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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (1S,6S)-6-methyl-1,4-thiazepane 1-oxide —— C6H13NOS
    (1S,6S)-6-methyl-1,4-thiazepane 1-oxide
    —— (1S,6R)-6-methyl-1,4-thiazepane 1-oxide —— C6H13NOS
    (1S,6R)-6-methyl-1,4-thiazepane 1-oxide
    —— (6S)-6-methyl-1,4-thiazepane 1,1-dioxide —— C6H13NO2S
    (6S)-6-methyl-1,4-thiazepane 1,1-dioxide
    —— 2-{[5-(4-chlorobenzyl)-4-methyl-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide —— C12H13ClN4OS
    2-{[5-(4-chlorobenzyl)-4-methyl-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide
    —— ethyl {[5-(2-methylfuran-3-yl)-4-(propan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetate —— C14H19N3O3S
    ethyl {[5-(2-methylfuran-3-yl)-4-(propan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetate
    —— 2-{[5-(5-methylthiophen-3-yl)-4-(tetrahydrofuran-2-ylmethyl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide —— C14H18N4O2S2
    2-{[5-(5-methylthiophen-3-yl)-4-(tetrahydrofuran-2-ylmethyl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide
    —— N-[[(1R,2S,4R)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-2-ethyl-2-methylsulfonylbutan-1-amine —— C15H27NO2S
    N-[[(1R,2S,4R)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-2-ethyl-2-methylsulfonylbutan-1-amine
    —— N-[[(1R,2R,4R)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-2-ethyl-2-methylsulfonylbutan-1-amine —— C15H27NO2S
    N-[[(1R,2R,4R)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-2-ethyl-2-methylsulfonylbutan-1-amine
    —— 3-[(3-chlorobenzyl)sulfanyl]-4-ethyl-5-methyl-4H-1,2,4-triazole —— C12H14ClN3S
    3-[(3-chlorobenzyl)sulfanyl]-4-ethyl-5-methyl-4H-1,2,4-triazole
    —— N-cyclopropyl-2-{[4-ethyl-5-(5-methylthiophen-3-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide —— C14H18N4OS2
    N-cyclopropyl-2-{[4-ethyl-5-(5-methylthiophen-3-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide
    —— (5S)-5-methyl-1,4-thiazepane 1,1-dioxide —— C6H13NO2S
    (5S)-5-methyl-1,4-thiazepane 1,1-dioxide
    —— (1S,5S)-5-methyl-1,4-thiazepane 1-oxide —— C6H13NOS
    (1S,5S)-5-methyl-1,4-thiazepane 1-oxide
    —— 4-Methyl-2-[(2-methylbenzyl)sulfanyl]pyrimidine —— C13H14N2S
    4-Methyl-2-[(2-methylbenzyl)sulfanyl]pyrimidine
    —— methyl {[4-methyl-5-(thiophen-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetate —— C10H11N3O2S2
    methyl {[4-methyl-5-(thiophen-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetate
    —— 2-(cyclohexen-1-yl)-N-methyl-N-[(1R,2R)-2-methylsulfonylcyclopentyl]acetamide —— C15H25NO3S
    2-(cyclohexen-1-yl)-N-methyl-N-[(1R,2R)-2-methylsulfonylcyclopentyl]acetamide
    —— 2-{[4-methyl-5-(5-propylthiophen-3-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide —— C12H16N4OS2
    2-{[4-methyl-5-(5-propylthiophen-3-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide
    —— 2-{[5-(5-methylthiophen-3-yl)-4-propyl-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide —— C12H16N4OS2
    2-{[5-(5-methylthiophen-3-yl)-4-propyl-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide
    —— 2-(cyclohexen-1-yl)-N-methyl-N-[(1S,2R)-2-methylsulfonylcyclopentyl]acetamide —— C15H25NO3S
    2-(cyclohexen-1-yl)-N-methyl-N-[(1S,2R)-2-methylsulfonylcyclopentyl]acetamide
    —— N-cyclopropyl-2-[(4,5-diethyl-4H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C11H18N4OS
    N-cyclopropyl-2-[(4,5-diethyl-4H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-cyclopentyl-2-[(5-cyclopropyl-4-ethyl-4H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C14H22N4OS
    N-cyclopentyl-2-[(5-cyclopropyl-4-ethyl-4H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (1S,5R)-5-methyl-1,4-thiazepane 1-oxide —— C6H13NOS
    (1S,5R)-5-methyl-1,4-thiazepane 1-oxide
    —— (3S)-3-[(1-tert-butylimidazol-2-yl)sulfanylmethyl]-1-methylsulfonylpiperidine —— C14H25N3O2S2
    (3S)-3-[(1-tert-butylimidazol-2-yl)sulfanylmethyl]-1-methylsulfonylpiperidine
    —— (1R,5R)-5-methyl-1,4-thiazepane 1-oxide —— C6H13NOS
    (1R,5R)-5-methyl-1,4-thiazepane 1-oxide
    —— 3-cyclopentyl-5-[(3-fluorobenzyl)sulfanyl]-4-methyl-4H-1,2,4-triazole —— C15H18FN3S
    3-cyclopentyl-5-[(3-fluorobenzyl)sulfanyl]-4-methyl-4H-1,2,4-triazole
    —— (5R)-5-methyl-1,4-thiazepane 1,1-dioxide —— C6H13NO2S
    (5R)-5-methyl-1,4-thiazepane 1,1-dioxide
    —— (1R,5S)-5-methyl-1,4-thiazepane 1-oxide —— C6H13NOS
    (1R,5S)-5-methyl-1,4-thiazepane 1-oxide
    —— 2-(cyclohexen-1-yl)-N-methyl-N-[(1R,2S)-2-methylsulfonylcyclopentyl]acetamide —— C15H25NO3S
    2-(cyclohexen-1-yl)-N-methyl-N-[(1R,2S)-2-methylsulfonylcyclopentyl]acetamide
    —— ethyl {[5-(furan-2-yl)-4-(tetrahydrofuran-2-ylmethyl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetate —— C15H19N3O4S
    ethyl {[5-(furan-2-yl)-4-(tetrahydrofuran-2-ylmethyl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetate
    —— (3R)-3-[(1-tert-butylimidazol-2-yl)sulfanylmethyl]-1-methylsulfonylpiperidine —— C14H25N3O2S2
    (3R)-3-[(1-tert-butylimidazol-2-yl)sulfanylmethyl]-1-methylsulfonylpiperidine
    —— 4-Oxo-4-{[2-(phenylsulfanyl)phenyl]amino}butanoic acid —— C16H15NO3S
    4-Oxo-4-{[2-(phenylsulfanyl)phenyl]amino}butanoic acid
    —— 2-{[5-(propan-2-yl)-4-(prop-2-en-1-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide —— C10H16N4OS
    2-{[5-(propan-2-yl)-4-(prop-2-en-1-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide
    —— 2-(cyclohexen-1-yl)-N-methyl-N-[(1S,2S)-2-methylsulfonylcyclopentyl]acetamide —— C15H25NO3S
    2-(cyclohexen-1-yl)-N-methyl-N-[(1S,2S)-2-methylsulfonylcyclopentyl]acetamide
    —— 3-[(2-chloro-6-fluorobenzyl)sulfanyl]-4,5-dimethyl-4H-1,2,4-triazole —— C11H11ClFN3S
    3-[(2-chloro-6-fluorobenzyl)sulfanyl]-4,5-dimethyl-4H-1,2,4-triazole
    —— 3-[(2S)-3-hydroxy-2-methylpropyl]sulfanyl-5,6-dimethylpyridazine-4-carbonitrile —— C11H15N3OS
    3-[(2S)-3-hydroxy-2-methylpropyl]sulfanyl-5,6-dimethylpyridazine-4-carbonitrile
    —— 3-[(2R)-3-hydroxy-2-methylpropyl]sulfanyl-5,6-dimethylpyridazine-4-carbonitrile —— C11H15N3OS
    3-[(2R)-3-hydroxy-2-methylpropyl]sulfanyl-5,6-dimethylpyridazine-4-carbonitrile
    —— (2-{[2-(Morpholin-4-ylmethyl)phenyl]thio}benzyl)amine dihydrochloride —— C18H24Cl2N2OS
    (2-{[2-(Morpholin-4-ylmethyl)phenyl]thio}benzyl)amine dihydrochloride
    —— (2R)-2-pyridin-2-ylsulfanyl-N-[(3-thiophen-2-yl-1H-1,2,4-triazol-5-yl)methyl]propanamide —— C15H15N5OS2
    (2R)-2-pyridin-2-ylsulfanyl-N-[(3-thiophen-2-yl-1H-1,2,4-triazol-5-yl)methyl]propanamide
    —— (2R)-N-[(1R)-1-(5-methyl-1H-1,2,4-triazol-3-yl)propyl]-2-pyridin-2-ylsulfanylpropanamide —— C14H19N5OS
    (2R)-N-[(1R)-1-(5-methyl-1H-1,2,4-triazol-3-yl)propyl]-2-pyridin-2-ylsulfanylpropanamide
    —— (2R)-1-[(2R)-2-(methoxymethyl)pyrrolidin-1-yl]-2-pyridin-2-ylsulfanylpropan-1-one —— C14H20N2O2S
    (2R)-1-[(2R)-2-(methoxymethyl)pyrrolidin-1-yl]-2-pyridin-2-ylsulfanylpropan-1-one
    —— (2R)-1-[4-[(3S)-1-methylpiperidin-3-yl]piperazin-1-yl]-2-pyridin-2-ylsulfanylpropan-1-one —— C18H28N4OS
    (2R)-1-[4-[(3S)-1-methylpiperidin-3-yl]piperazin-1-yl]-2-pyridin-2-ylsulfanylpropan-1-one
    —— (2S)-N-[(6-methylpyridin-2-yl)methyl]-N-prop-2-ynyl-2-pyridin-2-ylsulfanylpropanamide —— C18H19N3OS
    (2S)-N-[(6-methylpyridin-2-yl)methyl]-N-prop-2-ynyl-2-pyridin-2-ylsulfanylpropanamide
    —— (2R)-2-pyridin-2-ylsulfanyl-1-[(2R)-2-thiophen-3-ylpyrrolidin-1-yl]propan-1-one —— C16H18N2OS2
    (2R)-2-pyridin-2-ylsulfanyl-1-[(2R)-2-thiophen-3-ylpyrrolidin-1-yl]propan-1-one
    —— (2S)-1-[(2R)-2-(methoxymethyl)pyrrolidin-1-yl]-2-pyridin-2-ylsulfanylpropan-1-one —— C14H20N2O2S
    (2S)-1-[(2R)-2-(methoxymethyl)pyrrolidin-1-yl]-2-pyridin-2-ylsulfanylpropan-1-one
    —— (2R)-2-pyridin-2-ylsulfanyl-1-(4-pyrimidin-2-yl-1,4-diazepan-1-yl)propan-1-one —— C17H21N5OS
    (2R)-2-pyridin-2-ylsulfanyl-1-(4-pyrimidin-2-yl-1,4-diazepan-1-yl)propan-1-one
    —— (2R)-N-[(6-methylpyridin-2-yl)methyl]-N-prop-2-ynyl-2-pyridin-2-ylsulfanylpropanamide —— C18H19N3OS
    (2R)-N-[(6-methylpyridin-2-yl)methyl]-N-prop-2-ynyl-2-pyridin-2-ylsulfanylpropanamide
    —— (2S)-2-pyridin-2-ylsulfanyl-N-[(3-thiophen-2-yl-1H-1,2,4-triazol-5-yl)methyl]propanamide —— C15H15N5OS2
    (2S)-2-pyridin-2-ylsulfanyl-N-[(3-thiophen-2-yl-1H-1,2,4-triazol-5-yl)methyl]propanamide
    —— (2R)-1-[4-[(3R)-1-methylpiperidin-3-yl]piperazin-1-yl]-2-pyridin-2-ylsulfanylpropan-1-one —— C18H28N4OS
    (2R)-1-[4-[(3R)-1-methylpiperidin-3-yl]piperazin-1-yl]-2-pyridin-2-ylsulfanylpropan-1-one
    —— (2S)-2-pyridin-2-ylsulfanyl-1-[(2S)-2-thiophen-3-ylpyrrolidin-1-yl]propan-1-one —— C16H18N2OS2
    (2S)-2-pyridin-2-ylsulfanyl-1-[(2S)-2-thiophen-3-ylpyrrolidin-1-yl]propan-1-one
    —— (2R)-1-[(2S)-2-(methoxymethyl)pyrrolidin-1-yl]-2-pyridin-2-ylsulfanylpropan-1-one —— C14H20N2O2S
    (2R)-1-[(2S)-2-(methoxymethyl)pyrrolidin-1-yl]-2-pyridin-2-ylsulfanylpropan-1-one
    —— (2S)-N-ethyl-N-[[(3R)-oxolan-3-yl]methyl]-2-pyridin-2-ylsulfanylpropanamide —— C15H22N2O2S
    (2S)-N-ethyl-N-[[(3R)-oxolan-3-yl]methyl]-2-pyridin-2-ylsulfanylpropanamide