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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-(2-Phenyl-[1,3]dithiolan-2-yl)-ethanone 61571-95-7 C11H12OS2
    1-(2-Phenyl-[1,3]dithiolan-2-yl)-ethanone
    —— 3-cyano-2,6-bis(2-thienyl)-4-(methylthio)pyridine 130446-00-3 C15H10N2S3
    3-cyano-2,6-bis(2-thienyl)-4-(methylthio)pyridine
    —— 3-cyano-2-methyl-3-(methylthio)-6-(2-thienyl)pyridine 130445-74-8 C12H10N2S2
    3-cyano-2-methyl-3-(methylthio)-6-(2-thienyl)pyridine
    —— 2-mercaptodecan-1-ol 98204-65-0 C10H22OS
    2-mercaptodecan-1-ol
    —— (Z)-2-methyl-3-(phenylthio)propenoic acid 87531-38-2 C10H10O2S
    (Z)-2-methyl-3-(phenylthio)propenoic acid
    —— 5-ethyl-6-methyl-3-carbethoxy-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one 172469-91-9 C19H23NO3S
    5-ethyl-6-methyl-3-carbethoxy-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one
    —— 5-ethyl-6-methyl-2-(methylthio)pyrimidin-4(3H)-one 54855-82-2 C8H12N2OS
    5-ethyl-6-methyl-2-(methylthio)pyrimidin-4(3H)-one
    —— 5-ethyl-6-methyl-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one 172470-05-2 C16H19NOS
    5-ethyl-6-methyl-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one
    —— 2-(N-methylcarbamoyl)phenyl 2-nitrophenyl sulfide 252731-18-3 C14H12N2O3S
    2-(N-methylcarbamoyl)phenyl 2-nitrophenyl sulfide
    —— 2-(2'-nitrophenylthio)benzoic acid chloride 95906-78-8 C13H8ClNO3S
    2-(2'-nitrophenylthio)benzoic acid chloride
    —— 2-(2-nitrophenylthio)benzoic acid methyl ester 100866-62-4 C14H13NO2S
    2-(2-nitrophenylthio)benzoic acid methyl ester
    —— methyl 2-(2-nitrophenylthio)phenylacetate 95906-77-7 C15H13NO4S
    methyl 2-(2-nitrophenylthio)phenylacetate
    —— N-methyl-2-(2'-aminophenylthio)benzylamine 853180-71-9 C14H16N2S
    N-methyl-2-(2'-aminophenylthio)benzylamine
    —— ethyl 2-(2'-nitrophenylthio)benzoate 140425-59-8 C15H13NO4S
    ethyl 2-(2'-nitrophenylthio)benzoate
    —— N-methyl-2-(2'-aminophenylthio)benzamide 860778-57-0 C14H14N2OS
    N-methyl-2-(2'-aminophenylthio)benzamide
    —— 3-Phenylthioheptan-2-on 62870-24-0 C13H18OS
    3-Phenylthioheptan-2-on
    —— N-Benzyl-5-(phenylthio)pentanamide 130422-38-7 C18H21NOS
    N-Benzyl-5-(phenylthio)pentanamide
    —— 4-[2-(2-hydroxyethoxy)-ethyl]-piperazine-carboxylic acid (2-phenylsulfanyl-phenyl)-amide 848786-52-7 C21H27N3O3S
    4-[2-(2-hydroxyethoxy)-ethyl]-piperazine-carboxylic acid (2-phenylsulfanyl-phenyl)-amide
    —— <i>N'</i>-[2-(4-chloro-phenylsulfanyl)-phenyl]-<i>N,N</i>-dimethyl-propanediyldiamine 108975-28-6 C17H21ClN2S
    <i>N'</i>-[2-(4-chloro-phenylsulfanyl)-phenyl]-<i>N,N</i>-dimethyl-propanediyldiamine
    —— sulfide 213380-63-3 C16H14O2S
    sulfide
    —— diethyl 2-{3-[2-chloro-4-(3-trifluoromethylphenylthio)phenyl]propyl}-2-methylmalonate 1006727-20-3 C24H26ClF3O4S
    diethyl 2-{3-[2-chloro-4-(3-trifluoromethylphenylthio)phenyl]propyl}-2-methylmalonate
    —— N-Benzyl-6-(phenylthio)hexanamide 130422-39-8 C19H23NOS
    N-Benzyl-6-(phenylthio)hexanamide
    —— N-ethenylsulfanylcycloheptanimine 132065-72-6 C9H15NS
    N-ethenylsulfanylcycloheptanimine
    —— 2-Sulfinylheptane 133619-36-0 C7H14OS
    2-Sulfinylheptane
    —— 2-phenylthio-2-trimethylsilylheptane 85969-79-5 C16H28SSi
    2-phenylthio-2-trimethylsilylheptane
    —— 2-methylnonane-2-thiol 30174-58-4 C10H22S
    2-methylnonane-2-thiol
    —— 2-(2-aminophenylthio)-5-chlorobenzoic acid 81890-74-6 C13H10ClNO2S
    2-(2-aminophenylthio)-5-chlorobenzoic acid
    —— 1-phenylthio-2-nonanone 38793-75-8 C15H22OS
    1-phenylthio-2-nonanone
    —— 2-(2-{4-[3-(benzyloxy)phenylthio]-2-chlorophenyl}ethyl)-2-methylmalonic acid diethyl ester 676481-40-6 C29H31ClO5S
    2-(2-{4-[3-(benzyloxy)phenylthio]-2-chlorophenyl}ethyl)-2-methylmalonic acid diethyl ester
    —— 2,3-Bis-isobutylsulfanyl-propionaldehyde 132279-15-3 C11H22OS2
    2,3-Bis-isobutylsulfanyl-propionaldehyde
    —— 3-phenylthio-2-nonanone 1356922-69-4 C15H22OS
    3-phenylthio-2-nonanone
    —— 1-(3-chloro-1-bicyclo[1.1.1]pentanyl)-3-methylsulfonylbicyclo[1.1.1]pentane 127321-12-4 C11H15ClO2S
    1-(3-chloro-1-bicyclo[1.1.1]pentanyl)-3-methylsulfonylbicyclo[1.1.1]pentane
    —— (Z)-5-((pyridin-2-ylthio)methylene)thiophen-2(5H)-one 1415508-81-4 C10H7NOS2
    (Z)-5-((pyridin-2-ylthio)methylene)thiophen-2(5H)-one
    —— 1-chloro-3-methanesulfonylbicyclo[1.1.1]pentane 127321-11-3 C6H9ClO2S
    1-chloro-3-methanesulfonylbicyclo[1.1.1]pentane
    —— 2-Heptyl-2-methyl-1,3-dithian 68971-92-6 C12H24S2
    2-Heptyl-2-methyl-1,3-dithian
    —— (Z)-5-(((4-chlorophenyl)thio)methylene)thiophen-2(5H)-one 1415508-87-0 C11H7ClOS2
    (Z)-5-(((4-chlorophenyl)thio)methylene)thiophen-2(5H)-one
    —— (Z)-5-((pyrimidin-2-ylthio)methylene)thiophen-2(5H)-one 1415508-82-5 C9H6N2OS2
    (Z)-5-((pyrimidin-2-ylthio)methylene)thiophen-2(5H)-one
    —— 2-phenylsulfanyl-acetoacetic acid ethyl ester 27872-73-7 C12H14O3S
    2-phenylsulfanyl-acetoacetic acid ethyl ester
    —— 2-heptyl-2-methyl-1,3-dithiolane 147777-28-4 C11H22S2
    2-heptyl-2-methyl-1,3-dithiolane
    —— N-[2-(4-methoxyphenyl)sulfanyl-5-methyl-phenyl]-7-methyl-pyrido[2,3-d]pyrimidin-4-amine 1365920-98-4 C22H20N4OS
    N-[2-(4-methoxyphenyl)sulfanyl-5-methyl-phenyl]-7-methyl-pyrido[2,3-d]pyrimidin-4-amine
    —— 6-[2-Hydroxy-2-(4-methylsulfanyl-phenyl)-ethyl]-2-oxo-1,2-dihydro-pyridine-3-carbonitrile 88251-94-9 C15H14N2O2S
    6-[2-Hydroxy-2-(4-methylsulfanyl-phenyl)-ethyl]-2-oxo-1,2-dihydro-pyridine-3-carbonitrile
    —— (5-Methyl-2-phenylsulfanyl-phenyl)-(7-methyl-pyrido[2,3-d]pyrimidin-4-yl)-amine 944642-35-7 C21H18N4S
    (5-Methyl-2-phenylsulfanyl-phenyl)-(7-methyl-pyrido[2,3-d]pyrimidin-4-yl)-amine
    —— 4-[4-methyl-2-(7-methyl-pyrido[2,3-d]pyrimidin-4-ylamino)-phenylsulfanyl]-phenol 944503-59-7 C21H18N4OS
    4-[4-methyl-2-(7-methyl-pyrido[2,3-d]pyrimidin-4-ylamino)-phenylsulfanyl]-phenol
    —— N-[2-(4-fluorophenyl)sulfanyl-5-methyl-phenyl]-7-methyl-pyrido[2,3-d]pyrimidin-4-amine 1365921-03-4 C21H17FN4S
    N-[2-(4-fluorophenyl)sulfanyl-5-methyl-phenyl]-7-methyl-pyrido[2,3-d]pyrimidin-4-amine
    —— 2-(But-3-ynyl)-2-phenyl-1,3-dithiane 126594-06-7 C14H16S2
    2-(But-3-ynyl)-2-phenyl-1,3-dithiane
    —— (3'aS,4'S,7'aS)-7'a-methyl-4'-prop-2-enylspiro[1,3-dithiolane-2,5'-2,3,3a,4,6,7-hexahydroindene]-1'-one 854759-80-1 C15H22OS2
    (3'aS,4'S,7'aS)-7'a-methyl-4'-prop-2-enylspiro[1,3-dithiolane-2,5'-2,3,3a,4,6,7-hexahydroindene]-1'-one
    —— (aminoiminomethyl)thioacetic acid ethyl ester hydrochloride 60263-46-9 C5H10N2O2S*ClH
    (aminoiminomethyl)thioacetic acid ethyl ester hydrochloride
    —— 2-[2-(Phenylsulfanyl)ethoxy]ethan-1-ol 95108-89-7 C10H14O2S
    2-[2-(Phenylsulfanyl)ethoxy]ethan-1-ol
    —— 1-((1R,2R)-2-Methyl-1-oxo-1λ<sup>4</sup>-[1,3]dithian-2-yl)-ethanone 131309-71-2 C7H12O2S2
    1-((1R,2R)-2-Methyl-1-oxo-1λ<sup>4</sup>-[1,3]dithian-2-yl)-ethanone
    —— 3-Chloro-2-isobutylsulfanyl-propionaldehyde 132279-11-9 C7H13ClOS
    3-Chloro-2-isobutylsulfanyl-propionaldehyde