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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [(1R)-1-[4-butyl-5-[2-[2-(4-fluorophenyl)ethylamino]-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C21H33FN5OS+
    [(1R)-1-[4-butyl-5-[2-[2-(4-fluorophenyl)ethylamino]-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— [(1S)-1-[4-benzyl-5-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C22H28FN4S+
    [(1S)-1-[4-benzyl-5-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— [(1R)-1-[4-benzyl-5-[(1S)-1-(4-fluorophenyl)ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C22H28FN4S+
    [(1R)-1-[4-benzyl-5-[(1S)-1-(4-fluorophenyl)ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— (2S)-2-[[4-butyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-carbamoyl-3-methylbutanamide —— C17H32N6O2S
    (2S)-2-[[4-butyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-carbamoyl-3-methylbutanamide
    —— 2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-(3-methylbutyl)acetamide —— C21H33N5OS
    2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-(3-methylbutyl)acetamide
    —— 2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-cyclopentylacetamide —— C21H31N5OS
    2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-cyclopentylacetamide
    —— 2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methoxyethyl)acetamide —— C19H29N5O2S
    2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methoxyethyl)acetamide
    —— (1R,2R)-1,2-bis(methylsulfonyl)ethane-1,2-diol —— C4H10O6S2
    (1R,2R)-1,2-bis(methylsulfonyl)ethane-1,2-diol
    —— (1S,2R)-1,2-bis(methylsulfonyl)ethane-1,2-diol —— C4H10O6S2
    (1S,2R)-1,2-bis(methylsulfonyl)ethane-1,2-diol
    —— (2R)-N-[(E)-3,3-dimethylbutan-2-ylideneamino]-2-pyrimidin-2-ylsulfanylpropanamide —— C13H20N4OS
    (2R)-N-[(E)-3,3-dimethylbutan-2-ylideneamino]-2-pyrimidin-2-ylsulfanylpropanamide
    —— (1S,2S)-1,2-bis(methylsulfonyl)ethane-1,2-diol —— C4H10O6S2
    (1S,2S)-1,2-bis(methylsulfonyl)ethane-1,2-diol
    —— (2R)-2-ethanimidoyl-4-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-oxobutanenitrile —— C15H14N4O2S
    (2R)-2-ethanimidoyl-4-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-oxobutanenitrile
    —— 2-(2-methylphenyl)sulfanyl-N-[[(3R)-1-pyrimidin-2-ylpiperidin-3-yl]methyl]acetamide —— C19H24N4OS
    2-(2-methylphenyl)sulfanyl-N-[[(3R)-1-pyrimidin-2-ylpiperidin-3-yl]methyl]acetamide
    —— 2-[(2,4-Difluorophenyl)methylsulfanyl]-3,6-dimethyl-5-[(2-methylphenyl)methyl]pyrimidin-4-one —— C21H20F2N2OS
    2-[(2,4-Difluorophenyl)methylsulfanyl]-3,6-dimethyl-5-[(2-methylphenyl)methyl]pyrimidin-4-one
    —— 2-(2-methylphenyl)sulfanyl-N-[[(3S)-1-pyrimidin-2-ylpiperidin-3-yl]methyl]acetamide —— C19H24N4OS
    2-(2-methylphenyl)sulfanyl-N-[[(3S)-1-pyrimidin-2-ylpiperidin-3-yl]methyl]acetamide
    —— 3-[(1S)-1-(2-fluorophenyl)ethyl]sulfanyl-1-(2-methylpropyl)pyrazin-2-one —— C16H19FN2OS
    3-[(1S)-1-(2-fluorophenyl)ethyl]sulfanyl-1-(2-methylpropyl)pyrazin-2-one
    —— [5-(3-Chloro-2-methylphenyl)furan-2-yl]methyl-[2-(1-methyltetrazol-5-yl)sulfanylethyl]azanium —— C16H19ClN5OS+
    [5-(3-Chloro-2-methylphenyl)furan-2-yl]methyl-[2-(1-methyltetrazol-5-yl)sulfanylethyl]azanium
    —— 3-[(1R)-1-(2-fluorophenyl)ethyl]sulfanyl-1-(2-methylpropyl)pyrazin-2-one —— C16H19FN2OS
    3-[(1R)-1-(2-fluorophenyl)ethyl]sulfanyl-1-(2-methylpropyl)pyrazin-2-one
    —— 3-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-1-(2-methylpropyl)pyrazin-2-one —— C16H19FN2OS
    3-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-1-(2-methylpropyl)pyrazin-2-one
    —— 3-[(1S)-1-(4-fluorophenyl)ethyl]sulfanyl-1-(2-methylpropyl)pyrazin-2-one —— C16H19FN2OS
    3-[(1S)-1-(4-fluorophenyl)ethyl]sulfanyl-1-(2-methylpropyl)pyrazin-2-one
    —— (4-methylsulfanylphenyl)methyl-(2H-tetrazol-5-yl)azanide —— C9H10N5S-
    (4-methylsulfanylphenyl)methyl-(2H-tetrazol-5-yl)azanide
    —— 4-[2-[(6-Phenyl-1,2,4-triazin-3-yl)sulfanyl]ethyl]morpholin-4-ium —— C15H19N4OS+
    4-[2-[(6-Phenyl-1,2,4-triazin-3-yl)sulfanyl]ethyl]morpholin-4-ium
    —— (2R,6S)-N,2,6-trimethyl-N-[(4-methylsulfanylphenyl)methyl]oxane-4-carboxamide —— C17H25NO2S
    (2R,6S)-N,2,6-trimethyl-N-[(4-methylsulfanylphenyl)methyl]oxane-4-carboxamide
    —— (2S,6S)-N,2,6-trimethyl-N-[(4-methylsulfanylphenyl)methyl]oxane-4-carboxamide —— C17H25NO2S
    (2S,6S)-N,2,6-trimethyl-N-[(4-methylsulfanylphenyl)methyl]oxane-4-carboxamide
    —— 2-Ethanimidoyl-4-(2-fluorophenyl)sulfanyl-3-oxobutanenitrile —— C12H11FN2OS
    2-Ethanimidoyl-4-(2-fluorophenyl)sulfanyl-3-oxobutanenitrile
    —— (6S)-4-methyl-5-[3-(4-methylphenyl)-2H-1,2,4-oxadiazol-5-ylidene]-6-(4-methylsulfanylphenyl)-1,6-dihydropyrimidine-2-thione —— C21H20N4OS2
    (6S)-4-methyl-5-[3-(4-methylphenyl)-2H-1,2,4-oxadiazol-5-ylidene]-6-(4-methylsulfanylphenyl)-1,6-dihydropyrimidine-2-thione
    —— (2R,6R)-N,2,6-trimethyl-N-[(4-methylsulfanylphenyl)methyl]oxane-4-carboxamide —— C17H25NO2S
    (2R,6R)-N,2,6-trimethyl-N-[(4-methylsulfanylphenyl)methyl]oxane-4-carboxamide
    —— N-[[(1R)-cyclohex-3-en-1-yl]methyl]-N,2-dimethyl-2-methylsulfonylpropan-1-amine —— C13H25NO2S
    N-[[(1R)-cyclohex-3-en-1-yl]methyl]-N,2-dimethyl-2-methylsulfonylpropan-1-amine
    —— N-[[(1S)-cyclohex-3-en-1-yl]methyl]-N,2-dimethyl-2-methylsulfonylpropan-1-amine —— C13H25NO2S
    N-[[(1S)-cyclohex-3-en-1-yl]methyl]-N,2-dimethyl-2-methylsulfonylpropan-1-amine
    —— (2R)-N-(cyclododecylideneamino)-2-(4,6-dimethylpyrimidin-2-yl)sulfanylpropanamide —— C21H34N4OS
    (2R)-N-(cyclododecylideneamino)-2-(4,6-dimethylpyrimidin-2-yl)sulfanylpropanamide
    —— 2-[[(1R)-2,2-dichlorocyclopropyl]methylsulfanyl]-5-phenyl-1,3,4-oxadiazole —— C12H10Cl2N2OS
    2-[[(1R)-2,2-dichlorocyclopropyl]methylsulfanyl]-5-phenyl-1,3,4-oxadiazole
    —— (2R)-5-ethoxy-2-[C-methyl-N-(2-phenylethyl)carbonimidoyl]-1-benzothiophen-3-one —— C20H21NO2S
    (2R)-5-ethoxy-2-[C-methyl-N-(2-phenylethyl)carbonimidoyl]-1-benzothiophen-3-one
    —— 5-[(2Z)-2-[(2-fluorophenyl)methylidene]hydrazinyl]-3-methylsulfanyl-1,2-thiazole-4-carbonitrile —— C12H9FN4S2
    5-[(2Z)-2-[(2-fluorophenyl)methylidene]hydrazinyl]-3-methylsulfanyl-1,2-thiazole-4-carbonitrile
    —— 5-Benzyl-3,6-dimethyl-2-(2-morpholin-4-yl-2-oxoethyl)sulfanylpyrimidin-4-one —— C19H23N3O3S
    5-Benzyl-3,6-dimethyl-2-(2-morpholin-4-yl-2-oxoethyl)sulfanylpyrimidin-4-one
    —— 3-methyl-2-[[1-[[(2S)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylmethyl]pyridine —— C13H17N5OS
    3-methyl-2-[[1-[[(2S)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylmethyl]pyridine
    —— 5-[(3-methylpyridin-2-yl)methylsulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine —— C14H18N4OS2
    5-[(3-methylpyridin-2-yl)methylsulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine
    —— 3-methyl-2-[[1-[[(2R)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylmethyl]pyridine —— C13H17N5OS
    3-methyl-2-[[1-[[(2R)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylmethyl]pyridine
    —— 5-[(3-methylpyridin-2-yl)methylsulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine —— C14H18N4OS2
    5-[(3-methylpyridin-2-yl)methylsulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]-1,3,4-thiadiazol-2-amine
    —— 3-[(3-methylpyridin-2-yl)methylsulfanyl]-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one —— C14H18N4O2S
    3-[(3-methylpyridin-2-yl)methylsulfanyl]-4-[[(2R)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one
    —— 3-[(3-methylpyridin-2-yl)methylsulfanyl]-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one —— C14H18N4O2S
    3-[(3-methylpyridin-2-yl)methylsulfanyl]-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-5-one
    —— (8R,8aS)-2-ethyl-6-imino-8-(4-methylsulfanylphenyl)-3,5,8,8a-tetrahydro-1H-isoquinoline-5,7,7-tricarbonitrile —— C21H21N5S
    (8R,8aS)-2-ethyl-6-imino-8-(4-methylsulfanylphenyl)-3,5,8,8a-tetrahydro-1H-isoquinoline-5,7,7-tricarbonitrile
    —— [(2S)-5-ethoxy-3-oxo-1-benzothiophen-2-yl]methylidene-(2-methylpropyl)azanium —— C15H20NO2S+
    [(2S)-5-ethoxy-3-oxo-1-benzothiophen-2-yl]methylidene-(2-methylpropyl)azanium
    —— 6-Ethyl-2-[(3-fluorophenyl)methylsulfanyl]-3-methylpyrimidin-4-one —— C14H15FN2OS
    6-Ethyl-2-[(3-fluorophenyl)methylsulfanyl]-3-methylpyrimidin-4-one
    —— (8R,8aS)-6-imino-8-(4-methylsulfanylphenyl)-2-propyl-3,5,8,8a-tetrahydro-1H-isoquinoline-5,7,7-tricarbonitrile —— C22H23N5S
    (8R,8aS)-6-imino-8-(4-methylsulfanylphenyl)-2-propyl-3,5,8,8a-tetrahydro-1H-isoquinoline-5,7,7-tricarbonitrile
    —— (2R)-2-methyl-3-[(2-methylsulfanyl-[1,3]thiazolo[4,5-d]pyrimidin-7-yl)sulfanyl]propan-1-ol —— C10H13N3OS3
    (2R)-2-methyl-3-[(2-methylsulfanyl-[1,3]thiazolo[4,5-d]pyrimidin-7-yl)sulfanyl]propan-1-ol
    —— 5-[[4-cyclopropyl-5-[(3S)-piperidin-3-yl]-1,2,4-triazol-3-yl]sulfanyl]-3-ethyl-1,2,4-thiadiazole —— C14H20N6S2
    5-[[4-cyclopropyl-5-[(3S)-piperidin-3-yl]-1,2,4-triazol-3-yl]sulfanyl]-3-ethyl-1,2,4-thiadiazole
    —— 5-[[4-cyclopropyl-5-[(3R)-piperidin-3-yl]-1,2,4-triazol-3-yl]sulfanyl]-3-ethyl-1,2,4-thiadiazole —— C14H20N6S2
    5-[[4-cyclopropyl-5-[(3R)-piperidin-3-yl]-1,2,4-triazol-3-yl]sulfanyl]-3-ethyl-1,2,4-thiadiazole
    —— (2S)-2-methyl-3-[(2-methylsulfanyl-[1,3]thiazolo[4,5-d]pyrimidin-7-yl)sulfanyl]propan-1-ol —— C10H13N3OS3
    (2S)-2-methyl-3-[(2-methylsulfanyl-[1,3]thiazolo[4,5-d]pyrimidin-7-yl)sulfanyl]propan-1-ol
    —— (5S,7S)-5,7-dimethyl-2-sulfanylidene-[1,3]dithiolo[4,5-b][1,4]dithiepin-6-one —— C8H8OS5
    (5S,7S)-5,7-dimethyl-2-sulfanylidene-[1,3]dithiolo[4,5-b][1,4]dithiepin-6-one
    —— ethyl (2S)-2-[5-[(3-fluorophenyl)methyl]-1,4-dimethyl-6-oxopyrimidin-2-yl]sulfanylpropanoate —— C18H21FN2O3S
    ethyl (2S)-2-[5-[(3-fluorophenyl)methyl]-1,4-dimethyl-6-oxopyrimidin-2-yl]sulfanylpropanoate