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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-chloro-2-{[2-(methylsulfanyl)benzyl]amino}pyrimidine-5-carbonitrile 1214727-96-4 C13H11ClN4S
    4-chloro-2-{[2-(methylsulfanyl)benzyl]amino}pyrimidine-5-carbonitrile
    —— 4-<<3-(ethoxycarbonyl)phenyl>thio>phenol 128950-15-2 C15H14O3S
    4-<<3-(ethoxycarbonyl)phenyl>thio>phenol
    —— thiosulfurous acid <i>O</i>-ethyl ester <i>S</i>-propyl ester 17796-39-3 C5H12O2S2
    thiosulfurous acid <i>O</i>-ethyl ester <i>S</i>-propyl ester
    —— <i>O</i>,<i>S</i>-Diaethyl-thiosulfit 68261-74-5 C4H10O2S2
    <i>O</i>,<i>S</i>-Diaethyl-thiosulfit
    —— 3-(4-Chloro-phenylsulfanyl)-2-(2,2,2-trifluoro-acetylamino)-imidazo[1,2-a]pyridine-6-carboxylic acid methyl ester 209971-61-9 C17H11ClF3N3O3S
    3-(4-Chloro-phenylsulfanyl)-2-(2,2,2-trifluoro-acetylamino)-imidazo[1,2-a]pyridine-6-carboxylic acid methyl ester
    —— Methyl 3-(4-fluorophenyl)sulfanyl-2-[(2,2,2-trifluoroacetyl)amino]imidazo[1,2-a]pyridine-6-carboxylate 209971-62-0 C17H11F4N3O3S
    Methyl 3-(4-fluorophenyl)sulfanyl-2-[(2,2,2-trifluoroacetyl)amino]imidazo[1,2-a]pyridine-6-carboxylate
    —— 3-[3-(2-Carboxy-ethyl)-4-(6-phenyl-hexyloxy)-phenylsulfanyl]-benzoic acid 128950-03-8 C28H30O5S
    3-[3-(2-Carboxy-ethyl)-4-(6-phenyl-hexyloxy)-phenylsulfanyl]-benzoic acid
    —— 3-cyano-2-(3-hydroxy-1H-pyrazol-5-ylmethylthio)-4,6-dimethylpyridine 750593-45-4 C12H12N4OS
    3-cyano-2-(3-hydroxy-1H-pyrazol-5-ylmethylthio)-4,6-dimethylpyridine
    —— S-allyl O-ethyl carbonothioate 116423-17-7 C6H10O2S
    S-allyl O-ethyl carbonothioate
    —— O-methyl S-phenyl carbonodithioate 6047-46-7 C8H8OS2
    O-methyl S-phenyl carbonodithioate
    —— N-<1,2,3,4-tetrahydro-8-methoxy-5-(phenylthio)-2-naphthalenyl>acetamide 80270-83-3 C19H21NO2S
    N-<1,2,3,4-tetrahydro-8-methoxy-5-(phenylthio)-2-naphthalenyl>acetamide
    —— ethyl 2-{6-amino-3,5-dicyano-4-(2-thiophene)pyridyl}thioacetate 136633-83-5 C15H12N4O2S2
    ethyl 2-{6-amino-3,5-dicyano-4-(2-thiophene)pyridyl}thioacetate
    —— Propan-2-yl 4-[(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanyl]-3-oxobutanoate 327167-61-3 C16H20N2O3S
    Propan-2-yl 4-[(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanyl]-3-oxobutanoate
    —— 2-(Benzofuran-5-ylthio)-1-(4-methoxybenzyl)-1H-imidazo[4,5-c]pyridin-4-amine 1061316-74-2 C22H18N4O2S
    2-(Benzofuran-5-ylthio)-1-(4-methoxybenzyl)-1H-imidazo[4,5-c]pyridin-4-amine
    —— 2,5-bis-phenylsulfanyl-[1,3,4]thiadiazole 21398-13-0 C14H10N2S3
    2,5-bis-phenylsulfanyl-[1,3,4]thiadiazole
    —— 2,4,6-Trimethyl-dithio-benzoesaeure-phenylester 20876-79-3 C16H16S2
    2,4,6-Trimethyl-dithio-benzoesaeure-phenylester
    —— S-Methyl-S'-phenyl-trithiocarbonat-S,S-dioxid 53271-53-7 C8H8O2S3
    S-Methyl-S'-phenyl-trithiocarbonat-S,S-dioxid
    —— 4-(3,5-Dibromobenzylthio)Aniline 1314034-15-5 C13H11Br2NS
    4-(3,5-Dibromobenzylthio)Aniline
    —— phenyl N-phenyl-N-methyldithiocarbamate 21168-04-7 C14H13NS2
    phenyl N-phenyl-N-methyldithiocarbamate
    —— ethyl 2-phenylsulphanylthiazole-5-carboxylate 56355-60-3 C12H11NO2S2
    ethyl 2-phenylsulphanylthiazole-5-carboxylate
    —— 1,6-anhydro-2,4-dideoxy-4-methyl-2-(phenylthiomethyl)-β-D-glucopyranose 100757-48-0 C14H18O3S
    1,6-anhydro-2,4-dideoxy-4-methyl-2-(phenylthiomethyl)-β-D-glucopyranose
    —— N,N-dimethyl-2-(6'-methyl-2'-phenylpyrimidin-4'-ylthio)ethylamine 90185-66-3 C15H19N3S
    N,N-dimethyl-2-(6'-methyl-2'-phenylpyrimidin-4'-ylthio)ethylamine
    —— N,N-Diethyl-α,α-dichlor-thioacetamid 89582-80-9 C6H11Cl2NS
    N,N-Diethyl-α,α-dichlor-thioacetamid
    —— 3-amino-6-phenylthioimidazo [1,2-a] pyridine 64064-73-9 C13H11N3S
    3-amino-6-phenylthioimidazo [1,2-a] pyridine
    —— 3-[(3-Chlorophenyl)sulfanyl]-1-methyl-1H-pyrrole-2,5-dione 132227-63-5 C11H8ClNO2S
    3-[(3-Chlorophenyl)sulfanyl]-1-methyl-1H-pyrrole-2,5-dione
    —— Ethyl 4-methyl-5-oxo-2-phenylsulfanylthiocarbonyl-2,5-dihydroisoxazole-3-carboxylate 197582-19-7 C14H13NO4S2
    Ethyl 4-methyl-5-oxo-2-phenylsulfanylthiocarbonyl-2,5-dihydroisoxazole-3-carboxylate
    —— 3-Methoxycarbonylamino-6-phenylthio-imidazo<1,2-a>pyridin 64064-74-0 C15H13N3O2S
    3-Methoxycarbonylamino-6-phenylthio-imidazo<1,2-a>pyridin
    —— Ethyl 5-oxo-2-phenylsulfanylthiocarbonyl-2,5-dihydroisoxazole-4-carboxylate 197582-15-3 C13H11NO4S2
    Ethyl 5-oxo-2-phenylsulfanylthiocarbonyl-2,5-dihydroisoxazole-4-carboxylate
    —— O-[(1R,3R,6Z,8S,9E)-3,7,11,11,14-pentamethyl-15-oxo-16-oxatricyclo[11.2.1.01,5]hexadeca-4,6,9,13-tetraen-8-yl] phenylsulfanylmethanethioate 1448443-57-9 C27H30O3S2
    O-[(1R,3R,6Z,8S,9E)-3,7,11,11,14-pentamethyl-15-oxo-16-oxatricyclo[11.2.1.01,5]hexadeca-4,6,9,13-tetraen-8-yl] phenylsulfanylmethanethioate
    —— 3-(2-chloro-5-pyridinylmethyl)-2-[(phenylthio)thiocarbonylimino]thiazolidine 1314458-04-2 C16H14ClN3S3
    3-(2-chloro-5-pyridinylmethyl)-2-[(phenylthio)thiocarbonylimino]thiazolidine
    —— 2-Dimethylamino-aethyl-2-dimethylamino-aethanthiolsulfonat 51263-82-2 C8H20N2O2S2
    2-Dimethylamino-aethyl-2-dimethylamino-aethanthiolsulfonat
    —— 2-Allylsulfanyl-propionaldehyde 132604-57-0 C6H10OS
    2-Allylsulfanyl-propionaldehyde
    —— 1-Butyl-3-(phenylsulfanyl)pyrrolidine-2,5-dione 62164-00-5 C14H17NO2S
    1-Butyl-3-(phenylsulfanyl)pyrrolidine-2,5-dione
    —— N,N-dimethyl-2-<4'-(thiazol-2"-yl)pyrimidin-2'-ylthio>ethylamine 83726-82-3 C11H14N4S2
    N,N-dimethyl-2-<4'-(thiazol-2"-yl)pyrimidin-2'-ylthio>ethylamine
    —— MC-241 131407-77-7 C16H17N3OS2
    MC-241
    —— 2-<<2'''-(dimethylamino)ethyl>thio>-4-(1'-methylpyrol-2'-yl)-6-thien-2''-ylpyrimidine 129224-85-7 C17H20N4S2
    2-<<2'''-(dimethylamino)ethyl>thio>-4-(1'-methylpyrol-2'-yl)-6-thien-2''-ylpyrimidine
    —— 5-(2-dimethylaminoethylthio)-2-thiophenecarboxaldehyde 174766-67-7 C9H13NOS2
    5-(2-dimethylaminoethylthio)-2-thiophenecarboxaldehyde
    —— 4-carbomethoxybicyclo[2.2.2]octane-1-carboxaldehyde 719274-88-1 C13H19F3O4S
    4-carbomethoxybicyclo[2.2.2]octane-1-carboxaldehyde
    —— (1-Chloro-oct-2-ynylsulfanyl)-benzene 194856-61-6 C14H17ClS
    (1-Chloro-oct-2-ynylsulfanyl)-benzene
    —— methyl 4-[(E)-2-ethylsulfonylethenyl]bicyclo[2.2.2]octane-1-carboxylate 719274-63-2 C14H22O4S
    methyl 4-[(E)-2-ethylsulfonylethenyl]bicyclo[2.2.2]octane-1-carboxylate
    —— 4-[3-(ethylsulfonyl)propyl]bicyclo[2.2.2]octane-1-carboxylic acid 719274-75-6 C14H24O4S
    4-[3-(ethylsulfonyl)propyl]bicyclo[2.2.2]octane-1-carboxylic acid
    —— methyl 4-[3-(ethylsulfonyl)propyl]bicyclo[2.2.2]octane-1-carboxylate 719274-74-5 C15H26O4S
    methyl 4-[3-(ethylsulfonyl)propyl]bicyclo[2.2.2]octane-1-carboxylate
    —— 4-[2-(ethylsulfonyl)ethyl]-N-methylbicyclo[2.2.2]octane-1-carboxamide 719274-66-5 C14H25NO3S
    4-[2-(ethylsulfonyl)ethyl]-N-methylbicyclo[2.2.2]octane-1-carboxamide
    —— 4-[2-(ethylsulfonyl)ethyl]bicyclo[2.2.2]octane-1-carboxyl chloride 876400-26-9 C13H21ClO3S
    4-[2-(ethylsulfonyl)ethyl]bicyclo[2.2.2]octane-1-carboxyl chloride
    —— N,N-dimethyl-2-<(4'-furan-2''-ylpyrimidin-2'-yl)thio>ethylamine 109628-19-5 C12H15N3OS
    N,N-dimethyl-2-<(4'-furan-2''-ylpyrimidin-2'-yl)thio>ethylamine
    —— methyl 4-[2-(ethylsulfonyl)ethyl]bicyclo[2.2.2]octane-1-carboxylate 719274-64-3 C14H24O4S
    methyl 4-[2-(ethylsulfonyl)ethyl]bicyclo[2.2.2]octane-1-carboxylate
    —— 4-[3-(ethylsulfonyl)propyl]-N-methylbicyclo[2.2.2]octane-1-carboxamide 719274-76-7 C15H27NO3S
    4-[3-(ethylsulfonyl)propyl]-N-methylbicyclo[2.2.2]octane-1-carboxamide
    —— 4-[2-(ethylsulfonyl)ethyl]bicyclo[2.2.2]octane-1-carboxylic acid 719274-65-4 C13H22O4S
    4-[2-(ethylsulfonyl)ethyl]bicyclo[2.2.2]octane-1-carboxylic acid
    —— Methyl 4-(2-ethylsulfonylethenyl)bicyclo[2.2.2]octane-1-carboxylate 876400-25-8 C14H22O4S
    Methyl 4-(2-ethylsulfonylethenyl)bicyclo[2.2.2]octane-1-carboxylate
    —— 1-methoxy-2-octynyl phenyl sulfide 194856-65-0 C15H20OS
    1-methoxy-2-octynyl phenyl sulfide