双-叔十二烷基五硫化物 | 31565-23-8

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫基化合物
• 中文名称: 双-叔十二烷基五硫化物
• 英文名称: Unii-BR515I2JQ6
• 英文别名: 2-methyl-2-(2-methylundecan-2-ylpentasulfanyl)undecane
• CAS: 31565-23-8
• 化学式: C₂₄H₅₀S₅
• 分子量: 499.0
• InChiKey: ADGRTOXXCXYHQT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.5
• 重原子数：
  29
• 可旋转键数：
  22
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  127
• 氢给体数：
  0
• 氢受体数：
  5

文献信息

• Antifouling paint
  申请人：NIPPON OIL AND FATS COMPANY, LIMITED

  公开号：EP0273457A2

  公开（公告）日：1988-07-06

  An antifouling paint is described, that contains or its essential components an antifoulant and a polymer of one or more of the monomers A represented by general formula (1) and/or copolymer composed of one or more of the monomers A and one or more vinyl polymerizable monomers B that are copolymerizable with said monomer A: wherein X is a hydrogen atom of a methyl group; n is an integer of 2 to 4; and m signifies the average degree of polymerization and is zero or a real number. The antifouling paint may contain a slipping agent as the third essential component to provide an even greater fouling resistance.

  本发明描述了一种防污漆，它含有防污剂和一种或多种由通式（1）表示的单体 A 组成的聚合物和/或由一种或多种单体 A 和一种或多种可与所述单体 A 共聚的乙烯基可聚合单体 B 组成的共聚物，或其基本成分： 其中 X 是甲基的氢原子；n 是 2 至 4 的整数；m 表示平均聚合度，为零或实数。防污漆可以含有滑动剂作为第三种基本成分，以提供更强的防污能力。
• UNDERSEA ANTIFOULING AGENT
  申请人：NIPPON OIL AND FATS COMPANY, LIMITED

  公开号：EP0425709A1

  公开（公告）日：1991-05-08

  An undersea antifouling agent applied by impregnation for the purpose of preventing aquatic organisms for a long period of time from depositing on, for example, nets for culturing, stationary net fishing, etc., and materials for supporting the net, such as ropes; a net for preventing medusas from invading an intake of sea water for cooling; and materials for shore protection. The first invention relates to an undersea antifouling agent comprising: (A) at least one member selected from among (A1) 2-(thiocyanomethylthis)benzothiazole, (A2) tetraethylthiuram disulfide, (A3) 2,4,5,6-tetrachloro-1,3-dicyanobenzene, (A4) N-(ethylmethylphenyl)dichloromaleimide, and (A5) N-(diethylphenyl)dichloromaleimide; (B) a film-forming material; and (C) at least one compound selected from among dialkyl polysulfides represented by the general formula R₁-(S)n-R₂. The second invention relates to another undersea antifouling agent further comprising the following component (D) polybutene with a degree of polymerization of 2 to 100, in addition to the aforementioned components (A) to (C). The effect of incorporating component (C) and, in addition, component (D) in the antifouling agent resides in that the velocity of releasing component (A) as the active ingredient of the antifouling agent can appropriately be controlled thereby, so that the antifouling effect can be retained for a long period of time.

  一种海底防污剂，采用浸渍法使用，目的是防止水生生物长期沉积在例如养殖网、固定网捕鱼等网具上，以及用于支撑网具的材料，如绳索；用于防止鳉鱼侵入冷却海水进水口的网；以及用于保护海岸的材料。第一项发明涉及一种海底防污剂，包括(A) 至少一种选自 (A1) 2-(硫氰基甲基)苯并噻唑、(A2) 二硫化四乙基秋兰姆、(A3) 2,4,5,6-四氯-1,3-二氰基苯、(A4) N-(乙基甲基苯基)二氯马来酰亚胺和 (A5) N-(二乙基苯基)二氯马来酰亚胺的成员；(C) 至少一种选自通式 R₁-(S)n-R₂ 所代表的二烷基多硫化物的化合物。第二项发明涉及另一种海底防污剂，除上述成分（A）至（C）外，还包括以下成分 （D）聚合度为 2 至 100 的聚丁烯。在防污剂中加入组分（C）和组分（D）的效果在于，可以适当控制作为防污剂有效成 分的组分（A）的释放速度，从而可以长期保持防污效果。
• Transition-metal free Lubricant
  申请人：ETHYL PETROLEUM ADDITIVES LIMITED

  公开号：EP0434464A1

  公开（公告）日：1991-06-26

  Lubricant compositions especially useful as hydraulic fluids contain a metal-free anti-wear or loadcarrying additive containing sulphur and/or phosphorus and an amino succinate ester as corrosion inhibitor. Such compositions are free from heavy metals and have improved environmental acceptability where heavy metals are to be avoided, e.g. in agriculture. The lubricant base stock may be a biodegradable natural oil.

  作为液压油特别有用的润滑油组合物含有一种不含金属的抗磨或承载添加剂，该添加剂含有硫和/或磷以及一种作为腐蚀抑制剂的氨基琥珀酸酯。此类组合物不含重金属，在农业等需要避免重金属的领域，其环境可接受性更高。润滑油基础油可以是可生物降解的天然油。
• TRIPHENYLBORANE-ROSIN AMINE ADDUCT AND USE OF THE SAME
  申请人：Yoshitomi Fine Chemicals, Ltd.

  公开号：EP0877061A1

  公开（公告）日：1998-11-11

  The triphenylborane-rosin amine adduct shows superior prevention of adhesion, and thus, antifouling effects against coelenterates such as obelia and hydrozoas; shellfish such as barnacle, blue mussel and oyster, tubicolous polychaetes such as Hydroides norvegica, Serpula vermicularis, Pomatoleios kraussii and Dexiospira spirillum and other aquatic organisms. The concurrent use of 1,3-dicyanotetrachlorobenzene, 2-(thiocyanomethylthio)benzothiazole, tetraalkylthiuramdisulfide, 2,3-dichloromaleimide, phenol, dialkylpolysulfide, polybutene, paraffin or petrolatum, and the above-mentioned compound results in the above-mentioned effects. Thus, the above-mentioned compound can be used to provide a preventive of fouling by the aquatic adhesion organisms, an antifouling agent for a fishnet and an antifouling coating, which have superior antifouling effects against fouling organisms such as coelenterates, shellfish, tubicolous polychaetes and the like.

  三苯硼烷-松香胺加合物具有出色的防附着能力，因此对肠衣纲动物（如 Obelia 和 hydrozoas）、贝类（如藤壶、蓝贻贝和牡蛎）、管状多毛目动物（如 Hydroides norvegica、Serpula vermicularis、Pomatoleios kraussii 和 Dexiospira spirillum）以及其他水生生物具有防污效果。同时使用 1,3-二氰基四氯苯、2-（硫氰基甲硫基）苯并噻唑、四烷基秋兰姆二硫化物、2,3-二氯马来酰亚胺、苯酚、二烷基聚硫、聚丁烯、石蜡或凡士林和上述化合物可产生上述效果。因此，上述化合物可用于提供一种水生附着生物污垢预防剂、一种鱼网防污剂和一种防污涂层，对诸如腔肠动物、贝类、管状多毛类等污垢生物具有卓越的防污效果。
• COATED BIS(2-PYRIDINETHIOL 1-OXIDE) COPPER SALT
  申请人：Yoshitomi Fine Chemicals, Ltd.

  公开号：EP1080640A1

  公开（公告）日：2001-03-07

  Bis(2-pyridinethiol 1-oxide) copper salt which has been coated with one or more members selected among glycerol, dialkyl phthalates, lubricating oils, acrylic resins, rosins, fatty acid amides, dialkylpolysulfides, polybutene, paraffins, and vaseline. Since the the coated copper salt does not fly off, it has good handleability and is excellent in safety and workability. The coating does not adversely influence the storage stability and antifouling effect inherent in the copper salt. Thus, a ship bottom paint having an excellent antifouling effect and excellent storage stability can be obtained.

  双（2-吡啶硫醇 1-氧化物）铜盐，其表面涂有甘油、邻苯二甲酸二烷基酯、润滑油、丙烯酸树脂、松香、脂肪酸酰胺、二烷基聚硫化物、聚丁烯、石蜡和凡士林中的一种或多种成分。由于铜盐涂层不会飞散，因此具有良好的可操作性、出色的安全性和可加工性。涂层不会对铜盐固有的储存稳定性和防污效果产生不利影响。因此，可以获得防污效果极佳、储存稳定性极佳的船底涂料。