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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[(2R,4R)-1,4-dihydroxy-4-phenylbutan-2-yl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide —— C18H19F3N2O3S
    N-[(2R,4R)-1,4-dihydroxy-4-phenylbutan-2-yl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide
    —— 4-chloro-N-[[5-(4-methylphenyl)sulfanyl-2-phenylimidazol-4-ylidene]methyl]aniline —— C23H18ClN3S
    4-chloro-N-[[5-(4-methylphenyl)sulfanyl-2-phenylimidazol-4-ylidene]methyl]aniline
    —— 3,4-dimethyl-N-[[5-(4-methylphenyl)sulfanyl-2-phenylimidazol-4-ylidene]methyl]aniline —— C25H23N3S
    3,4-dimethyl-N-[[5-(4-methylphenyl)sulfanyl-2-phenylimidazol-4-ylidene]methyl]aniline
    —— 6-[[[2,6-bis(phenylsulfanyl)pyridin-3-yl]amino]methylidene]-2,4-dichlorocyclohexa-2,4-dien-1-one —— C24H16Cl2N2OS2
    6-[[[2,6-bis(phenylsulfanyl)pyridin-3-yl]amino]methylidene]-2,4-dichlorocyclohexa-2,4-dien-1-one
    —— 4-chloro-N-{2-[6-methyl-3-(propylsulfanyl)-1,2,4-triazin-5-yl]ethenyl}aniline —— C15H17ClN4S
    4-chloro-N-{2-[6-methyl-3-(propylsulfanyl)-1,2,4-triazin-5-yl]ethenyl}aniline
    —— 2-(3,4-Dimethylphenyl)-4-[[4-[4-[[1-(3,4-dimethylphenyl)-3-methyl-5-oxopyrazol-4-ylidene]methylamino]phenyl]sulfanylanilino]methylidene]-5-methylpyrazol-3-one —— C38H36N6O2S
    2-(3,4-Dimethylphenyl)-4-[[4-[4-[[1-(3,4-dimethylphenyl)-3-methyl-5-oxopyrazol-4-ylidene]methylamino]phenyl]sulfanylanilino]methylidene]-5-methylpyrazol-3-one
    —— 3-(2-fluorophenyl)sulfanyl-N-[(2S)-2-hydroxy-2-pyridin-4-ylethyl]propanamide —— C16H17FN2O2S
    3-(2-fluorophenyl)sulfanyl-N-[(2S)-2-hydroxy-2-pyridin-4-ylethyl]propanamide
    —— 3-(2-fluorophenyl)sulfanyl-N-[(2R)-2-hydroxy-2-pyridin-4-ylethyl]propanamide —— C16H17FN2O2S
    3-(2-fluorophenyl)sulfanyl-N-[(2R)-2-hydroxy-2-pyridin-4-ylethyl]propanamide
    —— 1-[(2R)-2-[(2-chlorophenyl)methyl]pyrrolidin-1-yl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylethanone —— C18H19ClN2O2S
    1-[(2R)-2-[(2-chlorophenyl)methyl]pyrrolidin-1-yl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylethanone
    —— [(1R)-1-cyclopropyl-2,2,2-trifluoroethyl] 2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetate —— C12H12F3NO3S
    [(1R)-1-cyclopropyl-2,2,2-trifluoroethyl] 2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetate
    —— 5-[2-[[3-(4-fluorophenyl)pyrazol-4-ylidene]methyl]hydrazinyl]-3-methylsulfanyl-1,2-thiazole-4-carbonitrile —— C15H11FN6S2
    5-[2-[[3-(4-fluorophenyl)pyrazol-4-ylidene]methyl]hydrazinyl]-3-methylsulfanyl-1,2-thiazole-4-carbonitrile
    —— [(1S)-1-cyclopropyl-2,2,2-trifluoroethyl] 2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetate —— C12H12F3NO3S
    [(1S)-1-cyclopropyl-2,2,2-trifluoroethyl] 2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetate
    —— 1-[(2S)-4-methylsulfonylbutan-2-yl]-3-[(1S,2S)-2-propan-2-ylcyclohexyl]urea —— C15H30N2O3S
    1-[(2S)-4-methylsulfonylbutan-2-yl]-3-[(1S,2S)-2-propan-2-ylcyclohexyl]urea
    —— (2R)-N-[(1S)-2-methyl-1-pyridin-2-ylpropyl]-2-pyridin-2-ylsulfanylpropanamide —— C17H21N3OS
    (2R)-N-[(1S)-2-methyl-1-pyridin-2-ylpropyl]-2-pyridin-2-ylsulfanylpropanamide
    —— 1-[(2S)-4-methylsulfonylbutan-2-yl]-3-[(1R,2R)-2-propan-2-ylcyclohexyl]urea —— C15H30N2O3S
    1-[(2S)-4-methylsulfonylbutan-2-yl]-3-[(1R,2R)-2-propan-2-ylcyclohexyl]urea
    —— 1-[(2S)-4-methylsulfonylbutan-2-yl]-3-[(1R,2S)-2-propan-2-ylcyclohexyl]urea —— C15H30N2O3S
    1-[(2S)-4-methylsulfonylbutan-2-yl]-3-[(1R,2S)-2-propan-2-ylcyclohexyl]urea
    —— (2R)-N-[(1R)-2-methyl-1-pyridin-2-ylpropyl]-2-pyridin-2-ylsulfanylpropanamide —— C17H21N3OS
    (2R)-N-[(1R)-2-methyl-1-pyridin-2-ylpropyl]-2-pyridin-2-ylsulfanylpropanamide
    —— 1-[(2S)-4-methylsulfonylbutan-2-yl]-3-[(1S,2R)-2-propan-2-ylcyclohexyl]urea —— C15H30N2O3S
    1-[(2S)-4-methylsulfonylbutan-2-yl]-3-[(1S,2R)-2-propan-2-ylcyclohexyl]urea
    —— (2S)-N-[(1S)-2-methyl-1-pyridin-2-ylpropyl]-2-pyridin-2-ylsulfanylpropanamide —— C17H21N3OS
    (2S)-N-[(1S)-2-methyl-1-pyridin-2-ylpropyl]-2-pyridin-2-ylsulfanylpropanamide
    —— (2S)-N-[(1R)-2-methyl-1-pyridin-2-ylpropyl]-2-pyridin-2-ylsulfanylpropanamide —— C17H21N3OS
    (2S)-N-[(1R)-2-methyl-1-pyridin-2-ylpropyl]-2-pyridin-2-ylsulfanylpropanamide
    —— 2-(4-bromophenyl)-5-[[4-[[(2R)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3,4-oxadiazole —— C20H18BrN5O2S2
    2-(4-bromophenyl)-5-[[4-[[(2R)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3,4-oxadiazole
    —— 2-(4-bromophenyl)-5-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3,4-oxadiazole —— C20H18BrN5O2S2
    2-(4-bromophenyl)-5-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3,4-oxadiazole
    —— (3S)-1-cyclopropyl-3-thiophen-2-ylsulfanylpyrrolidin-2-one —— C11H13NOS2
    (3S)-1-cyclopropyl-3-thiophen-2-ylsulfanylpyrrolidin-2-one
    —— (3R)-1-cyclopropyl-3-thiophen-2-ylsulfanylpyrrolidin-2-one —— C11H13NOS2
    (3R)-1-cyclopropyl-3-thiophen-2-ylsulfanylpyrrolidin-2-one
    —— 2-(4-fluorophenyl)sulfanyl-N-[(3S)-1-pyridazin-3-ylpiperidin-3-yl]acetamide —— C17H19FN4OS
    2-(4-fluorophenyl)sulfanyl-N-[(3S)-1-pyridazin-3-ylpiperidin-3-yl]acetamide
    —— 2-(4-fluorophenyl)sulfanyl-N-[(3R)-1-pyridazin-3-ylpiperidin-3-yl]acetamide —— C17H19FN4OS
    2-(4-fluorophenyl)sulfanyl-N-[(3R)-1-pyridazin-3-ylpiperidin-3-yl]acetamide
    —— [2-(3-{[(4-Chlorophenyl)methyl]sulfanyl}-6-methyl-1,2,4-triazin-5-yl)ethenyl]dimethylamine —— C15H17ClN4S
    [2-(3-{[(4-Chlorophenyl)methyl]sulfanyl}-6-methyl-1,2,4-triazin-5-yl)ethenyl]dimethylamine
    —— Methyl 3-[(5-phenyl-1,2,4-triazin-3-yl)sulfanyl]prop-2-enoate —— C13H11N3O2S
    Methyl 3-[(5-phenyl-1,2,4-triazin-3-yl)sulfanyl]prop-2-enoate
    —— (3S)-1-(1-methylpyrazol-4-yl)-3-(2H-triazol-4-ylsulfanyl)piperidin-2-one —— C11H14N6OS
    (3S)-1-(1-methylpyrazol-4-yl)-3-(2H-triazol-4-ylsulfanyl)piperidin-2-one
    —— (3R)-1-(1-methylpyrazol-4-yl)-3-(2H-triazol-4-ylsulfanyl)piperidin-2-one —— C11H14N6OS
    (3R)-1-(1-methylpyrazol-4-yl)-3-(2H-triazol-4-ylsulfanyl)piperidin-2-one
    —— (1S)-2-[(6-benzylsulfanylpyrazin-2-yl)amino]-1-(1-methylpyrazol-4-yl)ethanol —— C17H19N5OS
    (1S)-2-[(6-benzylsulfanylpyrazin-2-yl)amino]-1-(1-methylpyrazol-4-yl)ethanol
    —— (1R)-2-[(6-benzylsulfanylpyrazin-2-yl)amino]-1-(1-methylpyrazol-4-yl)ethanol —— C17H19N5OS
    (1R)-2-[(6-benzylsulfanylpyrazin-2-yl)amino]-1-(1-methylpyrazol-4-yl)ethanol
    —— 2-[(1S)-1-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-5-(trifluoromethyl)-1,3,4-oxadiazole —— C8H7F3N4OS2
    2-[(1S)-1-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-5-(trifluoromethyl)-1,3,4-oxadiazole
    —— 2-[(1R)-1-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-5-(trifluoromethyl)-1,3,4-oxadiazole —— C8H7F3N4OS2
    2-[(1R)-1-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-5-(trifluoromethyl)-1,3,4-oxadiazole
    —— 2-[(2R)-2-methyl-3-(2-methylimidazol-1-yl)propyl]sulfanylpyrimidine —— C12H16N4S
    2-[(2R)-2-methyl-3-(2-methylimidazol-1-yl)propyl]sulfanylpyrimidine
    —— 2-[(2S)-2-methyl-3-(2-methylimidazol-1-yl)propyl]sulfanylpyrimidine —— C12H16N4S
    2-[(2S)-2-methyl-3-(2-methylimidazol-1-yl)propyl]sulfanylpyrimidine
    —— 2-[(5-tert-butyl-1,3-thiazol-2-yl)sulfanyl]-N-[(1S)-1-cyano-1-cyclopropylethyl]acetamide —— C15H21N3OS2
    2-[(5-tert-butyl-1,3-thiazol-2-yl)sulfanyl]-N-[(1S)-1-cyano-1-cyclopropylethyl]acetamide
    —— 4-(4-chlorophenyl)sulfanyl-N-[(1S)-1-(5-methyl-1,2,4-oxadiazol-3-yl)ethyl]butanamide —— C15H18ClN3O2S
    4-(4-chlorophenyl)sulfanyl-N-[(1S)-1-(5-methyl-1,2,4-oxadiazol-3-yl)ethyl]butanamide
    —— 4-(4-chlorophenyl)sulfanyl-N-[(1R)-1-(5-methyl-1,2,4-oxadiazol-3-yl)ethyl]butanamide —— C15H18ClN3O2S
    4-(4-chlorophenyl)sulfanyl-N-[(1R)-1-(5-methyl-1,2,4-oxadiazol-3-yl)ethyl]butanamide
    —— 1-[(1R)-1-(2-methyl-1,3-thiazol-4-yl)ethyl]-3-[3-(1,3-thiazol-2-ylsulfanyl)propyl]urea —— C13H18N4OS3
    1-[(1R)-1-(2-methyl-1,3-thiazol-4-yl)ethyl]-3-[3-(1,3-thiazol-2-ylsulfanyl)propyl]urea
    —— 1-[(1S)-1-(2-methyl-1,3-thiazol-4-yl)ethyl]-3-[3-(1,3-thiazol-2-ylsulfanyl)propyl]urea —— C13H18N4OS3
    1-[(1S)-1-(2-methyl-1,3-thiazol-4-yl)ethyl]-3-[3-(1,3-thiazol-2-ylsulfanyl)propyl]urea
    —— (2S)-3-(4-methylphenyl)-2-[(5-methyl-4-propyl-1,2,4-triazol-3-yl)sulfanyl]propanenitrile —— C16H20N4S
    (2S)-3-(4-methylphenyl)-2-[(5-methyl-4-propyl-1,2,4-triazol-3-yl)sulfanyl]propanenitrile
    —— (2R)-3-(4-methylphenyl)-2-[(5-methyl-4-propyl-1,2,4-triazol-3-yl)sulfanyl]propanenitrile —— C16H20N4S
    (2R)-3-(4-methylphenyl)-2-[(5-methyl-4-propyl-1,2,4-triazol-3-yl)sulfanyl]propanenitrile
    —— (2R)-2-cyclohexyl-2-[(5-methyl-4-propyl-1,2,4-triazol-3-yl)sulfanyl]acetonitrile —— C14H22N4S
    (2R)-2-cyclohexyl-2-[(5-methyl-4-propyl-1,2,4-triazol-3-yl)sulfanyl]acetonitrile
    —— 2-[[(5-chloropyridin-2-yl)amino]methylidene]-1-benzothiophen-3-one —— C14H9ClN2OS
    2-[[(5-chloropyridin-2-yl)amino]methylidene]-1-benzothiophen-3-one
    —— (2S)-2-cyclohexyl-2-[(5-methyl-4-propyl-1,2,4-triazol-3-yl)sulfanyl]acetonitrile —— C14H22N4S
    (2S)-2-cyclohexyl-2-[(5-methyl-4-propyl-1,2,4-triazol-3-yl)sulfanyl]acetonitrile
    —— 1-[(1S)-1-(4-methyl-1,3-thiazol-2-yl)ethyl]-3-[3-(1,3-thiazol-2-ylsulfanyl)propyl]urea —— C13H18N4OS3
    1-[(1S)-1-(4-methyl-1,3-thiazol-2-yl)ethyl]-3-[3-(1,3-thiazol-2-ylsulfanyl)propyl]urea
    —— S-[4-[(4-cyclobutyl-6-oxopyrimidin-1-yl)methyl]phenyl] N,N-dimethylcarbamothioate —— C18H21N3O2S
    S-[4-[(4-cyclobutyl-6-oxopyrimidin-1-yl)methyl]phenyl] N,N-dimethylcarbamothioate
    —— 1-[(1R)-1-(4-methyl-1,3-thiazol-2-yl)ethyl]-3-[3-(1,3-thiazol-2-ylsulfanyl)propyl]urea —— C13H18N4OS3
    1-[(1R)-1-(4-methyl-1,3-thiazol-2-yl)ethyl]-3-[3-(1,3-thiazol-2-ylsulfanyl)propyl]urea
    —— 1-[(1R)-1-(5-methyl-1,3-thiazol-2-yl)ethyl]-3-[3-(1,3-thiazol-2-ylsulfanyl)propyl]urea —— C13H18N4OS3
    1-[(1R)-1-(5-methyl-1,3-thiazol-2-yl)ethyl]-3-[3-(1,3-thiazol-2-ylsulfanyl)propyl]urea