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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Nitro-6-(4-trifluoromethyl-phenylsulfanyl)-benzonitrile 168910-84-7 C14H7F3N2O2S
    2-Nitro-6-(4-trifluoromethyl-phenylsulfanyl)-benzonitrile
    —— (2R,3S,4R)-2-amino-1-phenylsulfanyloctadecane-3,4-diol 1365757-12-5 C24H43NO2S
    (2R,3S,4R)-2-amino-1-phenylsulfanyloctadecane-3,4-diol
    —— 2-nitro-6-<(4-aminophenyl)thio>benzonitrile 168910-86-9 C13H9N3O2S
    2-nitro-6-<(4-aminophenyl)thio>benzonitrile
    —— 2-(4-tert-Butyl-phenylsulfanyl)-6-nitro-benzonitrile 168910-31-4 C17H16N2O2S
    2-(4-tert-Butyl-phenylsulfanyl)-6-nitro-benzonitrile
    —— 2-(4-Isopropyl-phenylsulfanyl)-6-nitro-benzonitrile 168910-30-3 C16H14N2O2S
    2-(4-Isopropyl-phenylsulfanyl)-6-nitro-benzonitrile
    —— 2-[(3-methoxyphenyl)thio]-6-nitrobenzonitrile 168910-89-2 C14H10N2O3S
    2-[(3-methoxyphenyl)thio]-6-nitrobenzonitrile
    —— 2-nitro-6-(4-tolylthio)benzonitrile 168910-26-7 C14H10N2O2S
    2-nitro-6-(4-tolylthio)benzonitrile
    —— [5-Chloro-2-(2,5-dimethoxy-phenylsulfanyl)-phenyl]-ethyl-phosphoramidic acid diethyl ester 72418-79-2 C20H27ClNO5PS
    [5-Chloro-2-(2,5-dimethoxy-phenylsulfanyl)-phenyl]-ethyl-phosphoramidic acid diethyl ester
    —— (R)-6-allyl-6-methyl-3-(phenylthio)cyclohex-2-enone 900493-92-7 C16H18OS
    (R)-6-allyl-6-methyl-3-(phenylthio)cyclohex-2-enone
    —— 1,3-bis(phenylthio)cyclohexene 60039-89-6 C18H18S2
    1,3-bis(phenylthio)cyclohexene
    —— 1-(t-butyldimethylsiloxy)-2-bromo-3-phenylthio-2-cyclohexene 470458-64-1 C18H27BrOSSi
    1-(t-butyldimethylsiloxy)-2-bromo-3-phenylthio-2-cyclohexene
    —— allyl 1-methyl-2-oxo-4-(phenylthio)cyclohex-3-enecarboxylate 900493-70-1 C17H18O3S
    allyl 1-methyl-2-oxo-4-(phenylthio)cyclohex-3-enecarboxylate
    —— 3-phenylthio-1-vinyl-cyclohex-2-en-1-ol 881417-41-0 C14H16OS
    3-phenylthio-1-vinyl-cyclohex-2-en-1-ol
    —— methyl trans-α-methylene-5-oxo-2<(methoxycyarbonyl)(phenylthio)methyl>cyclohexanepropanoate —— C20H24O5S
    methyl trans-α-methylene-5-oxo-2<(methoxycyarbonyl)(phenylthio)methyl>cyclohexanepropanoate
    —— Benzene, 1-bromo-4-(heptylthio)- 76542-22-8 C13H19BrS
    Benzene, 1-bromo-4-(heptylthio)-
    —— 1,1-bis(p-chlorophenylthio)-3-phenylpropane 613245-30-0 C21H18Cl2S2
    1,1-bis(p-chlorophenylthio)-3-phenylpropane
    —— ethyl 2-(p-chlorophenylthio)-4-phenylbutanoate 613245-42-4 C18H19ClO2S
    ethyl 2-(p-chlorophenylthio)-4-phenylbutanoate
    —— 2-nitro-6-(phenylthio)benzonirtile 123241-40-7 C13H8N2O2S
    2-nitro-6-(phenylthio)benzonirtile
    —— 5-acetyl-4-amino-1-methyl-2-methylsulfanyl-pyrrole-3-carbonitrile 145162-37-4 C9H11N3OS
    5-acetyl-4-amino-1-methyl-2-methylsulfanyl-pyrrole-3-carbonitrile
    —— tert-butyl {(2R)-1-hydroxy-3-[(3-nitro-2-oxo-1,2-dihydropyridin-4-yl)sulfanyl]propan-2-yl}carbamate 1374041-21-0 C13H19N3O6S
    tert-butyl {(2R)-1-hydroxy-3-[(3-nitro-2-oxo-1,2-dihydropyridin-4-yl)sulfanyl]propan-2-yl}carbamate
    —— 3-Amino-5-methylmercapto-thiazolo-(4,5-c)-isothiazol 68696-67-3 C5H5N3S3
    3-Amino-5-methylmercapto-thiazolo-(4,5-c)-isothiazol
    —— 2-methylsulfanyl benzene-1,3-diamine 32114-66-2 C7H10N2S
    2-methylsulfanyl benzene-1,3-diamine
    —— 1-(2,3-dichloro-propane-1-sulfonyl)-butane 73142-47-9 C7H14Cl2O2S
    1-(2,3-dichloro-propane-1-sulfonyl)-butane
    —— α-Phenylthio-α-ethyl-hexanal 73188-46-2 C14H20OS
    α-Phenylthio-α-ethyl-hexanal
    —— 2-[(2,4-dichloro-5-methylphenyl)sulfanyl]-1,3-dinitrobenzene 1137560-38-3 C13H8Cl2N2O4S
    2-[(2,4-dichloro-5-methylphenyl)sulfanyl]-1,3-dinitrobenzene
    —— 2-amino-6-(phenylthio)benzonitrile 123241-49-6 C13H10N2S
    2-amino-6-(phenylthio)benzonitrile
    —— CNS 5161 160754-76-7 C16H18ClN3S2
    CNS 5161
    —— 2,3,5-trifluoro-6-(methylthio)pyridine 1257072-14-2 C6H4F3NS
    2,3,5-trifluoro-6-(methylthio)pyridine
    —— 2,2'-(pentane-1,5-disulfonyl)-bis-ethanol 57100-56-8 C9H20O6S2
    2,2'-(pentane-1,5-disulfonyl)-bis-ethanol
    —— bis-1,5-(20chloroethylthio)pentane 142868-94-8 C9H18Cl2S2
    bis-1,5-(20chloroethylthio)pentane
    —— 2-isopropyl-2-<1-hydroxy-3,3-(1,3-dioxocyclopentyl)butyl>-1,3-dithiane 137853-40-8 C13H24O3S2
    2-isopropyl-2-<1-hydroxy-3,3-(1,3-dioxocyclopentyl)butyl>-1,3-dithiane
    —— 3-Methylthio-6-(4-methylphenyl)-1,2,4,5-tetrazin 72116-53-1 C10H10N4S
    3-Methylthio-6-(4-methylphenyl)-1,2,4,5-tetrazin
    —— 2-(1-phenylthiooctyl)cyclohex-2-enone 157584-94-6 C20H28OS
    2-(1-phenylthiooctyl)cyclohex-2-enone
    —— 2-(1-hydroxyoctyl)-3-phenylsulfanylcyclohexanone 157584-93-5 C20H30O2S
    2-(1-hydroxyoctyl)-3-phenylsulfanylcyclohexanone
    —— cis-2,6-dihexylsulfonyl-1,4-dithiafulvene 74057-79-7 C16H28O4S4
    cis-2,6-dihexylsulfonyl-1,4-dithiafulvene
    —— 2-methylthio-5-methyl-6-[1-(4-dimethylaminophenyl)-1-hydroxymethyl]-4(3H)-pyrimidinone 948859-54-9 C15H19N3O2S
    2-methylthio-5-methyl-6-[1-(4-dimethylaminophenyl)-1-hydroxymethyl]-4(3H)-pyrimidinone
    —— 2-(benzylthio)-5-(2-fluorophenyl)-1,3,4-oxadiazole 459846-23-2 C15H11FN2OS
    2-(benzylthio)-5-(2-fluorophenyl)-1,3,4-oxadiazole
    —— 2-methylthio-5-methyl-6-formyl-4(3H)-pyrimidinone 948859-52-7 C7H8N2O2S
    2-methylthio-5-methyl-6-formyl-4(3H)-pyrimidinone
    —— 1-(dimethylsulfamoyl)-5-(2-ethyl-6-methylphenylthio)pyrazole 143535-28-8 C14H19N3O2S2
    1-(dimethylsulfamoyl)-5-(2-ethyl-6-methylphenylthio)pyrazole
    —— 1-[(E)-3-(2-Thienyl)prop-2-en-1-yl]-6-(phenylthio)thymine 157401-07-5 C18H16N2O2S2
    1-[(E)-3-(2-Thienyl)prop-2-en-1-yl]-6-(phenylthio)thymine
    —— (Z)-3-methylpent-2-en-4-ybyl thiocyanate 342883-59-4 C7H7NS
    (Z)-3-methylpent-2-en-4-ybyl thiocyanate
    —— 4-methyl-1-phenylsulfonylnaphthalene 430430-72-1 C17H14S
    4-methyl-1-phenylsulfonylnaphthalene
    —— 4-Acetyl-1-[3-[(2-aminothiazol-5-yl)thio]benzoyl]piperazine 439578-81-1 C16H18N4O2S2
    4-Acetyl-1-[3-[(2-aminothiazol-5-yl)thio]benzoyl]piperazine
    —— ethyl-1-deoxy-1-ethylsulfonato-3,4,5-tri-O-methyl-2-thio-α-L-fuco-hept-2-ulopyranoside 286860-85-3 C14H28O7S2
    ethyl-1-deoxy-1-ethylsulfonato-3,4,5-tri-O-methyl-2-thio-α-L-fuco-hept-2-ulopyranoside
    —— 2,2,2-Trifluoroethyl ethylsulfanylformate 71674-19-6 C5H7F3O2S
    2,2,2-Trifluoroethyl ethylsulfanylformate
    —— 9-<1-(methylthio)ethylidene>bicyclo<4.2.1>nonane 83463-49-4 C12H20S
    9-<1-(methylthio)ethylidene>bicyclo<4.2.1>nonane
    —— 2-amino-2-methyl-thiopropanamide 16256-14-7 C4H10N2S
    2-amino-2-methyl-thiopropanamide
    —— ethyl 4-[4-(3-[2,2,2-trifluoroethyl]thioureido)pyrimid-2-ylthio]butyrate 84545-81-3 C13H17F3N4O2S2
    ethyl 4-[4-(3-[2,2,2-trifluoroethyl]thioureido)pyrimid-2-ylthio]butyrate
    —— 9-<1-(methylthio)ethylidene>bicyclo<4.2.1>nona-2,4,7-triene 83463-34-7 C12H14S
    9-<1-(methylthio)ethylidene>bicyclo<4.2.1>nona-2,4,7-triene
    —— cis-2,6-dibutylsulfonyl-1,4-dithiafulvene 74057-77-5 C12H20O4S4
    cis-2,6-dibutylsulfonyl-1,4-dithiafulvene