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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— potassium methylsulfinylacetate 156699-76-2 C3H5O3S*K
    potassium methylsulfinylacetate
    —— 2-hydroxymethyl-4-methylthio-6-ethylpyrimidine 911388-89-1 C8H12N2OS
    2-hydroxymethyl-4-methylthio-6-ethylpyrimidine
    —— 1-methylthio-4,5,6,7-tetrahydrobenzo[c]thiophene 125150-88-1 C9H12S2
    1-methylthio-4,5,6,7-tetrahydrobenzo[c]thiophene
    —— 1-acetyl-2,5,6,7-tetrahydrothiopyrano<3,2-c>pyrazole-3(1H)-one 124187-79-7 C8H10N2O2S
    1-acetyl-2,5,6,7-tetrahydrothiopyrano<3,2-c>pyrazole-3(1H)-one
    —— 4,4-bis(ethylthio)cyclohexa-2,5-dienone 1234217-82-3 C10H14OS2
    4,4-bis(ethylthio)cyclohexa-2,5-dienone
    —— (2-tert-Butyl-5-cyano-6-methylsulfanyl-pyrimidin-4-yloxy)-acetic acid 119491-71-3 C12H15N3O3S
    (2-tert-Butyl-5-cyano-6-methylsulfanyl-pyrimidin-4-yloxy)-acetic acid
    —— Benzene, 5-bromo-2-fluoro-1-methyl-3-(methylthio)- 1822862-39-4 C8H8BrFS
    Benzene, 5-bromo-2-fluoro-1-methyl-3-(methylthio)-
    —— 3-phenyl-1,1-bis(p-tolylthio)-3-(trimethylsilyloxy)propan-2-one 130796-21-3 C26H30O2S2Si
    3-phenyl-1,1-bis(p-tolylthio)-3-(trimethylsilyloxy)propan-2-one
    —— 4-(methylthio)-2-phenylpyrimido[4,5-d]pyridazin-5(6H)-one 1425383-92-1 C13H10N4OS
    4-(methylthio)-2-phenylpyrimido[4,5-d]pyridazin-5(6H)-one
    —— 3-hydroxy-3-phenyl-1,1-bis(p-tolylthio)propan-2-one 130796-23-5 C23H22O2S2
    3-hydroxy-3-phenyl-1,1-bis(p-tolylthio)propan-2-one
    —— 3-carbethoxy-2-(methylthio)-Δ<sup>1</sup>-pyrroline 61254-37-3 C8H13NO2S
    3-carbethoxy-2-(methylthio)-Δ<sup>1</sup>-pyrroline
    —— 3-(Methylsulfanyl)-6-phenylthieno[2,3-e][1,2,4]triazine 69347-03-1 C12H9N3S2
    3-(Methylsulfanyl)-6-phenylthieno[2,3-e][1,2,4]triazine
    —— 1-acetyl-3-acetyloxy-1,5,6,7-tetrahydrothiopyrano<3,2-c>pyrazole 124187-78-6 C10H12N2O3S
    1-acetyl-3-acetyloxy-1,5,6,7-tetrahydrothiopyrano<3,2-c>pyrazole
    —— 2-[4-[4-[3,6-bis(phenylimino)cyclohexa-1,4-dien-1-yl]sulfanylphenyl]sulfanylphenyl]sulfanyl-1-N,4-N-diphenylcyclohexa-2,5-diene-1,4-diimine 325963-57-3 C48H34N4S3
    2-[4-[4-[3,6-bis(phenylimino)cyclohexa-1,4-dien-1-yl]sulfanylphenyl]sulfanylphenyl]sulfanyl-1-N,4-N-diphenylcyclohexa-2,5-diene-1,4-diimine
    —— 2-butylsulfanyl-1-N,4-N-diphenylbenzene-1,4-diamine 911110-01-5 C22H24N2S
    2-butylsulfanyl-1-N,4-N-diphenylbenzene-1,4-diamine
    —— diethyl (1S,2S,3S,4S,5S)-3-ethyl-2-(4-methylphenyl)sulfanyl-5-nitrocyclohexane-1,4-dicarboxylate 1334997-74-8 C21H29NO6S
    diethyl (1S,2S,3S,4S,5S)-3-ethyl-2-(4-methylphenyl)sulfanyl-5-nitrocyclohexane-1,4-dicarboxylate
    —— diethyl (1S,2R,3S,4R,5S)-3-[tert-butyl(dimethyl)silyl]oxy-2-(4-methylphenyl)sulfanyl-5-nitrocyclohexane-1,4-dicarboxylate 1334997-78-2 C25H39NO7SSi
    diethyl (1S,2R,3S,4R,5S)-3-[tert-butyl(dimethyl)silyl]oxy-2-(4-methylphenyl)sulfanyl-5-nitrocyclohexane-1,4-dicarboxylate
    —— 2,6-bis(butylsulfanyl)-1-N,4-N-diphenylbenzene-1,4-diamine 911110-02-6 C26H32N2S2
    2,6-bis(butylsulfanyl)-1-N,4-N-diphenylbenzene-1,4-diamine
    —— 2-acetyl-3-acetyloxy-2,5,6,7-tetrahydrothiopyrano<3,2-c>pyrazole 124187-77-5 C10H12N2O3S
    2-acetyl-3-acetyloxy-2,5,6,7-tetrahydrothiopyrano<3,2-c>pyrazole
    —— N-(Thioacetyl)carbaminsaeure-ethylester 72139-54-9 C5H9NO2S
    N-(Thioacetyl)carbaminsaeure-ethylester
    —— 3-oxo 2-phenylthiomethyl cycloheptane carbonitrile 112496-78-3 C15H17NOS
    3-oxo 2-phenylthiomethyl cycloheptane carbonitrile
    —— methyl 5-chloro-2-(phenylthio)benzoate 1353055-80-7 C14H11ClO2S
    methyl 5-chloro-2-(phenylthio)benzoate
    —— 4-phenyl-1-phenylsulfanylbutan-2-one 83187-71-7 C16H16OS
    4-phenyl-1-phenylsulfanylbutan-2-one
    —— 2,2-bis(phenylthio)-4-phenyl-butane 108164-59-6 C22H22S2
    2,2-bis(phenylthio)-4-phenyl-butane
    —— 3-glycidylthio-5-methyl-1H-1,2,4-triazole 125707-68-8 C6H9N3OS
    3-glycidylthio-5-methyl-1H-1,2,4-triazole
    —— (4R)-(+)-2,4-dimethyl-1-iodo-5-phenylthiopent-1-ene 101212-38-8 C13H17IS
    (4R)-(+)-2,4-dimethyl-1-iodo-5-phenylthiopent-1-ene
    —— Dimethylphosphorylmethylphenylsulfid 70369-42-5 C9H13O3PS
    Dimethylphosphorylmethylphenylsulfid
    —— (3,3-Dimethyl-4-phenylsulfanylbut-1-en-2-yl) acetate 214960-41-5 C14H18O2S
    (3,3-Dimethyl-4-phenylsulfanylbut-1-en-2-yl) acetate
    —— (R)-(-)-2-methyl-3-(phenylthio)propan-1-ol 101212-36-6 C10H14OS
    (R)-(-)-2-methyl-3-(phenylthio)propan-1-ol
    —— 2-Phenylthiomethyl-2-methyl-1-propanol 51916-36-0 C11H16OS
    2-Phenylthiomethyl-2-methyl-1-propanol
    —— 1-Acetyl-4-(4-phenylsulfanyl-benzenesulfonyl)-piperidine-4-carboxylic acid 226397-56-4 C20H21NO5S2
    1-Acetyl-4-(4-phenylsulfanyl-benzenesulfonyl)-piperidine-4-carboxylic acid
    —— ethylcyanothioformanilide 13621-48-2 C4H6N2S
    ethylcyanothioformanilide
    —— 1,1-Bis-(phenylthio)-2-methyl-1,3-butadien 66581-88-2 C17H16S2
    1,1-Bis-(phenylthio)-2-methyl-1,3-butadien
    —— (2-methylthiophenylpyrrolyl)dipyrrolylphosphine 856702-67-5 C19H18N3PS
    (2-methylthiophenylpyrrolyl)dipyrrolylphosphine
    —— 3-oxo 2-phenylthiomethylcyclopentane carbonitrile 90380-01-1 C13H13NOS
    3-oxo 2-phenylthiomethylcyclopentane carbonitrile
    —— 3-oxo 2-phenylthiomethyl cyclohexane carbonitrile 112496-77-2 C14H15NOS
    3-oxo 2-phenylthiomethyl cyclohexane carbonitrile
    —— (Z)-1-nonen-1-yl phenyl sulfide 81114-93-4 C15H22S
    (Z)-1-nonen-1-yl phenyl sulfide
    —— (S)-2-methyl-3-phenylthiomethoxypropanal 116021-16-0 C11H14O2S
    (S)-2-methyl-3-phenylthiomethoxypropanal
    —— 5-methyl-6-(2-thienylmethyl)-2-{[(phenylsulfanyl)methyl]sulfanyl}pyrimidin-4(3H)-onepyrimidin-4(1H)-one 1290637-16-9 C17H16N2OS3
    5-methyl-6-(2-thienylmethyl)-2-{[(phenylsulfanyl)methyl]sulfanyl}pyrimidin-4(3H)-onepyrimidin-4(1H)-one
    —— (E)-1-nonen-1-yl phenyl sulfide 81114-87-6 C15H22S
    (E)-1-nonen-1-yl phenyl sulfide
    —— (+/-)-3c-allyl-4,4-dimethyl-2r-phenylsulfanylmethyl-cyclohexanone ethane-1,2-diyl acetal 123966-68-7 C20H28O2S
    (+/-)-3c-allyl-4,4-dimethyl-2r-phenylsulfanylmethyl-cyclohexanone ethane-1,2-diyl acetal
    —— ((phenylthio)methylene)cyclohexane 33521-88-9 C13H16S
    ((phenylthio)methylene)cyclohexane
    —— (1S,2R,3S,4R,5S)-ethyl 4-isocyanato-5-nitro-3-(pentan-3-yloxy)-2-(p-tolylthio)cyclohexanecarboxylate 1197396-53-4 C22H30N2O6S
    (1S,2R,3S,4R,5S)-ethyl 4-isocyanato-5-nitro-3-(pentan-3-yloxy)-2-(p-tolylthio)cyclohexanecarboxylate
    —— Phenylmercaptomethanphosphonsaeure 89854-56-8 C7H9O3PS
    Phenylmercaptomethanphosphonsaeure
    —— diethyl (1S,2R,3S,4R,5S)-2-(4-methylphenyl)sulfanyl-5-nitro-3-pentan-3-yloxycyclohexane-1,4-dicarboxylate 1334287-26-1 C24H35NO7S
    diethyl (1S,2R,3S,4R,5S)-2-(4-methylphenyl)sulfanyl-5-nitro-3-pentan-3-yloxycyclohexane-1,4-dicarboxylate
    —— (3-methylbut-1-enyl)(phenyl)sulfane 33923-89-6 C11H14S
    (3-methylbut-1-enyl)(phenyl)sulfane
    —— (+/-)-6t-hydroxy-4,4-dimethyl-8c-phenylsulfanyl-(4ar,8at)-octahydro-naphthalen-1-one ethane-1,2-diyl acetal 123966-75-6 C20H28O3S
    (+/-)-6t-hydroxy-4,4-dimethyl-8c-phenylsulfanyl-(4ar,8at)-octahydro-naphthalen-1-one ethane-1,2-diyl acetal
    —— methyl 3-oxo-5-(phenylthio)pentanoate 51849-20-8 C12H14O3S
    methyl 3-oxo-5-(phenylthio)pentanoate
    —— (+/-)-6c-hydroxy-4,4-dimethyl-8t-phenylsulfanyl-(4ar,8at)-octahydro-naphthalen-1-one ethane-1,2-diyl acetal 123966-75-6 C20H28O3S
    (+/-)-6c-hydroxy-4,4-dimethyl-8t-phenylsulfanyl-(4ar,8at)-octahydro-naphthalen-1-one ethane-1,2-diyl acetal
    —— (+/-)-3t-allyl-4,4-dimethyl-2r-phenylsulfanylmethyl-cyclohexanone ethane-1,2-diyl acetal 123966-68-7 C20H28O2S
    (+/-)-3t-allyl-4,4-dimethyl-2r-phenylsulfanylmethyl-cyclohexanone ethane-1,2-diyl acetal