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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-(3-fluoro-2-methylphenyl)-4-(5-methyl-3-methylsulfanyl-1,2-oxazol-4-yl)pyrimidin-2-amine —— C16H15FN4OS
    N-(3-fluoro-2-methylphenyl)-4-(5-methyl-3-methylsulfanyl-1,2-oxazol-4-yl)pyrimidin-2-amine
    —— 4-[3-(cyclopropylmethylsulfanyl)-5-methyl-1,2-oxazol-4-yl]-N-phenylpyrimidin-2-amine —— C18H18N4OS
    4-[3-(cyclopropylmethylsulfanyl)-5-methyl-1,2-oxazol-4-yl]-N-phenylpyrimidin-2-amine
    —— 4-[(3-benzylsulfanyl-1H-1,2,4-triazol-5-yl)methyl]-N,N-dimethylaniline —— C18H20N4S
    4-[(3-benzylsulfanyl-1H-1,2,4-triazol-5-yl)methyl]-N,N-dimethylaniline
    —— (+/-) 3-(6-Phenylthio-3-pyridyl)-9-methyl-3,9-diazabicyclo-[4.2.1]-nonane 387870-16-8 C19H23N3S
    (+/-) 3-(6-Phenylthio-3-pyridyl)-9-methyl-3,9-diazabicyclo-[4.2.1]-nonane
    —— 2-[(1R)-3-amino-1-phenylpropyl]sulfanyl-6-(difluoromethyl)pyridine-3-carbonitrile —— C16H15F2N3S
    2-[(1R)-3-amino-1-phenylpropyl]sulfanyl-6-(difluoromethyl)pyridine-3-carbonitrile
    —— [4-amino-5-(5-ethyl-furan-2-ylmethyl)-pyrimidin-2-ylsulfanyl]-acetic acid ethyl ester 476302-18-8 C15H19N3O3S
    [4-amino-5-(5-ethyl-furan-2-ylmethyl)-pyrimidin-2-ylsulfanyl]-acetic acid ethyl ester
    —— (4-amino-5-benzyl-pyrimidin-2-ylsulfanyl)-acetic acid ethyl ester 476302-05-3 C15H17N3O2S
    (4-amino-5-benzyl-pyrimidin-2-ylsulfanyl)-acetic acid ethyl ester
    —— 4-(3-ethylsulfanyl-5-methyl-1,2-oxazol-4-yl)-N-phenylpyrimidin-2-amine —— C16H16N4OS
    4-(3-ethylsulfanyl-5-methyl-1,2-oxazol-4-yl)-N-phenylpyrimidin-2-amine
    —— [4-amino-5-(5-methyl-furan-2-ylmethyl)-pyrimidin-2-ylsulfanyl]-acetic acid ethyl ester 476302-19-9 C14H17N3O3S
    [4-amino-5-(5-methyl-furan-2-ylmethyl)-pyrimidin-2-ylsulfanyl]-acetic acid ethyl ester
    —— 3-[(3-methylthiophen-2-yl)methylsulfanyl]-5-(thiophen-2-ylmethyl)-1H-1,2,4-triazole —— C13H13N3S3
    3-[(3-methylthiophen-2-yl)methylsulfanyl]-5-(thiophen-2-ylmethyl)-1H-1,2,4-triazole
    —— 5-[(3-methylphenyl)methyl]-3-(thiophen-3-ylmethylsulfanyl)-1H-1,2,4-triazole —— C15H15N3S2
    5-[(3-methylphenyl)methyl]-3-(thiophen-3-ylmethylsulfanyl)-1H-1,2,4-triazole
    —— 4-[2-(4-Methoxyphenyl)sulfanylphenyl]-1,2,3,6-tetrahydropyridine —— C18H19NOS
    4-[2-(4-Methoxyphenyl)sulfanylphenyl]-1,2,3,6-tetrahydropyridine
    —— 2-[(3S)-3-amino-4-hydroxy-1-(1,2-oxazol-3-yl)butyl]sulfanyl-6-methylpyridine-3-carbonitrile —— C14H16N4O2S
    2-[(3S)-3-amino-4-hydroxy-1-(1,2-oxazol-3-yl)butyl]sulfanyl-6-methylpyridine-3-carbonitrile
    —— Methyl 2-[4-amino-5-(furan-3-ylmethyl)pyrimidin-2-yl]sulfanylacetate —— C12H13N3O3S
    Methyl 2-[4-amino-5-(furan-3-ylmethyl)pyrimidin-2-yl]sulfanylacetate
    —— 1-(Methylsulfonylmethyldisulfanyl)pentane —— C7H16O2S3
    1-(Methylsulfonylmethyldisulfanyl)pentane
    —— 3-aminopropyl(2-methylthioethyl)phosphinic acid —— C6H16NO2PS
    3-aminopropyl(2-methylthioethyl)phosphinic acid
    —— 5-(Cyclopentylsulfanyl)-4H-1,2,4-triazol-3-amine —— C7H12N4S
    5-(Cyclopentylsulfanyl)-4H-1,2,4-triazol-3-amine
    —— 5-Hydroxy-1-benzothiophen-3-one —— C8H6O2S
    5-Hydroxy-1-benzothiophen-3-one
    —— 2-[(4-Ethylphenyl)sulfanylmethyl]oxirane —— C11H14OS
    2-[(4-Ethylphenyl)sulfanylmethyl]oxirane
    —— 2-mercapto ethanol amine —— C2H7NOS
    2-mercapto ethanol amine
    —— N'-(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)-N-hydroxymethanimidamide —— C5H8N4OS2
    N'-(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)-N-hydroxymethanimidamide
    —— butyl 2-[[(4R,9R,14R,19R)-3,10,13,20,26-pentazatetracyclo[20.3.1.04,9.014,19]hexacosa-1(25),22(26),23-trien-24-yl]sulfanyl]acetate —— C27H45N5O2S
    butyl 2-[[(4R,9R,14R,19R)-3,10,13,20,26-pentazatetracyclo[20.3.1.04,9.014,19]hexacosa-1(25),22(26),23-trien-24-yl]sulfanyl]acetate
    —— (4R,9R,14R,19R)-24-cyclohexylsulfanyl-3,10,13,20,26-pentazatetracyclo[20.3.1.04,9.014,19]hexacosa-1(25),22(26),23-triene;dichloromanganese —— C27H45Cl2MnN5S
    (4R,9R,14R,19R)-24-cyclohexylsulfanyl-3,10,13,20,26-pentazatetracyclo[20.3.1.04,9.014,19]hexacosa-1(25),22(26),23-triene;dichloromanganese
    —— 3-chloro-N-[3,5-dichloro-4-[(5-methyl-1,3-benzothiazol-2-yl)sulfanyl]phenyl]-5-(trifluoromethyl)benzenesulfonamide —— C21H12Cl3F3N2O2S3
    3-chloro-N-[3,5-dichloro-4-[(5-methyl-1,3-benzothiazol-2-yl)sulfanyl]phenyl]-5-(trifluoromethyl)benzenesulfonamide
    —— [4-[6-Acetyl-2-(4-fluorophenyl)-5-methyl-3-oxopyridazin-4-yl]sulfanylphenyl]-trimethylazanium;iodide —— C22H23FIN3O2S
    [4-[6-Acetyl-2-(4-fluorophenyl)-5-methyl-3-oxopyridazin-4-yl]sulfanylphenyl]-trimethylazanium;iodide
    —— [4-[6-Acetyl-2-(4-fluorophenyl)-5-methyl-3-oxopyridazin-4-yl]sulfanylphenyl]-trimethylazanium —— C22H23FN3O2S+
    [4-[6-Acetyl-2-(4-fluorophenyl)-5-methyl-3-oxopyridazin-4-yl]sulfanylphenyl]-trimethylazanium
    —— 3-chloro-N-(3,5-dichloro-4-naphthalen-2-ylsulfanylphenyl)-5-(trifluoromethyl)benzenesulfonamide —— C23H13Cl3F3NO2S2
    3-chloro-N-(3,5-dichloro-4-naphthalen-2-ylsulfanylphenyl)-5-(trifluoromethyl)benzenesulfonamide
    —— 3-(2-methyl-2-aminopropanethio)-2-pyridylmethyl 3-(2,2-difluoro-2-(2-pyridyl-N-oxide)ethylamino)-6-chloropyrazin-2-one-1-acetamide 342815-90-1 C23H26ClF2N7O3S
    3-(2-methyl-2-aminopropanethio)-2-pyridylmethyl 3-(2,2-difluoro-2-(2-pyridyl-N-oxide)ethylamino)-6-chloropyrazin-2-one-1-acetamide
    —— N-[1-benzyl-3-[[4-[2-(dimethylamino)ethylsulfanyl]anilino]methyl]cyclopent-2-en-1-yl]-3,3,3-trichloropropanamide —— C26H32Cl3N3OS
    N-[1-benzyl-3-[[4-[2-(dimethylamino)ethylsulfanyl]anilino]methyl]cyclopent-2-en-1-yl]-3,3,3-trichloropropanamide
    —— N-(2-methylquinolin-6-yl)-2-[[3-[(E)-2-phenylethenyl]-1H-indazol-6-yl]sulfanyl]benzamide —— C32H24N4OS
    N-(2-methylquinolin-6-yl)-2-[[3-[(E)-2-phenylethenyl]-1H-indazol-6-yl]sulfanyl]benzamide
    —— 3-(2-Carboxyethylsulfanyl)-2-hydroxy-3-[3-(7-phenylheptylsulfanyl)pyridin-2-yl]propanoic acid —— C24H31NO5S2
    3-(2-Carboxyethylsulfanyl)-2-hydroxy-3-[3-(7-phenylheptylsulfanyl)pyridin-2-yl]propanoic acid
    —— (Z,Z)-2-bromo-3-phenyl-N-(3-thiophen-2-yl-5-thiophen-2-ylsulfanyl-1,2,4-triazol-4-yl)prop-2-en-1-imine —— C19H13BrN4S3
    (Z,Z)-2-bromo-3-phenyl-N-(3-thiophen-2-yl-5-thiophen-2-ylsulfanyl-1,2,4-triazol-4-yl)prop-2-en-1-imine
    —— (E,1R)-1-(4-methylsulfanylphenyl)-4-tributylstannylbut-3-en-1-ol —— C23H40OSSn
    (E,1R)-1-(4-methylsulfanylphenyl)-4-tributylstannylbut-3-en-1-ol
    —— N-[3-(dimethylamino)propyl]-2-[2-(phenylsulfamoyl)phenyl]sulfanylbenzamide —— C24H27N3O3S2
    N-[3-(dimethylamino)propyl]-2-[2-(phenylsulfamoyl)phenyl]sulfanylbenzamide
    —— N-[3,5-dimethyl-4-(2-pyrrolidin-1-ylethoxy)phenyl]-4-(3-methoxyphenyl)sulfanylpyrimidin-2-amine —— C25H30N4O2S
    N-[3,5-dimethyl-4-(2-pyrrolidin-1-ylethoxy)phenyl]-4-(3-methoxyphenyl)sulfanylpyrimidin-2-amine
    —— XR5118 —— C20H21N3O2S2
    XR5118
    —— 4-Ethenylpyridine;2-(2-oxidophenyl)sulfanylphenolate;palladium(2+) —— C19H15NO2PdS
    4-Ethenylpyridine;2-(2-oxidophenyl)sulfanylphenolate;palladium(2+)
    —— 5-[(2,3-difluorophenyl)methylsulfanyl]-7-[1-(2-hydroxyethylamino)propan-2-ylamino]-3H-[1,3]thiazolo[4,5-d]pyrimidin-2-one —— C17H19F2N5O2S2
    5-[(2,3-difluorophenyl)methylsulfanyl]-7-[1-(2-hydroxyethylamino)propan-2-ylamino]-3H-[1,3]thiazolo[4,5-d]pyrimidin-2-one
    —— 4-[(6-chloro-1H-benzimidazol-2-yl)sulfanyl]-6-(piperazine-1-carbonyl)-1,3-dihydrobenzimidazol-2-one —— C19H17ClN6O2S
    4-[(6-chloro-1H-benzimidazol-2-yl)sulfanyl]-6-(piperazine-1-carbonyl)-1,3-dihydrobenzimidazol-2-one
    —— 6-(3,5-Dichlorophenyl)sulfanyl-5-propan-2-yl-1-(pyridin-4-ylmethyl)pyrimidine-2,4-dione —— C19H17Cl2N3O2S
    6-(3,5-Dichlorophenyl)sulfanyl-5-propan-2-yl-1-(pyridin-4-ylmethyl)pyrimidine-2,4-dione
    —— 2-methoxyethyl 5-chloro-2-[(2-oxo-2,3-dihydro-1H-indol-5-yl)thio]-3H-benzimidazole-4-carboxylate —— C19H16ClN3O4S
    2-methoxyethyl 5-chloro-2-[(2-oxo-2,3-dihydro-1H-indol-5-yl)thio]-3H-benzimidazole-4-carboxylate
    —— 3-(1-hydroxy-3-methylbutyl)-4,11-dimethoxy-9-methyl-7H-dibenzo[c,f][1,5]oxathiocin-5-one 143096-54-2 C22H26O5S
    3-(1-hydroxy-3-methylbutyl)-4,11-dimethoxy-9-methyl-7H-dibenzo[c,f][1,5]oxathiocin-5-one
    —— 2-(6-acetyl-2-(4-fluorophenyl)-5-methyl-3-oxo-2-hydropyridazin-4-ylthio)ethyl methylsulfonate 259194-07-5 C16H17FN2O5S2
    2-(6-acetyl-2-(4-fluorophenyl)-5-methyl-3-oxo-2-hydropyridazin-4-ylthio)ethyl methylsulfonate
    —— (Z,E)-3-phenyl-N-(3-thiophen-2-yl-5-thiophen-2-ylsulfanyl-1,2,4-triazol-4-yl)prop-2-en-1-imine —— C19H14N4S3
    (Z,E)-3-phenyl-N-(3-thiophen-2-yl-5-thiophen-2-ylsulfanyl-1,2,4-triazol-4-yl)prop-2-en-1-imine
    —— N-{4-[5-fluoro-3-(4-methoxytetrahydropyran-4-yl)phenylthio]-α-methylbenzyl}-O-methylhydroxylamine —— C21H26FNO3S
    N-{4-[5-fluoro-3-(4-methoxytetrahydropyran-4-yl)phenylthio]-α-methylbenzyl}-O-methylhydroxylamine
    —— 6-methoxy-3-(2-nitro-phenylsulfanyl)-1-pyrimidin-5-ylmethyl-1H-indole 691400-49-4 C20H16N4O3S
    6-methoxy-3-(2-nitro-phenylsulfanyl)-1-pyrimidin-5-ylmethyl-1H-indole
    —— 5-(5-chlorothiadiazol-4-yl)sulfanyl-7-(1-hydroxypropan-2-ylamino)-3H-[1,3]thiazolo[4,5-d]pyrimidin-2-one —— C10H9ClN6O2S3
    5-(5-chlorothiadiazol-4-yl)sulfanyl-7-(1-hydroxypropan-2-ylamino)-3H-[1,3]thiazolo[4,5-d]pyrimidin-2-one
    —— 2-[6-fluoro-2-methyl-4-(4-methylsulfinylphenyl)sulfanyl-3H-inden-1-yl]acetic acid —— C19H17FO3S2
    2-[6-fluoro-2-methyl-4-(4-methylsulfinylphenyl)sulfanyl-3H-inden-1-yl]acetic acid
    —— azanide;dichloroplatinum(2+);thiourea —— CH8Cl2N4PtS
    azanide;dichloroplatinum(2+);thiourea
    —— 1-(4-tert-butylphenyl)-N-methyl-N-[(3-phenylsulfanylphenyl)methyl]methanamine —— C25H29NS
    1-(4-tert-butylphenyl)-N-methyl-N-[(3-phenylsulfanylphenyl)methyl]methanamine