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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Methyl 4-bromo-5-(phenylthio)furan-2-carboxylate —— C12H9BrO3S
    Methyl 4-bromo-5-(phenylthio)furan-2-carboxylate
    —— 4-Bromo-5-phenylsulfanyl-furan-2-carboxylic acid —— C11H7BrO3S
    4-Bromo-5-phenylsulfanyl-furan-2-carboxylic acid
    —— 5-Phenylmercaptomethyl-furfural 3260-99-9 C12H10O2S
    5-Phenylmercaptomethyl-furfural
    —— 1-(5-Bromothiophen-2-yl)-2-[(5,6-dipyridin-2-yl-1,2,4-triazin-3-yl)sulfanyl]ethanone —— C19H12BrN5OS2
    1-(5-Bromothiophen-2-yl)-2-[(5,6-dipyridin-2-yl-1,2,4-triazin-3-yl)sulfanyl]ethanone
    —— N-Cyclohexyl-2-(6-methyl-5-oxo-4,5-dihydro-[1,2,4]triazin-3-ylsulfanyl)-propionamide —— C13H20N4O2S
    N-Cyclohexyl-2-(6-methyl-5-oxo-4,5-dihydro-[1,2,4]triazin-3-ylsulfanyl)-propionamide
    —— 5-(Pyridin-2-ylsulfanylmethyl)-furan-2-carbaldehyde 685904-13-6 C11H9NO2S
    5-(Pyridin-2-ylsulfanylmethyl)-furan-2-carbaldehyde
    —— N-[2-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]oxolane-2-carboxamide —— C17H22N4O2S
    N-[2-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]oxolane-2-carboxamide
    —— 2-[(5-Benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-1-(4-methylpiperazin-1-yl)ethanone —— C16H20N4O2S
    2-[(5-Benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-1-(4-methylpiperazin-1-yl)ethanone
    —— 3-[4-Ethyl-5-(2-pyrrolidin-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]-1-methylsulfonylpiperidine —— C16H29N5O2S2
    3-[4-Ethyl-5-(2-pyrrolidin-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]-1-methylsulfonylpiperidine
    —— 1-Benzyl-3-[(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]urea —— C14H19N5OS
    1-Benzyl-3-[(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]urea
    —— 1-Cyclohexyl-3-[2-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]urea —— C14H25N5OS
    1-Cyclohexyl-3-[2-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]urea
    —— 3-[1-(Furan-2-ylmethyl)pyrrolidin-2-yl]-4-methyl-5-(2-pyrrolidin-1-ylethylsulfanyl)-1,2,4-triazole —— C18H27N5OS
    3-[1-(Furan-2-ylmethyl)pyrrolidin-2-yl]-4-methyl-5-(2-pyrrolidin-1-ylethylsulfanyl)-1,2,4-triazole
    —— N-[2-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]-4-methylcyclohexan-1-amine —— C14H26N4S
    N-[2-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]-4-methylcyclohexan-1-amine
    —— [2-(5-Ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)pyrrolidin-1-yl]-(4-methoxycyclohexyl)methanone —— C17H28N4O2S
    [2-(5-Ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)pyrrolidin-1-yl]-(4-methoxycyclohexyl)methanone
    —— 1-Cyclohexyl-3-[2-(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethyl]urea —— C14H25N5OS
    1-Cyclohexyl-3-[2-(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethyl]urea
    —— 3-[[3-(5-Ethylsulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl)piperidin-1-yl]methyl]pyridine —— C18H27N5S
    3-[[3-(5-Ethylsulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl)piperidin-1-yl]methyl]pyridine
    —— 1-Benzyl-3-[(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]urea —— C13H17N5OS
    1-Benzyl-3-[(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]urea
    —— 1-(Isothiocyanatomethyl)-3-methylcyclobutane —— C7H11NS
    1-(Isothiocyanatomethyl)-3-methylcyclobutane
    —— N-cycloheptyl-2-[[5-(5-methyl-1,2-oxazol-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C15H20N4O3S
    N-cycloheptyl-2-[[5-(5-methyl-1,2-oxazol-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— (3-Methylcyclobutyl)methylthiourea —— C7H14N2S
    (3-Methylcyclobutyl)methylthiourea
    —— 1-(Methoxymethyl)cyclobutane-1-carbothioamide —— C7H13NOS
    1-(Methoxymethyl)cyclobutane-1-carbothioamide
    —— 1-Phenylsulfanylmethyl-cyclobutanecarboxylic acid —— C12H14O2S
    1-Phenylsulfanylmethyl-cyclobutanecarboxylic acid
    —— 2-Isobutylsulfanyl-pyrimidine-5-carbaldehyde —— C9H12N2OS
    2-Isobutylsulfanyl-pyrimidine-5-carbaldehyde
    —— 1-(Phenylsulfanylmethyl)cyclobutane-1-carbonitrile —— C12H13NS
    1-(Phenylsulfanylmethyl)cyclobutane-1-carbonitrile
    —— 4-Phenylsulfanylmethyl-tetrahydro-pyran-4-carboxylic acid —— C13H16O3S
    4-Phenylsulfanylmethyl-tetrahydro-pyran-4-carboxylic acid
    —— 3-(1-methyltetrazol-5-yl)sulfanyl-N-(thiophen-3-ylmethyl)propan-1-amine —— C10H15N5S2
    3-(1-methyltetrazol-5-yl)sulfanyl-N-(thiophen-3-ylmethyl)propan-1-amine
    —— 4-Phenylsulfanylmethyl-tetrahydro-pyran-4-carbonitrile —— C13H15NOS
    4-Phenylsulfanylmethyl-tetrahydro-pyran-4-carbonitrile
    —— 2-[(5-Pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]-1-pyrrolidin-1-ylethanone —— C13H14N4O2S
    2-[(5-Pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]-1-pyrrolidin-1-ylethanone
    —— (3R,3aR,7E)-2,5-dimethyl-3-(4-methylsulfanylphenyl)-7-[(4-methylsulfanylphenyl)methylidene]-3,3a,4,6-tetrahydropyrazolo[4,3-c]pyridine —— C23H27N3S2
    (3R,3aR,7E)-2,5-dimethyl-3-(4-methylsulfanylphenyl)-7-[(4-methylsulfanylphenyl)methylidene]-3,3a,4,6-tetrahydropyrazolo[4,3-c]pyridine
    —— [6-(cyclopropylamino)-5-nitro-pyrimidin-4-yl] N,N-diethylcarbamodithioate —— C12H17N5O2S2
    [6-(cyclopropylamino)-5-nitro-pyrimidin-4-yl] N,N-diethylcarbamodithioate
    —— [6-(Methylamino)-5-nitro-pyrimidin-4-yl] pyrrolidine-1-carbodithioate —— C10H13N5O2S2
    [6-(Methylamino)-5-nitro-pyrimidin-4-yl] pyrrolidine-1-carbodithioate
    —— 4-Tert-butyl-2-(chloromethylsulfanyl)pyrimidine —— C9H13ClN2S
    4-Tert-butyl-2-(chloromethylsulfanyl)pyrimidine
    —— (2R)-2-amino-3,4-dihydro-2H-[1,3]thiazolo[4,5-b]pyridin-5-one —— C6H7N3OS
    (2R)-2-amino-3,4-dihydro-2H-[1,3]thiazolo[4,5-b]pyridin-5-one
    —— (2S)-2-amino-3,4-dihydro-2H-[1,3]thiazolo[4,5-b]pyridin-5-one —— C6H7N3OS
    (2S)-2-amino-3,4-dihydro-2H-[1,3]thiazolo[4,5-b]pyridin-5-one
    —— (7S)-7-methyl-1,4-thiazepane 1,1-dioxide —— C6H13NO2S
    (7S)-7-methyl-1,4-thiazepane 1,1-dioxide
    —— 2-[3-(3-Thiophen-2-yl-1,2,4-oxadiazol-5-yl)pyridin-2-yl]sulfanylacetic acid —— C13H9N3O3S2
    2-[3-(3-Thiophen-2-yl-1,2,4-oxadiazol-5-yl)pyridin-2-yl]sulfanylacetic acid
    —— (1S,7S)-7-methyl-1,4-thiazepane 1-oxide —— C6H13NOS
    (1S,7S)-7-methyl-1,4-thiazepane 1-oxide
    —— (1R,7R)-7-methyl-1,4-thiazepane 1-oxide —— C6H13NOS
    (1R,7R)-7-methyl-1,4-thiazepane 1-oxide
    —— 5-ethyl-1-[(E)-3-(2-furyl)allyl]-6-phenylsulfanyl-pyrimidine-2,4-dione —— C19H18N2O3S
    5-ethyl-1-[(E)-3-(2-furyl)allyl]-6-phenylsulfanyl-pyrimidine-2,4-dione
    —— 5-[(E)-4-(4-chlorophenyl)sulfanyl-4-(2-thienyl)but-2-enyl]-6-methyl-1,2,4-triazin-3-amine —— C18H17ClN4S2
    5-[(E)-4-(4-chlorophenyl)sulfanyl-4-(2-thienyl)but-2-enyl]-6-methyl-1,2,4-triazin-3-amine
    —— 1-[(E)-3-(2-Benzofuranyl)prop-2-en-1-yl]-6-(phenylthio)thymine —— C22H18N2O3S
    1-[(E)-3-(2-Benzofuranyl)prop-2-en-1-yl]-6-(phenylthio)thymine
    —— 3-[(5-Benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanoic acid —— C12H12N2O3S
    3-[(5-Benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanoic acid
    —— 2-{[3-cyano-4-(methoxymethyl)-6-methylpyridin-2-yl]sulfanyl}-N-(tricyclo[3.3.1.1~3,7~]dec-2-yl)acetamide —— C21H27N3O2S
    2-{[3-cyano-4-(methoxymethyl)-6-methylpyridin-2-yl]sulfanyl}-N-(tricyclo[3.3.1.1~3,7~]dec-2-yl)acetamide
    —— (1R,6S)-6-methyl-1,4-thiazepane 1-oxide —— C6H13NOS
    (1R,6S)-6-methyl-1,4-thiazepane 1-oxide
    —— (1S,7R)-7-methyl-1,4-thiazepane 1-oxide —— C6H13NOS
    (1S,7R)-7-methyl-1,4-thiazepane 1-oxide
    —— (7R)-7-methyl-1,4-thiazepane 1,1-dioxide —— C6H13NO2S
    (7R)-7-methyl-1,4-thiazepane 1,1-dioxide
    —— (6R)-6-methyl-1,4-thiazepane 1,1-dioxide —— C6H13NO2S
    (6R)-6-methyl-1,4-thiazepane 1,1-dioxide
    —— (1R,7S)-7-methyl-1,4-thiazepane 1-oxide —— C6H13NOS
    (1R,7S)-7-methyl-1,4-thiazepane 1-oxide
    —— N-(2-adamantyl)-2-(1-methylimidazol-2-yl)sulfanylacetamide —— C16H23N3OS
    N-(2-adamantyl)-2-(1-methylimidazol-2-yl)sulfanylacetamide
    —— (1R,6R)-6-methyl-1,4-thiazepane 1-oxide —— C6H13NOS
    (1R,6R)-6-methyl-1,4-thiazepane 1-oxide