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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N'-[(E)-[5-(Pyridin-2-ylsulfanyl)furan-2-YL]methylidene]octanehydrazide —— C18H23N3O2S
    N'-[(E)-[5-(Pyridin-2-ylsulfanyl)furan-2-YL]methylidene]octanehydrazide
    —— N',N''-{sulfanediylbis[furan-5,2-diyl(E)methylylidene]}bis[2-(3-methylphenoxy)acetohydrazide] —— C28H26N4O6S
    N',N''-{sulfanediylbis[furan-5,2-diyl(E)methylylidene]}bis[2-(3-methylphenoxy)acetohydrazide]
    —— N'-[(E)-[5-(1,3-Benzothiazol-2-ylsulfanyl)furan-2-YL]methylidene]-3-nitrobenzohydrazide —— C19H12N4O4S2
    N'-[(E)-[5-(1,3-Benzothiazol-2-ylsulfanyl)furan-2-YL]methylidene]-3-nitrobenzohydrazide
    —— dibutyltin(2+);[2-[methylsulfanyl(sulfoniumylidene)methyl]cyclopentylidene]azanide —— C22H40N2S4Sn+2
    dibutyltin(2+);[2-[methylsulfanyl(sulfoniumylidene)methyl]cyclopentylidene]azanide
    —— N'-{(E)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylidene}-3-bromobenzohydrazide —— C19H13BrN4O2S
    N'-{(E)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylidene}-3-bromobenzohydrazide
    —— 2-(naphthalen-1-yl)-N'-[(E)-{5-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl}methylidene]acetohydrazide —— C24H16N4O4S2
    2-(naphthalen-1-yl)-N'-[(E)-{5-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl}methylidene]acetohydrazide
    —— dimethyltin(2+);[2-[methylsulfanyl(sulfoniumylidene)methyl]cyclopentylidene]azanide —— C16H28N2S4Sn+2
    dimethyltin(2+);[2-[methylsulfanyl(sulfoniumylidene)methyl]cyclopentylidene]azanide
    —— 1-phenyl-3-[(E)-1-[[5-[(2E)-2-(phenylcarbamothioylhydrazinylidene)propyl]sulfanyl-2-sulfanylidene-1,3-dithiol-4-yl]sulfanyl]propan-2-ylideneamino]thiourea —— C23H24N6S7
    1-phenyl-3-[(E)-1-[[5-[(2E)-2-(phenylcarbamothioylhydrazinylidene)propyl]sulfanyl-2-sulfanylidene-1,3-dithiol-4-yl]sulfanyl]propan-2-ylideneamino]thiourea
    —— N-[(E)-benzylideneamino]-2-(2,3,4,5,6-pentachlorophenyl)sulfanylacetamide —— C15H9Cl5N2OS
    N-[(E)-benzylideneamino]-2-(2,3,4,5,6-pentachlorophenyl)sulfanylacetamide
    —— N-[(E)-(4-methoxyphenyl)methylideneamino]-4-(4-phenylsulfanylphenyl)-1,3-thiazol-2-amine —— C23H19N3OS2
    N-[(E)-(4-methoxyphenyl)methylideneamino]-4-(4-phenylsulfanylphenyl)-1,3-thiazol-2-amine
    —— [(E)-(5-quinolin-8-ylsulfanylfuran-2-yl)methylideneamino]thiourea —— C15H12N4OS2
    [(E)-(5-quinolin-8-ylsulfanylfuran-2-yl)methylideneamino]thiourea
    —— 2-(1,3-benzothiazol-2-ylsulfanyl)-3-[(E)-(2-phenylhydrazinylidene)methyl]-4H-pyrido[1,2-a]pyrimidin-4-one —— C22H15N5OS2
    2-(1,3-benzothiazol-2-ylsulfanyl)-3-[(E)-(2-phenylhydrazinylidene)methyl]-4H-pyrido[1,2-a]pyrimidin-4-one
    —— Carbon monoxide;manganese;methyl(3-oxopropyl)sulfanium —— C8H8MnO5S
    Carbon monoxide;manganese;methyl(3-oxopropyl)sulfanium
    —— 2-benzylsulfanyl-N-[(E)-1-(4-pentylphenyl)ethylideneamino]pyrimidin-4-amine —— C24H28N4S
    2-benzylsulfanyl-N-[(E)-1-(4-pentylphenyl)ethylideneamino]pyrimidin-4-amine
    —— 2-benzylsulfanyl-N-[(E)-1-(4-butylphenyl)ethylideneamino]pyrimidin-4-amine —— C23H26N4S
    2-benzylsulfanyl-N-[(E)-1-(4-butylphenyl)ethylideneamino]pyrimidin-4-amine
    —— 2-(4-chlorophenyl)sulfanyl-N-[(E)-1-phenylethylideneamino]acetamide —— C16H15ClN2OS
    2-(4-chlorophenyl)sulfanyl-N-[(E)-1-phenylethylideneamino]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(E)-[4-[(E)-[[2-(4-chlorophenyl)sulfanylacetyl]hydrazinylidene]methyl]phenyl]methylideneamino]acetamide —— C24H20Cl2N4O2S2
    2-(4-chlorophenyl)sulfanyl-N-[(E)-[4-[(E)-[[2-(4-chlorophenyl)sulfanylacetyl]hydrazinylidene]methyl]phenyl]methylideneamino]acetamide
    —— N'-{(E)-[4-(methylsulfanyl)phenyl]methylidene}-2-phenylcyclopropanecarbohydrazide —— C18H18N2OS
    N'-{(E)-[4-(methylsulfanyl)phenyl]methylidene}-2-phenylcyclopropanecarbohydrazide
    —— (NE)-N-[[4-[(E)-hydroxyiminomethyl]-2,5-bis(methylsulfanyl)thiophen-3-yl]methylidene]hydroxylamine —— C8H10N2O2S3
    (NE)-N-[[4-[(E)-hydroxyiminomethyl]-2,5-bis(methylsulfanyl)thiophen-3-yl]methylidene]hydroxylamine
    —— N'-(4-(Methylthio)benzylidene)bicyclo[4.1.0]heptane-7-carbohydrazide —— C16H20N2OS
    N'-(4-(Methylthio)benzylidene)bicyclo[4.1.0]heptane-7-carbohydrazide
    —— 2-[(4-Bromo-2-fluorophenyl)methylsulfanyl]-5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazole —— C16H11BrClFN2S3
    2-[(4-Bromo-2-fluorophenyl)methylsulfanyl]-5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazole
    —— N'-[5-[(2-chloro-6-fluorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]-N,N-dimethylmethanimidamide —— C12H12ClFN4S2
    N'-[5-[(2-chloro-6-fluorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]-N,N-dimethylmethanimidamide
    —— N'-[5-[(5-chloro-1,3-benzothiazol-2-yl)sulfanyl]-1,3,4-thiadiazol-2-yl]-N,N-dimethylethanimidamide —— C13H12ClN5S3
    N'-[5-[(5-chloro-1,3-benzothiazol-2-yl)sulfanyl]-1,3,4-thiadiazol-2-yl]-N,N-dimethylethanimidamide
    —— [(E)-(4,6-dichloro-2-methylsulfanylpyrimidin-5-yl)methylideneamino] N-(3-methylphenyl)carbamate —— C14H12Cl2N4O2S
    [(E)-(4,6-dichloro-2-methylsulfanylpyrimidin-5-yl)methylideneamino] N-(3-methylphenyl)carbamate
    —— 2-(tert-butylthio)benzaldehyde oxime —— C11H15NOS
    2-(tert-butylthio)benzaldehyde oxime
    —— N,N-dimethyl-N'-[3-(3-nitropyridin-2-yl)sulfanyl-1H-1,2,4-triazol-5-yl]methanimidamide —— C10H11N7O2S
    N,N-dimethyl-N'-[3-(3-nitropyridin-2-yl)sulfanyl-1H-1,2,4-triazol-5-yl]methanimidamide
    —— N'-[3-(2-chloro-6-nitrophenyl)sulfanyl-1H-1,2,4-triazol-5-yl]-N,N-dimethylmethanimidamide —— C11H11ClN6O2S
    N'-[3-(2-chloro-6-nitrophenyl)sulfanyl-1H-1,2,4-triazol-5-yl]-N,N-dimethylmethanimidamide
    —— N,N-dimethyl-N'-[5-(3-nitropyridin-2-yl)sulfanyl-1,3,4-thiadiazol-2-yl]methanimidamide —— C10H10N6O2S2
    N,N-dimethyl-N'-[5-(3-nitropyridin-2-yl)sulfanyl-1,3,4-thiadiazol-2-yl]methanimidamide
    —— 1-[(E)-(2-tert-butylsulfanylphenyl)methylideneamino]-3-(2-methylbutan-2-yl)thiourea —— C17H27N3S2
    1-[(E)-(2-tert-butylsulfanylphenyl)methylideneamino]-3-(2-methylbutan-2-yl)thiourea
    —— (E)-6-methyl-5-(2-(4-(methylthio)benzylidene)hydrazinyl)-1,2,4-triazin-3(2H)-one —— C12H13N5OS
    (E)-6-methyl-5-(2-(4-(methylthio)benzylidene)hydrazinyl)-1,2,4-triazin-3(2H)-one
    —— 2-[(4-chlorophenyl)sulfanyl]-2-methylpropanal O-methyloxime —— C11H14ClNOS
    2-[(4-chlorophenyl)sulfanyl]-2-methylpropanal O-methyloxime
    —— 2-methyl-2-(phenylsulfanyl)propanal O-methyloxime —— C11H15NOS
    2-methyl-2-(phenylsulfanyl)propanal O-methyloxime
    —— (E)-N-[2-methyl-2-(phenylsulfanyl)propylidene]hydroxylamine —— C10H13NOS
    (E)-N-[2-methyl-2-(phenylsulfanyl)propylidene]hydroxylamine
    —— 3-nitro-4-{[3-(trifluoromethyl)phenyl]sulfanyl}benzenecarbaldehyde O-(2,6-dichlorobenzyl)oxime —— C21H13Cl2F3N2O3S
    3-nitro-4-{[3-(trifluoromethyl)phenyl]sulfanyl}benzenecarbaldehyde O-(2,6-dichlorobenzyl)oxime
    —— 4-[(4-chlorophenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-(3,4-dichlorobenzyl)oxime —— C20H13Cl3N2O3S
    4-[(4-chlorophenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-(3,4-dichlorobenzyl)oxime
    —— 4-[(4-methylphenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-methyloxime —— C15H14N2O3S
    4-[(4-methylphenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-methyloxime
    —— [(E)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino]thiourea —— C14H10ClF3N4S2
    [(E)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino]thiourea
    —— (E)-1-(4-chlorophenyl)-2-(4-chlorophenyl)sulfanyl-N-methoxyethanimine —— C15H13Cl2NOS
    (E)-1-(4-chlorophenyl)-2-(4-chlorophenyl)sulfanyl-N-methoxyethanimine
    —— 4-[(4-chlorophenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-(2,4-dichlorobenzyl)oxime —— C20H13Cl3N2O3S
    4-[(4-chlorophenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-(2,4-dichlorobenzyl)oxime
    —— 1-tert-butyl-3-[(E)-[2-[(4-chlorophenyl)methylsulfanyl]pyrimidin-4-yl]methylideneamino]thiourea —— C17H20ClN5S2
    1-tert-butyl-3-[(E)-[2-[(4-chlorophenyl)methylsulfanyl]pyrimidin-4-yl]methylideneamino]thiourea
    —— 4-[(4-Chlorophenyl)sulfanyl]-3-nitrobenzenecarbaldehyde oxime —— C13H9ClN2O3S
    4-[(4-Chlorophenyl)sulfanyl]-3-nitrobenzenecarbaldehyde oxime
    —— N,N-dimethyl-N'-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]methanimidamide —— C13H16N4S2
    N,N-dimethyl-N'-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]methanimidamide
    —— N'-(5-hexylsulfanyl-1,3,4-thiadiazol-2-yl)-N,N-dimethylmethanimidamide —— C11H20N4S2
    N'-(5-hexylsulfanyl-1,3,4-thiadiazol-2-yl)-N,N-dimethylmethanimidamide
    —— N,N-dimethyl-N'-(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)methanimidamide —— C8H14N4S2
    N,N-dimethyl-N'-(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)methanimidamide
    —— 1-tert-butyl-3-[(E)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino]thiourea —— C18H18ClF3N4S2
    1-tert-butyl-3-[(E)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino]thiourea
    —— 3-(methylsulfanyl)-N-[(E)-thiophen-2-ylmethylidene]-7H-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-amine —— C9H8N6S2
    3-(methylsulfanyl)-N-[(E)-thiophen-2-ylmethylidene]-7H-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-amine
    —— 2-Methyl-N'-[(E)-[5-(pyridin-2-ylsulfanyl)furan-2-YL]methylidene]benzohydrazide —— C18H15N3O2S
    2-Methyl-N'-[(E)-[5-(pyridin-2-ylsulfanyl)furan-2-YL]methylidene]benzohydrazide
    —— (NE)-N-(5,6-dihydrothieno[2,3-b]thiopyran-4-ylidene)hydroxylamine —— C7H7NOS2
    (NE)-N-(5,6-dihydrothieno[2,3-b]thiopyran-4-ylidene)hydroxylamine
    —— N-{(E)-[5-(quinolin-8-ylsulfanyl)furan-2-yl]methylidene}-4H-1,2,4-triazol-4-amine —— C16H11N5OS
    N-{(E)-[5-(quinolin-8-ylsulfanyl)furan-2-yl]methylidene}-4H-1,2,4-triazol-4-amine
    —— 2-[(4,6-dimethylpyrimidin-2-yl)sulfanyl]-N'-[(E)-thiophen-2-ylmethylidene]acetohydrazide —— C13H14N4OS2
    2-[(4,6-dimethylpyrimidin-2-yl)sulfanyl]-N'-[(E)-thiophen-2-ylmethylidene]acetohydrazide