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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [2-[[(1R)-1-(3,4-dimethylphenyl)ethyl]amino]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylacetate —— C22H27NO3S
    [2-[[(1R)-1-(3,4-dimethylphenyl)ethyl]amino]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylacetate
    —— [(2R)-1-(furan-2-ylmethylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylacetate —— C18H21NO4S
    [(2R)-1-(furan-2-ylmethylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylacetate
    —— ethyl (3S,4S)-3-cyano-6-methyl-4-(4-methylsulfanylphenyl)-2-oxo-3,4-dihydro-1H-pyridine-5-carboxylate —— C17H18N2O3S
    ethyl (3S,4S)-3-cyano-6-methyl-4-(4-methylsulfanylphenyl)-2-oxo-3,4-dihydro-1H-pyridine-5-carboxylate
    —— [(2R)-1-(benzylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylacetate —— C20H23NO3S
    [(2R)-1-(benzylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylacetate
    —— [2-[2-(4-Fluorophenyl)ethylamino]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylacetate —— C20H22FNO3S
    [2-[2-(4-Fluorophenyl)ethylamino]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylacetate
    —— [2-[2-(2,4-Dioxo-1,3-thiazolidin-3-yl)ethylamino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C17H20N2O5S2
    [2-[2-(2,4-Dioxo-1,3-thiazolidin-3-yl)ethylamino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylacetate —— C16H21NO3S
    [(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylacetate
    —— [2-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C20H23NO4S
    [2-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [2-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylacetate —— C22H24N2O4S
    [2-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylacetate
    —— [2-[2-(4-Chlorophenyl)ethylamino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C20H22ClNO3S
    [2-[2-(4-Chlorophenyl)ethylamino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [2-[2,5-dimethyl-1-[[(2S)-oxolan-2-yl]methyl]pyrrol-3-yl]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylacetate —— C23H29NO4S
    [2-[2,5-dimethyl-1-[[(2S)-oxolan-2-yl]methyl]pyrrol-3-yl]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylacetate
    —— [(2R)-1-(cyclopentylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylacetate —— C18H25NO3S
    [(2R)-1-(cyclopentylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylacetate
    —— [(2S)-1-(benzylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylacetate —— C20H23NO3S
    [(2S)-1-(benzylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylacetate
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C11H18N4O3S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (2R)-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C8H14N4OS
    (2R)-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— N-[2-(4-chlorophenyl)ethyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C15H19ClN4OS
    N-[2-(4-chlorophenyl)ethyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-(1-cyanocyclopentyl)-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C13H19N5OS
    N-(1-cyanocyclopentyl)-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-[(5-Cyano-2-pyridinyl)thio]acetamide, AldrichCPR —— C8H7N3OS
    2-[(5-Cyano-2-pyridinyl)thio]acetamide, AldrichCPR
    —— 2-(Allylthio)-5-chloropyridine, AldrichCPR —— C8H8ClNS
    2-(Allylthio)-5-chloropyridine, AldrichCPR
    —— 2-[(4-Cyano-2-pyridinyl)thio]acetamide, AldrichCPR —— C8H7N3OS
    2-[(4-Cyano-2-pyridinyl)thio]acetamide, AldrichCPR
    —— 5-Chloro-2-(ethylthio)pyrimidine —— C6H7ClN2S
    5-Chloro-2-(ethylthio)pyrimidine
    —— 2-[(5-Chloro-2-pyrimidinyl)thio]acetamide, AldrichCPR —— C6H6ClN3OS
    2-[(5-Chloro-2-pyrimidinyl)thio]acetamide, AldrichCPR
    —— 2-(Allylthio)-5-bromopyridine, AldrichCPR —— C8H8BrNS
    2-(Allylthio)-5-bromopyridine, AldrichCPR
    —— 2-(Allylthio)pyridine-5-carbonitrile, AldrichCPR —— C9H8N2S
    2-(Allylthio)pyridine-5-carbonitrile, AldrichCPR
    —— 2-(Allylthio)-3-bromopyridine, AldrichCPR —— C8H8BrNS
    2-(Allylthio)-3-bromopyridine, AldrichCPR
    —— 1-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-3,3-dimethylbutan-2-one —— C23H25N3OS
    1-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-3,3-dimethylbutan-2-one
    —— 2-[4-chloro-6-(diethylamino)pyrimidin-2-yl]sulfanyl-N-[(2S)-4-phenylbutan-2-yl]acetamide —— C20H27ClN4OS
    2-[4-chloro-6-(diethylamino)pyrimidin-2-yl]sulfanyl-N-[(2S)-4-phenylbutan-2-yl]acetamide
    —— 3-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-5,6-bis(4-methylphenyl)-1,2,4-triazine —— C25H22FN3S
    3-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-5,6-bis(4-methylphenyl)-1,2,4-triazine
    —— Ethyl 4-(4-ethyl-1-methyl-6-oxopyrimidin-2-yl)sulfanylbutanoate —— C13H20N2O3S
    Ethyl 4-(4-ethyl-1-methyl-6-oxopyrimidin-2-yl)sulfanylbutanoate
    —— methyl (2S)-2-(5-benzyl-1,4-dimethyl-6-oxopyrimidin-2-yl)sulfanylpropanoate —— C17H20N2O3S
    methyl (2S)-2-(5-benzyl-1,4-dimethyl-6-oxopyrimidin-2-yl)sulfanylpropanoate
    —— 2-[(3,5-Difluorophenyl)methylsulfanyl]-3-methyl-6-propan-2-ylpyrimidin-4-one —— C15H16F2N2OS
    2-[(3,5-Difluorophenyl)methylsulfanyl]-3-methyl-6-propan-2-ylpyrimidin-4-one
    —— 2-[(4-Fluorophenyl)methylsulfanyl]-3-methyl-6-propylpyrimidin-4-one —— C15H17FN2OS
    2-[(4-Fluorophenyl)methylsulfanyl]-3-methyl-6-propylpyrimidin-4-one
    —— (4R)-4-methyl-11-propan-2-yl-5-thia-2,7,13-triaza-11-azoniatricyclo[7.4.0.02,6]trideca-1(9),6-dien-8-one —— C12H19N4OS+
    (4R)-4-methyl-11-propan-2-yl-5-thia-2,7,13-triaza-11-azoniatricyclo[7.4.0.02,6]trideca-1(9),6-dien-8-one
    —— 2-[[6-cyclopentyl-1-(furan-2-ylmethyl)-4-oxo-1,5,7,8-tetrahydropyrimido[4,5-d]pyrimidin-1-ium-2-yl]sulfanyl]acetonitrile —— C18H22N5O2S+
    2-[[6-cyclopentyl-1-(furan-2-ylmethyl)-4-oxo-1,5,7,8-tetrahydropyrimido[4,5-d]pyrimidin-1-ium-2-yl]sulfanyl]acetonitrile
    —— (1'S,2S,4S,5'R,6'R)-2'-amino-4-methyl-6'-(4-methylsulfanylphenyl)spiro[1,3-dioxolane-2,4'-3-azabicyclo[3.1.0]hex-2-ene]-1',5'-dicarbonitrile —— C17H16N4O2S
    (1'S,2S,4S,5'R,6'R)-2'-amino-4-methyl-6'-(4-methylsulfanylphenyl)spiro[1,3-dioxolane-2,4'-3-azabicyclo[3.1.0]hex-2-ene]-1',5'-dicarbonitrile
    —— N-[[(2S)-oxiran-2-yl]methyl]-2-phenylsulfanylacetamide —— C11H13NO2S
    N-[[(2S)-oxiran-2-yl]methyl]-2-phenylsulfanylacetamide
    —— N-[[(2R)-oxiran-2-yl]methyl]-2-phenylsulfanylacetamide —— C11H13NO2S
    N-[[(2R)-oxiran-2-yl]methyl]-2-phenylsulfanylacetamide
    —— 4,4-dimethyl-11-propan-2-yl-5-thia-7,11,13-triaza-2-azoniatricyclo[7.4.0.02,6]trideca-1(9),6-dien-8-one —— C13H21N4OS+
    4,4-dimethyl-11-propan-2-yl-5-thia-7,11,13-triaza-2-azoniatricyclo[7.4.0.02,6]trideca-1(9),6-dien-8-one
    —— 1-cyclopropyl-3-[(2R)-2-methylbutyl]thiourea —— C9H18N2S
    1-cyclopropyl-3-[(2R)-2-methylbutyl]thiourea
    —— 1-{[5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}propan-2-one —— C9H8N2O3S
    1-{[5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}propan-2-one
    —— 2-{[5-(4-Bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}-1-(pyrrolidin-1-yl)ethanone —— C14H14BrN3O2S
    2-{[5-(4-Bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}-1-(pyrrolidin-1-yl)ethanone
    —— 1-(3-Chlorophenyl)-3-[2-(phenylsulfanyl)phenyl]thiourea —— C19H15ClN2S2
    1-(3-Chlorophenyl)-3-[2-(phenylsulfanyl)phenyl]thiourea
    —— 9-[(4-Chlorophenyl)sulfanyl]-5-methylbenzimidazo[2,1-a]phthalazine —— C21H14ClN3S
    9-[(4-Chlorophenyl)sulfanyl]-5-methylbenzimidazo[2,1-a]phthalazine
    —— 2-[[4-Methyl-5-(morpholin-4-ium-4-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-1-pyrrolidin-1-ylethanone —— C14H24N5O2S+
    2-[[4-Methyl-5-(morpholin-4-ium-4-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-1-pyrrolidin-1-ylethanone
    —— ethyl (3aR,7aR)-2-[[2-(1-methyltetrazol-5-yl)sulfanylacetyl]amino]-3a,4,5,6,7,7a-hexahydro-1-benzothiophene-3-carboxylate —— C15H21N5O3S2
    ethyl (3aR,7aR)-2-[[2-(1-methyltetrazol-5-yl)sulfanylacetyl]amino]-3a,4,5,6,7,7a-hexahydro-1-benzothiophene-3-carboxylate
    —— N-[(E)-1-(4-aminophenyl)ethylideneamino]-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C12H14N6OS2
    N-[(E)-1-(4-aminophenyl)ethylideneamino]-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— 3-Methyl-2-[(2-methylphenyl)methylsulfanyl]-6-propan-2-ylpyrimidin-4-one —— C16H20N2OS
    3-Methyl-2-[(2-methylphenyl)methylsulfanyl]-6-propan-2-ylpyrimidin-4-one
    —— 2-[5-[(3-fluorophenyl)methyl]-1,4-dimethyl-6-oxopyrimidin-2-yl]sulfanyl-N,N-di(propan-2-yl)acetamide —— C21H28FN3O2S
    2-[5-[(3-fluorophenyl)methyl]-1,4-dimethyl-6-oxopyrimidin-2-yl]sulfanyl-N,N-di(propan-2-yl)acetamide
    —— (8R,8aR)-6-imino-8-(4-methylsulfanylphenyl)-2-propan-2-yl-1,2,3,5,8,8a-hexahydroisoquinolin-2-ium-5,7,7-tricarbonitrile —— C22H24N5S+
    (8R,8aR)-6-imino-8-(4-methylsulfanylphenyl)-2-propan-2-yl-1,2,3,5,8,8a-hexahydroisoquinolin-2-ium-5,7,7-tricarbonitrile
    —— (8R,8aS)-6-imino-8-(4-methylsulfanylphenyl)-2-propan-2-yl-3,5,8,8a-tetrahydro-1H-isoquinoline-5,7,7-tricarbonitrile —— C22H23N5S
    (8R,8aS)-6-imino-8-(4-methylsulfanylphenyl)-2-propan-2-yl-3,5,8,8a-tetrahydro-1H-isoquinoline-5,7,7-tricarbonitrile