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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylideneamino]phthalazin-1-amine —— C19H15N7O2S
    N-[[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylideneamino]phthalazin-1-amine
    —— 4-[1-(hydroxyamino)ethylidene]-2-methoxycyclohexa-2,5-diene-1-thione —— C9H11NO2S
    4-[1-(hydroxyamino)ethylidene]-2-methoxycyclohexa-2,5-diene-1-thione
    —— 2-(1-Anilinoethylidene)-3(2H)-benzo<b>thiophenone —— C16H13NOS
    2-(1-Anilinoethylidene)-3(2H)-benzo<b>thiophenone
    —— 1-[(1R)-1-(oxan-4-yl)ethyl]-3-(3-phenylsulfanylpropyl)urea —— C17H26N2O2S
    1-[(1R)-1-(oxan-4-yl)ethyl]-3-(3-phenylsulfanylpropyl)urea
    —— 1-[(1S)-1-(oxan-4-yl)ethyl]-3-(3-phenylsulfanylpropyl)urea —— C17H26N2O2S
    1-[(1S)-1-(oxan-4-yl)ethyl]-3-(3-phenylsulfanylpropyl)urea
    —— 5-tert-butyl-2-[(1S)-1-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,3-oxazole —— C14H22N4OS
    5-tert-butyl-2-[(1S)-1-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,3-oxazole
    —— 5-tert-butyl-2-[(1R)-1-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,3-oxazole —— C14H22N4OS
    5-tert-butyl-2-[(1R)-1-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,3-oxazole
    —— 2-[1-(4-hydroxyanilino)ethylidene]-1-benzothiophen-3-one —— C16H13NO2S
    2-[1-(4-hydroxyanilino)ethylidene]-1-benzothiophen-3-one
    —— 2-[(3,4-dimethylanilino)methylidene]-1-benzothiophen-3-one —— C17H15NOS
    2-[(3,4-dimethylanilino)methylidene]-1-benzothiophen-3-one
    —— 2-propan-2-yloxy-5-[(2R)-1,1,1-trifluoropropan-2-yl]sulfanyl-1,3,4-thiadiazole —— C8H11F3N2OS2
    2-propan-2-yloxy-5-[(2R)-1,1,1-trifluoropropan-2-yl]sulfanyl-1,3,4-thiadiazole
    —— 2-propan-2-yloxy-5-[(2S)-1,1,1-trifluoropropan-2-yl]sulfanyl-1,3,4-thiadiazole —— C8H11F3N2OS2
    2-propan-2-yloxy-5-[(2S)-1,1,1-trifluoropropan-2-yl]sulfanyl-1,3,4-thiadiazole
    —— 4-[2-[[(2R)-oxolan-2-yl]methoxy]ethylsulfanyl]pyridine —— C12H17NO2S
    4-[2-[[(2R)-oxolan-2-yl]methoxy]ethylsulfanyl]pyridine
    —— 2-[(3S)-2-oxo-3-pyridin-4-ylsulfanylpyrrolidin-1-yl]thiophene-3-carbonitrile —— C14H11N3OS2
    2-[(3S)-2-oxo-3-pyridin-4-ylsulfanylpyrrolidin-1-yl]thiophene-3-carbonitrile
    —— 2-[(3R)-2-oxo-3-pyridin-4-ylsulfanylpyrrolidin-1-yl]thiophene-3-carbonitrile —— C14H11N3OS2
    2-[(3R)-2-oxo-3-pyridin-4-ylsulfanylpyrrolidin-1-yl]thiophene-3-carbonitrile
    —— (3S)-N-(2-pyridin-2-ylsulfanylpyridin-4-yl)-1-(thiophene-2-carbonyl)piperidine-3-carboxamide —— C21H20N4O2S2
    (3S)-N-(2-pyridin-2-ylsulfanylpyridin-4-yl)-1-(thiophene-2-carbonyl)piperidine-3-carboxamide
    —— 4-[2-[[(2S)-oxolan-2-yl]methoxy]ethylsulfanyl]pyridine —— C12H17NO2S
    4-[2-[[(2S)-oxolan-2-yl]methoxy]ethylsulfanyl]pyridine
    —— (3R)-N-(2-pyridin-2-ylsulfanylpyridin-4-yl)-1-(thiophene-2-carbonyl)piperidine-3-carboxamide —— C21H20N4O2S2
    (3R)-N-(2-pyridin-2-ylsulfanylpyridin-4-yl)-1-(thiophene-2-carbonyl)piperidine-3-carboxamide
    —— [4-[(5-cyano-4-methyl-2,6-dioxopyridin-3-ylidene)methylamino]phenyl] thiocyanate —— C15H10N4O2S
    [4-[(5-cyano-4-methyl-2,6-dioxopyridin-3-ylidene)methylamino]phenyl] thiocyanate
    —— 3-[(3S)-2-oxo-1-propan-2-ylpyrrolidin-3-yl]sulfanyl-4-prop-2-enyl-1H-1,2,4-triazol-5-one —— C12H18N4O2S
    3-[(3S)-2-oxo-1-propan-2-ylpyrrolidin-3-yl]sulfanyl-4-prop-2-enyl-1H-1,2,4-triazol-5-one
    —— 2-[(2-oxo-1-benzothiophen-3-ylidene)amino]guanidine —— C9H8N4OS
    2-[(2-oxo-1-benzothiophen-3-ylidene)amino]guanidine
    —— [4-(2,2-difluoroethyl)piperazin-1-yl]-[(3S)-2,3-dihydro-1-benzothiophen-3-yl]methanone —— C15H18F2N2OS
    [4-(2,2-difluoroethyl)piperazin-1-yl]-[(3S)-2,3-dihydro-1-benzothiophen-3-yl]methanone
    —— [4-(2,2-difluoroethyl)piperazin-1-yl]-[(3R)-2,3-dihydro-1-benzothiophen-3-yl]methanone —— C15H18F2N2OS
    [4-(2,2-difluoroethyl)piperazin-1-yl]-[(3R)-2,3-dihydro-1-benzothiophen-3-yl]methanone
    —— (2S)-2-(6-chloropyridazin-3-yl)sulfanyl-N-methyl-N-propan-2-ylpropanamide —— C11H16ClN3OS
    (2S)-2-(6-chloropyridazin-3-yl)sulfanyl-N-methyl-N-propan-2-ylpropanamide
    —— (2R)-2-(6-chloropyridazin-3-yl)sulfanyl-N-methyl-N-propan-2-ylpropanamide —— C11H16ClN3OS
    (2R)-2-(6-chloropyridazin-3-yl)sulfanyl-N-methyl-N-propan-2-ylpropanamide
    —— N-[(3R)-6-oxopiperidin-3-yl]-2-phenylsulfanylbenzamide —— C18H18N2O2S
    N-[(3R)-6-oxopiperidin-3-yl]-2-phenylsulfanylbenzamide
    —— 2-phenylsulfanyl-1-[(3R)-3-(pyrrolidin-1-ylmethyl)pyrrolidin-1-yl]ethanone —— C17H24N2OS
    2-phenylsulfanyl-1-[(3R)-3-(pyrrolidin-1-ylmethyl)pyrrolidin-1-yl]ethanone
    —— 4-bromo-6-[[4-(4-nitrophenyl)sulfanylanilino]methylidene]cyclohexa-2,4-dien-1-one —— C19H13BrN2O3S
    4-bromo-6-[[4-(4-nitrophenyl)sulfanylanilino]methylidene]cyclohexa-2,4-dien-1-one
    —— 1-(4-ethoxyphenyl)-5-[[4-(4-nitrophenyl)sulfanylanilino]methylidene]-2-sulfanylidene-1,3-diazinane-4,6-dione —— C25H20N4O5S2
    1-(4-ethoxyphenyl)-5-[[4-(4-nitrophenyl)sulfanylanilino]methylidene]-2-sulfanylidene-1,3-diazinane-4,6-dione
    —— 2-phenylsulfanyl-1-[(3S)-3-(pyrrolidin-1-ylmethyl)pyrrolidin-1-yl]ethanone —— C17H24N2OS
    2-phenylsulfanyl-1-[(3S)-3-(pyrrolidin-1-ylmethyl)pyrrolidin-1-yl]ethanone
    —— 1-[(2R)-2-[(2R)-2-(furan-2-yl)-2-hydroxyethyl]pyrrolidin-1-yl]-2-phenylsulfanylethanone —— C18H21NO3S
    1-[(2R)-2-[(2R)-2-(furan-2-yl)-2-hydroxyethyl]pyrrolidin-1-yl]-2-phenylsulfanylethanone
    —— 3-[(1R)-1-(2-methylpropoxy)ethyl]-5-(2H-triazol-4-ylsulfanylmethyl)-1,2,4-oxadiazole —— C11H17N5O2S
    3-[(1R)-1-(2-methylpropoxy)ethyl]-5-(2H-triazol-4-ylsulfanylmethyl)-1,2,4-oxadiazole
    —— 1-[(2R)-2-[(2S)-2-(furan-2-yl)-2-hydroxyethyl]pyrrolidin-1-yl]-2-phenylsulfanylethanone —— C18H21NO3S
    1-[(2R)-2-[(2S)-2-(furan-2-yl)-2-hydroxyethyl]pyrrolidin-1-yl]-2-phenylsulfanylethanone
    —— (4S)-2-oxo-N-[(2-phenylsulfanylphenyl)methyl]piperidine-4-carboxamide —— C19H20N2O2S
    (4S)-2-oxo-N-[(2-phenylsulfanylphenyl)methyl]piperidine-4-carboxamide
    —— N-[2-[(3-oxo-1-benzothiophen-2-ylidene)methylamino]ethyl]acetamide —— C13H14N2O2S
    N-[2-[(3-oxo-1-benzothiophen-2-ylidene)methylamino]ethyl]acetamide
    —— (2S)-2-[(6-benzylsulfanylpyrazin-2-yl)amino]-2-(furan-2-yl)ethanol —— C17H17N3O2S
    (2S)-2-[(6-benzylsulfanylpyrazin-2-yl)amino]-2-(furan-2-yl)ethanol
    —— (4R)-2-oxo-N-[(2-phenylsulfanylphenyl)methyl]piperidine-4-carboxamide —— C19H20N2O2S
    (4R)-2-oxo-N-[(2-phenylsulfanylphenyl)methyl]piperidine-4-carboxamide
    —— N-[(3S)-6-oxopiperidin-3-yl]-2-phenylsulfanylbenzamide —— C18H18N2O2S
    N-[(3S)-6-oxopiperidin-3-yl]-2-phenylsulfanylbenzamide
    —— 3-[(1S)-1-(2-methylpropoxy)ethyl]-5-(2H-triazol-4-ylsulfanylmethyl)-1,2,4-oxadiazole —— C11H17N5O2S
    3-[(1S)-1-(2-methylpropoxy)ethyl]-5-(2H-triazol-4-ylsulfanylmethyl)-1,2,4-oxadiazole
    —— (2R)-2-[(6-benzylsulfanylpyrazin-2-yl)amino]-2-(furan-2-yl)ethanol —— C17H17N3O2S
    (2R)-2-[(6-benzylsulfanylpyrazin-2-yl)amino]-2-(furan-2-yl)ethanol
    —— 1-[(2S)-2-[(2S)-2-(furan-2-yl)-2-hydroxyethyl]pyrrolidin-1-yl]-2-phenylsulfanylethanone —— C18H21NO3S
    1-[(2S)-2-[(2S)-2-(furan-2-yl)-2-hydroxyethyl]pyrrolidin-1-yl]-2-phenylsulfanylethanone
    —— 1-[(2S)-2-[(2R)-2-(furan-2-yl)-2-hydroxyethyl]pyrrolidin-1-yl]-2-phenylsulfanylethanone —— C18H21NO3S
    1-[(2S)-2-[(2R)-2-(furan-2-yl)-2-hydroxyethyl]pyrrolidin-1-yl]-2-phenylsulfanylethanone
    —— 2-[1-(4-methylanilino)ethylidene]-1-benzothiophen-3-one —— C17H15NOS
    2-[1-(4-methylanilino)ethylidene]-1-benzothiophen-3-one
    —— 2-[3-[(4-chlorophenyl)methylsulfanyl]-6-methyl-1,2,4-triazin-5-yl]-N-[(3-fluorophenyl)methoxy]ethenamine —— C20H18ClFN4OS
    2-[3-[(4-chlorophenyl)methylsulfanyl]-6-methyl-1,2,4-triazin-5-yl]-N-[(3-fluorophenyl)methoxy]ethenamine
    —— 2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[3-(furan-2-yl)prop-2-enylideneamino]acetamide —— C18H15ClN4O2S3
    2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[3-(furan-2-yl)prop-2-enylideneamino]acetamide
    —— 2-[3-[(4-chlorophenyl)methylsulfanyl]-6-methyl-1,2,4-triazin-5-yl]-N-methoxyethenamine —— C14H15ClN4OS
    2-[3-[(4-chlorophenyl)methylsulfanyl]-6-methyl-1,2,4-triazin-5-yl]-N-methoxyethenamine
    —— (1S)-2-[[4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-1-phenylethanol —— C15H15N3O2S
    (1S)-2-[[4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-1-phenylethanol
    —— (1R)-2-[[4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-1-phenylethanol —— C15H15N3O2S
    (1R)-2-[[4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-1-phenylethanol
    —— N-[(2S,4R)-1,4-dihydroxy-4-phenylbutan-2-yl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide —— C18H19F3N2O3S
    N-[(2S,4R)-1,4-dihydroxy-4-phenylbutan-2-yl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide
    —— N-[(2S,4S)-1,4-dihydroxy-4-phenylbutan-2-yl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide —— C18H19F3N2O3S
    N-[(2S,4S)-1,4-dihydroxy-4-phenylbutan-2-yl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide
    —— N-[(2R,4S)-1,4-dihydroxy-4-phenylbutan-2-yl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide —— C18H19F3N2O3S
    N-[(2R,4S)-1,4-dihydroxy-4-phenylbutan-2-yl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide