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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(7-ethyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C17H23N5O4S
    2-(7-ethyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— 2-(7-ethyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C17H23N5O4S
    2-(7-ethyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— 3-[[2-[(4-Amino-5-butyl-1,2,4-triazol-3-yl)sulfanylmethyl]phenyl]methylsulfanyl]-5-butyl-1,2,4-triazol-4-amine —— C20H30N8S2
    3-[[2-[(4-Amino-5-butyl-1,2,4-triazol-3-yl)sulfanylmethyl]phenyl]methylsulfanyl]-5-butyl-1,2,4-triazol-4-amine
    —— (2R)-N-(2,3-dihydroimidazo[2,1-b][1,3]thiazol-6-ylmethyl)-2-pyrazol-1-ylbutanamide —— C13H17N5OS
    (2R)-N-(2,3-dihydroimidazo[2,1-b][1,3]thiazol-6-ylmethyl)-2-pyrazol-1-ylbutanamide
    —— (3R)-1-methyl-3-[(10R)-9-oxa-2-thiatricyclo[9.4.0.0^{3,8}]pentadeca-1(15),3,5,7,11,13-hexaen-10-ylmethyl]piperidin-1-ium —— C20H24NOS+
    (3R)-1-methyl-3-[(10R)-9-oxa-2-thiatricyclo[9.4.0.0^{3,8}]pentadeca-1(15),3,5,7,11,13-hexaen-10-ylmethyl]piperidin-1-ium
    —— 2-[[5-[(3-Chloro-4-methylanilino)methyl]-4-ethyl-1,2,4-triazol-3-yl]sulfanyl]acetate —— C14H16ClN4O2S-
    2-[[5-[(3-Chloro-4-methylanilino)methyl]-4-ethyl-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 4-[(6S)-8-chloro-2-fluoro-6H-benzo[b][4,1]benzoxathiepin-6-yl]-1-methylpiperidin-1-ium —— C19H20ClFNOS+
    4-[(6S)-8-chloro-2-fluoro-6H-benzo[b][4,1]benzoxathiepin-6-yl]-1-methylpiperidin-1-ium
    —— (3R,4S)-6-amino-2-imino-4-(4-methylsulfanylphenyl)-3,4-dihydrothiopyran-3,5-dicarbonitrile —— C14H12N4S2
    (3R,4S)-6-amino-2-imino-4-(4-methylsulfanylphenyl)-3,4-dihydrothiopyran-3,5-dicarbonitrile
    —— 2-[[5-[(3-Chloro-4-methylanilino)methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetate —— C13H14ClN4O2S-
    2-[[5-[(3-Chloro-4-methylanilino)methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 6-methyl-2-[(1R)-1-[2-[(2-methylphenyl)methyl]-1,2,4-triazol-3-yl]ethyl]sulfanyl-1H-pyrimidin-4-one —— C17H19N5OS
    6-methyl-2-[(1R)-1-[2-[(2-methylphenyl)methyl]-1,2,4-triazol-3-yl]ethyl]sulfanyl-1H-pyrimidin-4-one
    —— 6-methyl-2-[(1S)-1-[2-[(2-methylphenyl)methyl]-1,2,4-triazol-3-yl]ethyl]sulfanyl-1H-pyrimidin-4-one —— C17H19N5OS
    6-methyl-2-[(1S)-1-[2-[(2-methylphenyl)methyl]-1,2,4-triazol-3-yl]ethyl]sulfanyl-1H-pyrimidin-4-one
    —— methyl (1R,6R)-3-(4-chlorophenyl)sulfanyl-2-hydroxy-4-oxo-6-phenylcyclohex-2-ene-1-carboxylate —— C20H17ClO4S
    methyl (1R,6R)-3-(4-chlorophenyl)sulfanyl-2-hydroxy-4-oxo-6-phenylcyclohex-2-ene-1-carboxylate
    —— (5S)-5-(4-chlorophenyl)sulfanyl-1,3-thiazolidine-2,4-dione —— C9H6ClNO2S2
    (5S)-5-(4-chlorophenyl)sulfanyl-1,3-thiazolidine-2,4-dione
    —— (2R)-N-[(Z)-butan-2-ylideneamino]-2-phenylsulfanylpropanamide —— C13H18N2OS
    (2R)-N-[(Z)-butan-2-ylideneamino]-2-phenylsulfanylpropanamide
    —— N-(1-adamantyl)-3,3-dimethylbutanethioamide —— C16H27NS
    N-(1-adamantyl)-3,3-dimethylbutanethioamide
    —— (3R)-N,N-diethyl-5-phenyl-3-phenylsulfanyl-3H-azepin-2-amine —— C22H24N2S
    (3R)-N,N-diethyl-5-phenyl-3-phenylsulfanyl-3H-azepin-2-amine
    —— ethyl (2S)-2-pyrazin-2-ylsulfanylpropanoate —— C9H12N2O2S
    ethyl (2S)-2-pyrazin-2-ylsulfanylpropanoate
    —— (2S)-2-pyrazin-2-ylsulfanylpropanoic acid —— C7H8N2O2S
    (2S)-2-pyrazin-2-ylsulfanylpropanoic acid
    —— (2R)-2-pyrazin-2-ylsulfanylpropanoate —— C7H7N2O2S-
    (2R)-2-pyrazin-2-ylsulfanylpropanoate
    —— (2R)-2-pyrazin-2-ylsulfanylpropanoic acid —— C7H8N2O2S
    (2R)-2-pyrazin-2-ylsulfanylpropanoic acid
    —— ethyl (2S)-2-[[4-[(4-fluorophenyl)methyl]-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]propanoate —— C15H15F4N3O2S
    ethyl (2S)-2-[[4-[(4-fluorophenyl)methyl]-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]propanoate
    —— (2S)-1-[5-methyl-3-(phenylsulfanylmethyl)-1,2,4-triazol-1-yl]butan-2-ol —— C14H19N3OS
    (2S)-1-[5-methyl-3-(phenylsulfanylmethyl)-1,2,4-triazol-1-yl]butan-2-ol
    —— (2R)-1-[5-methyl-3-(phenylsulfanylmethyl)-1,2,4-triazol-1-yl]butan-2-ol —— C14H19N3OS
    (2R)-1-[5-methyl-3-(phenylsulfanylmethyl)-1,2,4-triazol-1-yl]butan-2-ol
    —— (3S)-3-amino-3-(4-methylsulfanylphenyl)propan-1-ol —— C10H15NOS
    (3S)-3-amino-3-(4-methylsulfanylphenyl)propan-1-ol
    —— 7-(Furan-2-yl)-1,3-dimethyl-5-(pyridin-3-ylmethylsulfanyl)pyrimido[4,5-d]pyrimidine-2,4-dione —— C18H15N5O3S
    7-(Furan-2-yl)-1,3-dimethyl-5-(pyridin-3-ylmethylsulfanyl)pyrimido[4,5-d]pyrimidine-2,4-dione
    —— 1-[(6S)-4-(6-amino-2-methylsulfanylpyrimidin-4-yl)-6-hydroxy-1,4-diazepan-1-yl]ethanone —— C12H19N5O2S
    1-[(6S)-4-(6-amino-2-methylsulfanylpyrimidin-4-yl)-6-hydroxy-1,4-diazepan-1-yl]ethanone
    —— 1-[(6R)-4-(6-amino-2-methylsulfanylpyrimidin-4-yl)-6-hydroxy-1,4-diazepan-1-yl]ethanone —— C12H19N5O2S
    1-[(6R)-4-(6-amino-2-methylsulfanylpyrimidin-4-yl)-6-hydroxy-1,4-diazepan-1-yl]ethanone
    —— 2-ethylsulfanyl-5-[1-[[(3R)-1-methylsulfonylpiperidin-3-yl]methyl]triazol-4-yl]pyrimidine —— C15H22N6O2S2
    2-ethylsulfanyl-5-[1-[[(3R)-1-methylsulfonylpiperidin-3-yl]methyl]triazol-4-yl]pyrimidine
    —— 2-ethylsulfanyl-5-[1-[[(3S)-1-methylsulfonylpiperidin-3-yl]methyl]triazol-4-yl]pyrimidine —— C15H22N6O2S2
    2-ethylsulfanyl-5-[1-[[(3S)-1-methylsulfonylpiperidin-3-yl]methyl]triazol-4-yl]pyrimidine
    —— (5R)-5-methyl-N-(3-phenylsulfanylpropyl)-1,4-oxazepane-4-carboxamide —— C16H24N2O2S
    (5R)-5-methyl-N-(3-phenylsulfanylpropyl)-1,4-oxazepane-4-carboxamide
    —— (5S)-5-methyl-N-(3-phenylsulfanylpropyl)-1,4-oxazepane-4-carboxamide —— C16H24N2O2S
    (5S)-5-methyl-N-(3-phenylsulfanylpropyl)-1,4-oxazepane-4-carboxamide
    —— 4-methyl-3-[(1R)-1-[4-[5-(4-methylphenyl)sulfanylfuran-2-yl]triazol-1-yl]ethyl]-1,2,4-triazole —— C18H18N6OS
    4-methyl-3-[(1R)-1-[4-[5-(4-methylphenyl)sulfanylfuran-2-yl]triazol-1-yl]ethyl]-1,2,4-triazole
    —— 4-methyl-3-[(1S)-1-[4-[5-(4-methylphenyl)sulfanylfuran-2-yl]triazol-1-yl]ethyl]-1,2,4-triazole —— C18H18N6OS
    4-methyl-3-[(1S)-1-[4-[5-(4-methylphenyl)sulfanylfuran-2-yl]triazol-1-yl]ethyl]-1,2,4-triazole
    —— (2R)-2-(4-chlorophenyl)sulfanylpropanoate —— C9H8ClO2S-
    (2R)-2-(4-chlorophenyl)sulfanylpropanoate
    —— 4-[(1S)-cyclohex-3-en-1-yl]-2-prop-2-enylsulfanyl-6,7-dihydro-5H-cyclopenta[b]pyridine-3-carbonitrile —— C18H20N2S
    4-[(1S)-cyclohex-3-en-1-yl]-2-prop-2-enylsulfanyl-6,7-dihydro-5H-cyclopenta[b]pyridine-3-carbonitrile
    —— 2-[[4-Ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C10H10N3O3S-
    2-[[4-Ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 2-[(1S)-1-chloro-2,2,2-trifluoroethyl]sulfanylpyridine —— C7H5ClF3NS
    2-[(1S)-1-chloro-2,2,2-trifluoroethyl]sulfanylpyridine
    —— 2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]ethylazanium —— C5H9N4O2S+
    2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]ethylazanium
    —— 2-methylsulfanyl-4-[(3S)-3-[1-(pyridin-4-ylmethyl)imidazol-2-yl]piperidin-1-yl]pyrimidine —— C19H22N6S
    2-methylsulfanyl-4-[(3S)-3-[1-(pyridin-4-ylmethyl)imidazol-2-yl]piperidin-1-yl]pyrimidine
    —— 2-methylsulfanyl-4-[(3R)-3-[1-(pyridin-4-ylmethyl)imidazol-2-yl]piperidin-1-yl]pyrimidine —— C19H22N6S
    2-methylsulfanyl-4-[(3R)-3-[1-(pyridin-4-ylmethyl)imidazol-2-yl]piperidin-1-yl]pyrimidine
    —— {[5-(4-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetate 49809-28-1 C10H6ClN2O3S-
    {[5-(4-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetate
    —— (1'S,5'R)-spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxylate —— C12H17O2S2-
    (1'S,5'R)-spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxylate
    —— (1R,5S)-spiro[bicyclo[3.3.1]nonane-9,2'-[1,3]dithiolane]-3-carboxylic acid —— C12H18O2S2
    (1R,5S)-spiro[bicyclo[3.3.1]nonane-9,2'-[1,3]dithiolane]-3-carboxylic acid
    —— 2-(2,3-Dihydroimidazo[2,1-b][1,3]thiazol-6-yl)ethylazanium —— C7H12N3S+
    2-(2,3-Dihydroimidazo[2,1-b][1,3]thiazol-6-yl)ethylazanium
    —— 2-[4-[[(2R)-oxolan-2-yl]methyl]phenyl]sulfanylacetamide —— C13H17NO2S
    2-[4-[[(2R)-oxolan-2-yl]methyl]phenyl]sulfanylacetamide
    —— 2-[4-[[(2S)-oxolan-2-yl]methyl]phenyl]sulfanylacetamide —— C13H17NO2S
    2-[4-[[(2S)-oxolan-2-yl]methyl]phenyl]sulfanylacetamide
    —— methyl (1S,6R)-3-(4-chlorophenyl)sulfanyl-2-hydroxy-4-oxo-6-phenylcyclohex-2-ene-1-carboxylate —— C20H17ClO4S
    methyl (1S,6R)-3-(4-chlorophenyl)sulfanyl-2-hydroxy-4-oxo-6-phenylcyclohex-2-ene-1-carboxylate
    —— 2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(2S)-2-(3-pyridin-2-yl-1,2,4-oxadiazol-5-yl)pyrrolidin-1-yl]ethanone —— C16H17N7O2S
    2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(2S)-2-(3-pyridin-2-yl-1,2,4-oxadiazol-5-yl)pyrrolidin-1-yl]ethanone
    —— 2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(2R)-2-(3-pyridin-2-yl-1,2,4-oxadiazol-5-yl)pyrrolidin-1-yl]ethanone —— C16H17N7O2S
    2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(2R)-2-(3-pyridin-2-yl-1,2,4-oxadiazol-5-yl)pyrrolidin-1-yl]ethanone
    —— (2R)-2,3,3,3-tetrafluoro-2-methoxy-N-(3-nitro-5-phenylsulfanylphenyl)propanamide —— C16H12F4N2O4S
    (2R)-2,3,3,3-tetrafluoro-2-methoxy-N-(3-nitro-5-phenylsulfanylphenyl)propanamide