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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[(E)-(3-chlorophenyl)methylideneamino]-2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C18H14Cl2N4OS3
    N-[(E)-(3-chlorophenyl)methylideneamino]-2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N'-[(E)-(3-bromophenyl)methylidene]-2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide —— C18H14BrClN4OS3
    N'-[(E)-(3-bromophenyl)methylidene]-2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide
    —— 1-[(1S)-2,2-dimethylcyclohexyl]-3-(2,2-dimethyl-4-methylsulfonylbutyl)urea —— C16H32N2O3S
    1-[(1S)-2,2-dimethylcyclohexyl]-3-(2,2-dimethyl-4-methylsulfonylbutyl)urea
    —— 2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(E)-(5-methylthiophen-2-yl)methylidene]acetohydrazide —— C17H15ClN4OS4
    2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(E)-(5-methylthiophen-2-yl)methylidene]acetohydrazide
    —— 1-[(1R)-2,2-dimethylcyclohexyl]-3-(2,2-dimethyl-4-methylsulfonylbutyl)urea —— C16H32N2O3S
    1-[(1R)-2,2-dimethylcyclohexyl]-3-(2,2-dimethyl-4-methylsulfonylbutyl)urea
    —— 2-{[5-(benzylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}-N'-[(E)-(3-bromophenyl)methylidene]acetohydrazide —— C18H15BrN4OS3
    2-{[5-(benzylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}-N'-[(E)-(3-bromophenyl)methylidene]acetohydrazide
    —— 3-[(4-bromobenzyl)sulfanyl]-N-[(E)-phenylmethylidene]-5-(trifluoromethyl)-4H-1,2,4-triazol-4-amine —— C17H12BrF3N4S
    3-[(4-bromobenzyl)sulfanyl]-N-[(E)-phenylmethylidene]-5-(trifluoromethyl)-4H-1,2,4-triazol-4-amine
    —— 2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-thiophen-2-ylmethylideneamino]acetamide —— C16H13ClN4OS4
    2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-thiophen-2-ylmethylideneamino]acetamide
    —— N'-{(E)-[4-(Dimethylamino)phenyl]methylidene}-2-[(4,6-dimethyl-2-pyrimidinyl)sulfanyl]acetohydrazide —— C17H21N5OS
    N'-{(E)-[4-(Dimethylamino)phenyl]methylidene}-2-[(4,6-dimethyl-2-pyrimidinyl)sulfanyl]acetohydrazide
    —— (E)-1-(4-chlorophenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C17H15ClN4S
    (E)-1-(4-chlorophenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— 2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-[(E)-3-(furan-2-yl)-2-methylprop-2-enylidene]amino]acetamide —— C19H17ClN4O2S3
    2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-[(E)-3-(furan-2-yl)-2-methylprop-2-enylidene]amino]acetamide
    —— N'-[(E)-pyridin-2-ylmethylidene]-2-(pyridin-2-ylsulfanyl)acetohydrazide —— C13H12N4OS
    N'-[(E)-pyridin-2-ylmethylidene]-2-(pyridin-2-ylsulfanyl)acetohydrazide
    —— 2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-pyridin-2-ylmethylideneamino]acetamide —— C17H14ClN5OS3
    2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-pyridin-2-ylmethylideneamino]acetamide
    —— N'-[(E)-(5-bromo-2-fluorophenyl)methylidene]-2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide —— C19H16BrFN4OS3
    N'-[(E)-(5-bromo-2-fluorophenyl)methylidene]-2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide
    —— [5-[(1R)-1-(5-tert-butyl-1,3-oxazol-2-yl)ethyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]methanol —— C13H20N4O2S
    [5-[(1R)-1-(5-tert-butyl-1,3-oxazol-2-yl)ethyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]methanol
    —— 3-(6-methoxypyridin-3-yl)-5-[(1R)-1-pyridin-2-ylsulfanylethyl]-1,2,4-oxadiazole —— C15H14N4O2S
    3-(6-methoxypyridin-3-yl)-5-[(1R)-1-pyridin-2-ylsulfanylethyl]-1,2,4-oxadiazole
    —— [5-[(1S)-1-(5-tert-butyl-1,3-oxazol-2-yl)ethyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]methanol —— C13H20N4O2S
    [5-[(1S)-1-(5-tert-butyl-1,3-oxazol-2-yl)ethyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]methanol
    —— 5-[(1S)-1-(5-tert-butyl-1,3-oxazol-2-yl)ethyl]sulfanyl-4-methyl-1,2,4-triazol-3-amine —— C12H19N5OS
    5-[(1S)-1-(5-tert-butyl-1,3-oxazol-2-yl)ethyl]sulfanyl-4-methyl-1,2,4-triazol-3-amine
    —— 5-tert-butyl-2-[(1R)-1-(2H-triazol-4-ylsulfanyl)ethyl]-1,3-oxazole —— C11H16N4OS
    5-tert-butyl-2-[(1R)-1-(2H-triazol-4-ylsulfanyl)ethyl]-1,3-oxazole
    —— 3-(6-methoxypyridin-3-yl)-5-[(1S)-1-pyridin-2-ylsulfanylethyl]-1,2,4-oxadiazole —— C15H14N4O2S
    3-(6-methoxypyridin-3-yl)-5-[(1S)-1-pyridin-2-ylsulfanylethyl]-1,2,4-oxadiazole
    —— (2Z)-2-[1-(4-methylanilino)ethylidene]-1-benzothiophen-3-one —— C17H15NOS
    (2Z)-2-[1-(4-methylanilino)ethylidene]-1-benzothiophen-3-one
    —— 3-(2-methoxypyridin-4-yl)-5-[(1R)-1-pyridin-2-ylsulfanylethyl]-1,2,4-oxadiazole —— C15H14N4O2S
    3-(2-methoxypyridin-4-yl)-5-[(1R)-1-pyridin-2-ylsulfanylethyl]-1,2,4-oxadiazole
    —— 2-[(1R)-1-methoxyethyl]-4-(2H-triazol-4-ylsulfanylmethyl)-1,3-thiazole —— C9H12N4OS2
    2-[(1R)-1-methoxyethyl]-4-(2H-triazol-4-ylsulfanylmethyl)-1,3-thiazole
    —— 3-(2-methoxypyridin-4-yl)-5-[(1S)-1-pyridin-2-ylsulfanylethyl]-1,2,4-oxadiazole —— C15H14N4O2S
    3-(2-methoxypyridin-4-yl)-5-[(1S)-1-pyridin-2-ylsulfanylethyl]-1,2,4-oxadiazole
    —— 5-tert-butyl-2-[(1S)-1-(2H-triazol-4-ylsulfanyl)ethyl]-1,3-oxazole —— C11H16N4OS
    5-tert-butyl-2-[(1S)-1-(2H-triazol-4-ylsulfanyl)ethyl]-1,3-oxazole
    —— N-{(E)-[4-(methylsulfanyl)phenyl]methylidene}-4H-1,2,4-triazol-4-amine —— C10H10N4S
    N-{(E)-[4-(methylsulfanyl)phenyl]methylidene}-4H-1,2,4-triazol-4-amine
    —— 5-[(1R)-1-(5-tert-butyl-1,3-oxazol-2-yl)ethyl]sulfanyl-4-methyl-1,2,4-triazol-3-amine —— C12H19N5OS
    5-[(1R)-1-(5-tert-butyl-1,3-oxazol-2-yl)ethyl]sulfanyl-4-methyl-1,2,4-triazol-3-amine
    —— 1-[(1R)-1-pyridin-4-ylethyl]-3-[3-(1,3-thiazol-2-ylsulfanyl)propyl]urea —— C14H18N4OS2
    1-[(1R)-1-pyridin-4-ylethyl]-3-[3-(1,3-thiazol-2-ylsulfanyl)propyl]urea
    —— 2-[(1S)-1-methoxyethyl]-4-(pyridin-4-ylsulfanylmethyl)-1,3-thiazole —— C12H14N2OS2
    2-[(1S)-1-methoxyethyl]-4-(pyridin-4-ylsulfanylmethyl)-1,3-thiazole
    —— 2-[(1R)-1-methoxyethyl]-4-(pyridin-4-ylsulfanylmethyl)-1,3-thiazole —— C12H14N2OS2
    2-[(1R)-1-methoxyethyl]-4-(pyridin-4-ylsulfanylmethyl)-1,3-thiazole
    —— 2-[(1S)-1-methoxyethyl]-4-(2H-triazol-4-ylsulfanylmethyl)-1,3-thiazole —— C9H12N4OS2
    2-[(1S)-1-methoxyethyl]-4-(2H-triazol-4-ylsulfanylmethyl)-1,3-thiazole
    —— 1-[(1S)-1-(furan-2-yl)ethyl]-1-methyl-3-(3-methylsulfanyl-1,2,4-thiadiazol-5-yl)urea —— C11H14N4O2S2
    1-[(1S)-1-(furan-2-yl)ethyl]-1-methyl-3-(3-methylsulfanyl-1,2,4-thiadiazol-5-yl)urea
    —— 1-[(1S)-1-pyridin-4-ylethyl]-3-[3-(1,3-thiazol-2-ylsulfanyl)propyl]urea —— C14H18N4OS2
    1-[(1S)-1-pyridin-4-ylethyl]-3-[3-(1,3-thiazol-2-ylsulfanyl)propyl]urea
    —— 1-[(1R)-1-(furan-2-yl)ethyl]-1-methyl-3-(3-methylsulfanyl-1,2,4-thiadiazol-5-yl)urea —— C11H14N4O2S2
    1-[(1R)-1-(furan-2-yl)ethyl]-1-methyl-3-(3-methylsulfanyl-1,2,4-thiadiazol-5-yl)urea
    —— N-[(1S)-1-(4-chlorophenyl)ethyl]-N-methyl-2-(2H-triazol-4-ylsulfanyl)acetamide —— C13H15ClN4OS
    N-[(1S)-1-(4-chlorophenyl)ethyl]-N-methyl-2-(2H-triazol-4-ylsulfanyl)acetamide
    —— 1-Pyrimidin-2-yl-3-(3-pyrimidin-2-ylsulfanylpropyl)urea —— C12H14N6OS
    1-Pyrimidin-2-yl-3-(3-pyrimidin-2-ylsulfanylpropyl)urea
    —— N-[(1R)-1-(4-chlorophenyl)ethyl]-N-methyl-2-(2H-triazol-4-ylsulfanyl)acetamide —— C13H15ClN4OS
    N-[(1R)-1-(4-chlorophenyl)ethyl]-N-methyl-2-(2H-triazol-4-ylsulfanyl)acetamide
    —— 4-chloro-N-[2-(6-methyl-3-prop-2-enylsulfanyl-1,2,4-triazin-5-yl)ethenyl]aniline —— C15H15ClN4S
    4-chloro-N-[2-(6-methyl-3-prop-2-enylsulfanyl-1,2,4-triazin-5-yl)ethenyl]aniline
    —— 1-[(2R)-4-phenylsulfanylbutan-2-yl]-4-(1,2,4-triazol-1-yl)piperidine —— C17H24N4S
    1-[(2R)-4-phenylsulfanylbutan-2-yl]-4-(1,2,4-triazol-1-yl)piperidine
    —— 1-[(2S)-4-(1-methylpyrrol-2-yl)butan-2-yl]-3-(3-methylsulfanyl-1,2,4-thiadiazol-5-yl)urea —— C13H19N5OS2
    1-[(2S)-4-(1-methylpyrrol-2-yl)butan-2-yl]-3-(3-methylsulfanyl-1,2,4-thiadiazol-5-yl)urea
    —— 2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2S)-4-phenylbutan-2-yl]acetamide —— C20H22N4OS2
    2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2S)-4-phenylbutan-2-yl]acetamide
    —— 5-[(2R)-4-phenylsulfanylbutan-2-yl]sulfanyl-1H-1,2,4-triazole —— C12H15N3S2
    5-[(2R)-4-phenylsulfanylbutan-2-yl]sulfanyl-1H-1,2,4-triazole
    —— 2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]acetamide —— C20H22N4OS2
    2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]acetamide
    —— 5-[(2S)-4-phenylsulfanylbutan-2-yl]sulfanyl-1H-1,2,4-triazole —— C12H15N3S2
    5-[(2S)-4-phenylsulfanylbutan-2-yl]sulfanyl-1H-1,2,4-triazole
    —— 1-cyclopropyl-5-[(2S)-5-methoxypentan-2-yl]sulfanyltetrazole —— C10H18N4OS
    1-cyclopropyl-5-[(2S)-5-methoxypentan-2-yl]sulfanyltetrazole
    —— 1-[(2S)-4-phenylsulfanylbutan-2-yl]-4-(1,2,4-triazol-1-yl)piperidine —— C17H24N4S
    1-[(2S)-4-phenylsulfanylbutan-2-yl]-4-(1,2,4-triazol-1-yl)piperidine
    —— 1-cyclopropyl-5-[(2R)-5-methoxypentan-2-yl]sulfanyltetrazole —— C10H18N4OS
    1-cyclopropyl-5-[(2R)-5-methoxypentan-2-yl]sulfanyltetrazole
    —— 1-[(2R)-4-cyclohexylbutan-2-yl]-3-(3-methylsulfonylpropyl)urea —— C15H30N2O3S
    1-[(2R)-4-cyclohexylbutan-2-yl]-3-(3-methylsulfonylpropyl)urea
    —— 1-[(2S)-4-cyclohexylbutan-2-yl]-3-(3-methylsulfonylpropyl)urea —— C15H30N2O3S
    1-[(2S)-4-cyclohexylbutan-2-yl]-3-(3-methylsulfonylpropyl)urea
    —— 2-[[5-(1,5-dimethylpyrazol-3-yl)-4-(oxolan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N'-[1-(6-methyl-2,4-dioxopyran-3-ylidene)ethyl]acetohydrazide —— C22H27N7O5S
    2-[[5-(1,5-dimethylpyrazol-3-yl)-4-(oxolan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N'-[1-(6-methyl-2,4-dioxopyran-3-ylidene)ethyl]acetohydrazide