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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Pentyl 2-(3-cyano-4,6-dimethylpyridin-1-ium-2-yl)sulfanylbutanoate —— C17H25N2O2S+
    Pentyl 2-(3-cyano-4,6-dimethylpyridin-1-ium-2-yl)sulfanylbutanoate
    —— Propan-2-yl 2-(3-cyano-4,6-dimethylpyridin-2-yl)sulfanylbutanoate —— C15H20N2O2S
    Propan-2-yl 2-(3-cyano-4,6-dimethylpyridin-2-yl)sulfanylbutanoate
    —— N-[(4-benzyl-5-butylsulfanyl-1,2,4-triazol-3-yl)methyl]adamantane-1-carboxamide —— C25H34N4OS
    N-[(4-benzyl-5-butylsulfanyl-1,2,4-triazol-3-yl)methyl]adamantane-1-carboxamide
    —— S-(M-Tolyl) N-(2-chloro-6-methylphenyl)thiocarbamate —— C15H14ClNOS
    S-(M-Tolyl) N-(2-chloro-6-methylphenyl)thiocarbamate
    —— [2-Tert-butyl-4-(4-chlorophenyl)sulfanyl-5-methylpyrazol-3-yl] 2-(4-methoxyphenyl)acetate —— C23H25ClN2O3S
    [2-Tert-butyl-4-(4-chlorophenyl)sulfanyl-5-methylpyrazol-3-yl] 2-(4-methoxyphenyl)acetate
    —— 3,5-Bis[(2-nitrophenyl)sulfanyl]-4-phenyl-1,2,4-triazole —— C20H13N5O4S2
    3,5-Bis[(2-nitrophenyl)sulfanyl]-4-phenyl-1,2,4-triazole
    —— 2-[[(2-Fluorophenyl)methyl]thio]-4-methylpyrimidine 710966-55-5 C12H11FN2S
    2-[[(2-Fluorophenyl)methyl]thio]-4-methylpyrimidine
    —— [2-Tert-butyl-4-(4-chlorophenyl)sulfanyl-5-methylpyrazol-3-yl] 2-methylbenzoate —— C22H23ClN2O2S
    [2-Tert-butyl-4-(4-chlorophenyl)sulfanyl-5-methylpyrazol-3-yl] 2-methylbenzoate
    —— 2-{[3-(3,4-Dimethylphenyl)-6-(4-methylphenyl)-7-oxo-2-sulfanylidene-2H,3H,6H,7H-[1,3]thiazolo[4,5-D]pyrimidin-5-YL]sulfanyl}-N-[(furan-2-YL)methyl]acetamide —— C27H24N4O3S3
    2-{[3-(3,4-Dimethylphenyl)-6-(4-methylphenyl)-7-oxo-2-sulfanylidene-2H,3H,6H,7H-[1,3]thiazolo[4,5-D]pyrimidin-5-YL]sulfanyl}-N-[(furan-2-YL)methyl]acetamide
    —— 4-[2-[(3-Phenyl-[1,2]thiazolo[4,5-d]pyrimidin-7-yl)sulfanyl]ethyl]morpholine —— C17H18N4OS2
    4-[2-[(3-Phenyl-[1,2]thiazolo[4,5-d]pyrimidin-7-yl)sulfanyl]ethyl]morpholine
    —— 2-{[3-(4-Chloro-3-methylphenyl)-6-(4-methylphenyl)-7-oxo-2-thioxo-2,3,6,7-tetrahydro[1,3]thiazolo[4,5-D]pyrimidin-5-YL]sulfanyl}acetic acid —— C21H16ClN3O3S3
    2-{[3-(4-Chloro-3-methylphenyl)-6-(4-methylphenyl)-7-oxo-2-thioxo-2,3,6,7-tetrahydro[1,3]thiazolo[4,5-D]pyrimidin-5-YL]sulfanyl}acetic acid
    —— 2-(3-Methylphenyl)-5-[(4-methylphenyl)methylsulfanyl]-1,3,4-oxadiazole —— C17H16N2OS
    2-(3-Methylphenyl)-5-[(4-methylphenyl)methylsulfanyl]-1,3,4-oxadiazole
    —— 1-[[5-(4-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3,3-dimethylbutan-2-one —— C14H15ClN2O2S
    1-[[5-(4-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3,3-dimethylbutan-2-one
    —— 2-[4-Chloro-6-[cyclohexyl(methyl)amino]pyrimidin-2-yl]sulfanyl-1-morpholin-4-ylethanone —— C17H25ClN4O2S
    2-[4-Chloro-6-[cyclohexyl(methyl)amino]pyrimidin-2-yl]sulfanyl-1-morpholin-4-ylethanone
    —— 1-[1-[(2-Chlorophenyl)methyl]-2,5-dimethylpyrrol-3-yl]-2-(2,5-dimethylphenyl)sulfanylethanone —— C23H24ClNOS
    1-[1-[(2-Chlorophenyl)methyl]-2,5-dimethylpyrrol-3-yl]-2-(2,5-dimethylphenyl)sulfanylethanone
    —— 7-[(2-Chlorophenyl)sulfanylmethyl]-[1,3]thiazolo[3,2-a]pyrimidin-5-one —— C13H9ClN2OS2
    7-[(2-Chlorophenyl)sulfanylmethyl]-[1,3]thiazolo[3,2-a]pyrimidin-5-one
    —— 3-(3-(3-(4-Propyl-2-oxazolidinon-3-yl)-1-propylthio)-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridine 165116-38-1 C17H26N4O2S2
    3-(3-(3-(4-Propyl-2-oxazolidinon-3-yl)-1-propylthio)-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridine
    —— 2-[[4-(4-chlorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-cyclopentylacetamide —— C15H16ClN3OS3
    2-[[4-(4-chlorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-cyclopentylacetamide
    —— 2-Benzyl-4-methyl-7-[3-(1,2,4-triazol-1-yl)prop-1-ynyl]pyrido[4,3-b][1,4]thiazin-3-one —— C20H17N5OS
    2-Benzyl-4-methyl-7-[3-(1,2,4-triazol-1-yl)prop-1-ynyl]pyrido[4,3-b][1,4]thiazin-3-one
    —— (2E,4'R,5'S,6'S,7'R)-3-{7'-hydroxy-4',6'-dimethyl-4'-(3''-methylenepent-4''-enyl)-[1',2',3']-trithiocan-5'-yl}acrylic acid —— C16H24O3S3
    (2E,4'R,5'S,6'S,7'R)-3-{7'-hydroxy-4',6'-dimethyl-4'-(3''-methylenepent-4''-enyl)-[1',2',3']-trithiocan-5'-yl}acrylic acid
    —— (2E,4E)-5-(3,4-dibutyl-5-butylsulfanylthiophen-2-yl)penta-2,4-dienal —— C21H32OS2
    (2E,4E)-5-(3,4-dibutyl-5-butylsulfanylthiophen-2-yl)penta-2,4-dienal
    —— (1S,3S)-2-(2-deuterio-2-phenyl-1-phenylsulfanylethyl)-1,3-dithiolane 1,3-dioxide —— C17H18O2S3
    (1S,3S)-2-(2-deuterio-2-phenyl-1-phenylsulfanylethyl)-1,3-dithiolane 1,3-dioxide
    —— (R*)-<(1S*,2S*)-2-(Phenylthio)-2-(trimethylsilyl)cyclopropyl>cyclohexylmethyl methyl ether —— C20H32OSSi
    (R*)-<(1S*,2S*)-2-(Phenylthio)-2-(trimethylsilyl)cyclopropyl>cyclohexylmethyl methyl ether
    —— (1S,5R)-1,3-ditert-butyl-2-thiabicyclo[3.2.2]nona-3,8-diene-6,6,7,7-tetracarbonitrile —— C20H22N4S
    (1S,5R)-1,3-ditert-butyl-2-thiabicyclo[3.2.2]nona-3,8-diene-6,6,7,7-tetracarbonitrile
    —— 2-(5-amino-3-methylthio-1H-1,2,4-triazol-1-yl)-5-benzylthio-1,3,4-thiadiazole —— C12H12N6S3
    2-(5-amino-3-methylthio-1H-1,2,4-triazol-1-yl)-5-benzylthio-1,3,4-thiadiazole
    —— 3-[(4-Chlorobenzyl)sulfanyl]-6-phenyl-1,2,4-triazin-5-ol —— C16H12ClN3OS
    3-[(4-Chlorobenzyl)sulfanyl]-6-phenyl-1,2,4-triazin-5-ol
    —— (2-benzyl-6,7-dihydro-5H-[1,2,4]triazolo[5,1-b][1,3]thiazin-6-yl) methanesulfonate —— C13H15N3O3S2
    (2-benzyl-6,7-dihydro-5H-[1,2,4]triazolo[5,1-b][1,3]thiazin-6-yl) methanesulfonate
    —— 2,6-Dimethyl-3,5-bis(methylsulfanyl)-1,2,4-triazin-2-ium —— C7H12N3S2+
    2,6-Dimethyl-3,5-bis(methylsulfanyl)-1,2,4-triazin-2-ium
    —— ethyl 2-[(5-oxo-6-phenyl-4H-1,2,4-triazin-3-yl)sulfanyl]butanoate —— C15H17N3O3S
    ethyl 2-[(5-oxo-6-phenyl-4H-1,2,4-triazin-3-yl)sulfanyl]butanoate
    —— 8a-Phenyl-2,3,5,6,7,8-hexahydro-[1,3]dithiolo[1,2-a]thiopyran-4-ium;bromide —— C13H17BrS2
    8a-Phenyl-2,3,5,6,7,8-hexahydro-[1,3]dithiolo[1,2-a]thiopyran-4-ium;bromide
    —— 8a-Phenyl-2,3,5,6,7,8-hexahydro-[1,3]dithiolo[1,2-a]thiopyran-4-ium —— C13H17S2+
    8a-Phenyl-2,3,5,6,7,8-hexahydro-[1,3]dithiolo[1,2-a]thiopyran-4-ium
    —— zinc;(6E)-6-(1H-[1,3]thiazolo[5,4-b]pyridin-2-ylidene)cyclohexa-2,4-diene-1-thione —— C12H8N2S2Zn+2
    zinc;(6E)-6-(1H-[1,3]thiazolo[5,4-b]pyridin-2-ylidene)cyclohexa-2,4-diene-1-thione
    —— 3-[2-(5-hydroxy-3,5-dimethyl-4H-pyrazol-1-yl)-2-oxoethyl]-6-methyl-2-methylsulfanylpyrimidin-4-one —— C13H18N4O3S
    3-[2-(5-hydroxy-3,5-dimethyl-4H-pyrazol-1-yl)-2-oxoethyl]-6-methyl-2-methylsulfanylpyrimidin-4-one
    —— 2-endo-(Hydroxymethyl)-3-exo-((methoxymethoxy)methyl)-5-(phenylsulfenyl)-7-oxabicyclo<2.2.1>hept-5-ene —— C16H20O4S
    2-endo-(Hydroxymethyl)-3-exo-((methoxymethoxy)methyl)-5-(phenylsulfenyl)-7-oxabicyclo<2.2.1>hept-5-ene
    —— spiro<12-methyl-2-thiatricyclo<6.3.1.0<sup>4,12</sup>>dodeca-3,7-diene-9,2'-<1',3'>dithiane> —— C15H20S3
    spiro<12-methyl-2-thiatricyclo<6.3.1.0<sup>4,12</sup>>dodeca-3,7-diene-9,2'-<1',3'>dithiane>
    —— (1aS,3aR,7aR)-2,3a,7,7-tetramethyl-2-phenylsulfanyl-1,1a,3,4,5,6-hexahydrocyclopropa[i]indene —— C20H28S
    (1aS,3aR,7aR)-2,3a,7,7-tetramethyl-2-phenylsulfanyl-1,1a,3,4,5,6-hexahydrocyclopropa[i]indene
    —— 6-(Pyridin-2-ylsulfanyl)-2-trifluoromethyl-1H-benzoimidazole —— C13H8F3N3S
    6-(Pyridin-2-ylsulfanyl)-2-trifluoromethyl-1H-benzoimidazole
    —— 1-Methyl-4-((Z)-1-nitro-4-phenyl-but-1-enylsulfanyl)-benzene —— C17H17NO2S
    1-Methyl-4-((Z)-1-nitro-4-phenyl-but-1-enylsulfanyl)-benzene
    —— ethyl (E)-4-[4-(dimethylamino)phenyl]sulfanyl-2-methylpent-2-enoate —— C16H23NO2S
    ethyl (E)-4-[4-(dimethylamino)phenyl]sulfanyl-2-methylpent-2-enoate
    —— 2,2-Bis(phenylsulfanyl)oxolane —— C16H16OS2
    2,2-Bis(phenylsulfanyl)oxolane
    —— 1-methyl-3-methylsulfanyl-4H-1,2,4-triazin-1-ium-5-one —— C5H8N3OS+
    1-methyl-3-methylsulfanyl-4H-1,2,4-triazin-1-ium-5-one
    —— 4,5-dihydro-1-methyl-3-methylthio-5-oxo-1,2,4-triazonium iodide —— C5H8N3OS*I
    4,5-dihydro-1-methyl-3-methylthio-5-oxo-1,2,4-triazonium iodide
    —— (2-Phenylsulfanylphenyl)-pyrrolidin-1-yldiazene —— C16H17N3S
    (2-Phenylsulfanylphenyl)-pyrrolidin-1-yldiazene
    —— (3-Methyl-2-phenylsulfanyl-but-1-enylidene)-p-tolyl-amine —— C18H19NS
    (3-Methyl-2-phenylsulfanyl-but-1-enylidene)-p-tolyl-amine
    —— 1-(2-Methylphenyl)sulfanyl-4-morpholin-4-ylbutan-2-one —— C15H21NO2S
    1-(2-Methylphenyl)sulfanyl-4-morpholin-4-ylbutan-2-one
    —— Tert-butyl-dimethyl-(2-phenylsulfanylethenoxy)silane —— C14H22OSSi
    Tert-butyl-dimethyl-(2-phenylsulfanylethenoxy)silane
    —— 2-<6'-(ethynyloxy)hexyl>-2-methyl-1,3-dithiane —— C13H22OS2
    2-<6'-(ethynyloxy)hexyl>-2-methyl-1,3-dithiane
    —— trans-4-Thiophenoxy-1,1,1-trifluoro-3-buten-2-one —— C10H7F3OS
    trans-4-Thiophenoxy-1,1,1-trifluoro-3-buten-2-one
    —— (5r,6t)-5,6-epoxy-5-methyl-1-hepten-3-yl phenyl sulfide —— C14H18OS
    (5r,6t)-5,6-epoxy-5-methyl-1-hepten-3-yl phenyl sulfide
    —— 2,3,4,5,6,7-Hexahydro-8H-1,8-benzothiazecine-8-carboxaldehyde —— C13H17NOS
    2,3,4,5,6,7-Hexahydro-8H-1,8-benzothiazecine-8-carboxaldehyde