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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-benzyl-N-ethylacetamide —— C18H18N5OS+
    2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-benzyl-N-ethylacetamide
    —— 2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-[(2R)-butan-2-yl]acetamide —— C13H16N5OS+
    2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-[(2R)-butan-2-yl]acetamide
    —— 2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-(cyclopropylmethyl)-N-propylacetamide —— C16H20N5OS+
    2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-(cyclopropylmethyl)-N-propylacetamide
    —— N-[(1S)-1-(1-adamantyl)ethyl]-2-(6-amino-3,5-dicyanopyridin-2-yl)sulfanylacetamide —— C21H25N5OS
    N-[(1S)-1-(1-adamantyl)ethyl]-2-(6-amino-3,5-dicyanopyridin-2-yl)sulfanylacetamide
    —— (2S)-2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-[2-(cyclohexen-1-yl)ethyl]propanamide —— C18H22N5OS+
    (2S)-2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-[2-(cyclohexen-1-yl)ethyl]propanamide
    —— (2R)-2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-cyclopropylpropanamide —— C13H14N5OS+
    (2R)-2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-cyclopropylpropanamide
    —— 2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N,N-di(propan-2-yl)acetamide —— C15H20N5OS+
    2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N,N-di(propan-2-yl)acetamide
    —— 2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-[(2-chlorophenyl)methyl]acetamide —— C16H13ClN5OS+
    2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-[(2-chlorophenyl)methyl]acetamide
    —— 2-Amino-6-(2-oxo-2-pyrrolidin-1-ylethyl)sulfanylpyridin-1-ium-3,5-dicarbonitrile —— C13H14N5OS+
    2-Amino-6-(2-oxo-2-pyrrolidin-1-ylethyl)sulfanylpyridin-1-ium-3,5-dicarbonitrile
    —— (2S)-2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-cyclopentylpropanamide —— C15H18N5OS+
    (2S)-2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-cyclopentylpropanamide
    —— 3-(4-Ethylsulfanylphenyl)propan-1-ol —— C11H16OS
    3-(4-Ethylsulfanylphenyl)propan-1-ol
    —— ethyl (4R)-6-amino-5-cyano-2-[(3-cyano-6,7-dihydro-5H-cyclopenta[b]pyridin-2-yl)sulfanylmethyl]-4-(4-methylsulfanylphenyl)-4H-pyran-3-carboxylate —— C26H24N4O3S2
    ethyl (4R)-6-amino-5-cyano-2-[(3-cyano-6,7-dihydro-5H-cyclopenta[b]pyridin-2-yl)sulfanylmethyl]-4-(4-methylsulfanylphenyl)-4H-pyran-3-carboxylate
    —— 2-[2-(1-Adamantyl)-2-oxoethyl]sulfanyl-6-amino-4-thiophen-2-ylpyridin-1-ium-3,5-dicarbonitrile —— C23H23N4OS2+
    2-[2-(1-Adamantyl)-2-oxoethyl]sulfanyl-6-amino-4-thiophen-2-ylpyridin-1-ium-3,5-dicarbonitrile
    —— ethyl (4R)-6-amino-2-[(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanylmethyl]-5-cyano-4-thiophen-2-yl-4H-pyran-3-carboxylate —— C21H17N6O3S2+
    ethyl (4R)-6-amino-2-[(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanylmethyl]-5-cyano-4-thiophen-2-yl-4H-pyran-3-carboxylate
    —— ethyl (4R)-6-amino-2-[(6-amino-3,5-dicyanopyridin-2-yl)sulfanylmethyl]-5-cyano-4-thiophen-2-yl-4H-pyran-3-carboxylate —— C21H16N6O3S2
    ethyl (4R)-6-amino-2-[(6-amino-3,5-dicyanopyridin-2-yl)sulfanylmethyl]-5-cyano-4-thiophen-2-yl-4H-pyran-3-carboxylate
    —— N-[3-(2,4-dimethylphenyl)propyl]-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C21H26N4O2S
    N-[3-(2,4-dimethylphenyl)propyl]-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— (2R)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-pyrrolidin-1-ylpropan-1-one —— C14H17N3O3S
    (2R)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-pyrrolidin-1-ylpropan-1-one
    —— N-[[5-[2-[1-(thiophen-2-ylmethyl)tetrazol-5-yl]sulfanylacetyl]thiophen-2-yl]methyl]acetamide —— C15H15N5O2S3
    N-[[5-[2-[1-(thiophen-2-ylmethyl)tetrazol-5-yl]sulfanylacetyl]thiophen-2-yl]methyl]acetamide
    —— N'-acetyl-2-(3-chloro-4-fluorophenyl)sulfanylacetohydrazide —— C10H10ClFN2O2S
    N'-acetyl-2-(3-chloro-4-fluorophenyl)sulfanylacetohydrazide
    —— 2-(3-chloro-4-fluorophenyl)sulfanyl-N-[(1R)-1-cyano-1-cyclopropylethyl]acetamide —— C14H14ClFN2OS
    2-(3-chloro-4-fluorophenyl)sulfanyl-N-[(1R)-1-cyano-1-cyclopropylethyl]acetamide
    —— 2-(3-chloro-4-fluorophenyl)sulfanyl-N-[(1R,2S)-2-methylcyclohexyl]acetamide —— C15H19ClFNOS
    2-(3-chloro-4-fluorophenyl)sulfanyl-N-[(1R,2S)-2-methylcyclohexyl]acetamide
    —— 3-[(2-Chloro-6-fluorophenyl)methylsulfanyl]-4-prop-2-enyl-1,2,4-triazole —— C12H11ClFN3S
    3-[(2-Chloro-6-fluorophenyl)methylsulfanyl]-4-prop-2-enyl-1,2,4-triazole
    —— 2-(3-chloro-4-fluorophenyl)sulfanyl-N-[(1R,2R)-2-methylcyclohexyl]acetamide —— C15H19ClFNOS
    2-(3-chloro-4-fluorophenyl)sulfanyl-N-[(1R,2R)-2-methylcyclohexyl]acetamide
    —— 2-(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanyl-N-methyl-N-[(1S)-1-phenylethyl]acetamide —— C20H23N3OS
    2-(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanyl-N-methyl-N-[(1S)-1-phenylethyl]acetamide
    —— 2-(3-chloro-4-fluorophenyl)sulfanyl-N-[(1R)-1-phenylethyl]acetamide —— C16H15ClFNOS
    2-(3-chloro-4-fluorophenyl)sulfanyl-N-[(1R)-1-phenylethyl]acetamide
    —— (2R)-2-(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanyl-N-propan-2-ylpropanamide —— C15H21N3OS
    (2R)-2-(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanyl-N-propan-2-ylpropanamide
    —— 2,3,5,6-tetrafluoro-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]pyridin-4-amine —— C13H9F4N3S
    2,3,5,6-tetrafluoro-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]pyridin-4-amine
    —— N-methyl-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-phenylethyl]acetamide —— C21H24N4O2S
    N-methyl-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-phenylethyl]acetamide
    —— [2-[2-(4-chlorophenyl)sulfanylethylamino]-2-oxoethyl] (1R,2S)-2-methylcyclopropane-1-carboxylate —— C15H18ClNO3S
    [2-[2-(4-chlorophenyl)sulfanylethylamino]-2-oxoethyl] (1R,2S)-2-methylcyclopropane-1-carboxylate
    —— N-[(5-chlorothiophen-2-yl)methyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-methylacetamide —— C16H22ClN5O2S2
    N-[(5-chlorothiophen-2-yl)methyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-methylacetamide
    —— Methyl 2-[[4-amino-5-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C8H14N4O3S
    Methyl 2-[[4-amino-5-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 7-(4-bromophenyl)-3-phenyl-8H-[1,2,4]triazino[3,4-b][1,3,4]thiadiazin-4-one —— C17H11BrN4OS
    7-(4-bromophenyl)-3-phenyl-8H-[1,2,4]triazino[3,4-b][1,3,4]thiadiazin-4-one
    —— 3-[(2-Chlorophenyl)methylsulfanyl]-5-(methoxymethyl)-1,2,4-triazol-4-amine —— C11H13ClN4OS
    3-[(2-Chlorophenyl)methylsulfanyl]-5-(methoxymethyl)-1,2,4-triazol-4-amine
    —— (2S)-2-[[5-[(5R)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propan-2-ylpropanamide —— C17H23N3O2S2
    (2S)-2-[[5-[(5R)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propan-2-ylpropanamide
    —— 6-(4-chlorophenyl)-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanylmethyl]-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C14H11ClN6S3
    6-(4-chlorophenyl)-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanylmethyl]-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 3-[(2-Chlorophenyl)methylsulfanyl]-5-(phenylsulfanylmethyl)-1,2,4-triazol-4-amine —— C16H15ClN4S2
    3-[(2-Chlorophenyl)methylsulfanyl]-5-(phenylsulfanylmethyl)-1,2,4-triazol-4-amine
    —— 3-ethyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazin-6-amine —— C6H9N5S
    3-ethyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazin-6-amine
    —— 2-[[4-Amino-5-(4,5-dihydro-1,3-thiazol-2-ylsulfanylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C8H12N6OS3
    2-[[4-Amino-5-(4,5-dihydro-1,3-thiazol-2-ylsulfanylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-[(4-Amino-5-propyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C7H13N5OS
    2-[(4-Amino-5-propyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 6-methyl-3-propan-2-yl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C8H12N4S
    6-methyl-3-propan-2-yl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 2-[[4-Amino-5-(phenylsulfanylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C11H13N5OS2
    2-[[4-Amino-5-(phenylsulfanylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-[[4-Amino-5-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C7H13N5O2S
    2-[[4-Amino-5-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— Ethyl 2-[[4-amino-5-(phenylsulfanylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C13H16N4O2S2
    Ethyl 2-[[4-amino-5-(phenylsulfanylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— Methyl 2-[(4-amino-5-oxo-6-phenyl-1,2,4-triazin-3-yl)sulfanyl]acetate —— C12H12N4O3S
    Methyl 2-[(4-amino-5-oxo-6-phenyl-1,2,4-triazin-3-yl)sulfanyl]acetate
    —— 6-(4-bromophenyl)-3-(methoxymethyl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C12H11BrN4OS
    6-(4-bromophenyl)-3-(methoxymethyl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 3-(phenylsulfanylmethyl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazin-6-amine —— C11H11N5S2
    3-(phenylsulfanylmethyl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazin-6-amine
    —— (2R)-2-[[5-[(5R)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propan-2-ylpropanamide —— C17H23N3O2S2
    (2R)-2-[[5-[(5R)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propan-2-ylpropanamide
    —— 6-(4-bromophenyl)-3-(2-methylfuran-3-yl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C15H11BrN4OS
    6-(4-bromophenyl)-3-(2-methylfuran-3-yl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 3-(2-thienyl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazin-6-amine —— C8H7N5S2
    3-(2-thienyl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazin-6-amine
    —— 3-Benzylsulfanyl-5-(phenylsulfanylmethyl)-1,2,4-triazol-4-amine —— C16H16N4S2
    3-Benzylsulfanyl-5-(phenylsulfanylmethyl)-1,2,4-triazol-4-amine