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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (E)-N-[(Z)-(2-chlorophenyl)methylideneamino]-2-cyano-3-[5-[4-(difluoromethylsulfanyl)phenyl]furan-2-yl]prop-2-enamide —— C22H14ClF2N3O2S
    (E)-N-[(Z)-(2-chlorophenyl)methylideneamino]-2-cyano-3-[5-[4-(difluoromethylsulfanyl)phenyl]furan-2-yl]prop-2-enamide
    —— 6-tert-butyl-4-[(Z)-[(1R)-cyclohex-3-en-1-yl]methylideneamino]-3-methylsulfanyl-1,2,4-triazin-5-one —— C15H22N4OS
    6-tert-butyl-4-[(Z)-[(1R)-cyclohex-3-en-1-yl]methylideneamino]-3-methylsulfanyl-1,2,4-triazin-5-one
    —— 6-tert-butyl-4-[(Z)-[(1S)-cyclohex-3-en-1-yl]methylideneamino]-3-methylsulfanyl-1,2,4-triazin-5-one —— C15H22N4OS
    6-tert-butyl-4-[(Z)-[(1S)-cyclohex-3-en-1-yl]methylideneamino]-3-methylsulfanyl-1,2,4-triazin-5-one
    —— (1S)-1-(3,4-difluorophenyl)-2-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanol —— C18H17F2N3OS2
    (1S)-1-(3,4-difluorophenyl)-2-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanol
    —— (1R)-1-(3,4-difluorophenyl)-2-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanol —— C18H17F2N3OS2
    (1R)-1-(3,4-difluorophenyl)-2-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanol
    —— (S)-(2-methylsulfanylphenyl)-(5-methylthiophen-2-yl)methanol —— C13H14OS2
    (S)-(2-methylsulfanylphenyl)-(5-methylthiophen-2-yl)methanol
    —— (R)-(2-methylsulfanylphenyl)-thiophen-2-ylmethanol —— C12H12OS2
    (R)-(2-methylsulfanylphenyl)-thiophen-2-ylmethanol
    —— (R)-(2-methylsulfanylphenyl)-(5-methylthiophen-2-yl)methanol —— C13H14OS2
    (R)-(2-methylsulfanylphenyl)-(5-methylthiophen-2-yl)methanol
    —— (S)-(2-methylsulfanylphenyl)-thiophen-2-ylmethanol —— C12H12OS2
    (S)-(2-methylsulfanylphenyl)-thiophen-2-ylmethanol
    —— (S)-(4-methylsulfanylphenyl)-(5-methylthiophen-2-yl)methanol —— C13H14OS2
    (S)-(4-methylsulfanylphenyl)-(5-methylthiophen-2-yl)methanol
    —— (R)-(4-methylsulfanylphenyl)-(5-methylthiophen-2-yl)methanol —— C13H14OS2
    (R)-(4-methylsulfanylphenyl)-(5-methylthiophen-2-yl)methanol
    —— 2-({5-[(2-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(1Z,2E)-2-methyl-3-phenylprop-2-en-1-ylidene]acetohydrazide —— C21H19ClN4OS3
    2-({5-[(2-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(1Z,2E)-2-methyl-3-phenylprop-2-en-1-ylidene]acetohydrazide
    —— (3R)-1-[2-(3,4-dimethylphenyl)sulfanylethyl]-3-pyrrolidin-1-ylpyrrolidine —— C18H28N2S
    (3R)-1-[2-(3,4-dimethylphenyl)sulfanylethyl]-3-pyrrolidin-1-ylpyrrolidine
    —— 5-[(3S)-1-[2-(3,4-dimethylphenyl)sulfanylethyl]piperidin-3-yl]-3-methyl-1,2,4-oxadiazole —— C18H25N3OS
    5-[(3S)-1-[2-(3,4-dimethylphenyl)sulfanylethyl]piperidin-3-yl]-3-methyl-1,2,4-oxadiazole
    —— (3S)-1-[2-(3,4-dimethylphenyl)sulfanylethyl]-3-pyrrolidin-1-ylpyrrolidine —— C18H28N2S
    (3S)-1-[2-(3,4-dimethylphenyl)sulfanylethyl]-3-pyrrolidin-1-ylpyrrolidine
    —— 1-[(1-ethylcyclobutyl)methyl]-3-[(1R,3S)-3-methylsulfonylcyclohexyl]urea —— C15H28N2O3S
    1-[(1-ethylcyclobutyl)methyl]-3-[(1R,3S)-3-methylsulfonylcyclohexyl]urea
    —— 1-[(1-ethylcyclobutyl)methyl]-3-[(1R,3R)-3-methylsulfonylcyclohexyl]urea —— C15H28N2O3S
    1-[(1-ethylcyclobutyl)methyl]-3-[(1R,3R)-3-methylsulfonylcyclohexyl]urea
    —— 1-[4-[(1S)-1-(3-chlorophenyl)-2-hydroxyethyl]piperazin-1-yl]-2-(4-methylphenyl)sulfanylethanone —— C21H25ClN2O2S
    1-[4-[(1S)-1-(3-chlorophenyl)-2-hydroxyethyl]piperazin-1-yl]-2-(4-methylphenyl)sulfanylethanone
    —— 1-[4-[(1R)-1-(3-chlorophenyl)-2-hydroxyethyl]piperazin-1-yl]-2-(4-methylphenyl)sulfanylethanone —— C21H25ClN2O2S
    1-[4-[(1R)-1-(3-chlorophenyl)-2-hydroxyethyl]piperazin-1-yl]-2-(4-methylphenyl)sulfanylethanone
    —— 1-[(1-ethylcyclobutyl)methyl]-3-[(1S,3S)-3-methylsulfonylcyclohexyl]urea —— C15H28N2O3S
    1-[(1-ethylcyclobutyl)methyl]-3-[(1S,3S)-3-methylsulfonylcyclohexyl]urea
    —— 1-[(1-ethylcyclobutyl)methyl]-3-[(1S,3R)-3-methylsulfonylcyclohexyl]urea —— C15H28N2O3S
    1-[(1-ethylcyclobutyl)methyl]-3-[(1S,3R)-3-methylsulfonylcyclohexyl]urea
    —— 1-cyclopropyl-3-[(1S,2R)-2-(trifluoromethyl)cyclohexyl]thiourea —— C11H17F3N2S
    1-cyclopropyl-3-[(1S,2R)-2-(trifluoromethyl)cyclohexyl]thiourea
    —— (2E)-2-[4-(4-methylphenyl)-3H-1,3-thiazol-2-ylidene]-3-oxo-4-(1H-1,2,4-triazol-5-ylsulfanyl)butanenitrile —— C16H13N5OS2
    (2E)-2-[4-(4-methylphenyl)-3H-1,3-thiazol-2-ylidene]-3-oxo-4-(1H-1,2,4-triazol-5-ylsulfanyl)butanenitrile
    —— 3-(2-methoxyethyl)-1-methyl-1-[(2R,3R)-3-methylsulfonylbutan-2-yl]urea —— C10H22N2O4S
    3-(2-methoxyethyl)-1-methyl-1-[(2R,3R)-3-methylsulfonylbutan-2-yl]urea
    —— 3-(2-methoxyethyl)-1-methyl-1-[(2S,3R)-3-methylsulfonylbutan-2-yl]urea —— C10H22N2O4S
    3-(2-methoxyethyl)-1-methyl-1-[(2S,3R)-3-methylsulfonylbutan-2-yl]urea
    —— 3-(2-methoxyethyl)-1-methyl-1-[(2S,3S)-3-methylsulfonylbutan-2-yl]urea —— C10H22N2O4S
    3-(2-methoxyethyl)-1-methyl-1-[(2S,3S)-3-methylsulfonylbutan-2-yl]urea
    —— 3-(2-methoxyethyl)-1-methyl-1-[(2R,3S)-3-methylsulfonylbutan-2-yl]urea —— C10H22N2O4S
    3-(2-methoxyethyl)-1-methyl-1-[(2R,3S)-3-methylsulfonylbutan-2-yl]urea
    —— 3-(4-chlorophenyl)sulfanyl-N-[(Z)-(3-methylphenyl)methylideneamino]propanamide —— C17H17ClN2OS
    3-(4-chlorophenyl)sulfanyl-N-[(Z)-(3-methylphenyl)methylideneamino]propanamide
    —— (5Z)-3-(2,5-dimethylpyrrol-1-yl)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one —— C23H19N3O3S3
    (5Z)-3-(2,5-dimethylpyrrol-1-yl)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one
    —— 1-cyclopropyl-3-[(1R,2S)-2-(trifluoromethyl)cyclohexyl]thiourea —— C11H17F3N2S
    1-cyclopropyl-3-[(1R,2S)-2-(trifluoromethyl)cyclohexyl]thiourea
    —— 1-cyclopropyl-3-[(1S,2S)-2-(trifluoromethyl)cyclohexyl]thiourea —— C11H17F3N2S
    1-cyclopropyl-3-[(1S,2S)-2-(trifluoromethyl)cyclohexyl]thiourea
    —— (E)-4-[[5-[[(2S)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]but-2-enenitrile —— C11H14N4OS2
    (E)-4-[[5-[[(2S)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]but-2-enenitrile
    —— 4-[[(2R)-oxolan-2-yl]methyl]-3-[[(2S)-oxolan-2-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one —— C12H19N3O3S
    4-[[(2R)-oxolan-2-yl]methyl]-3-[[(2S)-oxolan-2-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one
    —— 4-[[(2S)-oxolan-2-yl]methyl]-3-[[(2S)-oxolan-2-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one —— C12H19N3O3S
    4-[[(2S)-oxolan-2-yl]methyl]-3-[[(2S)-oxolan-2-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one
    —— 4-[[(2S)-oxolan-2-yl]methyl]-3-[[(2R)-oxolan-2-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one —— C12H19N3O3S
    4-[[(2S)-oxolan-2-yl]methyl]-3-[[(2R)-oxolan-2-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one
    —— 4-[[(2R)-oxolan-2-yl]methyl]-3-[[(2R)-oxolan-2-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one —— C12H19N3O3S
    4-[[(2R)-oxolan-2-yl]methyl]-3-[[(2R)-oxolan-2-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one
    —— 1-cyclopropyl-3-[(1R,2R)-2-(trifluoromethyl)cyclohexyl]thiourea —— C11H17F3N2S
    1-cyclopropyl-3-[(1R,2R)-2-(trifluoromethyl)cyclohexyl]thiourea
    —— (E)-4-[[5-[[(2R)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]but-2-enenitrile —— C11H14N4OS2
    (E)-4-[[5-[[(2R)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]but-2-enenitrile
    —— 2-[(1S)-1-[3-[(4-fluorophenyl)methyl]-1,2,4-oxadiazol-5-yl]ethyl]sulfanyl-6-methylpyrimidin-4-amine —— C16H16FN5OS
    2-[(1S)-1-[3-[(4-fluorophenyl)methyl]-1,2,4-oxadiazol-5-yl]ethyl]sulfanyl-6-methylpyrimidin-4-amine
    —— 2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-1-[(2S)-2-pyridin-4-ylazepan-1-yl]ethanone —— C19H24N4OS
    2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-1-[(2S)-2-pyridin-4-ylazepan-1-yl]ethanone
    —— 2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-1-[(2R)-2-pyridin-4-ylazepan-1-yl]ethanone —— C19H24N4OS
    2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-1-[(2R)-2-pyridin-4-ylazepan-1-yl]ethanone
    —— (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(2-chloro-6-fluorophenyl)methyl]-N-methylpropanamide —— C16H18ClFN4OS
    (2R)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(2-chloro-6-fluorophenyl)methyl]-N-methylpropanamide
    —— 2-[(1R)-1-[3-[(4-fluorophenyl)methyl]-1,2,4-oxadiazol-5-yl]ethyl]sulfanyl-6-methylpyrimidin-4-amine —— C16H16FN5OS
    2-[(1R)-1-[3-[(4-fluorophenyl)methyl]-1,2,4-oxadiazol-5-yl]ethyl]sulfanyl-6-methylpyrimidin-4-amine
    —— (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(2-chloro-6-fluorophenyl)methyl]-N-methylpropanamide —— C16H18ClFN4OS
    (2S)-2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(2-chloro-6-fluorophenyl)methyl]-N-methylpropanamide
    —— 1-[(2S)-2-(cyclohexylmethyl)pyrrolidin-1-yl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylethanone —— C19H29N3OS
    1-[(2S)-2-(cyclohexylmethyl)pyrrolidin-1-yl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylethanone
    —— 2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[[(5S,7R)-3-bromo-1-adamantyl]methyl]acetamide —— C18H25BrN4OS
    2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[[(5S,7R)-3-bromo-1-adamantyl]methyl]acetamide
    —— (2R)-N-[2-(1-methylimidazol-2-yl)sulfanylphenyl]-2-(2,2,2-trifluoroethoxy)propanamide —— C15H16F3N3O2S
    (2R)-N-[2-(1-methylimidazol-2-yl)sulfanylphenyl]-2-(2,2,2-trifluoroethoxy)propanamide
    —— (1S,2S)-N-methyl-N-(3-methylbut-2-enyl)-2-methylsulfonylcyclopentan-1-amine —— C12H23NO2S
    (1S,2S)-N-methyl-N-(3-methylbut-2-enyl)-2-methylsulfonylcyclopentan-1-amine
    —— (1R,2S)-N-methyl-N-(3-methylbut-2-enyl)-2-methylsulfonylcyclopentan-1-amine —— C12H23NO2S
    (1R,2S)-N-methyl-N-(3-methylbut-2-enyl)-2-methylsulfonylcyclopentan-1-amine
    —— (1R,2S)-N-(2-ethoxyethyl)-N-methyl-2-methylsulfonylcyclopentan-1-amine —— C11H23NO3S
    (1R,2S)-N-(2-ethoxyethyl)-N-methyl-2-methylsulfonylcyclopentan-1-amine