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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3,4-dihydro-2H-benzo[b][1,4]thiazocin-5(6H)-one 16175-48-7 C10H11NOS
    3,4-dihydro-2H-benzo[b][1,4]thiazocin-5(6H)-one
    —— 1-(3-carboxyprop-1-yl)-2-(4-fluorobenzyl)-thio-5-(2-methoxypyrimid-5-ylmethyl)-pyrimidin-4-one 304902-83-8 C21H21FN4O4S
    1-(3-carboxyprop-1-yl)-2-(4-fluorobenzyl)-thio-5-(2-methoxypyrimid-5-ylmethyl)-pyrimidin-4-one
    —— 1-α-Hydroxyaethyl-1-phenylthiocyclohexan 62291-78-5 C14H20OS
    1-α-Hydroxyaethyl-1-phenylthiocyclohexan
    —— (E)-1-ethoxy-4-phenylthio-1-butene 124224-90-4 C12H16OS
    (E)-1-ethoxy-4-phenylthio-1-butene
    —— 4-Aza-phenothiazin-10-carbonsaeure-2-piperidino-aethylester 99004-30-5 C19H21N3O2S
    4-Aza-phenothiazin-10-carbonsaeure-2-piperidino-aethylester
    —— N-methoxy-N-methyl-2-phenylsulfanylhept-6-enamide 1235329-29-9 C15H21NO2S
    N-methoxy-N-methyl-2-phenylsulfanylhept-6-enamide
    —— 6-thiophenyl-2-fluoro-purine 385434-58-2 C11H7FN4S
    6-thiophenyl-2-fluoro-purine
    —— 4,4'-ethanediyldimercapto-di-phenol 14490-33-6 C14H14O2S2
    4,4'-ethanediyldimercapto-di-phenol
    —— 5-(1,1-Dioxo-4-phenylsulfanyl-2,5-dihydrothiophen-2-yl)pentanal 205110-27-6 C15H18O3S2
    5-(1,1-Dioxo-4-phenylsulfanyl-2,5-dihydrothiophen-2-yl)pentanal
    —— 1,1-bis(mercaptomethyl)cyclobutane 110206-37-6 C6H12S2
    1,1-bis(mercaptomethyl)cyclobutane
    —— 5-(1,1-dioxo-4-phenylsulfanyl-2,5-dihydrothiophen-2-yl)pentan-1-ol 205110-24-3 C15H20O3S2
    5-(1,1-dioxo-4-phenylsulfanyl-2,5-dihydrothiophen-2-yl)pentan-1-ol
    —— tert-butyl (7R,8R,9S)-8-(tert-butyldimethylsilyloxymethyl)-9-methyl-1,4-dithiaspiro<4.4>nonane-7-thiocarboxylate 124443-57-8 C20H38O2S3Si
    tert-butyl (7R,8R,9S)-8-(tert-butyldimethylsilyloxymethyl)-9-methyl-1,4-dithiaspiro<4.4>nonane-7-thiocarboxylate
    —— trans-1-methyl-2-(phenylthio)cyclopentane 110434-51-0 C12H16S
    trans-1-methyl-2-(phenylthio)cyclopentane
    —— 4-nitrophenyl 2-methyl-4-methoxyphenyl sulfide 122443-56-5 C14H13NO3S
    4-nitrophenyl 2-methyl-4-methoxyphenyl sulfide
    —— 2-(Ethylthio)-4-(tridecafluorohexyl)pyrimidine 127598-45-2 C12H7F13N2S
    2-(Ethylthio)-4-(tridecafluorohexyl)pyrimidine
    —— 2-(4-Pentenyl)-4-(phenylthio)-3-sulfolene 124243-68-1 C15H18O2S2
    2-(4-Pentenyl)-4-(phenylthio)-3-sulfolene
    —— 1,3-bis(methylthio)-4-methyl-6,7,8,9-tetrahydro-5H-cyclohepta<c>pyridine 128736-33-4 C13H19NS2
    1,3-bis(methylthio)-4-methyl-6,7,8,9-tetrahydro-5H-cyclohepta<c>pyridine
    —— 4,5-dithiomethyl-1,2-dithiole-3-thione 72713-45-2 C5H6S5
    4,5-dithiomethyl-1,2-dithiole-3-thione
    —— Hydrazinecarbothioyl cyanide 80229-03-4 C2H3N3S
    Hydrazinecarbothioyl cyanide
    —— ethyl 2-phenylthio-2-hexenoate 91077-20-2 C14H18O2S
    ethyl 2-phenylthio-2-hexenoate
    —— 5-methylthio-1-methyl-1,2,3-triazole-4-carbothiamide 129257-17-6 C5H8N4S2
    5-methylthio-1-methyl-1,2,3-triazole-4-carbothiamide
    —— 2-amino-3-methanesulfonyl-2-methyl-propionitrile 1613238-69-9 C5H10N2O2S
    2-amino-3-methanesulfonyl-2-methyl-propionitrile
    —— N-butyl-2-<1-(2-pyridylthio)-1-methylethyl>pyrrolidine 115961-66-5 C16H26N2S
    N-butyl-2-<1-(2-pyridylthio)-1-methylethyl>pyrrolidine
    —— 4-(2-{6-amino-8-[(6-chloro-1,3-benzodioxol-5-yl)thio]-9H-purin-9-yl}ethyl)piperidine-1-carbaldehyde 1156467-41-2 C20H21ClN6O3S
    4-(2-{6-amino-8-[(6-chloro-1,3-benzodioxol-5-yl)thio]-9H-purin-9-yl}ethyl)piperidine-1-carbaldehyde
    —— 4-(2-{6-Amino-8-[(6-bromo-1,3-benzodioxol-5-yl)thio]-3H-purin-3-yl}ethyl)piperidine-1-carbaldehyde 958022-72-5 C20H21BrN6O3S
    4-(2-{6-Amino-8-[(6-bromo-1,3-benzodioxol-5-yl)thio]-3H-purin-3-yl}ethyl)piperidine-1-carbaldehyde
    —— 8-[(6-Bromo-1,3-benzodioxol-5-yl)thio]-9-{2-[1-(cyclopropylcarbonyl)piperidin-4-yl]ethyl}-9H-purin-6-amine 958020-96-7 C23H25BrN6O3S
    8-[(6-Bromo-1,3-benzodioxol-5-yl)thio]-9-{2-[1-(cyclopropylcarbonyl)piperidin-4-yl]ethyl}-9H-purin-6-amine
    —— 2-[4-(2-{6-amino-8-[(7-bromo-2,3-dihydro-1,4-benzodioxin-6-yl)thio]-9H-purin-9-yl}ethyl)piperidin-1-yl]-2-oxoethanol 1156466-06-6 C22H25BrN6O4S
    2-[4-(2-{6-amino-8-[(7-bromo-2,3-dihydro-1,4-benzodioxin-6-yl)thio]-9H-purin-9-yl}ethyl)piperidin-1-yl]-2-oxoethanol
    —— 8-[(6-Bromo-1,3-benzodioxol-5-yl)thio]-9-{2-[1-(2,2,2-trifluoroethyl)piperidin-4-yl]ethyl}-9H-purin-6-amine 958022-38-3 C21H22BrF3N6O2S
    8-[(6-Bromo-1,3-benzodioxol-5-yl)thio]-9-{2-[1-(2,2,2-trifluoroethyl)piperidin-4-yl]ethyl}-9H-purin-6-amine
    —— tert-butyl (7R,8R,9S)-8-hydroxymethyl-9-methyl-1,4-dithiaspiro<4.4>nonane-7-thiocarboxylate 124443-56-7 C14H24O2S3
    tert-butyl (7R,8R,9S)-8-hydroxymethyl-9-methyl-1,4-dithiaspiro<4.4>nonane-7-thiocarboxylate
    —— 2,4-bis(methylthio)-indane-5H-<2,1-c>pyridine 128736-26-5 C14H13NS2
    2,4-bis(methylthio)-indane-5H-<2,1-c>pyridine
    —— 2,6-bis(methylthio)-4-ethylpyridine 128736-17-4 C9H13NS2
    2,6-bis(methylthio)-4-ethylpyridine
    —— 2-[4-(2-{6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)thio]-9H-purin-9-yl}ethyl)piperidine-1-yl]-2-oxoethanol 958025-74-6 C21H23BrN6O4S
    2-[4-(2-{6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)thio]-9H-purin-9-yl}ethyl)piperidine-1-yl]-2-oxoethanol
    —— tert-butyl 4-[2-[6-amino-8-[(5-bromo-2,3-dihydrobenzofuran-6-yl)sulfanyl]purin-9-yl]ethyl]piperidine-1-carboxylate 1156467-20-7 C25H31BrN6O3S
    tert-butyl 4-[2-[6-amino-8-[(5-bromo-2,3-dihydrobenzofuran-6-yl)sulfanyl]purin-9-yl]ethyl]piperidine-1-carboxylate
    —— (2R)-1-[4-(2-{6-amino-8-[(7-bromo-2,3-dihydro-1,4-benzodioxin-6-yl)thio]-9H-purin-9-yl}ethyl)piperidin-1-yl]-1-oxopropan-2-ol 1156466-32-8 C23H27BrN6O4S
    (2R)-1-[4-(2-{6-amino-8-[(7-bromo-2,3-dihydro-1,4-benzodioxin-6-yl)thio]-9H-purin-9-yl}ethyl)piperidin-1-yl]-1-oxopropan-2-ol
    —— 4-(2-{6-Amino-8-[(7-bromo-2,3-dihydro-1,4-benzodioxin-6-yl)thio]-9H-purin-9-yl}ethyl)piperidine-1-carbaldehyde 958021-58-4 C21H23BrN6O3S
    4-(2-{6-Amino-8-[(7-bromo-2,3-dihydro-1,4-benzodioxin-6-yl)thio]-9H-purin-9-yl}ethyl)piperidine-1-carbaldehyde
    —— 8-[(6-Bromo-1,3-benzodioxol-5-yl)thio]-9-{2-[1-(1-methyl-1H-tetrazol-5-yl)piperidin-4-yl]ethyl}-9H-purin-6-amine 958022-86-1 C21H23BrN10O2S
    8-[(6-Bromo-1,3-benzodioxol-5-yl)thio]-9-{2-[1-(1-methyl-1H-tetrazol-5-yl)piperidin-4-yl]ethyl}-9H-purin-6-amine
    —— 4-(2-{6-amino-8-[(7-bromo-4-methyl-3,4-dihydro-2H-1,4-benzoxazin-6-yl)thio]-9H-purin-9-yl}ethyl)piperidine-1-carbaldehyde 1156467-36-5 C22H26BrN7O2S
    4-(2-{6-amino-8-[(7-bromo-4-methyl-3,4-dihydro-2H-1,4-benzoxazin-6-yl)thio]-9H-purin-9-yl}ethyl)piperidine-1-carbaldehyde
    —— 4-(2-{6-amino-8-[(6-bromo-4-methyl-3,4-dihydro-2H-1,4-benzoxazin-7-yl)thio]-9H-purin-9-yl}ethyl)piperidine-1-carbaldehyde 1156467-38-7 C22H26BrN7O2S
    4-(2-{6-amino-8-[(6-bromo-4-methyl-3,4-dihydro-2H-1,4-benzoxazin-7-yl)thio]-9H-purin-9-yl}ethyl)piperidine-1-carbaldehyde
    —— tert-butyl 4-[2-[6-amino-8-[(6-bromo-2,3-dihydro-1,4-benzodioxin-7-yl)sulfanyl]purin-9-yl]ethyl]piperidine-1-carboxylate 1156468-51-7 C25H31BrN6O4S
    tert-butyl 4-[2-[6-amino-8-[(6-bromo-2,3-dihydro-1,4-benzodioxin-7-yl)sulfanyl]purin-9-yl]ethyl]piperidine-1-carboxylate
    —— 4-(2-{6-amino-8-[(5-bromo-2,3-dihydro-1-benzofuran-6-yl)thio]-9H-purin-9-yl}ethyl)piperidine-1-carbaldehyde 1156467-11-6 C21H23BrN6O2S
    4-(2-{6-amino-8-[(5-bromo-2,3-dihydro-1-benzofuran-6-yl)thio]-9H-purin-9-yl}ethyl)piperidine-1-carbaldehyde
    —— 4-(2-{6-amino-8-[(5-bromo-1-benzofuran-6-yl)thio]-9H-purin-9-yl}ethyl)piperidine-1-carbaldehyde 1156467-12-7 C21H21BrN6O2S
    4-(2-{6-amino-8-[(5-bromo-1-benzofuran-6-yl)thio]-9H-purin-9-yl}ethyl)piperidine-1-carbaldehyde
    —— 8-[(6-Bromo-1,3-benzodioxol-5-yl)thio]-9-[2-(1-isopropylpiperidin-4-yl)ethyl]-9H-purin-6-amine 958022-32-7 C22H27BrN6O2S
    8-[(6-Bromo-1,3-benzodioxol-5-yl)thio]-9-[2-(1-isopropylpiperidin-4-yl)ethyl]-9H-purin-6-amine
    —— 8-[(6-Bromo-1,3-benzodioxol-5-yl)thio]-9-{2-[1-(cyclohexylmethyl)piperidin-4-yl]ethyl}-9H-purin-6-amine 958022-30-5 C26H33BrN6O2S
    8-[(6-Bromo-1,3-benzodioxol-5-yl)thio]-9-{2-[1-(cyclohexylmethyl)piperidin-4-yl]ethyl}-9H-purin-6-amine
    —— 8-[(6-Bromo-1,3-benzodioxol-5-yl)thio]-9-[2-(1-prop-2-yn-1-ylpiperidin-4-yl)ethyl]-9H-purin-6-amine 958023-18-2 C22H23BrN6O2S
    8-[(6-Bromo-1,3-benzodioxol-5-yl)thio]-9-[2-(1-prop-2-yn-1-ylpiperidin-4-yl)ethyl]-9H-purin-6-amine
    —— (2R)-1-[4-(2-{6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-9H-purin-9-yl}ethyl)piperidin-1-yl]-2-hydroxypropan-1-one 958025-86-0 C22H25BrN6O4S
    (2R)-1-[4-(2-{6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-9H-purin-9-yl}ethyl)piperidin-1-yl]-2-hydroxypropan-1-one
    —— 8-[(6-bromo-1,3-benzodioxol-5-yl)thio]-9-[2-(1-butyrylpiperidin-4-yl)ethyl]-9H-purin-6-amine 1156465-97-2 C23H27BrN6O3S
    8-[(6-bromo-1,3-benzodioxol-5-yl)thio]-9-[2-(1-butyrylpiperidin-4-yl)ethyl]-9H-purin-6-amine
    —— 2-(3-methylbenzyl)-4-(methylsulfanyl)-6-oxo-1,6-dihydro-5-pyrimidinecarbonitrile 860815-01-6 C14H13N3OS
    2-(3-methylbenzyl)-4-(methylsulfanyl)-6-oxo-1,6-dihydro-5-pyrimidinecarbonitrile
    —— 1-<(7R,8R,9S)-8-(tert-butyldimethylsilyloxymethyl)-9-methyl-1,4-dithiaspiro<4.4>non-7yl>ethanone 124443-59-0 C17H32O2S2Si
    1-<(7R,8R,9S)-8-(tert-butyldimethylsilyloxymethyl)-9-methyl-1,4-dithiaspiro<4.4>non-7yl>ethanone
    —— 1,3-bis(methylthio)-6,7,8,9-tetrahydro-5H-cyclohepta<c>pyridine 128736-25-4 C12H17NS2
    1,3-bis(methylthio)-6,7,8,9-tetrahydro-5H-cyclohepta<c>pyridine
    —— 6-Amino-1,4-dimethyl-7-phenylsulfanyl-1,4-dihydro-quinoxaline-2,3-dione 126473-90-3 C16H15N3O2S
    6-Amino-1,4-dimethyl-7-phenylsulfanyl-1,4-dihydro-quinoxaline-2,3-dione