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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(2-Chloro-6-fluorophenyl)methylsulfanyl]-5-[(3-fluorophenyl)methyl]-3,6-dimethylpyrimidin-4-one —— C20H17ClF2N2OS
    2-[(2-Chloro-6-fluorophenyl)methylsulfanyl]-5-[(3-fluorophenyl)methyl]-3,6-dimethylpyrimidin-4-one
    —— [4-methyl-5-[[(1R,3R)-3-methylcyclohexyl]methylsulfanyl]-1,2,4-triazol-3-yl]methanol —— C12H21N3OS
    [4-methyl-5-[[(1R,3R)-3-methylcyclohexyl]methylsulfanyl]-1,2,4-triazol-3-yl]methanol
    —— 4-methyl-3-[[(1R,3R)-3-methylcyclohexyl]methylsulfanyl]-1,2,4-triazole —— C11H19N3S
    4-methyl-3-[[(1R,3R)-3-methylcyclohexyl]methylsulfanyl]-1,2,4-triazole
    —— 4-methyl-3-[[(1S,3R)-3-methylcyclohexyl]methylsulfanyl]-1,2,4-triazole —— C11H19N3S
    4-methyl-3-[[(1S,3R)-3-methylcyclohexyl]methylsulfanyl]-1,2,4-triazole
    —— 4-methyl-3-[[(1R,3S)-3-methylcyclohexyl]methylsulfanyl]-1,2,4-triazole —— C11H19N3S
    4-methyl-3-[[(1R,3S)-3-methylcyclohexyl]methylsulfanyl]-1,2,4-triazole
    —— [4-methyl-5-[[(1S,3R)-3-methylcyclohexyl]methylsulfanyl]-1,2,4-triazol-3-yl]methanol —— C12H21N3OS
    [4-methyl-5-[[(1S,3R)-3-methylcyclohexyl]methylsulfanyl]-1,2,4-triazol-3-yl]methanol
    —— 4-methyl-3-[[(1S,3S)-3-methylcyclohexyl]methylsulfanyl]-1,2,4-triazole —— C11H19N3S
    4-methyl-3-[[(1S,3S)-3-methylcyclohexyl]methylsulfanyl]-1,2,4-triazole
    —— [4-methyl-5-[[(1R,3S)-3-methylcyclohexyl]methylsulfanyl]-1,2,4-triazol-3-yl]methanol —— C12H21N3OS
    [4-methyl-5-[[(1R,3S)-3-methylcyclohexyl]methylsulfanyl]-1,2,4-triazol-3-yl]methanol
    —— [4-methyl-5-[[(1S,3S)-3-methylcyclohexyl]methylsulfanyl]-1,2,4-triazol-3-yl]methanol —— C12H21N3OS
    [4-methyl-5-[[(1S,3S)-3-methylcyclohexyl]methylsulfanyl]-1,2,4-triazol-3-yl]methanol
    —— (2S,6S)-N-[2-(2,2-difluoroethylsulfanyl)-5-fluorophenyl]-2,6-dimethyloxan-4-amine —— C15H20F3NOS
    (2S,6S)-N-[2-(2,2-difluoroethylsulfanyl)-5-fluorophenyl]-2,6-dimethyloxan-4-amine
    —— (2R,6R)-N-[2-(2,2-difluoroethylsulfanyl)-5-fluorophenyl]-2,6-dimethyloxan-4-amine —— C15H20F3NOS
    (2R,6R)-N-[2-(2,2-difluoroethylsulfanyl)-5-fluorophenyl]-2,6-dimethyloxan-4-amine
    —— 5-[(3-Fluorophenyl)methyl]-3,6-dimethyl-2-prop-2-enylsulfanylpyrimidin-4-one —— C16H17FN2OS
    5-[(3-Fluorophenyl)methyl]-3,6-dimethyl-2-prop-2-enylsulfanylpyrimidin-4-one
    —— 2-(3-Nitropyridin-2-yl)sulfanylpyridine-3-carboxylate —— C11H6N3O4S-
    2-(3-Nitropyridin-2-yl)sulfanylpyridine-3-carboxylate
    —— (2R,6S)-N-[2-(2,2-difluoroethylsulfanyl)-5-fluorophenyl]-2,6-dimethyloxan-4-amine —— C15H20F3NOS
    (2R,6S)-N-[2-(2,2-difluoroethylsulfanyl)-5-fluorophenyl]-2,6-dimethyloxan-4-amine
    —— [2-(2-Methoxyethylamino)-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate —— C14H19NO4S
    [2-(2-Methoxyethylamino)-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate
    —— [2-[[(2R)-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate —— C16H23NO3S
    [2-[[(2R)-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate
    —— [(2R)-1-(cyclohexylamino)-1-oxopropan-2-yl] 2-(2-methylphenyl)sulfanylacetate —— C18H25NO3S
    [(2R)-1-(cyclohexylamino)-1-oxopropan-2-yl] 2-(2-methylphenyl)sulfanylacetate
    —— [(2S)-1-oxo-1-[[(2R)-4-phenylbutan-2-yl]amino]propan-2-yl] 2-(2-methylphenyl)sulfanylacetate —— C22H27NO3S
    [(2S)-1-oxo-1-[[(2R)-4-phenylbutan-2-yl]amino]propan-2-yl] 2-(2-methylphenyl)sulfanylacetate
    —— [2-(Cyclopropylamino)-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate —— C14H17NO3S
    [2-(Cyclopropylamino)-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate
    —— [2-[[(1R)-1-(4-chlorophenyl)ethyl]amino]-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate —— C19H20ClNO3S
    [2-[[(1R)-1-(4-chlorophenyl)ethyl]amino]-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate
    —— [2-Oxo-2-[2-(4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl)ethylamino]ethyl] 2-(2-methylphenyl)sulfanylacetate —— C16H18N2O4S3
    [2-Oxo-2-[2-(4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl)ethylamino]ethyl] 2-(2-methylphenyl)sulfanylacetate
    —— [2-[[(1S,2R)-2-methylcyclohexyl]amino]-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate —— C18H25NO3S
    [2-[[(1S,2R)-2-methylcyclohexyl]amino]-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate
    —— [2-[(4-Methylcyclohexyl)amino]-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate —— C18H25NO3S
    [2-[(4-Methylcyclohexyl)amino]-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate
    —— [2-Oxo-2-(2-phenylethylamino)ethyl] 2-(2-methylphenyl)sulfanylacetate —— C19H21NO3S
    [2-Oxo-2-(2-phenylethylamino)ethyl] 2-(2-methylphenyl)sulfanylacetate
    —— N-[(1R)-1-(2-chlorophenyl)ethyl]-2-(4-fluorophenyl)sulfanylacetamide —— C16H15ClFNOS
    N-[(1R)-1-(2-chlorophenyl)ethyl]-2-(4-fluorophenyl)sulfanylacetamide
    —— 1-[1-[(4-Fluorophenyl)methyl]-2,5-dimethylpyrrol-3-yl]-2-(4-fluorophenyl)sulfanylethanone —— C21H19F2NOS
    1-[1-[(4-Fluorophenyl)methyl]-2,5-dimethylpyrrol-3-yl]-2-(4-fluorophenyl)sulfanylethanone
    —— (2R)-2-(4-fluorophenyl)sulfanyl-N-(furan-2-ylmethyl)propanamide —— C14H14FNO2S
    (2R)-2-(4-fluorophenyl)sulfanyl-N-(furan-2-ylmethyl)propanamide
    —— methyl 5-[(2R)-2-(4-fluorophenyl)sulfanylpropanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate —— C17H18FNO3S
    methyl 5-[(2R)-2-(4-fluorophenyl)sulfanylpropanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate
    —— N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-2-(4-fluorophenyl)sulfanylacetamide —— C22H20FNOS2
    N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-2-(4-fluorophenyl)sulfanylacetamide
    —— [2-[[(1R)-1-(3-chlorophenyl)ethyl]amino]-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate —— C19H20ClNO3S
    [2-[[(1R)-1-(3-chlorophenyl)ethyl]amino]-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate
    —— N,N-dimethyl-4-[(2S,5R)-5-[(5-pyridin-4-yl-1,3,4-thiadiazol-2-yl)sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]aniline —— C19H22N5OS2+
    N,N-dimethyl-4-[(2S,5R)-5-[(5-pyridin-4-yl-1,3,4-thiadiazol-2-yl)sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]aniline
    —— (2R,3R,4R,5R)-1,1-bis(ethylsulfanyl)hexane-2,3,4,5-tetrol —— C10H22O4S2
    (2R,3R,4R,5R)-1,1-bis(ethylsulfanyl)hexane-2,3,4,5-tetrol
    —— [2-(4-Methylanilino)-1,3-thiazol-4-yl]methyl 2-(2,4-dimethylphenyl)sulfanylacetate —— C21H22N2O2S2
    [2-(4-Methylanilino)-1,3-thiazol-4-yl]methyl 2-(2,4-dimethylphenyl)sulfanylacetate
    —— 6-[(3R)-3-[1-(2-methoxyethyl)imidazol-2-yl]piperidin-1-yl]-2-methylsulfanylpyrimidin-4-amine —— C16H24N6OS
    6-[(3R)-3-[1-(2-methoxyethyl)imidazol-2-yl]piperidin-1-yl]-2-methylsulfanylpyrimidin-4-amine
    —— 6-[(3S)-3-[1-(2-methoxyethyl)imidazol-2-yl]piperidin-1-yl]-2-methylsulfanylpyrimidin-4-amine —— C16H24N6OS
    6-[(3S)-3-[1-(2-methoxyethyl)imidazol-2-yl]piperidin-1-yl]-2-methylsulfanylpyrimidin-4-amine
    —— (4S)-4-(bromomethyl)-11-cyclohexyl-5-thia-2,7,13-triaza-11-azoniatricyclo[7.4.0.02,6]trideca-1(9),6-dien-8-one —— C15H22BrN4OS+
    (4S)-4-(bromomethyl)-11-cyclohexyl-5-thia-2,7,13-triaza-11-azoniatricyclo[7.4.0.02,6]trideca-1(9),6-dien-8-one
    —— 4-(4-Methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)piperidin-1-ium —— C9H17N4S+
    4-(4-Methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)piperidin-1-ium
    —— 2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(2R)-2-(3-propan-2-yl-1,2,4-oxadiazol-5-yl)pyrrolidin-1-yl]ethanone —— C15H22N6O2S
    2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(2R)-2-(3-propan-2-yl-1,2,4-oxadiazol-5-yl)pyrrolidin-1-yl]ethanone
    —— 2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(2S)-2-(3-propan-2-yl-1,2,4-oxadiazol-5-yl)pyrrolidin-1-yl]ethanone —— C15H22N6O2S
    2-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(2S)-2-(3-propan-2-yl-1,2,4-oxadiazol-5-yl)pyrrolidin-1-yl]ethanone
    —— 3-((4-Bromobenzyl)thio)-6-(pyridin-4-yl)pyridazine —— C16H12BrN3S
    3-((4-Bromobenzyl)thio)-6-(pyridin-4-yl)pyridazine
    —— 3-((3-Chlorobenzyl)thio)-6-(pyridin-4-yl)pyridazine —— C16H12ClN3S
    3-((3-Chlorobenzyl)thio)-6-(pyridin-4-yl)pyridazine
    —— 2-methyl-5-[3-[4-[(3R)-oxolan-3-yl]triazol-1-yl]propylsulfanyl]-1,3,4-thiadiazole —— C12H17N5OS2
    2-methyl-5-[3-[4-[(3R)-oxolan-3-yl]triazol-1-yl]propylsulfanyl]-1,3,4-thiadiazole
    —— 2-methyl-5-[3-[4-[(3S)-oxolan-3-yl]triazol-1-yl]propylsulfanyl]-1,3,4-thiadiazole —— C12H17N5OS2
    2-methyl-5-[3-[4-[(3S)-oxolan-3-yl]triazol-1-yl]propylsulfanyl]-1,3,4-thiadiazole
    —— (3S)-3-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)-1-(furan-2-ylmethyl)piperidine —— C20H24N4OS
    (3S)-3-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)-1-(furan-2-ylmethyl)piperidine
    —— [amino-(4-ethylanilino)methylidene]-[6-oxo-4-(pyridin-2-ylsulfanylmethyl)-1H-pyrimidin-2-yl]azanium —— C19H21N6OS+
    [amino-(4-ethylanilino)methylidene]-[6-oxo-4-(pyridin-2-ylsulfanylmethyl)-1H-pyrimidin-2-yl]azanium
    —— (2R)-N-cyclohexyl-2-[(6-methyl-5-oxo-4H-1,2,4-triazin-3-yl)sulfanyl]propanamide —— C13H20N4O2S
    (2R)-N-cyclohexyl-2-[(6-methyl-5-oxo-4H-1,2,4-triazin-3-yl)sulfanyl]propanamide
    —— (2R)-2-(4-methylpyrimidin-2-yl)sulfanylpropanoate —— C8H9N2O2S-
    (2R)-2-(4-methylpyrimidin-2-yl)sulfanylpropanoate
    —— (2S)-2-[(5-benzyl-4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]butanoate —— C16H17N2O3S-
    (2S)-2-[(5-benzyl-4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]butanoate
    —— Ethyl 2-[1,4-dimethyl-5-[(2-methylphenyl)methyl]-6-oxopyrimidin-2-yl]sulfanylacetate —— C18H22N2O3S
    Ethyl 2-[1,4-dimethyl-5-[(2-methylphenyl)methyl]-6-oxopyrimidin-2-yl]sulfanylacetate
    —— 4-ethyl-3-methyl-5-[2-[4-[(3S)-oxolan-3-yl]triazol-1-yl]ethylsulfanyl]-1,2,4-triazole —— C13H20N6OS
    4-ethyl-3-methyl-5-[2-[4-[(3S)-oxolan-3-yl]triazol-1-yl]ethylsulfanyl]-1,2,4-triazole