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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Ethoxycarbonylmethylsulfanyl-1-methyl-pyridinium; chloride 62058-68-8 C10H14NO2S*Cl
    2-Ethoxycarbonylmethylsulfanyl-1-methyl-pyridinium; chloride
    —— 4,7-dioctyl-5,6-dicyano-2-(4',5'-bis(methylthio)-1',3'-dithiole-2'-ylidene)benzo[d]-1,3-dithiole 1345829-22-2 C30H40N2S6
    4,7-dioctyl-5,6-dicyano-2-(4',5'-bis(methylthio)-1',3'-dithiole-2'-ylidene)benzo[d]-1,3-dithiole
    —— 4-(4-bromophenyl)-4-(phenylsulfanyl)nona-1,8-dien-5-one 878480-48-9 C21H21BrOS
    4-(4-bromophenyl)-4-(phenylsulfanyl)nona-1,8-dien-5-one
    —— 1-(4-bromophenyl)-1-(phenylsulfanyl)hex-5-en-2-one 878480-41-2 C18H17BrOS
    1-(4-bromophenyl)-1-(phenylsulfanyl)hex-5-en-2-one
    —— 4-Amino-6-chloro-2-(1-(4-acetyl-pyridin-2-yl)ethyl)thio-pyrimidine 185219-26-5 C13H13ClN4OS
    4-Amino-6-chloro-2-(1-(4-acetyl-pyridin-2-yl)ethyl)thio-pyrimidine
    —— Dimethyl bis(ethylsulfanyl)propanedioate 61930-52-7 C9H16O4S2
    Dimethyl bis(ethylsulfanyl)propanedioate
    —— 2-propanethial S-oxide 4933-34-0 C3H6OS
    2-propanethial S-oxide
    —— Dimethyl 1,3-dithiepane-2,2-dicarboxylate 61930-53-8 C9H14O4S2
    Dimethyl 1,3-dithiepane-2,2-dicarboxylate
    —— 1,1',1''-[methylidynetris(thio)]tris[4-fluoro-benzene] 17241-09-7 C19H13F3S3
    1,1',1''-[methylidynetris(thio)]tris[4-fluoro-benzene]
    —— (5-Allylsulfanyl-[1,3,4]thiadiazol-2-yl)-carbamic acid allyl ester 141992-82-7 C9H11N3O2S2
    (5-Allylsulfanyl-[1,3,4]thiadiazol-2-yl)-carbamic acid allyl ester
    —— [5-(4-Morpholin-4-yl-but-2-ynylsulfanyl)-[1,3,4]thiadiazol-2-yl]-carbamic acid allyl ester 141992-77-0 C14H18N4O3S2
    [5-(4-Morpholin-4-yl-but-2-ynylsulfanyl)-[1,3,4]thiadiazol-2-yl]-carbamic acid allyl ester
    —— 2-(2-Methylsulfonylethyl)-cyclohexanon 55930-55-7 C9H16O3S
    2-(2-Methylsulfonylethyl)-cyclohexanon
    —— (2-methylsulfanyl-pyrimidin-4-ylsulfanyl)-acetic acid ethyl ester 64679-76-1 C9H12N2O2S2
    (2-methylsulfanyl-pyrimidin-4-ylsulfanyl)-acetic acid ethyl ester
    —— Methyl cyclohexyl(2-pyridinylsulfanyl)acetate 139620-34-1 C14H19NO2S
    Methyl cyclohexyl(2-pyridinylsulfanyl)acetate
    —— 3-Hydroxy-1-(phenylthio)-2-decanone 123541-70-8 C16H24O2S
    3-Hydroxy-1-(phenylthio)-2-decanone
    —— 2,2-dimethyl-1,3-oxathiolane 5809-68-7 C6H12OS
    2,2-dimethyl-1,3-oxathiolane
    —— 2,2,5,5-tetramethyl-4-oxo-3-hexanethione 68506-06-9 C10H18OS
    2,2,5,5-tetramethyl-4-oxo-3-hexanethione
    —— 2,3-di-tert-butylthiirene 1-oxide 317363-66-9 C10H18OS
    2,3-di-tert-butylthiirene 1-oxide
    —— (6,7-dimethyl-4<i>H</i>-pyrazino[2,3-<i>b</i>][1,4]thiazin-3-yl)-acetic acid ethyl ester 63766-86-9 C12H15N3O2S
    (6,7-dimethyl-4<i>H</i>-pyrazino[2,3-<i>b</i>][1,4]thiazin-3-yl)-acetic acid ethyl ester
    —— 4,6-dimethyl-5-(phenylthio)-2-(phenylthiomethyl)-2,3-dihydrobenzofuran 126708-21-2 C23H22OS2
    4,6-dimethyl-5-(phenylthio)-2-(phenylthiomethyl)-2,3-dihydrobenzofuran
    —— 2-allyl-3,5-dimethyl-4-(phenylthio)phenol 126708-22-3 C17H18OS
    2-allyl-3,5-dimethyl-4-(phenylthio)phenol
    —— 2,4,6-trimethylphenyl 2,4,6-trimethylphenylthio sulfine 40490-50-4 C19H22OS2
    2,4,6-trimethylphenyl 2,4,6-trimethylphenylthio sulfine
    —— 2,6-bis-[(2-methylthiophenyl)-2-azaethenyl]pyridine 90149-02-3 C21H19N3S2
    2,6-bis-[(2-methylthiophenyl)-2-azaethenyl]pyridine
    —— <i>N</i>-cyclohexyl-<i>N'</i>-(1,1,3,3-tetramethyl-butyl)-thiourea 101452-81-7 C15H30N2S
    <i>N</i>-cyclohexyl-<i>N'</i>-(1,1,3,3-tetramethyl-butyl)-thiourea
    —— diethyl 2,2'-[(3-nitropyridine-2,6-diyl)bissulfanediyl]diacetate 1378233-77-2 C13H16N2O6S2
    diethyl 2,2'-[(3-nitropyridine-2,6-diyl)bissulfanediyl]diacetate
    —— di-n-butyl 2,2'-[(3-nitropyridine-2,6-diyl)disulfanediyl]diacetate 1379575-26-4 C17H24N2O6S2
    di-n-butyl 2,2'-[(3-nitropyridine-2,6-diyl)disulfanediyl]diacetate
    —— dimethyl 2,2'-[(3-nitropyridine-2,6-diyl)disulfanediyl]diacetate 259792-96-6 C11H12N2O6S2
    dimethyl 2,2'-[(3-nitropyridine-2,6-diyl)disulfanediyl]diacetate
    —— di-n-propyl 2,2'-[(3-nitropyridine-2,6-diyl)disulfanediyl]diacetate 1378234-61-7 C15H20N2O6S2
    di-n-propyl 2,2'-[(3-nitropyridine-2,6-diyl)disulfanediyl]diacetate
    —— 2-[6-(Carboxymethylsulfanyl)-5-nitropyridin-2-yl]sulfanylacetic acid 1378233-36-3 C9H8N2O6S2
    2-[6-(Carboxymethylsulfanyl)-5-nitropyridin-2-yl]sulfanylacetic acid
    —— <i>N</i>-methyl-<i>N</i>'-(1,1,3,3-tetramethyl-butyl)-thiourea 86375-16-8 C10H22N2S
    <i>N</i>-methyl-<i>N</i>'-(1,1,3,3-tetramethyl-butyl)-thiourea
    —— non-6-en-2-one-thioketal 146405-08-5 C11H20S2
    non-6-en-2-one-thioketal
    —— 3,6-dioctyl-4,5-(o-xylylenedithio)phthalonitrile 885694-89-3 C32H42N2S2
    3,6-dioctyl-4,5-(o-xylylenedithio)phthalonitrile
    —— 3,6-dibutyl-4,5-(o-xylylenedithio)phthalonitrile 885694-88-2 C24H26N2S2
    3,6-dibutyl-4,5-(o-xylylenedithio)phthalonitrile
    —— 3-(Methylsulfanyl)-5,6-bis(trifluoromethyl)-1,2,4-triazine 120943-60-4 C6H3F6N3S
    3-(Methylsulfanyl)-5,6-bis(trifluoromethyl)-1,2,4-triazine
    —— 1-[4-[Methyl(diphenyl)silyl]-4-oxobutyl]-6-phenylsulfanylpiperidin-2-one 185098-95-7 C28H31NO2SSi
    1-[4-[Methyl(diphenyl)silyl]-4-oxobutyl]-6-phenylsulfanylpiperidin-2-one
    —— 1,3-dithiolo<4,5-f><1,3,5>trithiepin-2-thione 102567-30-6 C5H4S6
    1,3-dithiolo<4,5-f><1,3,5>trithiepin-2-thione
    —— bis<thiobis(methylenethio)>tetrathiafulvalene 88682-20-6 C10H8S10
    bis<thiobis(methylenethio)>tetrathiafulvalene
    —— Acetoxyethylenedithio-1,3-dithiole-2-thione 110789-37-2 C7H6O2S5
    Acetoxyethylenedithio-1,3-dithiole-2-thione
    —— (phenyl-[1,3,4]thiadiazol-2-ylmercapto)-acetic acid ethyl ester 64145-10-4 C12H12N2O2S2
    (phenyl-[1,3,4]thiadiazol-2-ylmercapto)-acetic acid ethyl ester
    —— 3-(4-phenylethynyl-phenylsulfanyl)propionic acid 2-ethylhexyl ester 881664-11-5 C25H30O2S
    3-(4-phenylethynyl-phenylsulfanyl)propionic acid 2-ethylhexyl ester
    —— 3-(4-bromophenylsulfanyl)propionic acid 2-ethylhexyl ester 881664-08-0 C17H25BrO2S
    3-(4-bromophenylsulfanyl)propionic acid 2-ethylhexyl ester
    —— Methyl 3-[methoxy(phenylsulfanyl)methyl]tetradec-2-enoate 89171-42-6 C23H36O3S
    Methyl 3-[methoxy(phenylsulfanyl)methyl]tetradec-2-enoate
    —— 1-Methoxy-1-(phenylsulfanyl)tridecan-2-one 89171-36-8 C20H32O2S
    1-Methoxy-1-(phenylsulfanyl)tridecan-2-one
    —— 3-[Methoxy(phenylsulfanyl)methyl]tetradec-2-en-1-ol 89171-52-8 C22H36O2S
    3-[Methoxy(phenylsulfanyl)methyl]tetradec-2-en-1-ol
    —— (E)-3-(5-Methylsulfanyl-furan-2-yl)-acrylic acid 111252-38-1 C8H8O3S
    (E)-3-(5-Methylsulfanyl-furan-2-yl)-acrylic acid
    —— 1-benzyl-3-phenylsulfanyl-pyrrolidin-2-one 64330-40-1 C17H17NOS
    1-benzyl-3-phenylsulfanyl-pyrrolidin-2-one
    —— E-3,6-Dimethyl-2-(phenylthio)-hept-3-en 63996-71-4 C15H22S
    E-3,6-Dimethyl-2-(phenylthio)-hept-3-en
    —— (2R,3S,5S)-3-[tert-butyl(diphenyl)silyl]oxy-5-methyl-6-(2-methyl-1,3-dithian-2-yl)hexane-1,2-diol 218439-23-7 C28H42O3S2Si
    (2R,3S,5S)-3-[tert-butyl(diphenyl)silyl]oxy-5-methyl-6-(2-methyl-1,3-dithian-2-yl)hexane-1,2-diol
    —— (3E,5E)-2,5-dimethyl-3-(ethoxycarbonyl)-6-thiophenyl-3,5-hexadienoic acid 382150-24-5 C17H20O4S
    (3E,5E)-2,5-dimethyl-3-(ethoxycarbonyl)-6-thiophenyl-3,5-hexadienoic acid
    —— (3E,5E)-3-(ethoxycarbonyl)-5-methyl-6-thiophenyl-3,5-hexadienoic acid 382150-21-2 C16H18O4S
    (3E,5E)-3-(ethoxycarbonyl)-5-methyl-6-thiophenyl-3,5-hexadienoic acid