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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-Dodecyl-2-[6-(1-dodecylpyridin-1-ium-2-yl)sulfanylhexylsulfanyl]pyridin-1-ium;dibromide —— C40H70Br2N2S2
    1-Dodecyl-2-[6-(1-dodecylpyridin-1-ium-2-yl)sulfanylhexylsulfanyl]pyridin-1-ium;dibromide
    —— 1-Dodecyl-2-[6-(1-dodecylpyridin-1-ium-2-yl)sulfanylhexylsulfanyl]pyridin-1-ium —— C40H70N2S2+2
    1-Dodecyl-2-[6-(1-dodecylpyridin-1-ium-2-yl)sulfanylhexylsulfanyl]pyridin-1-ium
    —— 3-[4-[6-(3,5-di-t-butyl-4-hydroxyphenylthio)-1-methyl-1H-benzimidazol-2-ylmethoxy]phenyl]-2-(4-fluorobenzyloxy)propionic acid —— C39H43FN2O5S
    3-[4-[6-(3,5-di-t-butyl-4-hydroxyphenylthio)-1-methyl-1H-benzimidazol-2-ylmethoxy]phenyl]-2-(4-fluorobenzyloxy)propionic acid
    —— 1-(2-Benzylsulfanyl-5-chlorothiophen-3-yl)ethanone;3-(2-bromoacetyl)-5-chlorothiophene-2-sulfonamide —— C19H16BrCl2NO4S4
    1-(2-Benzylsulfanyl-5-chlorothiophen-3-yl)ethanone;3-(2-bromoacetyl)-5-chlorothiophene-2-sulfonamide
    —— N-[(4-fluorophenyl)methyl]-1-[4-[2-[(4-fluorophenyl)methylsulfanyl]-4-oxo-5-(pyrimidin-5-ylmethyl)pyrimidin-1-yl]phenyl]-N-methylmethanesulfonamide —— C31H27F2N5O3S2
    N-[(4-fluorophenyl)methyl]-1-[4-[2-[(4-fluorophenyl)methylsulfanyl]-4-oxo-5-(pyrimidin-5-ylmethyl)pyrimidin-1-yl]phenyl]-N-methylmethanesulfonamide
    —— methyl 2-[[(4R,9R,14R,19R)-3,10,13,20,26-pentazatetracyclo[20.3.1.04,9.014,19]hexacosa-1(25),22(26),23-trien-24-yl]sulfanyl]acetate —— C24H39N5O2S
    methyl 2-[[(4R,9R,14R,19R)-3,10,13,20,26-pentazatetracyclo[20.3.1.04,9.014,19]hexacosa-1(25),22(26),23-trien-24-yl]sulfanyl]acetate
    —— dichloromanganese;methyl 2-[[(4R,9R,14R,19R)-3,10,13,20,26-pentazatetracyclo[20.3.1.04,9.014,19]hexacosa-1(25),22(26),23-trien-24-yl]sulfanyl]acetate —— C24H39Cl2MnN5O2S
    dichloromanganese;methyl 2-[[(4R,9R,14R,19R)-3,10,13,20,26-pentazatetracyclo[20.3.1.04,9.014,19]hexacosa-1(25),22(26),23-trien-24-yl]sulfanyl]acetate
    —— 5-[1-[3,4-Bis(difluoromethoxy)phenyl]-2-pyridin-4-ylethyl]-2-(3-methoxyphenyl)sulfanylpyridine —— C27H22F4N2O3S
    5-[1-[3,4-Bis(difluoromethoxy)phenyl]-2-pyridin-4-ylethyl]-2-(3-methoxyphenyl)sulfanylpyridine
    —— 32-Aminodotriacontane-1-thiol —— C32H67NS
    32-Aminodotriacontane-1-thiol
    —— [(E)-[(2Z)-5,5-dimethyl-2-(6-oxo-1,3-benzothiazol-2-ylidene)-1,3-thiazolidin-4-ylidene]-phenylsulfanylmethyl] dihydrogen phosphate —— C19H17N2O5PS3
    [(E)-[(2Z)-5,5-dimethyl-2-(6-oxo-1,3-benzothiazol-2-ylidene)-1,3-thiazolidin-4-ylidene]-phenylsulfanylmethyl] dihydrogen phosphate
    —— 1-cyclopropyl-4-[4-(4-fluorophenyl)sulfanylphenyl]sulfonyl-N-hydroxypiperidine-4-carboxamide —— C21H23FN2O4S2
    1-cyclopropyl-4-[4-(4-fluorophenyl)sulfanylphenyl]sulfonyl-N-hydroxypiperidine-4-carboxamide
    —— Tert-butyl 1-(3-chlorophenyl)-5-(2-fluorophenyl)sulfanyl-4-methyl-6-oxopyridazine-3-carboxylate —— C22H20ClFN2O3S
    Tert-butyl 1-(3-chlorophenyl)-5-(2-fluorophenyl)sulfanyl-4-methyl-6-oxopyridazine-3-carboxylate
    —— N-[3-chloro-4-[3-(4-methoxyoxan-4-yl)phenyl]sulfanylphenyl]-N-methylmethanesulfonamide —— C20H24ClNO4S2
    N-[3-chloro-4-[3-(4-methoxyoxan-4-yl)phenyl]sulfanylphenyl]-N-methylmethanesulfonamide
    —— 1-[5-[[5-(4-Amino-2-methylpyrimidin-5-yl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-2-methylpyrimidin-4-yl]-2,3-diethylguanidine —— C18H24N10OS
    1-[5-[[5-(4-Amino-2-methylpyrimidin-5-yl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-2-methylpyrimidin-4-yl]-2,3-diethylguanidine
    —— N-hydroxy-4-(4-phenylsulfanylphenyl)sulfonyl-1-prop-2-ynylpiperidine-4-carboxamide —— C21H22N2O4S2
    N-hydroxy-4-(4-phenylsulfanylphenyl)sulfonyl-1-prop-2-ynylpiperidine-4-carboxamide
    —— 1,2-diethyl-3-[5-[[5-(5-nitro-1H-pyrazol-3-yl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]pyrimidin-4-yl]guanidine —— C15H18N10O3S
    1,2-diethyl-3-[5-[[5-(5-nitro-1H-pyrazol-3-yl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]pyrimidin-4-yl]guanidine
    —— 1-[(3,5-Dimethylphenyl)methyl]-6-(3,5-dimethylphenyl)sulfanyl-5-propylpyrimidine-2,4-dione —— C24H28N2O2S
    1-[(3,5-Dimethylphenyl)methyl]-6-(3,5-dimethylphenyl)sulfanyl-5-propylpyrimidine-2,4-dione
    —— 5-[(3-chloro-2-fluorophenyl)methylsulfanyl]-7-(1-hydroxypropan-2-ylamino)-3H-[1,3]thiazolo[4,5-d]pyrimidin-2-one —— C15H14ClFN4O2S2
    5-[(3-chloro-2-fluorophenyl)methylsulfanyl]-7-(1-hydroxypropan-2-ylamino)-3H-[1,3]thiazolo[4,5-d]pyrimidin-2-one
    —— 7-[(1,3-dihydroxy-2-methylpropan-2-yl)amino]-5-[(2,3-dimethylphenyl)methylsulfanyl]-3H-[1,3]thiazolo[4,5-d]pyrimidin-2-one —— C18H22N4O3S2
    7-[(1,3-dihydroxy-2-methylpropan-2-yl)amino]-5-[(2,3-dimethylphenyl)methylsulfanyl]-3H-[1,3]thiazolo[4,5-d]pyrimidin-2-one
    —— Methyl 3-(2-hydroxyphenyl)sulfanyl-6-(imidazol-1-ylmethyl)-1-benzothiophene-2-carboxylate —— C20H16N2O3S2
    Methyl 3-(2-hydroxyphenyl)sulfanyl-6-(imidazol-1-ylmethyl)-1-benzothiophene-2-carboxylate
    —— 4-[(5-amino-1,3,4-thiadiazol-2-yl)thio]-6-ethyl-2-(phenylmethyl)thieno[2,3-d]pyrimidine —— C17H15N5S3
    4-[(5-amino-1,3,4-thiadiazol-2-yl)thio]-6-ethyl-2-(phenylmethyl)thieno[2,3-d]pyrimidine
    —— (Z)-cyclohexyl-hydroxy-[[5-[4-(trifluoromethoxy)phenyl]sulfanylfuran-2-yl]methylidene]azanium —— C18H19F3NO3S+
    (Z)-cyclohexyl-hydroxy-[[5-[4-(trifluoromethoxy)phenyl]sulfanylfuran-2-yl]methylidene]azanium
    —— 4-acetylthio-1-(4-phenylthiobenzyl)pyrrolidin-2-one 262288-13-1 C19H19NO2S2
    4-acetylthio-1-(4-phenylthiobenzyl)pyrrolidin-2-one
    —— 4-[2-[2-(1H-imidazol-2-ylsulfanylmethyl)-3-methylpyridin-4-yl]sulfanylethyl]morpholine —— C16H22N4OS2
    4-[2-[2-(1H-imidazol-2-ylsulfanylmethyl)-3-methylpyridin-4-yl]sulfanylethyl]morpholine
    —— 4-[[2-Amino-5-(4-chlorophenyl)sulfanylpyrimidin-4-yl]amino]phenol —— C16H13ClN4OS
    4-[[2-Amino-5-(4-chlorophenyl)sulfanylpyrimidin-4-yl]amino]phenol
    —— 4-[2-Amino-5-(4-ethylphenyl)sulfanylpyrimidin-4-yl]cyclohexan-1-one —— C18H21N3OS
    4-[2-Amino-5-(4-ethylphenyl)sulfanylpyrimidin-4-yl]cyclohexan-1-one
    —— 3-[(1-Methylimidazol-2-yl)sulfanylmethyl]-2-(pyridin-4-ylsulfanylmethyl)pyridine —— C16H16N4S2
    3-[(1-Methylimidazol-2-yl)sulfanylmethyl]-2-(pyridin-4-ylsulfanylmethyl)pyridine
    —— Allyl [(4-amino-5-benzyl-2-pyrimidinyl)sulfanyl]acetate —— C16H17N3O2S
    Allyl [(4-amino-5-benzyl-2-pyrimidinyl)sulfanyl]acetate
    —— 4-[2-[2-(1-Methylpyrrol-2-yl)sulfanylethoxy]ethylsulfanyl]phenol —— C15H19NO2S2
    4-[2-[2-(1-Methylpyrrol-2-yl)sulfanylethoxy]ethylsulfanyl]phenol
    —— (5-benzylsulfanyl-1<i>H</i>-[1,2,4]triazol-3-yl)-<i>p</i>-tolyl-amine 4288-96-4 C16H16N4S
    (5-benzylsulfanyl-1<i>H</i>-[1,2,4]triazol-3-yl)-<i>p</i>-tolyl-amine
    —— 4,5-dichloro-2-(3-chlorophenyl)sulfanyl-1H-imidazole —— C9H5Cl3N2S
    4,5-dichloro-2-(3-chlorophenyl)sulfanyl-1H-imidazole
    —— 4,5-dichloro-2-(4-propan-2-ylphenyl)sulfanyl-1H-imidazole —— C12H12Cl2N2S
    4,5-dichloro-2-(4-propan-2-ylphenyl)sulfanyl-1H-imidazole
    —— 3-(2-methylbutylsulfanyl)-N-(4-methylphenyl)-1H-1,2,4-triazol-5-amine —— C14H20N4S
    3-(2-methylbutylsulfanyl)-N-(4-methylphenyl)-1H-1,2,4-triazol-5-amine
    —— 2-phenylsulfanyl-4-bromothiophene —— C10H7BrS2
    2-phenylsulfanyl-4-bromothiophene
    —— 1-(5-Phenylsulfanylthiophen-2-yl)ethanone —— C12H10OS2
    1-(5-Phenylsulfanylthiophen-2-yl)ethanone
    —— 4,5-dichloro-2-(4-fluorophenyl)sulfanyl-1H-imidazole —— C9H5Cl2FN2S
    4,5-dichloro-2-(4-fluorophenyl)sulfanyl-1H-imidazole
    —— N-phenyl-3-thiophen-3-ylsulfanyl-1H-1,2,4-triazol-5-amine —— C12H10N4S2
    N-phenyl-3-thiophen-3-ylsulfanyl-1H-1,2,4-triazol-5-amine
    —— 6-Methyl-2-[1-(methylamino)hexan-3-ylsulfanyl]pyridine-3-carbonitrile —— C14H21N3S
    6-Methyl-2-[1-(methylamino)hexan-3-ylsulfanyl]pyridine-3-carbonitrile
    —— 2-[2-(2-Aminoethylsulfanyl)ethylsulfanyl]ethanethiol —— C6H15NS3
    2-[2-(2-Aminoethylsulfanyl)ethylsulfanyl]ethanethiol
    —— 6-methyl-4-[(E)-(4-methylsulfanylphenyl)methylideneamino]-3-sulfanylidene-2H-1,2,4-triazin-5-one —— C12H12N4OS2
    6-methyl-4-[(E)-(4-methylsulfanylphenyl)methylideneamino]-3-sulfanylidene-2H-1,2,4-triazin-5-one
    —— 3-[(2E)-2-{[4-(Methylsulfanyl)phenyl]methylidene}hydrazin-1-YL]-5-phenyl-1,2,4-triazine —— C17H15N5S
    3-[(2E)-2-{[4-(Methylsulfanyl)phenyl]methylidene}hydrazin-1-YL]-5-phenyl-1,2,4-triazine
    —— N-[(Z)-[4-(4-methylsulfanylphenyl)-3-prop-2-enyl-1,3-thiazol-2-ylidene]amino]adamantane-1-carboxamide —— C24H29N3OS2
    N-[(Z)-[4-(4-methylsulfanylphenyl)-3-prop-2-enyl-1,3-thiazol-2-ylidene]amino]adamantane-1-carboxamide
    —— N'-{[5-(1,3-benzothiazol-2-ylsulfanyl)-2-furyl]methylene}-2-(1-naphthyloxy)acetohydrazide —— C24H17N3O3S2
    N'-{[5-(1,3-benzothiazol-2-ylsulfanyl)-2-furyl]methylene}-2-(1-naphthyloxy)acetohydrazide
    —— (2R)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-1-phenylethylideneamino]propanamide —— C23H26N6OS
    (2R)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-1-phenylethylideneamino]propanamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(E)-thiophen-2-ylmethylideneamino]acetamide —— C13H11ClN2OS2
    2-(4-chlorophenyl)sulfanyl-N-[(E)-thiophen-2-ylmethylideneamino]acetamide
    —— N-[(E)-(2-chlorophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide —— C15H12Cl2N2OS
    N-[(E)-(2-chlorophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(E)-1-pyridin-2-ylethylideneamino]acetamide —— C15H14ClN3OS
    2-(4-chlorophenyl)sulfanyl-N-[(E)-1-pyridin-2-ylethylideneamino]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(E)-cyclohexylmethylideneamino]acetamide —— C15H19ClN2OS
    2-(4-chlorophenyl)sulfanyl-N-[(E)-cyclohexylmethylideneamino]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(E)-thiophen-3-ylmethylideneamino]acetamide —— C13H11ClN2OS2
    2-(4-chlorophenyl)sulfanyl-N-[(E)-thiophen-3-ylmethylideneamino]acetamide
    —— N-[(E)-(2-chloro-6-fluorophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide —— C15H11Cl2FN2OS
    N-[(E)-(2-chloro-6-fluorophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide