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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (3R)-1-methyl-3-pyridin-4-ylsulfanylpyrrolidin-2-one —— C10H12N2OS
    (3R)-1-methyl-3-pyridin-4-ylsulfanylpyrrolidin-2-one
    —— (3S)-1-methyl-3-thiophen-2-ylsulfanylpyrrolidin-2-one —— C9H11NOS2
    (3S)-1-methyl-3-thiophen-2-ylsulfanylpyrrolidin-2-one
    —— (3S)-1-methyl-3-pyridin-4-ylsulfanylpyrrolidin-2-one —— C10H12N2OS
    (3S)-1-methyl-3-pyridin-4-ylsulfanylpyrrolidin-2-one
    —— (1R,6S)-9-methyl-N-[3-(1,3-thiazol-2-ylsulfanyl)propyl]-3,9-diazabicyclo[4.2.1]nonane-3-carboxamide —— C15H24N4OS2
    (1R,6S)-9-methyl-N-[3-(1,3-thiazol-2-ylsulfanyl)propyl]-3,9-diazabicyclo[4.2.1]nonane-3-carboxamide
    —— (2R)-N-[(2-chloro-6-fluorophenyl)methyl]-2-(6-chloropyridazin-3-yl)sulfanyl-N-methylpropanamide —— C15H14Cl2FN3OS
    (2R)-N-[(2-chloro-6-fluorophenyl)methyl]-2-(6-chloropyridazin-3-yl)sulfanyl-N-methylpropanamide
    —— (2S)-N-[(2-chloro-6-fluorophenyl)methyl]-2-(6-chloropyridazin-3-yl)sulfanyl-N-methylpropanamide —— C15H14Cl2FN3OS
    (2S)-N-[(2-chloro-6-fluorophenyl)methyl]-2-(6-chloropyridazin-3-yl)sulfanyl-N-methylpropanamide
    —— (2R)-N-(2-cyanoethyl)-2-(2-hydroxyphenyl)sulfanyl-N-methylpropanamide —— C13H16N2O2S
    (2R)-N-(2-cyanoethyl)-2-(2-hydroxyphenyl)sulfanyl-N-methylpropanamide
    —— (1S,2S)-N-methyl-2-methylsulfonyl-N-(2,2,2-trifluoroethyl)cyclopentan-1-amine —— C9H16F3NO2S
    (1S,2S)-N-methyl-2-methylsulfonyl-N-(2,2,2-trifluoroethyl)cyclopentan-1-amine
    —— (2S)-N-(2-cyanoethyl)-2-(2-hydroxyphenyl)sulfanyl-N-methylpropanamide —— C13H16N2O2S
    (2S)-N-(2-cyanoethyl)-2-(2-hydroxyphenyl)sulfanyl-N-methylpropanamide
    —— (1R,2S)-N-methyl-2-methylsulfonyl-N-(2,2,2-trifluoroethyl)cyclopentan-1-amine —— C9H16F3NO2S
    (1R,2S)-N-methyl-2-methylsulfonyl-N-(2,2,2-trifluoroethyl)cyclopentan-1-amine
    —— 2-ethylsulfanyl-5-[(2R)-1,1,1-trifluoropropan-2-yl]sulfanyl-1,3,4-thiadiazole —— C7H9F3N2S3
    2-ethylsulfanyl-5-[(2R)-1,1,1-trifluoropropan-2-yl]sulfanyl-1,3,4-thiadiazole
    —— [(2S)-1-oxo-1-(2-phenylsulfanylanilino)propan-2-yl] 4-ethylthiadiazole-5-carboxylate —— C20H19N3O3S2
    [(2S)-1-oxo-1-(2-phenylsulfanylanilino)propan-2-yl] 4-ethylthiadiazole-5-carboxylate
    —— 2-[(1S)-1-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C12H13N5OS2
    2-[(1S)-1-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— (3R)-3-[(5-ethyl-1H-imidazol-2-yl)sulfanylmethyl]-1-methylsulfonylpiperidine —— C12H21N3O2S2
    (3R)-3-[(5-ethyl-1H-imidazol-2-yl)sulfanylmethyl]-1-methylsulfonylpiperidine
    —— (3S)-3-[(5-ethyl-1H-imidazol-2-yl)sulfanylmethyl]-1-methylsulfonylpiperidine —— C12H21N3O2S2
    (3S)-3-[(5-ethyl-1H-imidazol-2-yl)sulfanylmethyl]-1-methylsulfonylpiperidine
    —— 2-[(1R)-1-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C12H13N5OS2
    2-[(1R)-1-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— [(2R)-1-oxo-1-(2-phenylsulfanylanilino)propan-2-yl] 4-ethylthiadiazole-5-carboxylate —— C20H19N3O3S2
    [(2R)-1-oxo-1-(2-phenylsulfanylanilino)propan-2-yl] 4-ethylthiadiazole-5-carboxylate
    —— 5-tert-butyl-2-[(1R)-1-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,3-oxazole —— C13H20N4OS
    5-tert-butyl-2-[(1R)-1-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,3-oxazole
    —— N-[2-[[(1R)-1-(4-ethylsulfanylphenyl)ethyl]carbamoylamino]ethyl]acetamide —— C15H23N3O2S
    N-[2-[[(1R)-1-(4-ethylsulfanylphenyl)ethyl]carbamoylamino]ethyl]acetamide
    —— 5-tert-butyl-2-[(1S)-1-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,3-oxazole —— C13H20N4OS
    5-tert-butyl-2-[(1S)-1-[(5-ethyl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,3-oxazole
    —— 5-ethyl-3-[(2S)-5-methoxypentan-2-yl]sulfanyl-1H-1,2,4-triazole —— C10H19N3OS
    5-ethyl-3-[(2S)-5-methoxypentan-2-yl]sulfanyl-1H-1,2,4-triazole
    —— 5-ethyl-3-[(2R)-5-methoxypentan-2-yl]sulfanyl-1H-1,2,4-triazole —— C10H19N3OS
    5-ethyl-3-[(2R)-5-methoxypentan-2-yl]sulfanyl-1H-1,2,4-triazole
    —— 2-ethylsulfanyl-5-[(2S)-1,1,1-trifluoropropan-2-yl]sulfanyl-1,3,4-thiadiazole —— C7H9F3N2S3
    2-ethylsulfanyl-5-[(2S)-1,1,1-trifluoropropan-2-yl]sulfanyl-1,3,4-thiadiazole
    —— N-[2-[[(1S)-1-(4-ethylsulfanylphenyl)ethyl]carbamoylamino]ethyl]acetamide —— C15H23N3O2S
    N-[2-[[(1S)-1-(4-ethylsulfanylphenyl)ethyl]carbamoylamino]ethyl]acetamide
    —— 1-[(2S)-1-ethylsulfonylpropan-2-yl]-3-(2,4,4-trimethylpentan-2-yl)urea —— C14H30N2O3S
    1-[(2S)-1-ethylsulfonylpropan-2-yl]-3-(2,4,4-trimethylpentan-2-yl)urea
    —— 1-[(2R)-1-ethylsulfonylpropan-2-yl]-3-(2,4,4-trimethylpentan-2-yl)urea —— C14H30N2O3S
    1-[(2R)-1-ethylsulfonylpropan-2-yl]-3-(2,4,4-trimethylpentan-2-yl)urea
    —— 2-((4-Chlorophenyl)thio)-8-methylquinoline-3-carbaldehyde —— C17H12ClNOS
    2-((4-Chlorophenyl)thio)-8-methylquinoline-3-carbaldehyde
    —— 6-Ethoxy-2-p-tolylsulfanyl-quinoline-3-carbaldehyde —— C19H17NO2S
    6-Ethoxy-2-p-tolylsulfanyl-quinoline-3-carbaldehyde
    —— 8-Methyl-2-phenylsulfanyl-quinoline-3-carbaldehyde —— C17H13NOS
    8-Methyl-2-phenylsulfanyl-quinoline-3-carbaldehyde
    —— 2-((4-Chlorophenyl)thio)-6-ethoxyquinoline-3-carbaldehyde —— C18H14ClNO2S
    2-((4-Chlorophenyl)thio)-6-ethoxyquinoline-3-carbaldehyde
    —— 6-Ethoxy-2-phenylsulfanyl-quinoline-3-carbaldehyde —— C18H15NO2S
    6-Ethoxy-2-phenylsulfanyl-quinoline-3-carbaldehyde
    —— 7-Methyl-2-phenylsulfanyl-quinoline-3-carbaldehyde —— C17H13NOS
    7-Methyl-2-phenylsulfanyl-quinoline-3-carbaldehyde
    —— ethyl (2S)-2-([1,3]thiazolo[4,5-b]pyridin-2-ylsulfanyl)propanoate —— C11H12N2O2S2
    ethyl (2S)-2-([1,3]thiazolo[4,5-b]pyridin-2-ylsulfanyl)propanoate
    —— ethyl (2R)-2-([1,3]thiazolo[4,5-b]pyridin-2-ylsulfanyl)propanoate —— C11H12N2O2S2
    ethyl (2R)-2-([1,3]thiazolo[4,5-b]pyridin-2-ylsulfanyl)propanoate
    —— (2R)-3-[2-[(3S,5S)-3,5-dimethylcyclohexyl]ethylsulfonyl]propane-1,2-diol —— C13H26O4S
    (2R)-3-[2-[(3S,5S)-3,5-dimethylcyclohexyl]ethylsulfonyl]propane-1,2-diol
    —— (2R)-3-[2-[(3S,5R)-3,5-dimethylcyclohexyl]ethylsulfonyl]propane-1,2-diol —— C13H26O4S
    (2R)-3-[2-[(3S,5R)-3,5-dimethylcyclohexyl]ethylsulfonyl]propane-1,2-diol
    —— (2R)-3-[2-[(3R,5R)-3,5-dimethylcyclohexyl]ethylsulfonyl]propane-1,2-diol —— C13H26O4S
    (2R)-3-[2-[(3R,5R)-3,5-dimethylcyclohexyl]ethylsulfonyl]propane-1,2-diol
    —— 1,2-Dimethyl-3-[(5-methyl-1,2,4-oxadiazol-3-yl)methyl]-1-[(4-methylsulfanylphenyl)methyl]guanidine —— C15H21N5OS
    1,2-Dimethyl-3-[(5-methyl-1,2,4-oxadiazol-3-yl)methyl]-1-[(4-methylsulfanylphenyl)methyl]guanidine
    —— N-phenethyl-2-((6-(pyridin-4-yl)pyridazin-3-yl)thio)acetamide —— C19H18N4OS
    N-phenethyl-2-((6-(pyridin-4-yl)pyridazin-3-yl)thio)acetamide
    —— 3-Benzylsulfanyl-6-(furan-2-yl)pyridazine —— C15H12N2OS
    3-Benzylsulfanyl-6-(furan-2-yl)pyridazine
    —— Ethyl 2-((3-(p-tolyl)-1,2,4-thiadiazol-5-yl)thio)acetate —— C13H14N2O2S2
    Ethyl 2-((3-(p-tolyl)-1,2,4-thiadiazol-5-yl)thio)acetate
    —— 3-(Benzylthio)-6-(pyridin-4-yl)pyridazine —— C16H13N3S
    3-(Benzylthio)-6-(pyridin-4-yl)pyridazine
    —— 3-(benzylthio)-6-methyl-N-(p-tolyl)-1,2,4-triazin-5-amine —— C18H18N4S
    3-(benzylthio)-6-methyl-N-(p-tolyl)-1,2,4-triazin-5-amine
    —— 2-[(1R)-1-[3-[(4-fluorophenyl)methyl]-1,2,4-oxadiazol-5-yl]ethyl]sulfanylpyridine-4-carbonitrile —— C17H13FN4OS
    2-[(1R)-1-[3-[(4-fluorophenyl)methyl]-1,2,4-oxadiazol-5-yl]ethyl]sulfanylpyridine-4-carbonitrile
    —— 6-[(5-Cyclohexylsulfanylfuran-2-yl)methylidene]-5-imino-[1,3]thiazolo[3,2-a]pyrimidin-7-one —— C17H17N3O2S2
    6-[(5-Cyclohexylsulfanylfuran-2-yl)methylidene]-5-imino-[1,3]thiazolo[3,2-a]pyrimidin-7-one
    —— 2-[(1S)-1-[3-[(4-fluorophenyl)methyl]-1,2,4-oxadiazol-5-yl]ethyl]sulfanylpyridine-4-carbonitrile —— C17H13FN4OS
    2-[(1S)-1-[3-[(4-fluorophenyl)methyl]-1,2,4-oxadiazol-5-yl]ethyl]sulfanylpyridine-4-carbonitrile
    —— 5-[(5-Benzylsulfanylfuran-2-yl)methylidene]-3-methyl-2-sulfanylidene-1,3-thiazolidin-4-one —— C16H13NO2S3
    5-[(5-Benzylsulfanylfuran-2-yl)methylidene]-3-methyl-2-sulfanylidene-1,3-thiazolidin-4-one
    —— 6-Cyclopenta-1,4-dien-1-ylhexane-1-thiol —— C11H18S
    6-Cyclopenta-1,4-dien-1-ylhexane-1-thiol
    —— 2-{[3-(prop-2-en-1-yl)-2-sulfanylidene-2H,3H-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]sulfanyl}acetamide —— C10H10N4OS3
    2-{[3-(prop-2-en-1-yl)-2-sulfanylidene-2H,3H-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]sulfanyl}acetamide
    —— 3-Acetyl-2-imino-5-[(2-phenylsulfanylquinolin-3-yl)methylidene]-1,3-thiazolidin-4-one —— C21H15N3O2S2
    3-Acetyl-2-imino-5-[(2-phenylsulfanylquinolin-3-yl)methylidene]-1,3-thiazolidin-4-one