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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(4-cyclopropyl-5-{[3-(difluoromethyl)-5-methyl-1H-pyrazol-1-yl]methyl}-4H-1,2,4-triazol-3-yl)sulfanyl]-N-(prop-2-en-1-yl)acetamide —— C16H20F2N6OS
    2-[(4-cyclopropyl-5-{[3-(difluoromethyl)-5-methyl-1H-pyrazol-1-yl]methyl}-4H-1,2,4-triazol-3-yl)sulfanyl]-N-(prop-2-en-1-yl)acetamide
    —— 1-(4-Methylsulfanylphenyl)-2-piperazin-1-ylethanol —— C13H20N2OS
    1-(4-Methylsulfanylphenyl)-2-piperazin-1-ylethanol
    —— 5-nitro-N-[(4-phenylsulfanylphenyl)methylideneamino]-1-benzothiophene-2-carboxamide —— C22H15N3O3S2
    5-nitro-N-[(4-phenylsulfanylphenyl)methylideneamino]-1-benzothiophene-2-carboxamide
    —— 3-[(4-Phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propane-1-sulfonate —— C11H11N2O3S4-
    3-[(4-Phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propane-1-sulfonate
    —— S-(2-acetylsulfanyl-6-methylpyrimidin-4-yl) ethanethioate —— C9H10N2O2S2
    S-(2-acetylsulfanyl-6-methylpyrimidin-4-yl) ethanethioate
    —— 3,3-Dimethylbut-1-yne-1-thiol —— C6H10S
    3,3-Dimethylbut-1-yne-1-thiol
    —— 5-methyl-3-nonylsulfanyl-1H-1,2,4-triazole —— C12H23N3S
    5-methyl-3-nonylsulfanyl-1H-1,2,4-triazole
    —— 2-[(4-benzyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-(1,1-dioxothiolan-3-yl)acetamide —— C19H20N4O3S3
    2-[(4-benzyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-(1,1-dioxothiolan-3-yl)acetamide
    —— 2-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(oxolan-2-ylmethyl)acetamide —— C17H22N4O2S2
    2-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(oxolan-2-ylmethyl)acetamide
    —— [2-oxo-2-(2-phenylsulfanylanilino)ethyl] 1H-indazole-3-carboxylate —— C22H17N3O3S
    [2-oxo-2-(2-phenylsulfanylanilino)ethyl] 1H-indazole-3-carboxylate
    —— 4-amino-2-(imidazo[2,1-b][1,3]thiazol-6-ylmethylsulfanyl)-1H-pyrimidin-6-one —— C10H9N5OS2
    4-amino-2-(imidazo[2,1-b][1,3]thiazol-6-ylmethylsulfanyl)-1H-pyrimidin-6-one
    —— 5-(2-Nitrophenyl)-3-([2-nitro-4-(trifluoromethyl)phenyl]sulfanyl)-1H-1,2,4-triazole —— C15H8F3N5O4S
    5-(2-Nitrophenyl)-3-([2-nitro-4-(trifluoromethyl)phenyl]sulfanyl)-1H-1,2,4-triazole
    —— 3-(3-Chloro-4-methoxyphenyl)-5-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one —— C23H14Cl2N2O4S3
    3-(3-Chloro-4-methoxyphenyl)-5-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one
    —— ethyl N-[2-[[4-(4-chlorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]carbamate —— C13H12ClN3O3S3
    ethyl N-[2-[[4-(4-chlorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]carbamate
    —— (2E)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-(pentylidenehydrazinylidene)-1,3-thiazolidin-4-one —— C16H19F2N3OS2
    (2E)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-(pentylidenehydrazinylidene)-1,3-thiazolidin-4-one
    —— 2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(1,1-dioxothiolan-3-yl)-N-(2-methylpropyl)acetamide —— C18H22BrN3O4S2
    2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(1,1-dioxothiolan-3-yl)-N-(2-methylpropyl)acetamide
    —— 2-[6-(4-Methylphenyl)-2-(4-methylsulfanylphenyl)-1,2,3,4-tetrahydropyrimidin-3-ium-4-yl]phenol —— C24H25N2OS+
    2-[6-(4-Methylphenyl)-2-(4-methylsulfanylphenyl)-1,2,3,4-tetrahydropyrimidin-3-ium-4-yl]phenol
    —— N-[(4-ethyl-5-ethylsulfanyl-1,2,4-triazol-3-yl)methyl]adamantane-1-carboxamide —— C18H28N4OS
    N-[(4-ethyl-5-ethylsulfanyl-1,2,4-triazol-3-yl)methyl]adamantane-1-carboxamide
    —— 3-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide —— C13H14ClN3O2S
    3-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide
    —— N-octyl-4-octylsulfanylaniline —— C22H39NS
    N-octyl-4-octylsulfanylaniline
    —— N-[[1-[(3-methylphenyl)methyl]pyrrol-2-yl]methyl]-2-phenylsulfanyl-N-propan-2-ylacetamide —— C24H28N2OS
    N-[[1-[(3-methylphenyl)methyl]pyrrol-2-yl]methyl]-2-phenylsulfanyl-N-propan-2-ylacetamide
    —— Ethyl 2-[(5-{[(adamantan-1-YL)formamido]methyl}-4-ethyl-4H-1,2,4-triazol-3-YL)sulfanyl]acetate —— C20H30N4O3S
    Ethyl 2-[(5-{[(adamantan-1-YL)formamido]methyl}-4-ethyl-4H-1,2,4-triazol-3-YL)sulfanyl]acetate
    —— Methyl 2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate —— C12H11FN2O3S
    Methyl 2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate
    —— 1-[(4-Amino-5-anilino-1,2,4-triazol-3-yl)sulfanyl]propan-2-one —— C11H13N5OS
    1-[(4-Amino-5-anilino-1,2,4-triazol-3-yl)sulfanyl]propan-2-one
    —— benzenecarbaldehyde N-[6-chloro-2-(methylsulfanyl)-4-pyrimidinyl]hydrazone 339017-98-0 C12H11ClN4S
    benzenecarbaldehyde N-[6-chloro-2-(methylsulfanyl)-4-pyrimidinyl]hydrazone
    —— Tert-butyl (1-{5-[(4-fluorobenzyl)sulfanyl]-1,3,4-oxadiazol-2-yl}-2-methylbutyl)carbamate —— C19H26FN3O3S
    Tert-butyl (1-{5-[(4-fluorobenzyl)sulfanyl]-1,3,4-oxadiazol-2-yl}-2-methylbutyl)carbamate
    —— 1-[2,5-Dimethyl-1-(oxolan-2-ylmethyl)pyrrol-3-yl]-2-[[5-[2-[2,5-dimethyl-1-(oxolan-2-ylmethyl)pyrrol-3-yl]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C28H36N4O4S3
    1-[2,5-Dimethyl-1-(oxolan-2-ylmethyl)pyrrol-3-yl]-2-[[5-[2-[2,5-dimethyl-1-(oxolan-2-ylmethyl)pyrrol-3-yl]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— 2-[4-(methoxyiminomethyl)-2-nitrophenyl]sulfanylaniline —— C14H13N3O3S
    2-[4-(methoxyiminomethyl)-2-nitrophenyl]sulfanylaniline
    —— 3,4-dimethyl-5-({[2-(4-methylphenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)-4H-1,2,4-triazole —— C15H16N4S2
    3,4-dimethyl-5-({[2-(4-methylphenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)-4H-1,2,4-triazole
    —— 5-Phenylsulfanylthiadiazole —— C8H6N2S2
    5-Phenylsulfanylthiadiazole
    —— 3-[5-[4-(Difluoromethylsulfanyl)phenyl]furan-2-yl]-2-(4-phenyl-1,3-thiazol-2-yl)prop-2-enenitrile —— C23H14F2N2OS2
    3-[5-[4-(Difluoromethylsulfanyl)phenyl]furan-2-yl]-2-(4-phenyl-1,3-thiazol-2-yl)prop-2-enenitrile
    —— 12-Methoxysulfonothioyldodecan-1-amine —— C13H29NO2S2
    12-Methoxysulfonothioyldodecan-1-amine
    —— Ethyl 2-{[3-(4-ethylphenyl)-7-oxo-6-phenyl-2-sulfanylidene-2H,3H,6H,7H-[1,3]thiazolo[4,5-D]pyrimidin-5-YL]sulfanyl}acetate —— C23H21N3O3S3
    Ethyl 2-{[3-(4-ethylphenyl)-7-oxo-6-phenyl-2-sulfanylidene-2H,3H,6H,7H-[1,3]thiazolo[4,5-D]pyrimidin-5-YL]sulfanyl}acetate
    —— 6-methylsulfanyl-3,8-diphenyl-1H-[1,3]thiazolo[3,4-b][1,2,4]triazin-5-ium-2-one —— C18H14N3OS2+
    6-methylsulfanyl-3,8-diphenyl-1H-[1,3]thiazolo[3,4-b][1,2,4]triazin-5-ium-2-one
    —— 3-(ethylsulfanyl)-5-(thiophen-2-yl)-4H-1,2,4-triazol-4-amine 118158-92-2 C8H10N4S2
    3-(ethylsulfanyl)-5-(thiophen-2-yl)-4H-1,2,4-triazol-4-amine
    —— bis(7-methyl-5-oxo-5H-1,3,4-thiadiazolo<3,2-a>pyrimidyl-2)sulfide —— C12H8N6O2S3
    bis(7-methyl-5-oxo-5H-1,3,4-thiadiazolo<3,2-a>pyrimidyl-2)sulfide
    —— 2-{[4-(2-Thienyl)-2-pyrimidinyl]sulfanyl}acetonitrile —— C10H7N3S2
    2-{[4-(2-Thienyl)-2-pyrimidinyl]sulfanyl}acetonitrile
    —— (2-Benzylsulfanyl-5-chlorophenyl)-cyclopropylmethanamine —— C17H18ClNS
    (2-Benzylsulfanyl-5-chlorophenyl)-cyclopropylmethanamine
    —— N-[2-(cyclohexen-1-yl)ethyl]-2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C18H20FN3OS3
    N-[2-(cyclohexen-1-yl)ethyl]-2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 3-(4-chlorophenyl)sulfanyl-N-(1-methoxypropan-2-yl)propanamide —— C13H18ClNO2S
    3-(4-chlorophenyl)sulfanyl-N-(1-methoxypropan-2-yl)propanamide
    —— 5-[[4-Bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-3-(2-methoxyethyl)-2-(4-methoxyphenyl)imino-1,3-thiazolidin-4-one —— C24H20BrClN2O4S2
    5-[[4-Bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-3-(2-methoxyethyl)-2-(4-methoxyphenyl)imino-1,3-thiazolidin-4-one
    —— 2-[(5-Amino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-(furan-2-yl)ethanone —— C8H7N3O2S2
    2-[(5-Amino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-(furan-2-yl)ethanone
    —— 2-cyano-N-(furan-2-ylmethyl)-3-(5-phenylsulfanylfuran-2-yl)prop-2-enamide —— C19H14N2O3S
    2-cyano-N-(furan-2-ylmethyl)-3-(5-phenylsulfanylfuran-2-yl)prop-2-enamide
    —— {5-[1-Methyl-pent-4-en-(Z)-ylidene-hydrazinocarbonylmethylsulfanyl]-[1,3,4]thiadiazol-2-ylsulfanyl}-acetic acid [1-methyl-pent-4-en-(E)-ylidene]-hydrazide —— C18H26N6O2S3
    {5-[1-Methyl-pent-4-en-(Z)-ylidene-hydrazinocarbonylmethylsulfanyl]-[1,3,4]thiadiazol-2-ylsulfanyl}-acetic acid [1-methyl-pent-4-en-(E)-ylidene]-hydrazide
    —— 2-[[4-(4-chlorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-methylcyclohexyl)acetamide —— C17H20ClN3OS3
    2-[[4-(4-chlorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-methylcyclohexyl)acetamide
    —— sodium;1-[(4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-phenylmethanimidothioate —— C12H10N3NaOS2
    sodium;1-[(4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-phenylmethanimidothioate
    —— N-ethyl-3-[[5-(5-methyl-1,2-oxazol-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C11H14N4O3S
    N-ethyl-3-[[5-(5-methyl-1,2-oxazol-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— 3-chloro-N-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]benzamide —— C20H13Cl2N3O3S
    3-chloro-N-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]benzamide
    —— 4-[[4-(4-Chlorophenyl)sulfanylphenyl]methylidene]-5-methyl-2-phenylpyrazol-3-one —— C23H17ClN2OS
    4-[[4-(4-Chlorophenyl)sulfanylphenyl]methylidene]-5-methyl-2-phenylpyrazol-3-one
    —— N-[(6-methylpyridin-2-yl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide —— C14H14N4OS
    N-[(6-methylpyridin-2-yl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide