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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— ethyl (Z)-3-(4-methylsulfanylanilino)but-2-enoate —— C13H17NO2S
    ethyl (Z)-3-(4-methylsulfanylanilino)but-2-enoate
    —— (3E)-5-(4-methylphenyl)-3-(4-{[4-methyl-5-(pyridin-3-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}-3-nitrobenzylidene)furan-2(3H)-one —— C26H19N5O4S
    (3E)-5-(4-methylphenyl)-3-(4-{[4-methyl-5-(pyridin-3-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}-3-nitrobenzylidene)furan-2(3H)-one
    —— (E)-3-amino-2-[2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]but-2-enenitrile —— C15H15N5OS2
    (E)-3-amino-2-[2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]but-2-enenitrile
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-N'-[(1E)-1-(4-methylphenyl)ethylidene]-1H-1,2,3-triazole-4-carbohydrazide —— C21H19ClN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-N'-[(1E)-1-(4-methylphenyl)ethylidene]-1H-1,2,3-triazole-4-carbohydrazide
    —— 2-[(E)-2-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]ethenyl]-1H-benzimidazole —— C18H14N6O2S
    2-[(E)-2-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]ethenyl]-1H-benzimidazole
    —— N'-{(Z)-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylidene}benzohydrazide —— C21H14N4O3S2
    N'-{(Z)-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylidene}benzohydrazide
    —— (6E)-4-bromo-6-[[2-[4-[methyl-[(4-methyl-1,2,5-oxadiazol-3-yl)methyl]amino]-6-phenylsulfanyl-1,3,5-triazin-2-yl]hydrazinyl]methylidene]cyclohexa-2,4-dien-1-one —— C21H19BrN8O2S
    (6E)-4-bromo-6-[[2-[4-[methyl-[(4-methyl-1,2,5-oxadiazol-3-yl)methyl]amino]-6-phenylsulfanyl-1,3,5-triazin-2-yl]hydrazinyl]methylidene]cyclohexa-2,4-dien-1-one
    —— (5E)-5-({4-bromo-5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-1,3-thiazolidine-2,4-dione —— C14H7BrClNO3S2
    (5E)-5-({4-bromo-5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-1,3-thiazolidine-2,4-dione
    —— N'-{(E)-[4-(dimethylamino)phenyl]methylidene}-3-[(4-methylphenyl)sulfanyl]propanehydrazide —— C19H23N3OS
    N'-{(E)-[4-(dimethylamino)phenyl]methylidene}-3-[(4-methylphenyl)sulfanyl]propanehydrazide
    —— N,N'-dimethyl-N,N'-bis[(Z)-(4-methylsulfanylphenyl)methylideneamino]ethane-1,2-diamine —— C20H26N4S2
    N,N'-dimethyl-N,N'-bis[(Z)-(4-methylsulfanylphenyl)methylideneamino]ethane-1,2-diamine
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]methyl}-N'-[(2E)-4-phenylbutan-2-ylidene]-1H-1,2,3-triazole-4-carbohydrazide —— C19H21N11O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]methyl}-N'-[(2E)-4-phenylbutan-2-ylidene]-1H-1,2,3-triazole-4-carbohydrazide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(1E)-1-(5-chlorothiophen-2-yl)ethylidene]-5-{[(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]methyl}-1H-1,2,3-triazole-4-carbohydrazide —— C15H14ClN11O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(1E)-1-(5-chlorothiophen-2-yl)ethylidene]-5-{[(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]methyl}-1H-1,2,3-triazole-4-carbohydrazide
    —— 4-[(2Z)-2-[[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylidene]hydrazinyl]-3-nitrobenzenesulfonamide —— C16H14N8O6S2
    4-[(2Z)-2-[[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylidene]hydrazinyl]-3-nitrobenzenesulfonamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-5-propyltriazole-4-carboxamide —— C16H18N8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-5-propyltriazole-4-carboxamide
    —— 2-[(Z)-1-(1-benzofuran-2-yl)ethylideneamino]oxy-N-[2-(4-chlorophenyl)sulfanylphenyl]acetamide —— C24H19ClN2O3S
    2-[(Z)-1-(1-benzofuran-2-yl)ethylideneamino]oxy-N-[2-(4-chlorophenyl)sulfanylphenyl]acetamide
    —— (6Z)-2-(1-adamantyl)-5-imino-6-[(5-phenylsulfanylfuran-2-yl)methylidene]-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one —— C26H24N4O2S2
    (6Z)-2-(1-adamantyl)-5-imino-6-[(5-phenylsulfanylfuran-2-yl)methylidene]-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one
    —— (5E)-5-[(2-methoxyphenyl)methylidene]-2-phenyl-3-(6-phenylsulfanyl-1H-benzimidazol-2-yl)imidazol-4-one —— C30H22N4O2S
    (5E)-5-[(2-methoxyphenyl)methylidene]-2-phenyl-3-(6-phenylsulfanyl-1H-benzimidazol-2-yl)imidazol-4-one
    —— (E)-N-(cyclopropylmethyl)-3-phenylsulfanylprop-2-enamide —— C13H15NOS
    (E)-N-(cyclopropylmethyl)-3-phenylsulfanylprop-2-enamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(5-methylfuran-2-yl)methylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide —— C18H16N8O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(5-methylfuran-2-yl)methylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide
    —— (6E)-6-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-5-imino-2-propyl-5,6-dihydro-7H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one —— C19H15ClN4O2S2
    (6E)-6-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-5-imino-2-propyl-5,6-dihydro-7H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one
    —— 5-(2-(4-Bromoanilino)vinyl)-3-((3-chloro-5-(trifluoromethyl)-2-pyridinyl)sulfanyl)-4-isothiazolecarbonitrile —— C18H9BrClF3N4S2
    5-(2-(4-Bromoanilino)vinyl)-3-((3-chloro-5-(trifluoromethyl)-2-pyridinyl)sulfanyl)-4-isothiazolecarbonitrile
    —— (2Z)-2-[(4-bromothiophen-2-yl)methylidene]-6-chloro-4-methyl-1-benzothiophen-3-one —— C14H8BrClOS2
    (2Z)-2-[(4-bromothiophen-2-yl)methylidene]-6-chloro-4-methyl-1-benzothiophen-3-one
    —— 3-[(2-Chloro-6-fluorobenzyl)sulfanyl]-5-[2-(dimethylamino)vinyl]-4-isothiazolecarbonitrile —— C15H13ClFN3S2
    3-[(2-Chloro-6-fluorobenzyl)sulfanyl]-5-[2-(dimethylamino)vinyl]-4-isothiazolecarbonitrile
    —— (Z)-1-[5-(4-chlorophenyl)sulfanyl-1-methyl-3-(trifluoromethyl)pyrazol-4-yl]-N-methoxymethanimine —— C13H11ClF3N3OS
    (Z)-1-[5-(4-chlorophenyl)sulfanyl-1-methyl-3-(trifluoromethyl)pyrazol-4-yl]-N-methoxymethanimine
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(4-chlorophenyl)ethylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide —— C20H17ClN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(4-chlorophenyl)ethylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide
    —— (10'Z)-3'-phenylsulfanylspiro[1,3-dioxolane-2,4'-2,3,3a,5,6,7,8,9-octahydro-1H-cyclopenta[9]annulene] —— C20H26O2S
    (10'Z)-3'-phenylsulfanylspiro[1,3-dioxolane-2,4'-2,3,3a,5,6,7,8,9-octahydro-1H-cyclopenta[9]annulene]
    —— (E)-N-[2-(furan-2-ylmethylsulfanyl)ethyl]-3-phenylsulfanylprop-2-enamide —— C16H17NO2S2
    (E)-N-[2-(furan-2-ylmethylsulfanyl)ethyl]-3-phenylsulfanylprop-2-enamide
    —— 5-[2-(4-Chloroanilino)vinyl]-3-{[(2-methyl-1,3-thiazol-4-yl)methyl]sulfanyl}-4-isothiazolecarbonitrile —— C17H13ClN4S3
    5-[2-(4-Chloroanilino)vinyl]-3-{[(2-methyl-1,3-thiazol-4-yl)methyl]sulfanyl}-4-isothiazolecarbonitrile
    —— (Z)-N-methoxy-1-[2-(3-methoxyphenyl)sulfanyl-5-nitrophenyl]methanimine —— C15H14N2O4S
    (Z)-N-methoxy-1-[2-(3-methoxyphenyl)sulfanyl-5-nitrophenyl]methanimine
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(1E)-1-(4-methylphenyl)ethylidene]-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide —— C21H20N8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(1E)-1-(4-methylphenyl)ethylidene]-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide
    —— (E)-6-(benzylthio)imidazo[2,1-b]thiazole-5-carbaldehyde oxime —— C13H11N3OS2
    (E)-6-(benzylthio)imidazo[2,1-b]thiazole-5-carbaldehyde oxime
    —— 3-methyl-1-octylthio-1-phenylthio-1-butene —— C19H30S2
    3-methyl-1-octylthio-1-phenylthio-1-butene
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-methylphenyl)sulfanylmethyl]-N-[(Z)-1-pyridin-2-ylethylideneamino]triazole-4-carboxamide —— C20H19N9O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-methylphenyl)sulfanylmethyl]-N-[(Z)-1-pyridin-2-ylethylideneamino]triazole-4-carboxamide
    —— Methyl 5-(2-(4-((4-chlorophenyl)sulfanyl)-3-(2,6-dichlorophenyl)isoxazolo[4,5-c]pyridin-7-yl)vinyl)-3-(2,6-dichlorophenyl)-4-isoxazolecarboxylate —— C31H16Cl5N3O4S
    Methyl 5-(2-(4-((4-chlorophenyl)sulfanyl)-3-(2,6-dichlorophenyl)isoxazolo[4,5-c]pyridin-7-yl)vinyl)-3-(2,6-dichlorophenyl)-4-isoxazolecarboxylate
    —— 7-methyl-3-{(Z)-[4-oxo-3-(tetrahydrofuran-2-ylmethyl)-2-thioxo-1,3-thiazolidin-5-ylidene]methyl}-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-4-one —— C24H21N3O3S3
    7-methyl-3-{(Z)-[4-oxo-3-(tetrahydrofuran-2-ylmethyl)-2-thioxo-1,3-thiazolidin-5-ylidene]methyl}-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-4-one
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(3-bromophenyl)methylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide —— C19H15BrN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(3-bromophenyl)methylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide
    —— (1Z,4Z)-1,5-bis(dimethylamino)-2,4-bis(phenylsulfanyl)penta-1,4-dien-3-one —— C21H24N2OS2
    (1Z,4Z)-1,5-bis(dimethylamino)-2,4-bis(phenylsulfanyl)penta-1,4-dien-3-one
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(4-methylphenyl)ethylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide —— C18H19N11O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(4-methylphenyl)ethylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide
    —— N-[(Z)-(4-nitrophenyl)methylideneamino]-4-(4-phenylsulfanylphenyl)-1,3-thiazol-2-amine —— C22H16N4O2S2
    N-[(Z)-(4-nitrophenyl)methylideneamino]-4-(4-phenylsulfanylphenyl)-1,3-thiazol-2-amine
    —— (5E)-2-phenyl-3-(6-phenylsulfanyl-1H-benzimidazol-2-yl)-5-[(3,4,5-trimethoxyphenyl)methylidene]imidazol-4-one —— C32H26N4O4S
    (5E)-2-phenyl-3-(6-phenylsulfanyl-1H-benzimidazol-2-yl)-5-[(3,4,5-trimethoxyphenyl)methylidene]imidazol-4-one
    —— methyl (E)-3-[4-[(E)-3-methoxy-3-oxoprop-1-enyl]sulfanyl-2-sulfanylidenepyrimidin-1-yl]prop-2-enoate —— C12H12N2O4S2
    methyl (E)-3-[4-[(E)-3-methoxy-3-oxoprop-1-enyl]sulfanyl-2-sulfanylidenepyrimidin-1-yl]prop-2-enoate
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-furan-2-ylmethylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide —— C14H13N11O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-furan-2-ylmethylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide
    —— N'-[(1E)-1-(4-fluorophenyl)ethylidene]-2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide —— C20H19FN4OS3
    N'-[(1E)-1-(4-fluorophenyl)ethylidene]-2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide
    —— 6-Acetyl-2-(2-chloro-benzylidene)-5-methyl-thiazolo[2,3-b]thiazol-3-one —— C15H11ClNO2S2+
    6-Acetyl-2-(2-chloro-benzylidene)-5-methyl-thiazolo[2,3-b]thiazol-3-one
    —— (5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one 1266110-50-2 C17H12N2O3S3
    (5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (6Z)-5-imino-6-[4-(methylsulfanyl)benzylidene]-2-[2-oxo-2-(pyrrolidin-1-yl)ethyl]-5,6-dihydro-7H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one —— C19H19N5O2S2
    (6Z)-5-imino-6-[4-(methylsulfanyl)benzylidene]-2-[2-oxo-2-(pyrrolidin-1-yl)ethyl]-5,6-dihydro-7H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one
    —— [(Z)-[2-(4-chlorophenyl)sulfanylphenyl]methylideneamino]thiourea —— C14H12ClN3S2
    [(Z)-[2-(4-chlorophenyl)sulfanylphenyl]methylideneamino]thiourea
    —— [(Z)-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]urea —— C12H9BrClN3O2S
    [(Z)-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]urea
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]triazole-4-carboxamide —— C20H16ClFN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]triazole-4-carboxamide
    —— (Z)-1-[2-(2,6-dichlorophenyl)sulfanyl-5-nitrophenyl]-N-methoxymethanimine —— C14H10Cl2N2O3S
    (Z)-1-[2-(2,6-dichlorophenyl)sulfanyl-5-nitrophenyl]-N-methoxymethanimine