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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[2-[(3R,5R)-3,5-dimethylcyclohexyl]ethylsulfonyl]ethanol —— C12H24O3S
    2-[2-[(3R,5R)-3,5-dimethylcyclohexyl]ethylsulfonyl]ethanol
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[(2R)-2-cyano-3-methylbutan-2-yl]acetamide —— C25H27N5OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[(2R)-2-cyano-3-methylbutan-2-yl]acetamide
    —— 3-(4-fluorobenzylthio)-5,6-diphenyl-1,2,4-triazine —— C22H16FN3S
    3-(4-fluorobenzylthio)-5,6-diphenyl-1,2,4-triazine
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C24H26N4O2S
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— 2-[(5,6-diethyl-1,2,4-triazin-3-yl)sulfanyl]-N-(2-phenylethyl)acetamide —— C17H22N4OS
    2-[(5,6-diethyl-1,2,4-triazin-3-yl)sulfanyl]-N-(2-phenylethyl)acetamide
    —— 1-[3-(methylsulfanyl)-1,2,4-triazin-5-yl]ethanone O-methyloxime —— C7H10N4OS
    1-[3-(methylsulfanyl)-1,2,4-triazin-5-yl]ethanone O-methyloxime
    —— (3S)-3-[5-[(1R)-cyclohex-2-en-1-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide —— C15H21N3O2S2
    (3S)-3-[5-[(1R)-cyclohex-2-en-1-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide
    —— Ethyl 5-[(4-methoxyphenyl)sulfanyl]-3-[3-(trifluoromethyl)phenyl]-1,2,4-triazine-6-carboxylate —— C20H16F3N3O3S
    Ethyl 5-[(4-methoxyphenyl)sulfanyl]-3-[3-(trifluoromethyl)phenyl]-1,2,4-triazine-6-carboxylate
    —— (3R)-3-[5-[(1S)-cyclohex-2-en-1-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide —— C15H21N3O2S2
    (3R)-3-[5-[(1S)-cyclohex-2-en-1-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide
    —— Ethyl 5-[(6-phenyl-1,2,4-triazin-3-yl)sulfanyl]thiadiazole-4-carboxylate —— C14H11N5O2S2
    Ethyl 5-[(6-phenyl-1,2,4-triazin-3-yl)sulfanyl]thiadiazole-4-carboxylate
    —— Propan-2-yl 2-[[5,6-bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]acetate —— C16H15N3O4S
    Propan-2-yl 2-[[5,6-bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]acetate
    —— (2S)-2-(4-chlorophenyl)-2-(6-phenylsulfanylpyridazin-3-yl)acetamide —— C18H14ClN3OS
    (2S)-2-(4-chlorophenyl)-2-(6-phenylsulfanylpyridazin-3-yl)acetamide
    —— (2R)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]propanoic acid —— C18H15N3O2S
    (2R)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]propanoic acid
    —— ethyl 2-[[(1R,8S)-8,11,11-trimethyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-trien-5-yl]sulfanyl]acetate —— C15H21N3O2S
    ethyl 2-[[(1R,8S)-8,11,11-trimethyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-trien-5-yl]sulfanyl]acetate
    —— ethyl (2R)-2-[[5,6-bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]propanoate —— C16H15N3O4S
    ethyl (2R)-2-[[5,6-bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]propanoate
    —— (1R)-2,2-dichloro-N-[5-chloro-2-(1-methylimidazol-2-yl)sulfanylphenyl]-1-methylcyclopropane-1-carboxamide —— C15H14Cl3N3OS
    (1R)-2,2-dichloro-N-[5-chloro-2-(1-methylimidazol-2-yl)sulfanylphenyl]-1-methylcyclopropane-1-carboxamide
    —— (1S)-2,2-dichloro-N-[5-chloro-2-(1-methylimidazol-2-yl)sulfanylphenyl]-1-methylcyclopropane-1-carboxamide —— C15H14Cl3N3OS
    (1S)-2,2-dichloro-N-[5-chloro-2-(1-methylimidazol-2-yl)sulfanylphenyl]-1-methylcyclopropane-1-carboxamide
    —— N-(2-(3-(Benzylsulfanyl)-6-methyl-1,2,4-triazin-5-yl)vinyl)-4-fluoroaniline —— C19H17FN4S
    N-(2-(3-(Benzylsulfanyl)-6-methyl-1,2,4-triazin-5-yl)vinyl)-4-fluoroaniline
    —— (3S)-3-[5-[(1S)-cyclohex-2-en-1-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide —— C15H21N3O2S2
    (3S)-3-[5-[(1S)-cyclohex-2-en-1-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide
    —— (3R)-3-[5-[(1R)-cyclohex-2-en-1-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide —— C15H21N3O2S2
    (3R)-3-[5-[(1R)-cyclohex-2-en-1-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide
    —— 2-[(5,6-diethyl-1,2,4-triazin-3-yl)sulfanyl]-N-methylacetamide —— C10H16N4OS
    2-[(5,6-diethyl-1,2,4-triazin-3-yl)sulfanyl]-N-methylacetamide
    —— 3-[[5,6-Bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]propanoic acid —— C14H11N3O4S
    3-[[5,6-Bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]propanoic acid
    —— 1,9-dimethyl-2H-triazolo[4,5-c]phenothiazine —— C14H12N4S
    1,9-dimethyl-2H-triazolo[4,5-c]phenothiazine
    —— [amino-(4,5-dimethoxypyridazin-3-yl)sulfanylmethylidene]azanium —— C7H11N4O2S+
    [amino-(4,5-dimethoxypyridazin-3-yl)sulfanylmethylidene]azanium
    —— 3-[(4-fluorophenyl)methyl]-5-[(1S)-1-(1-prop-2-enyltetrazol-5-yl)sulfanylethyl]-1,2,4-oxadiazole —— C15H15FN6OS
    3-[(4-fluorophenyl)methyl]-5-[(1S)-1-(1-prop-2-enyltetrazol-5-yl)sulfanylethyl]-1,2,4-oxadiazole
    —— 5-Ethylsulfanylpyridazine-3,4-diamine —— C6H10N4S
    5-Ethylsulfanylpyridazine-3,4-diamine
    —— 4-amino-2-[(1S)-1-(5-tert-butyl-1,3-oxazol-2-yl)ethyl]sulfanylpyrimidine-5-carbonitrile —— C14H17N5OS
    4-amino-2-[(1S)-1-(5-tert-butyl-1,3-oxazol-2-yl)ethyl]sulfanylpyrimidine-5-carbonitrile
    —— 4-amino-2-[(1R)-1-(5-tert-butyl-1,3-oxazol-2-yl)ethyl]sulfanylpyrimidine-5-carbonitrile —— C14H17N5OS
    4-amino-2-[(1R)-1-(5-tert-butyl-1,3-oxazol-2-yl)ethyl]sulfanylpyrimidine-5-carbonitrile
    —— 3-[(4-fluorophenyl)methyl]-5-[(1R)-1-(1-prop-2-enyltetrazol-5-yl)sulfanylethyl]-1,2,4-oxadiazole —— C15H15FN6OS
    3-[(4-fluorophenyl)methyl]-5-[(1R)-1-(1-prop-2-enyltetrazol-5-yl)sulfanylethyl]-1,2,4-oxadiazole
    —— 4-[(1R)-1-(2-fluorophenyl)ethyl]sulfanyl-2H-triazole —— C10H10FN3S
    4-[(1R)-1-(2-fluorophenyl)ethyl]sulfanyl-2H-triazole
    —— 4-[(1S)-1-(2-fluorophenyl)ethyl]sulfanyl-2H-triazole —— C10H10FN3S
    4-[(1S)-1-(2-fluorophenyl)ethyl]sulfanyl-2H-triazole
    —— N-[(1S)-1-(2-hydroxyphenyl)ethyl]-N-methyl-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide —— C17H17F3N2O2S
    N-[(1S)-1-(2-hydroxyphenyl)ethyl]-N-methyl-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide
    —— N-[(1R)-1-(2-hydroxyphenyl)ethyl]-N-methyl-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide —— C17H17F3N2O2S
    N-[(1R)-1-(2-hydroxyphenyl)ethyl]-N-methyl-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide
    —— [(E)-2,3-bis(phenylsulfanyl)prop-2-enyl]-dimethylazanium —— C17H20NS2+
    [(E)-2,3-bis(phenylsulfanyl)prop-2-enyl]-dimethylazanium
    —— N-Cyclohexyldithiocarbamic acid, ammonium salt —— C7H15N2S2+
    N-Cyclohexyldithiocarbamic acid, ammonium salt
    —— 2-[(4-Chlorophenyl)sulfanyl]-1-phenyl-1-ethanone oxime —— C14H12ClNOS
    2-[(4-Chlorophenyl)sulfanyl]-1-phenyl-1-ethanone oxime
    —— (Z)-3-[5-(4-chlorophenyl)sulfanylfuran-2-yl]-2-cyano-N-(oxolan-2-ylmethyl)prop-2-enamide —— C19H17ClN2O3S
    (Z)-3-[5-(4-chlorophenyl)sulfanylfuran-2-yl]-2-cyano-N-(oxolan-2-ylmethyl)prop-2-enamide
    —— (2S)-3-(4-fluorophenyl)sulfanyl-2-methyl-N-[[(3R)-3-morpholin-4-ylthiolan-3-yl]methyl]propanamide —— C19H27FN2O2S2
    (2S)-3-(4-fluorophenyl)sulfanyl-2-methyl-N-[[(3R)-3-morpholin-4-ylthiolan-3-yl]methyl]propanamide
    —— N-cyclopropyl-2-[(1S)-1-(2,6-difluorophenyl)ethyl]sulfanyl-5-nitropyrimidin-4-amine —— C15H14F2N4O2S
    N-cyclopropyl-2-[(1S)-1-(2,6-difluorophenyl)ethyl]sulfanyl-5-nitropyrimidin-4-amine
    —— 1-bromo-2-[(2S)-2-methyl-3-methylsulfonylpropyl]sulfanylbenzene —— C11H15BrO2S2
    1-bromo-2-[(2S)-2-methyl-3-methylsulfonylpropyl]sulfanylbenzene
    —— (2R)-3-(4-fluorophenyl)sulfanyl-2-methyl-N-[[(3S)-3-morpholin-4-ylthiolan-3-yl]methyl]propanamide —— C19H27FN2O2S2
    (2R)-3-(4-fluorophenyl)sulfanyl-2-methyl-N-[[(3S)-3-morpholin-4-ylthiolan-3-yl]methyl]propanamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-[(E)-2-methyl-3-phenylprop-2-enylidene]amino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide —— C19H19N11O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-[(E)-2-methyl-3-phenylprop-2-enylidene]amino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide
    —— (2R)-3-(4-fluorophenyl)sulfanyl-2-methyl-N-[[(3R)-3-morpholin-4-ylthiolan-3-yl]methyl]propanamide —— C19H27FN2O2S2
    (2R)-3-(4-fluorophenyl)sulfanyl-2-methyl-N-[[(3R)-3-morpholin-4-ylthiolan-3-yl]methyl]propanamide
    —— 1-bromo-2-[(2R)-2-methyl-3-methylsulfonylpropyl]sulfanylbenzene —— C11H15BrO2S2
    1-bromo-2-[(2R)-2-methyl-3-methylsulfonylpropyl]sulfanylbenzene
    —— (2S)-3-(4-fluorophenyl)sulfanyl-2-methyl-N-[[(3S)-3-morpholin-4-ylthiolan-3-yl]methyl]propanamide —— C19H27FN2O2S2
    (2S)-3-(4-fluorophenyl)sulfanyl-2-methyl-N-[[(3S)-3-morpholin-4-ylthiolan-3-yl]methyl]propanamide
    —— [(Z)-4-amino-3-cyano-2-oxopent-3-enyl] 3-phenylsulfanylpropanoate —— C15H16N2O3S
    [(Z)-4-amino-3-cyano-2-oxopent-3-enyl] 3-phenylsulfanylpropanoate
    —— (4E)-5-{[(4-chlorophenyl)sulfanyl]methyl}-4-[4-(dimethylamino)benzylidene]-2-phenyl-2,4-dihydro-3H-pyrazol-3-one —— C25H22ClN3OS
    (4E)-5-{[(4-chlorophenyl)sulfanyl]methyl}-4-[4-(dimethylamino)benzylidene]-2-phenyl-2,4-dihydro-3H-pyrazol-3-one
    —— 3-cyclopropyl-5-[(2S)-4-phenylsulfanylbutan-2-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazole —— C18H23N3S2
    3-cyclopropyl-5-[(2S)-4-phenylsulfanylbutan-2-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazole
    —— 3-cyclopropyl-5-[(2R)-4-phenylsulfanylbutan-2-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazole —— C18H23N3S2
    3-cyclopropyl-5-[(2R)-4-phenylsulfanylbutan-2-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazole
    —— N-[(Z)-1-(4-chlorophenyl)ethylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide —— C16H17ClN4OS
    N-[(Z)-1-(4-chlorophenyl)ethylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide