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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-2-(2-ethoxyethoxy)-N-methyl-N-[(1S,2S)-2-methylsulfonylcyclohexyl]propanamide —— C15H29NO5S
    (2S)-2-(2-ethoxyethoxy)-N-methyl-N-[(1S,2S)-2-methylsulfonylcyclohexyl]propanamide
    —— 2-[[3-[(1R)-1-ethoxyethyl]-1,2,4-oxadiazol-5-yl]methylsulfanyl]-5-pyridin-4-yl-1,3,4-oxadiazole —— C14H15N5O3S
    2-[[3-[(1R)-1-ethoxyethyl]-1,2,4-oxadiazol-5-yl]methylsulfanyl]-5-pyridin-4-yl-1,3,4-oxadiazole
    —— ethyl N-[2-[[(2S)-2-propan-2-ylsulfonylpropanoyl]amino]ethyl]carbamate —— C11H22N2O5S
    ethyl N-[2-[[(2S)-2-propan-2-ylsulfonylpropanoyl]amino]ethyl]carbamate
    —— N-[(1R,3S)-3-ethoxyspiro[3.5]nonan-1-yl]-2-ethylsulfonyl-N-methylacetamide —— C16H29NO4S
    N-[(1R,3S)-3-ethoxyspiro[3.5]nonan-1-yl]-2-ethylsulfonyl-N-methylacetamide
    —— 2-[[3-[(1S)-1-ethoxyethyl]-1,2,4-oxadiazol-5-yl]methylsulfanyl]-5-pyridin-4-yl-1,3,4-oxadiazole —— C14H15N5O3S
    2-[[3-[(1S)-1-ethoxyethyl]-1,2,4-oxadiazol-5-yl]methylsulfanyl]-5-pyridin-4-yl-1,3,4-oxadiazole
    —— ethyl N-[2-[[(2R)-2-propan-2-ylsulfonylpropanoyl]amino]ethyl]carbamate —— C11H22N2O5S
    ethyl N-[2-[[(2R)-2-propan-2-ylsulfonylpropanoyl]amino]ethyl]carbamate
    —— N-[(Z)-benzylideneamino]-6-methyl-2-propan-2-ylsulfanylpyrimidin-4-amine —— C15H18N4S
    N-[(Z)-benzylideneamino]-6-methyl-2-propan-2-ylsulfanylpyrimidin-4-amine
    —— (2S)-2-[[5-[4-(diethylamino)phenyl]-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one —— C18H23N3O2S
    (2S)-2-[[5-[4-(diethylamino)phenyl]-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one
    —— (2R)-2-[[5-[4-(diethylamino)phenyl]-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one —— C18H23N3O2S
    (2R)-2-[[5-[4-(diethylamino)phenyl]-1,3,4-oxadiazol-2-yl]sulfanyl]cyclohexan-1-one
    —— N-[(Z)-[5-(diethylamino)-4-(2-nitrophenyl)sulfanylfuran-2-yl]methylideneamino]-3-nitrobenzamide —— C22H21N5O6S
    N-[(Z)-[5-(diethylamino)-4-(2-nitrophenyl)sulfanylfuran-2-yl]methylideneamino]-3-nitrobenzamide
    —— 3-(4-bromophenyl)sulfanyl-N-[(2R)-2-cyanopropyl]-N-ethylpropanamide —— C15H19BrN2OS
    3-(4-bromophenyl)sulfanyl-N-[(2R)-2-cyanopropyl]-N-ethylpropanamide
    —— 3-(4-bromophenyl)sulfanyl-N-[(2S)-2-cyanopropyl]-N-ethylpropanamide —— C15H19BrN2OS
    3-(4-bromophenyl)sulfanyl-N-[(2S)-2-cyanopropyl]-N-ethylpropanamide
    —— 1-methyl-1-[(2S,3R)-3-methylsulfonylbutan-2-yl]-3-pentylurea —— C12H26N2O3S
    1-methyl-1-[(2S,3R)-3-methylsulfonylbutan-2-yl]-3-pentylurea
    —— 1-methyl-1-[(2R,3S)-3-methylsulfonylbutan-2-yl]-3-pentylurea —— C12H26N2O3S
    1-methyl-1-[(2R,3S)-3-methylsulfonylbutan-2-yl]-3-pentylurea
    —— 1-methyl-1-[(2R,3R)-3-methylsulfonylbutan-2-yl]-3-pentylurea —— C12H26N2O3S
    1-methyl-1-[(2R,3R)-3-methylsulfonylbutan-2-yl]-3-pentylurea
    —— 1-methyl-1-[(2S,3S)-3-methylsulfonylbutan-2-yl]-3-pentylurea —— C12H26N2O3S
    1-methyl-1-[(2S,3S)-3-methylsulfonylbutan-2-yl]-3-pentylurea
    —— 2-(1-oxidopyridin-1-ium-2-yl)sulfanyl-1-[(4S)-4-propylazepan-1-yl]ethanone —— C16H24N2O2S
    2-(1-oxidopyridin-1-ium-2-yl)sulfanyl-1-[(4S)-4-propylazepan-1-yl]ethanone
    —— 3-[(2S)-pentan-2-yl]sulfanyl-4-(2,2,2-trifluoroethyl)-1,2,4-triazole —— C9H14F3N3S
    3-[(2S)-pentan-2-yl]sulfanyl-4-(2,2,2-trifluoroethyl)-1,2,4-triazole
    —— 3-[(2R)-pentan-2-yl]sulfanyl-4-(2,2,2-trifluoroethyl)-1,2,4-triazole —— C9H14F3N3S
    3-[(2R)-pentan-2-yl]sulfanyl-4-(2,2,2-trifluoroethyl)-1,2,4-triazole
    —— [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(3R,4R)-3-ethyl-4-morpholin-4-ylpyrrolidin-1-yl]methanone —— C19H26N2O2S
    [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(3R,4R)-3-ethyl-4-morpholin-4-ylpyrrolidin-1-yl]methanone
    —— (2Z)-2-(4-methylpiperazin-1-yl)imino-1-(4-phenylsulfanylphenyl)ethanone —— C19H21N3OS
    (2Z)-2-(4-methylpiperazin-1-yl)imino-1-(4-phenylsulfanylphenyl)ethanone
    —— [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(3S,4R)-3-ethyl-4-morpholin-4-ylpyrrolidin-1-yl]methanone —— C19H26N2O2S
    [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(3S,4R)-3-ethyl-4-morpholin-4-ylpyrrolidin-1-yl]methanone
    —— [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(3S,4S)-3-ethyl-4-morpholin-4-ylpyrrolidin-1-yl]methanone —— C19H26N2O2S
    [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(3S,4S)-3-ethyl-4-morpholin-4-ylpyrrolidin-1-yl]methanone
    —— [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(3R,4S)-3-ethyl-4-morpholin-4-ylpyrrolidin-1-yl]methanone —— C19H26N2O2S
    [(3R)-2,3-dihydro-1-benzothiophen-3-yl]-[(3R,4S)-3-ethyl-4-morpholin-4-ylpyrrolidin-1-yl]methanone
    —— 1,2,3,5,6-Pentathiepane, 4,7-dimethyl, #1 —— C4H8S5
    1,2,3,5,6-Pentathiepane, 4,7-dimethyl, #1
    —— Phenyl thiolcarbamic acid, 5-anilino-1,3,4-thia-diazol-2-yl ester —— C15H12N4OS2
    Phenyl thiolcarbamic acid, 5-anilino-1,3,4-thia-diazol-2-yl ester
    —— 4,7,13,16-Tetraoxa-1,10-dithia-cyclooctadecan-disulfon 108846-58-8 C12H24O8S2
    4,7,13,16-Tetraoxa-1,10-dithia-cyclooctadecan-disulfon
    —— 1,2,3,5,6-Pentathiepane, 4,7-dimethyl, #2 —— C4H8S5
    1,2,3,5,6-Pentathiepane, 4,7-dimethyl, #2
    —— 1-cyclopropyl-1-[(2S,3R)-3-methylpentan-2-yl]-3-[(1R,3S)-3-methylsulfonylcyclohexyl]urea —— C17H32N2O3S
    1-cyclopropyl-1-[(2S,3R)-3-methylpentan-2-yl]-3-[(1R,3S)-3-methylsulfonylcyclohexyl]urea
    —— 1,2,4,7,9,10-Hexathiacyclododecane —— C7H14S5
    1,2,4,7,9,10-Hexathiacyclododecane
    —— 1-[4-[(3R)-2,3-dihydro-1-benzothiophene-3-carbonyl]piperazin-1-yl]ethanone —— C15H18N2O2S
    1-[4-[(3R)-2,3-dihydro-1-benzothiophene-3-carbonyl]piperazin-1-yl]ethanone
    —— 1-cyclopropyl-1-[(2R,3S)-3-methylpentan-2-yl]-3-[(1R,3S)-3-methylsulfonylcyclohexyl]urea —— C17H32N2O3S
    1-cyclopropyl-1-[(2R,3S)-3-methylpentan-2-yl]-3-[(1R,3S)-3-methylsulfonylcyclohexyl]urea
    —— 4-(Hydroxymethyl)-1,2-dithiepane —— C6H12OS2
    4-(Hydroxymethyl)-1,2-dithiepane
    —— Propyl hydrodisulfide —— C3H8S2
    Propyl hydrodisulfide
    —— 6-Ethyl-4,5,7,8-tetrathiaundecane —— C9H20S4
    6-Ethyl-4,5,7,8-tetrathiaundecane
    —— (7E)-4-thiophen-2-yl-7-(thiophen-2-ylmethylidene)-2-[(3R)-3,5,5-trimethylheptyl]sulfanyl-5,6-dihydrocyclopenta[b]pyridine-3-carbonitrile —— C28H32N2S3
    (7E)-4-thiophen-2-yl-7-(thiophen-2-ylmethylidene)-2-[(3R)-3,5,5-trimethylheptyl]sulfanyl-5,6-dihydrocyclopenta[b]pyridine-3-carbonitrile
    —— 1-cyclopropyl-1-[(2R,3R)-3-methylpentan-2-yl]-3-[(1R,3S)-3-methylsulfonylcyclohexyl]urea —— C17H32N2O3S
    1-cyclopropyl-1-[(2R,3R)-3-methylpentan-2-yl]-3-[(1R,3S)-3-methylsulfonylcyclohexyl]urea
    —— Isoxazole, 5-bromomethyl-3-(5-ethylsulfanylthiophen-2-yl)-4,5-dihydro- —— C10H12BrNOS2
    Isoxazole, 5-bromomethyl-3-(5-ethylsulfanylthiophen-2-yl)-4,5-dihydro-
    —— Carbamodithioic acid, diethyl-, 3,5-dichloro-2-(trichloromethyl)-4-pyridinyl ester —— C11H11Cl5N2S2
    Carbamodithioic acid, diethyl-, 3,5-dichloro-2-(trichloromethyl)-4-pyridinyl ester
    —— (7E)-4-thiophen-2-yl-7-(thiophen-2-ylmethylidene)-2-[(3S)-3,5,5-trimethylheptyl]sulfanyl-5,6-dihydrocyclopenta[b]pyridine-3-carbonitrile —— C28H32N2S3
    (7E)-4-thiophen-2-yl-7-(thiophen-2-ylmethylidene)-2-[(3S)-3,5,5-trimethylheptyl]sulfanyl-5,6-dihydrocyclopenta[b]pyridine-3-carbonitrile
    —— (2,6-Dimethyl-4-morpholine)carbodithioic acid, 2,3,5,6-tetrachloro-4-pyridinyl ester —— C12H12Cl4N2OS2
    (2,6-Dimethyl-4-morpholine)carbodithioic acid, 2,3,5,6-tetrachloro-4-pyridinyl ester
    —— 1-cyclopropyl-1-[(2S,3S)-3-methylpentan-2-yl]-3-[(1R,3S)-3-methylsulfonylcyclohexyl]urea —— C17H32N2O3S
    1-cyclopropyl-1-[(2S,3S)-3-methylpentan-2-yl]-3-[(1R,3S)-3-methylsulfonylcyclohexyl]urea
    —— 1-[4-[(3S)-2,3-dihydro-1-benzothiophene-3-carbonyl]piperazin-1-yl]ethanone —— C15H18N2O2S
    1-[4-[(3S)-2,3-dihydro-1-benzothiophene-3-carbonyl]piperazin-1-yl]ethanone
    —— 1-Pyrrolidindithiocarboxylic acid, 2,3,5,6-tetrachloropyrid-4-yl ester —— C10H8Cl4N2S2
    1-Pyrrolidindithiocarboxylic acid, 2,3,5,6-tetrachloropyrid-4-yl ester
    —— N-[(3R)-1-[(2S)-4-phenylsulfanylbutan-2-yl]piperidin-3-yl]propanamide —— C18H28N2OS
    N-[(3R)-1-[(2S)-4-phenylsulfanylbutan-2-yl]piperidin-3-yl]propanamide
    —— N-[(3S)-1-[(2S)-4-phenylsulfanylbutan-2-yl]piperidin-3-yl]propanamide —— C18H28N2OS
    N-[(3S)-1-[(2S)-4-phenylsulfanylbutan-2-yl]piperidin-3-yl]propanamide
    —— Dithiocarbonic acid, o-ethyl ester S-(3,3,4,4,5,5,6,6-octafluoro-1-pentyl-hexyl) ester —— C14H20F8OS2
    Dithiocarbonic acid, o-ethyl ester S-(3,3,4,4,5,5,6,6-octafluoro-1-pentyl-hexyl) ester
    —— Acetamide, N-benzyl-2-(3-cyano-4,5,6-trimethylpyridin-2-ylsulfanyl)-N-ethyl- —— C20H23N3OS
    Acetamide, N-benzyl-2-(3-cyano-4,5,6-trimethylpyridin-2-ylsulfanyl)-N-ethyl-
    —— (2R,6R)-4-[[(2S)-1-[3-(2-chlorophenyl)sulfanylpropyl]pyrrolidin-2-yl]methyl]-2,6-dimethylmorpholine —— C20H31ClN2OS
    (2R,6R)-4-[[(2S)-1-[3-(2-chlorophenyl)sulfanylpropyl]pyrrolidin-2-yl]methyl]-2,6-dimethylmorpholine
    —— (2S,6R)-4-[[(2S)-1-[3-(2-chlorophenyl)sulfanylpropyl]pyrrolidin-2-yl]methyl]-2,6-dimethylmorpholine —— C20H31ClN2OS
    (2S,6R)-4-[[(2S)-1-[3-(2-chlorophenyl)sulfanylpropyl]pyrrolidin-2-yl]methyl]-2,6-dimethylmorpholine