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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-[(1R,3S)-3-amino-4-hydroxy-1-phenylbutyl]sulfanyl-6-methoxypyridine-3-carbonitrile —— C17H19N3O2S
    4-[(1R,3S)-3-amino-4-hydroxy-1-phenylbutyl]sulfanyl-6-methoxypyridine-3-carbonitrile
    —— (+/-) 3-(6-Pyrid-2-ylthio-3-pyridyl)-9-methyl-3,9-diazabicyclo-[4.2.1]-nonane 387870-20-4 C18H22N4S
    (+/-) 3-(6-Pyrid-2-ylthio-3-pyridyl)-9-methyl-3,9-diazabicyclo-[4.2.1]-nonane
    —— 5-[(2-methylphenyl)methyl]-3-[(3-methylthiophen-2-yl)methylsulfanyl]-1H-1,2,4-triazole —— C16H17N3S2
    5-[(2-methylphenyl)methyl]-3-[(3-methylthiophen-2-yl)methylsulfanyl]-1H-1,2,4-triazole
    —— Methyl 2-[4-[4-(furan-2-yl)pyrazol-1-yl]pyrimidin-2-yl]sulfanylacetate —— C14H12N4O3S
    Methyl 2-[4-[4-(furan-2-yl)pyrazol-1-yl]pyrimidin-2-yl]sulfanylacetate
    —— 2-[[5-[(3-methylphenyl)methyl]-1H-1,2,4-triazol-3-yl]sulfanylmethyl]pyridine —— C16H16N4S
    2-[[5-[(3-methylphenyl)methyl]-1H-1,2,4-triazol-3-yl]sulfanylmethyl]pyridine
    —— 2-[1-(Methylamino)hexan-3-ylsulfanyl]-6-(trifluoromethyl)pyridine-3-carbonitrile —— C14H18F3N3S
    2-[1-(Methylamino)hexan-3-ylsulfanyl]-6-(trifluoromethyl)pyridine-3-carbonitrile
    —— 4-[[3-(furan-2-ylmethylsulfanyl)-1H-1,2,4-triazol-5-yl]methyl]-N,N-dimethylaniline —— C16H18N4OS
    4-[[3-(furan-2-ylmethylsulfanyl)-1H-1,2,4-triazol-5-yl]methyl]-N,N-dimethylaniline
    —— N-(3-fluorophenyl)-4-(5-methyl-3-methylsulfanyl-1,2-oxazol-4-yl)pyridin-2-amine —— C16H14FN3OS
    N-(3-fluorophenyl)-4-(5-methyl-3-methylsulfanyl-1,2-oxazol-4-yl)pyridin-2-amine
    —— N-(4-fluorophenyl)-4-(5-methyl-3-methylsulfanyl-1,2-oxazol-4-yl)pyridin-2-amine —— C16H14FN3OS
    N-(4-fluorophenyl)-4-(5-methyl-3-methylsulfanyl-1,2-oxazol-4-yl)pyridin-2-amine
    —— 4-(5-methyl-3-methylsulfanyl-1,2-oxazol-4-yl)-N-phenylpyrimidin-2-amine —— C15H14N4OS
    4-(5-methyl-3-methylsulfanyl-1,2-oxazol-4-yl)-N-phenylpyrimidin-2-amine
    —— (5S,6S)-6-(3-isohexylthio-1,2,5-thiadiazol-4-yl)-1-azabicyclo[3.2.1]octane 162183-71-3 C15H25N3S2
    (5S,6S)-6-(3-isohexylthio-1,2,5-thiadiazol-4-yl)-1-azabicyclo[3.2.1]octane
    —— 5-[(2-methylphenyl)methyl]-3-(thiophen-3-ylmethylsulfanyl)-1H-1,2,4-triazole —— C15H15N3S2
    5-[(2-methylphenyl)methyl]-3-(thiophen-3-ylmethylsulfanyl)-1H-1,2,4-triazole
    —— 2-[(4R)-2-amino-1,7-dihydroxyoctan-4-yl]sulfanyl-6-methylpyridine-3-carbonitrile —— C15H23N3O2S
    2-[(4R)-2-amino-1,7-dihydroxyoctan-4-yl]sulfanyl-6-methylpyridine-3-carbonitrile
    —— 2,2-Difluoroethyl 2-(4-pyrazol-1-ylpyrimidin-2-yl)sulfanylacetate —— C11H10F2N4O2S
    2,2-Difluoroethyl 2-(4-pyrazol-1-ylpyrimidin-2-yl)sulfanylacetate
    —— 2-[(1R)-3-amino-1-phenylpropyl]sulfanyl-6-(fluoromethyl)pyridine-3-carbonitrile —— C16H16FN3S
    2-[(1R)-3-amino-1-phenylpropyl]sulfanyl-6-(fluoromethyl)pyridine-3-carbonitrile
    —— 2-[(1R,3S)-3-amino-4-hydroxy-1-phenylbutyl]sulfanyl-6-methylpyridine-3-carbonitrile —— C17H19N3OS
    2-[(1R,3S)-3-amino-4-hydroxy-1-phenylbutyl]sulfanyl-6-methylpyridine-3-carbonitrile
    —— Ethyl 2-[4-(4-cyanopyrazol-1-yl)pyrimidin-2-yl]sulfanylacetate —— C12H11N5O2S
    Ethyl 2-[4-(4-cyanopyrazol-1-yl)pyrimidin-2-yl]sulfanylacetate
    —— 3-[(4-fluorophenyl)methylsulfanyl]-5-[(2-methylphenyl)methyl]-1H-1,2,4-triazole —— C17H16FN3S
    3-[(4-fluorophenyl)methylsulfanyl]-5-[(2-methylphenyl)methyl]-1H-1,2,4-triazole
    —— methyl (E)-4-phenyl-3-phenylsulfanylbut-2-enoate —— C17H16O2S
    methyl (E)-4-phenyl-3-phenylsulfanylbut-2-enoate
    —— 3-(furan-2-ylmethylsulfanyl)-5-[(2-methylphenyl)methyl]-1H-1,2,4-triazole —— C15H15N3OS
    3-(furan-2-ylmethylsulfanyl)-5-[(2-methylphenyl)methyl]-1H-1,2,4-triazole
    —— 2-(5-Benzylsulfanylthiophen-2-yl)pyrazine —— C15H12N2S2
    2-(5-Benzylsulfanylthiophen-2-yl)pyrazine
    —— 5-Methylsulfanyl-10,11,12,13,14,16-hexazatetracyclo[7.7.0.02,7.011,15]hexadeca-1(16),2(7),3,5,9,12,14-heptaen-8-one —— C11H6N6OS
    5-Methylsulfanyl-10,11,12,13,14,16-hexazatetracyclo[7.7.0.02,7.011,15]hexadeca-1(16),2(7),3,5,9,12,14-heptaen-8-one
    —— exo-6-(3-cyclopropylmethylthio-1,2,5-thiadiazol-4-yl)-1-azabicyclo[3.2.1]octane —— C13H19N3S2
    exo-6-(3-cyclopropylmethylthio-1,2,5-thiadiazol-4-yl)-1-azabicyclo[3.2.1]octane
    —— 5-(4-Hydroxyphenyl)sulfanyl-1,3-dihydroindol-2-one —— C14H11NO2S
    5-(4-Hydroxyphenyl)sulfanyl-1,3-dihydroindol-2-one
    —— 3-hexylsulfanyl-5-[(3-methylphenyl)methyl]-1H-1,2,4-triazole —— C16H23N3S
    3-hexylsulfanyl-5-[(3-methylphenyl)methyl]-1H-1,2,4-triazole
    —— ethyl (2E)-2-hydroxyimino-3-(4-methylphenyl)sulfanylpropanoate —— C12H15NO3S
    ethyl (2E)-2-hydroxyimino-3-(4-methylphenyl)sulfanylpropanoate
    —— 1-(2,3-Dimethyl-cyclopent-2-enyl)-3-(2-hydroxy-ethyl)-thiourea —— C10H18N2OS
    1-(2,3-Dimethyl-cyclopent-2-enyl)-3-(2-hydroxy-ethyl)-thiourea
    —— 2,2,5,5-tetramethyl-4-(oxiran-2-ylmethylsulfanyl)-1H-imidazole —— C10H18N2OS
    2,2,5,5-tetramethyl-4-(oxiran-2-ylmethylsulfanyl)-1H-imidazole
    —— 3-[(2-phenylethyl)sulfanyl]-4H-1,2,4-triazole —— C10H11N3S
    3-[(2-phenylethyl)sulfanyl]-4H-1,2,4-triazole
    —— 3-aminopropyl(methylthiomethyl)phosphinic acid —— C5H14NO2PS
    3-aminopropyl(methylthiomethyl)phosphinic acid
    —— 3-(2-ethoxy-ethylsulfanyl)-1<i>H</i>-[1,2,4]triazole 43171-67-1 C6H11N3OS
    3-(2-ethoxy-ethylsulfanyl)-1<i>H</i>-[1,2,4]triazole
    —— Thiopropylamin —— C3H9NS
    Thiopropylamin
    —— dichloromanganese;ethyl 2-[[(4R,9R,14R,19R)-3,10,13,20,26-pentazatetracyclo[20.3.1.04,9.014,19]hexacosa-1(25),22(26),23-trien-24-yl]sulfanyl]acetate —— C25H41Cl2MnN5O2S
    dichloromanganese;ethyl 2-[[(4R,9R,14R,19R)-3,10,13,20,26-pentazatetracyclo[20.3.1.04,9.014,19]hexacosa-1(25),22(26),23-trien-24-yl]sulfanyl]acetate
    —— 1-(1-Undecyl)-2-(4-fluorobenzyl)thio-5-(1-(dimethylaminocarbonylmethyl)-2-oxopyrimid-5-ylmethyl)pyrimidin4-one —— C31H42FN5O3S
    1-(1-Undecyl)-2-(4-fluorobenzyl)thio-5-(1-(dimethylaminocarbonylmethyl)-2-oxopyrimid-5-ylmethyl)pyrimidin4-one
    —— [(Z)-[5,5-dimethyl-2-(6-oxo-1,3-benzothiazol-2-ylidene)-1,3-thiazolidin-4-ylidene]-phenylsulfanylmethyl] dihydrogen phosphate —— C19H17N2O5PS3
    [(Z)-[5,5-dimethyl-2-(6-oxo-1,3-benzothiazol-2-ylidene)-1,3-thiazolidin-4-ylidene]-phenylsulfanylmethyl] dihydrogen phosphate
    —— 3-chloro-N-(3-chloro-4-naphthalen-2-ylsulfanylphenyl)-5-(trifluoromethyl)benzenesulfonamide —— C23H14Cl2F3NO2S2
    3-chloro-N-(3-chloro-4-naphthalen-2-ylsulfanylphenyl)-5-(trifluoromethyl)benzenesulfonamide
    —— 2-[5-[[2-[(4-fluorophenyl)methylsulfanyl]-1-methyl-4-oxopyrimidin-5-yl]methyl]-2-oxopyrimidin-1-yl]-N-octylacetamide —— C27H34FN5O3S
    2-[5-[[2-[(4-fluorophenyl)methylsulfanyl]-1-methyl-4-oxopyrimidin-5-yl]methyl]-2-oxopyrimidin-1-yl]-N-octylacetamide
    —— Methyl 4-[2-(2-chlorophenyl)sulfanylphenyl]-6-methyl-2-pyridin-2-yl-1,4-dihydropyrimidine-5-carboxylate —— C24H20ClN3O2S
    Methyl 4-[2-(2-chlorophenyl)sulfanylphenyl]-6-methyl-2-pyridin-2-yl-1,4-dihydropyrimidine-5-carboxylate
    —— ethyl 3-[(2-aminophenyl)sulfanyl]-6-(3-pyridylmethoxy)benzo[b]thiophene-2-carboxylate —— C23H20N2O3S2
    ethyl 3-[(2-aminophenyl)sulfanyl]-6-(3-pyridylmethoxy)benzo[b]thiophene-2-carboxylate
    —— 5-(3,5-Dichlorophenylthio)-4-isopropyl-1-[(3-pyridyl]methyl]-1H-pyrrole-2,3-dimethanol —— C21H22Cl2N2O2S
    5-(3,5-Dichlorophenylthio)-4-isopropyl-1-[(3-pyridyl]methyl]-1H-pyrrole-2,3-dimethanol
    —— 1-[4-(1,3-Benzothiazol-2-ylsulfanyl)phenyl]-3-(5-tert-butyl-1,2-oxazol-3-yl)urea —— C21H20N4O2S2
    1-[4-(1,3-Benzothiazol-2-ylsulfanyl)phenyl]-3-(5-tert-butyl-1,2-oxazol-3-yl)urea
    —— Methyl 5-(4-acetamidophenyl)sulfanyl-1-(4-fluorophenyl)-4-methyl-6-oxopyridazine-3-carboxylate —— C21H18FN3O4S
    Methyl 5-(4-acetamidophenyl)sulfanyl-1-(4-fluorophenyl)-4-methyl-6-oxopyridazine-3-carboxylate
    —— 1-[(3,5-Difluorophenyl)methyl]-6-(3,5-dimethylphenyl)sulfanyl-5-propylpyrimidine-2,4-dione —— C22H22F2N2O2S
    1-[(3,5-Difluorophenyl)methyl]-6-(3,5-dimethylphenyl)sulfanyl-5-propylpyrimidine-2,4-dione
    —— 4-[[3-[[6-(3-Chlorophenyl)sulfanylpyridin-3-yl]methyl]imidazol-4-yl]methyl]benzonitrile —— C23H17ClN4S
    4-[[3-[[6-(3-Chlorophenyl)sulfanylpyridin-3-yl]methyl]imidazol-4-yl]methyl]benzonitrile
    —— (Z)-hydroxy-[[5-[4-(trifluoromethoxy)phenyl]sulfanylfuran-2-yl]methylidene]-(2,4,4-trimethylpentan-2-yl)azanium —— C20H25F3NO3S+
    (Z)-hydroxy-[[5-[4-(trifluoromethoxy)phenyl]sulfanylfuran-2-yl]methylidene]-(2,4,4-trimethylpentan-2-yl)azanium
    —— (6S)-8-chloro-6-(4-methylpiperazin-1-yl)-5,6-dihydropyrrolo[2,1-b][1,3]benzothiazepine —— C17H20ClN3S
    (6S)-8-chloro-6-(4-methylpiperazin-1-yl)-5,6-dihydropyrrolo[2,1-b][1,3]benzothiazepine
    —— 5-[[(2,3-difluorophenyl)methyl]thio]-7-[[2-hydroxy-1-(hydroxymethyl)ethyl]amino] thiazolo[4,5-d]pyrimidin-2(3H)-one —— C15H14F2N4O3S2
    5-[[(2,3-difluorophenyl)methyl]thio]-7-[[2-hydroxy-1-(hydroxymethyl)ethyl]amino] thiazolo[4,5-d]pyrimidin-2(3H)-one
    —— 6-Amino-9-benzyl-8-hydroxy-2-(2-naphthylthio)purine —— C22H17N5OS
    6-Amino-9-benzyl-8-hydroxy-2-(2-naphthylthio)purine
    —— 2-[4-[4-(4-Chlorophenyl)-1,3-thiazol-2-yl]-5-methylsulfanylthiophen-2-yl]-2-oxoethanimidamide —— C16H12ClN3OS3
    2-[4-[4-(4-Chlorophenyl)-1,3-thiazol-2-yl]-5-methylsulfanylthiophen-2-yl]-2-oxoethanimidamide
    —— 3-anilino-5-(2-(4-chlorophenyl)-thiazol-4-ylmethylthio)-1,2,4-triazole 334538-64-6 C18H14ClN5S2
    3-anilino-5-(2-(4-chlorophenyl)-thiazol-4-ylmethylthio)-1,2,4-triazole