-[2-(3,4-dimethylphenyl)sulfanylacetyl]but-2-enenitrile —— C14H16N2OS
    (E)-3-amino-2-[2-(3,4-dimethylphenyl)sulfanylacetyl]but-2-enenitrile
    —— o-Methyloxime —— C14H10F3N3OS2
    o-Methyloxime
    —— (3R)-N-[4-[(2R,6R)-2,6-dimethylmorpholin-4-yl]butyl]-2,3-dihydro-1-benzothiophene-3-carboxamide —— C19H28N2O2S
    (3R)-N-[4-[(2R,6R)-2,6-dimethylmorpholin-4-yl]butyl]-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— (3R)-N-[4-[(2R,6S)-2,6-dimethylmorpholin-4-yl]butyl]-2,3-dihydro-1-benzothiophene-3-carboxamide —— C19H28N2O2S
    (3R)-N-[4-[(2R,6S)-2,6-dimethylmorpholin-4-yl]butyl]-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— N-[(1R)-1-cyano-2,2-dimethylpropyl]-2-[(2-sulfanylidene-3H-1,3,4-thiadiazol-5-yl)sulfanyl]acetamide —— C10H14N4OS3
    N-[(1R)-1-cyano-2,2-dimethylpropyl]-2-[(2-sulfanylidene-3H-1,3,4-thiadiazol-5-yl)sulfanyl]acetamide
    —— N-[(1S)-1-cyano-2,2-dimethylpropyl]-2-[(2-sulfanylidene-3H-1,3,4-thiadiazol-5-yl)sulfanyl]acetamide —— C10H14N4OS3
    N-[(1S)-1-cyano-2,2-dimethylpropyl]-2-[(2-sulfanylidene-3H-1,3,4-thiadiazol-5-yl)sulfanyl]acetamide
    —— (3R)-N-[4-[(2S,6S)-2,6-dimethylmorpholin-4-yl]butyl]-2,3-dihydro-1-benzothiophene-3-carboxamide —— C19H28N2O2S
    (3R)-N-[4-[(2S,6S)-2,6-dimethylmorpholin-4-yl]butyl]-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— 2-[(Z)-1-(benzenesulfonyl)-2-(1,3-benzodioxol-5-yl)ethenyl]-3-phenylsulfanyl-1H-indole —— C29H21NO4S2
    2-[(Z)-1-(benzenesulfonyl)-2-(1,3-benzodioxol-5-yl)ethenyl]-3-phenylsulfanyl-1H-indole
    —— (2Z)-2-[(5Z)-3-(2,4-dimethylphenyl)-5-[[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylidene]-4-oxo-1,3-thiazolidin-2-ylidene]-3-oxo-3-(4-propylphenyl)propanenitrile —— C33H28N6O4S2
    (2Z)-2-[(5Z)-3-(2,4-dimethylphenyl)-5-[[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylidene]-4-oxo-1,3-thiazolidin-2-ylidene]-3-oxo-3-(4-propylphenyl)propanenitrile
    —— (5E)-1-(2-methoxyphenyl)-5-[(5-phenylsulfanylfuran-2-yl)methylidene]-2-sulfanylidene-1,3-diazinane-4,6-dione —— C22H16N2O4S2
    (5E)-1-(2-methoxyphenyl)-5-[(5-phenylsulfanylfuran-2-yl)methylidene]-2-sulfanylidene-1,3-diazinane-4,6-dione
    —— (5E)-5-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-1-(2-methoxyphenyl)-2-thioxodihydropyrimidine-4,6(1H,5H)-dione —— C22H15ClN2O4S2
    (5E)-5-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-1-(2-methoxyphenyl)-2-thioxodihydropyrimidine-4,6(1H,5H)-dione
    —— (3Z,6Z)-6-Benzylidene-3-(4-(2-dimethylaminoethylthio)benzylidene)-2,5-piperazinedione —— C22H23N3O2S
    (3Z,6Z)-6-Benzylidene-3-(4-(2-dimethylaminoethylthio)benzylidene)-2,5-piperazinedione
    —— 1-[[5,6-Bis(furan-3-yl)-1,2,4-triazin-3-yl]sulfanyl]-3,3-dimethylbutan-2-one —— C17H17N3O3S
    1-[[5,6-Bis(furan-3-yl)-1,2,4-triazin-3-yl]sulfanyl]-3,3-dimethylbutan-2-one
    —— N-(butan-2-yl)-2-{[3-cyano-4-(methoxymethyl)-6-methylpyridin-2-yl]sulfanyl}acetamide —— C15H21N3O2S
    N-(butan-2-yl)-2-{[3-cyano-4-(methoxymethyl)-6-methylpyridin-2-yl]sulfanyl}acetamide
    —— 2-[(4-fluorophenyl)methylsulfanyl]-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione —— C12H8FN3O2S2
    2-[(4-fluorophenyl)methylsulfanyl]-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione
    —— 2-[(2-methylphenyl)methylsulfanyl]-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione —— C13H11N3O2S2
    2-[(2-methylphenyl)methylsulfanyl]-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione
    —— N-cyclohexyl-2-{[5-(furan-2-yl)-4-(propan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide —— C17H24N4O2S
    N-cyclohexyl-2-{[5-(furan-2-yl)-4-(propan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide
    —— 2-((4-Allyl-5-propyl-4H-1,2,4-triazol-3-yl)thio)acetic acid —— C10H15N3O2S
    2-((4-Allyl-5-propyl-4H-1,2,4-triazol-3-yl)thio)acetic acid
    —— 4-ethyl-2-propylsulfanyl-1H-pyrimidin-6-one —— C9H14N2OS
    4-ethyl-2-propylsulfanyl-1H-pyrimidin-6-one
    —— 2-[(3S)-7-(methoxymethyl)-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid —— C10H12N2O4S
    2-[(3S)-7-(methoxymethyl)-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid
    —— 5-Butoxy-2-(2,4-dinitro-phenylsulfanyl)-1H-benzoimidazole —— C17H16N4O5S
    5-Butoxy-2-(2,4-dinitro-phenylsulfanyl)-1H-benzoimidazole
    —— 2-[(3R)-7-(furan-2-yl)-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid —— C12H10N2O4S
    2-[(3R)-7-(furan-2-yl)-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid
    —— 2-[(3S)-5-oxo-7-thiophen-2-yl-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid —— C12H10N2O3S2
    2-[(3S)-5-oxo-7-thiophen-2-yl-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid
    —— 2-[(3S)-7-(furan-2-yl)-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid —— C12H10N2O4S
    2-[(3S)-7-(furan-2-yl)-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid
    —— 2-[(3R)-7-(methoxymethyl)-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid —— C10H12N2O4S
    2-[(3R)-7-(methoxymethyl)-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid
    —— 2-[(3R)-5-oxo-7-thiophen-2-yl-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid —— C12H10N2O3S2
    2-[(3R)-5-oxo-7-thiophen-2-yl-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid
    —— 2-(Difluoro(p-tolylthio)methyl)-5-methyl-1,3,4-oxadiazole —— C11H10F2N2OS
    2-(Difluoro(p-tolylthio)methyl)-5-methyl-1,3,4-oxadiazole
    —— 2-(Difluoro-phenylsulfanyl-methyl)-[1,3,4]oxadiazole —— C9H6F2N2OS
    2-(Difluoro-phenylsulfanyl-methyl)-[1,3,4]oxadiazole
    —— 2-(Difluoro-phenylsulfanyl-methyl)-5-methyl-[1,3,4]oxadiazole —— C10H8F2N2OS
    2-(Difluoro-phenylsulfanyl-methyl)-5-methyl-[1,3,4]oxadiazole
    —— 2-(Difluoro-p-tolylsulfanyl-methyl)-[1,3,4]oxadiazole —— C10H8F2N2OS
    2-(Difluoro-p-tolylsulfanyl-methyl)-[1,3,4]oxadiazole
    —— 2-(((4-Chlorophenyl)thio)difluoromethyl)-1,3,4-oxadiazole —— C9H5ClF2N2OS
    2-(((4-Chlorophenyl)thio)difluoromethyl)-1,3,4-oxadiazole
    —— 2-(((4-Chlorophenyl)thio)difluoromethyl)-5-methyl-1,3,4-oxadiazole —— C10H7ClF2N2OS
    2-(((4-Chlorophenyl)thio)difluoromethyl)-5-methyl-1,3,4-oxadiazole
    —— {[3-(Methylsulfanyl)-1,2,4-thiadiazol-5-yl]sulfanyl}acetonitrile —— C5H5N3S3
    {[3-(Methylsulfanyl)-1,2,4-thiadiazol-5-yl]sulfanyl}acetonitrile
    —— 4-(Methoxymethyl)-6-methyl-2-[(5-nitropyridin-2-yl)sulfanyl]pyridine-3-carbonitrile —— C14H12N4O3S
    4-(Methoxymethyl)-6-methyl-2-[(5-nitropyridin-2-yl)sulfanyl]pyridine-3-carbonitrile
    —— 5-(2-Methoxy-ethyl)-2-methylsulfanyl-pyrimidin-4-ol —— C8H12N2O2S
    5-(2-Methoxy-ethyl)-2-methylsulfanyl-pyrimidin-4-ol
    —— 2-{[5-(3-Chlorophenyl)-1,3,4-oxadiazol-2-YL]sulfanyl}-5-nitropyridine —— C13H7ClN4O3S
    2-{[5-(3-Chlorophenyl)-1,3,4-oxadiazol-2-YL]sulfanyl}-5-nitropyridine
    —— 2-{[5-(3-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}-3-nitropyridine —— C13H7ClN4O3S
    2-{[5-(3-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}-3-nitropyridine
    —— 4-({4-methyl-5-[(5-nitropyridin-2-yl)sulfanyl]-4H-1,2,4-triazol-3-yl}methyl)morpholine —— C13H16N6O3S
    4-({4-methyl-5-[(5-nitropyridin-2-yl)sulfanyl]-4H-1,2,4-triazol-3-yl}methyl)morpholine
    —— 2-((4-isopropyl-6-oxo-1,6-dihydropyrimidin-2-yl)thio)propanoic acid —— C10H14N2O3S
    2-((4-isopropyl-6-oxo-1,6-dihydropyrimidin-2-yl)thio)propanoic acid