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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— tert-butyl N-[[(2S)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]piperidin-2-yl]methyl]carbamate —— C17H28N4O2S
    tert-butyl N-[[(2S)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]piperidin-2-yl]methyl]carbamate
    —— [(3S)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]piperidin-3-yl]methanol —— C12H19N3OS
    [(3S)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]piperidin-3-yl]methanol
    —— [(2S)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]piperidin-2-yl]methanol —— C12H19N3OS
    [(2S)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]piperidin-2-yl]methanol
    —— (3R,5S)-3,5-dimethyl-1-[2-(2-phenylsulfanylethoxy)ethyl]piperidine —— C17H27NOS
    (3R,5S)-3,5-dimethyl-1-[2-(2-phenylsulfanylethoxy)ethyl]piperidine
    —— (2S,6R)-2,6-dimethyl-4-[2-(2-phenylsulfanylethoxy)ethyl]morpholine —— C16H25NO2S
    (2S,6R)-2,6-dimethyl-4-[2-(2-phenylsulfanylethoxy)ethyl]morpholine
    —— (2S,6R)-2,6-dimethyl-4-[2-[2-(4-methylphenyl)sulfanylethoxy]ethyl]morpholine —— C17H27NO2S
    (2S,6R)-2,6-dimethyl-4-[2-[2-(4-methylphenyl)sulfanylethoxy]ethyl]morpholine
    —— (2R,6R)-2,6-dimethyl-4-[3-(4-methylphenyl)sulfanylpropyl]morpholine —— C16H25NOS
    (2R,6R)-2,6-dimethyl-4-[3-(4-methylphenyl)sulfanylpropyl]morpholine
    —— (3R)-3-methyl-1-[2-(2-phenylsulfanylethoxy)ethyl]piperidine —— C16H25NOS
    (3R)-3-methyl-1-[2-(2-phenylsulfanylethoxy)ethyl]piperidine
    —— (2R,6S)-2,6-dimethyl-4-[3-(4-methylphenyl)sulfanylpropyl]morpholine —— C16H25NOS
    (2R,6S)-2,6-dimethyl-4-[3-(4-methylphenyl)sulfanylpropyl]morpholine
    —— (2S,6R)-2,6-dimethyl-4-[3-(4-methylphenyl)sulfanylpropyl]morpholin-4-ium —— C16H26NOS+
    (2S,6R)-2,6-dimethyl-4-[3-(4-methylphenyl)sulfanylpropyl]morpholin-4-ium
    —— (2R,6R)-2,6-dimethyl-4-[2-[2-(4-methylphenyl)sulfanylethoxy]ethyl]morpholin-4-ium —— C17H28NO2S+
    (2R,6R)-2,6-dimethyl-4-[2-[2-(4-methylphenyl)sulfanylethoxy]ethyl]morpholin-4-ium
    —— (2S,6R)-2,6-dimethyl-4-[2-(2-phenylsulfanylethoxy)ethyl]morpholin-4-ium —— C16H26NO2S+
    (2S,6R)-2,6-dimethyl-4-[2-(2-phenylsulfanylethoxy)ethyl]morpholin-4-ium
    —— [(3R)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]pyrrolidin-3-yl]methanol —— C11H17N3OS
    [(3R)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]pyrrolidin-3-yl]methanol
    —— tert-butyl N-[[(2R)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]piperidin-2-yl]methyl]carbamate —— C17H28N4O2S
    tert-butyl N-[[(2R)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]piperidin-2-yl]methyl]carbamate
    —— tert-butyl N-[[(2S)-1-(2-methylsulfanylpyrimidin-4-yl)piperidin-2-yl]methyl]carbamate —— C16H26N4O2S
    tert-butyl N-[[(2S)-1-(2-methylsulfanylpyrimidin-4-yl)piperidin-2-yl]methyl]carbamate
    —— [(3R)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]piperidin-3-yl]methanol —— C12H19N3OS
    [(3R)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]piperidin-3-yl]methanol
    —— tert-butyl N-[[(3R)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]piperidin-3-yl]methyl]carbamate —— C17H28N4O2S
    tert-butyl N-[[(3R)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]piperidin-3-yl]methyl]carbamate
    —— [(2R)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]pyrrolidin-2-yl]methanol —— C11H17N3OS
    [(2R)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]pyrrolidin-2-yl]methanol
    —— tert-butyl N-methyl-N-[(3S)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]piperidin-3-yl]carbamate —— C17H28N4O2S
    tert-butyl N-methyl-N-[(3S)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]piperidin-3-yl]carbamate
    —— [(2R)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]piperidin-2-yl]methanol —— C12H19N3OS
    [(2R)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]piperidin-2-yl]methanol
    —— tert-butyl N-[[(3R)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]pyrrolidin-3-yl]methyl]carbamate —— C16H26N4O2S
    tert-butyl N-[[(3R)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]pyrrolidin-3-yl]methyl]carbamate
    —— tert-butyl N-[[(2S)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]pyrrolidin-2-yl]methyl]carbamate —— C16H26N4O2S
    tert-butyl N-[[(2S)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]pyrrolidin-2-yl]methyl]carbamate
    —— tert-butyl N-[[(3S)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]piperidin-3-yl]methyl]carbamate —— C17H28N4O2S
    tert-butyl N-[[(3S)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]piperidin-3-yl]methyl]carbamate
    —— tert-butyl N-[[(2R)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]pyrrolidin-2-yl]methyl]carbamate —— C16H26N4O2S
    tert-butyl N-[[(2R)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]pyrrolidin-2-yl]methyl]carbamate
    —— tert-butyl N-methyl-N-[(3R)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]piperidin-3-yl]carbamate —— C17H28N4O2S
    tert-butyl N-methyl-N-[(3R)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]piperidin-3-yl]carbamate
    —— tert-butyl N-[[(3S)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]pyrrolidin-3-yl]methyl]carbamate —— C16H26N4O2S
    tert-butyl N-[[(3S)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]pyrrolidin-3-yl]methyl]carbamate
    —— [(2R)-1-(2-methylsulfanylpyrimidin-4-yl)pyrrolidin-2-yl]methanol —— C10H15N3OS
    [(2R)-1-(2-methylsulfanylpyrimidin-4-yl)pyrrolidin-2-yl]methanol
    —— tert-butyl N-[(3R)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]piperidin-3-yl]carbamate —— C16H26N4O2S
    tert-butyl N-[(3R)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]piperidin-3-yl]carbamate
    —— tert-butyl N-methyl-N-[(3R)-1-(2-methylsulfanylpyrimidin-4-yl)piperidin-3-yl]carbamate —— C16H26N4O2S
    tert-butyl N-methyl-N-[(3R)-1-(2-methylsulfanylpyrimidin-4-yl)piperidin-3-yl]carbamate
    —— tert-butyl N-methyl-N-[(3S)-1-(2-methylsulfanylpyrimidin-4-yl)piperidin-3-yl]carbamate —— C16H26N4O2S
    tert-butyl N-methyl-N-[(3S)-1-(2-methylsulfanylpyrimidin-4-yl)piperidin-3-yl]carbamate
    —— tert-butyl N-[[(2R)-1-(6-chloro-2-methylsulfanylpyrimidin-4-yl)pyrrolidin-2-yl]methyl]carbamate —— C15H23ClN4O2S
    tert-butyl N-[[(2R)-1-(6-chloro-2-methylsulfanylpyrimidin-4-yl)pyrrolidin-2-yl]methyl]carbamate
    —— [(3S)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]pyrrolidin-3-yl]methanol —— C11H17N3OS
    [(3S)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]pyrrolidin-3-yl]methanol
    —— [(3R)-1-(2-methylsulfanylpyrimidin-4-yl)pyrrolidin-3-yl]methanol —— C10H15N3OS
    [(3R)-1-(2-methylsulfanylpyrimidin-4-yl)pyrrolidin-3-yl]methanol
    —— [(2S)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]pyrrolidin-2-yl]methanol —— C11H17N3OS
    [(2S)-1-[(3-methylsulfanylpyrazin-2-yl)methyl]pyrrolidin-2-yl]methanol
    —— tert-butyl N-[[(3R)-1-(2-methylsulfanylpyrimidin-4-yl)piperidin-3-yl]methyl]carbamate —— C16H26N4O2S
    tert-butyl N-[[(3R)-1-(2-methylsulfanylpyrimidin-4-yl)piperidin-3-yl]methyl]carbamate
    —— tert-butyl N-[[(3R)-1-(6-chloro-2-methylsulfanylpyrimidin-4-yl)pyrrolidin-3-yl]methyl]carbamate —— C15H23ClN4O2S
    tert-butyl N-[[(3R)-1-(6-chloro-2-methylsulfanylpyrimidin-4-yl)pyrrolidin-3-yl]methyl]carbamate
    —— [(3S)-1-(2-methylsulfanylpyrimidin-4-yl)pyrrolidin-3-yl]methanol —— C10H15N3OS
    [(3S)-1-(2-methylsulfanylpyrimidin-4-yl)pyrrolidin-3-yl]methanol
    —— tert-butyl N-[[(3S)-1-(2-methylsulfanylpyrimidin-4-yl)piperidin-3-yl]methyl]carbamate —— C16H26N4O2S
    tert-butyl N-[[(3S)-1-(2-methylsulfanylpyrimidin-4-yl)piperidin-3-yl]methyl]carbamate
    —— tert-butyl N-[[(2R)-1-(2-methylsulfanylpyrimidin-4-yl)pyrrolidin-2-yl]methyl]carbamate —— C15H24N4O2S
    tert-butyl N-[[(2R)-1-(2-methylsulfanylpyrimidin-4-yl)pyrrolidin-2-yl]methyl]carbamate
    —— [(E)-1-(5-methyl-2-phenylsulfanylphenyl)ethylideneamino]urea —— C16H17N3OS
    [(E)-1-(5-methyl-2-phenylsulfanylphenyl)ethylideneamino]urea
    —— tert-butyl N-[[(2R)-1-(2-methylsulfanylpyrimidin-4-yl)piperidin-2-yl]methyl]carbamate —— C16H26N4O2S
    tert-butyl N-[[(2R)-1-(2-methylsulfanylpyrimidin-4-yl)piperidin-2-yl]methyl]carbamate
    —— tert-butyl N-[[(3R)-1-(2-methylsulfanylpyrimidin-4-yl)pyrrolidin-3-yl]methyl]carbamate —— C15H24N4O2S
    tert-butyl N-[[(3R)-1-(2-methylsulfanylpyrimidin-4-yl)pyrrolidin-3-yl]methyl]carbamate
    —— [(3R)-1-(6-chloro-2-methylsulfanylpyrimidin-4-yl)pyrrolidin-3-yl]methanol —— C10H14ClN3OS
    [(3R)-1-(6-chloro-2-methylsulfanylpyrimidin-4-yl)pyrrolidin-3-yl]methanol
    —— N-benzyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-(4-fluorophenyl)sulfanylacetamide —— C19H20FNO3S2
    N-benzyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-(4-fluorophenyl)sulfanylacetamide
    —— methyl (2Z)-2-(1,1,3,3-tetramethyl-2-oxo-6-phenylimino-5-oxa-8-thiaspiro[3.4]octan-7-ylidene)acetate —— C19H21NO4S
    methyl (2Z)-2-(1,1,3,3-tetramethyl-2-oxo-6-phenylimino-5-oxa-8-thiaspiro[3.4]octan-7-ylidene)acetate
    —— tert-butyl N-[[(2S)-1-(6-chloro-2-methylsulfanylpyrimidin-4-yl)pyrrolidin-2-yl]methyl]carbamate —— C15H23ClN4O2S
    tert-butyl N-[[(2S)-1-(6-chloro-2-methylsulfanylpyrimidin-4-yl)pyrrolidin-2-yl]methyl]carbamate
    —— tert-butyl N-[[(3S)-1-(2-methylsulfanylpyrimidin-4-yl)pyrrolidin-3-yl]methyl]carbamate —— C15H24N4O2S
    tert-butyl N-[[(3S)-1-(2-methylsulfanylpyrimidin-4-yl)pyrrolidin-3-yl]methyl]carbamate
    —— (2R,6R)-2,6-dimethyl-4-(3-phenylsulfanylpropyl)morpholin-4-ium —— C15H24NOS+
    (2R,6R)-2,6-dimethyl-4-(3-phenylsulfanylpropyl)morpholin-4-ium
    —— [(2S)-1-(2-methylsulfanylpyrimidin-4-yl)pyrrolidin-2-yl]methanol —— C10H15N3OS
    [(2S)-1-(2-methylsulfanylpyrimidin-4-yl)pyrrolidin-2-yl]methanol
    —— tert-butyl N-[[(2S)-1-(2-methylsulfanylpyrimidin-4-yl)pyrrolidin-2-yl]methyl]carbamate —— C15H24N4O2S
    tert-butyl N-[[(2S)-1-(2-methylsulfanylpyrimidin-4-yl)pyrrolidin-2-yl]methyl]carbamate