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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-(p-Bromophenylthio)-4-isopropyloxy-2-butanon 56163-60-1 C13H17BrO2S
    1-(p-Bromophenylthio)-4-isopropyloxy-2-butanon
    —— 8-chloro-5,5-dioxoimidazo[1,2-b][1,4,2]benzodithiazine-7-carboxylic acid 256513-52-7 C10H5ClN2O4S2
    8-chloro-5,5-dioxoimidazo[1,2-b][1,4,2]benzodithiazine-7-carboxylic acid
    —— 8-bromo-2,3-dihydro-3-oxo-5H-pyrido<3,4-b><1,4>benzothiazine-4-carbonitrile 76700-59-9 C12H6BrN3OS
    8-bromo-2,3-dihydro-3-oxo-5H-pyrido<3,4-b><1,4>benzothiazine-4-carbonitrile
    —— 2-Ethylthio-3-nitro-4-methylpyridin 66665-88-1 C8H10N2O2S
    2-Ethylthio-3-nitro-4-methylpyridin
    —— 2,3-dihydro-2-methyl-3-oxo-5H-pyrido<3,4-b><1,4>benzothiazine-4-carbonitrile 76700-45-3 C13H9N3OS
    2,3-dihydro-2-methyl-3-oxo-5H-pyrido<3,4-b><1,4>benzothiazine-4-carbonitrile
    —— 2,3-dihydro-8-nitro-3-oxo-5H-pyrido<3,4-b><1,4>benzothiazine-4-carbonitrile 76700-61-3 C12H6N4O3S
    2,3-dihydro-8-nitro-3-oxo-5H-pyrido<3,4-b><1,4>benzothiazine-4-carbonitrile
    —— 6-amino-2,3-dihydro-3-oxo-5H-pyrido<3,4-b><1,4>benzothiazine-4-carbonitrile 76700-64-6 C12H8N4OS
    6-amino-2,3-dihydro-3-oxo-5H-pyrido<3,4-b><1,4>benzothiazine-4-carbonitrile
    —— 3-methyl-2-(methylthio)-5-nitropyridine 66665-85-8 C7H8N2O2S
    3-methyl-2-(methylthio)-5-nitropyridine
    —— 4-propylthio-3-methylpyridine-2-thione 1248345-76-7 C9H13NS2
    4-propylthio-3-methylpyridine-2-thione
    —— N-cyclohexyl-2-methyl-2-phenylsulfanylpropan-1-imine 62134-85-4 C16H23NS
    N-cyclohexyl-2-methyl-2-phenylsulfanylpropan-1-imine
    —— 1-(4,6-dichloro-2-methylsulfanylpyrimidin-5-yl)ethanone 1447839-64-6 C7H6Cl2N2OS
    1-(4,6-dichloro-2-methylsulfanylpyrimidin-5-yl)ethanone
    —— 3,3-diamino-2-(5-cyano-2-methylsulfanylpyrimidin-4-yl)acrylic acid ethyl ester 1391611-41-8 C11H13N5O2S
    3,3-diamino-2-(5-cyano-2-methylsulfanylpyrimidin-4-yl)acrylic acid ethyl ester
    —— 1-(4-chloro-2-(methylthio)pyrimidin-5-yl)ethanone 66116-82-3 C7H7ClN2OS
    1-(4-chloro-2-(methylthio)pyrimidin-5-yl)ethanone
    —— 2-(3-Bromo-phenylsulfanyl)-6-fluoro-benzonitrile 171551-15-8 C13H7BrFNS
    2-(3-Bromo-phenylsulfanyl)-6-fluoro-benzonitrile
    —— 4-[(8-methoxy-octyl)thio]-3-methylpyridine-2-thione 1248345-68-7 C15H25NOS2
    4-[(8-methoxy-octyl)thio]-3-methylpyridine-2-thione
    —— 4-methylthio-3-methylpyridine-2-thione 1248345-73-4 C7H9NS2
    4-methylthio-3-methylpyridine-2-thione
    —— 4-[2-(2-(2,2,2-trifluoroethoxy)-ethoxy)ethyl]thio-3-methylpyridine-2-thione 1248345-81-4 C12H16F3NO2S2
    4-[2-(2-(2,2,2-trifluoroethoxy)-ethoxy)ethyl]thio-3-methylpyridine-2-thione
    —— 4-[(4-methoxy-butyl)thio]-3-methylpyridine-2-thione 1248345-62-1 C11H17NOS2
    4-[(4-methoxy-butyl)thio]-3-methylpyridine-2-thione
    —— 2-(2-Bromo-phenylsulfanyl)-6-fluoro-benzonitrile 348168-83-2 C13H7BrFNS
    2-(2-Bromo-phenylsulfanyl)-6-fluoro-benzonitrile
    —— 4-Methoxy-1-(o-tolylthio)-2-butanon 56163-58-7 C12H16O2S
    4-Methoxy-1-(o-tolylthio)-2-butanon
    —— N,N-dibenzyl-O-[(2S)-1-(phenylthio)propan-2-yl]hydroxylamine 1126795-29-6 C23H25NOS
    N,N-dibenzyl-O-[(2S)-1-(phenylthio)propan-2-yl]hydroxylamine
    —— 2-Fluoro-6-(2-methylphenyl)sulfanylbenzonitrile 348168-79-6 C14H10FNS
    2-Fluoro-6-(2-methylphenyl)sulfanylbenzonitrile
    —— 2-Fluoro-6-(3-trifluoromethyl-phenylsulfanyl)-benzonitrile 348168-89-8 C14H7F4NS
    2-Fluoro-6-(3-trifluoromethyl-phenylsulfanyl)-benzonitrile
    —— 3-Chlormethyl-3-methyl-2,3-dihydro-1,4-benzoxathiin 65331-08-0 C10H11ClOS
    3-Chlormethyl-3-methyl-2,3-dihydro-1,4-benzoxathiin
    —— 2-(4-Cyano-phenylsulfanyl)-6-fluoro-benzonitrile 348168-88-7 C14H7FN2S
    2-(4-Cyano-phenylsulfanyl)-6-fluoro-benzonitrile
    —— 6-(4-chlorophenyl)-9-(tetrahydro-2H-pyran-2-yl)pyridazino[4,5-b]pyrido[3,2-f][1,4]thiazepine-5,10(6H,9H)-dione 1441045-62-0 C21H17ClN4O3S
    6-(4-chlorophenyl)-9-(tetrahydro-2H-pyran-2-yl)pyridazino[4,5-b]pyrido[3,2-f][1,4]thiazepine-5,10(6H,9H)-dione
    —— 2-Fluoro-6-(4-methoxy-phenylsulfanyl)-benzonitrile 348168-78-5 C14H10FNOS
    2-Fluoro-6-(4-methoxy-phenylsulfanyl)-benzonitrile
    —— 2-Phenyl-6H-thiopyrano[2,3-b]furan-5-carboxylic acid 66860-02-4 C14H10O3S
    2-Phenyl-6H-thiopyrano[2,3-b]furan-5-carboxylic acid
    —— 2-(2-Chlorophenyl)sulfanyl-6-fluorobenzonitrile 348168-81-0 C13H7ClFNS
    2-(2-Chlorophenyl)sulfanyl-6-fluorobenzonitrile
    —— 2-(2-Cyanophenylthio)-6-fluorobenzonitrile 348168-86-5 C14H7FN2S
    2-(2-Cyanophenylthio)-6-fluorobenzonitrile
    —— 2-Fluoro-6-(3-fluoro-phenylsulfanyl)-benzonitrile 348168-85-4 C13H7F2NS
    2-Fluoro-6-(3-fluoro-phenylsulfanyl)-benzonitrile
    —— 2-Fluoro-6-(3-methoxy-5-trifluoromethyl-phenylsulfanyl)-benzonitrile 348168-93-4 C15H9F4NOS
    2-Fluoro-6-(3-methoxy-5-trifluoromethyl-phenylsulfanyl)-benzonitrile
    —— 2-Fluoro-6-(2-fluorophenyl)sulfanylbenzonitrile 348168-84-3 C13H7F2NS
    2-Fluoro-6-(2-fluorophenyl)sulfanylbenzonitrile
    —— 2-(3-Cyano-phenylsulfanyl)-6-fluoro-benzonitrile 348168-87-6 C14H7FN2S
    2-(3-Cyano-phenylsulfanyl)-6-fluoro-benzonitrile
    —— 2-[(3,5-Dimethylphenyl)thio]-6-fluorobenzonitrile 171102-65-1 C15H12FNS
    2-[(3,5-Dimethylphenyl)thio]-6-fluorobenzonitrile
    —— 2-Fluoro-6-(naphthalen-2-ylsulfanyl)-benzonitrile 348168-95-6 C17H10FNS
    2-Fluoro-6-(naphthalen-2-ylsulfanyl)-benzonitrile
    —— 2-fluoro-6-[(3-methoxyphenyl)thio]benzonitrile 171102-62-8 C14H10FNOS
    2-fluoro-6-[(3-methoxyphenyl)thio]benzonitrile
    —— 2-Fluoro-6-phenylsulfanyl-benzonitrile 348168-76-3 C13H8FNS
    2-Fluoro-6-phenylsulfanyl-benzonitrile
    —— 2-(3,5-Dichlorophenyl)sulfanyl-6-fluorobenzonitrile 348168-91-2 C13H6Cl2FNS
    2-(3,5-Dichlorophenyl)sulfanyl-6-fluorobenzonitrile
    —— 2-fluoro-6-[(3-methyl-5-methoxyphenyl)thio]benzonitrile 171102-68-4 C15H12FNOS
    2-fluoro-6-[(3-methyl-5-methoxyphenyl)thio]benzonitrile
    —— 2-(3-bromo-5-methylphenylthio)-6-fluorobenzonitrile 171551-22-7 C14H9BrFNS
    2-(3-bromo-5-methylphenylthio)-6-fluorobenzonitrile
    —— 1,3-bis-vinylmercapto-benzene 16079-06-4 C10H10S2
    1,3-bis-vinylmercapto-benzene
    —— Ethanesulfonothioic acid, S-(2-hydroxyethyl) ester 13700-09-9 C4H10O3S2
    Ethanesulfonothioic acid, S-(2-hydroxyethyl) ester
    —— ethyl phenylsufenylmethanephosphonic chloridate 114077-36-0 C9H12ClO2PS
    ethyl phenylsufenylmethanephosphonic chloridate
    —— 6-cyclohexyl-9-(tetrahydro-2H-pyran-2-yl)pyridazino[4,5-b]pyrido[3,2-f][1,4]thiazepine-5,10(6H,9H)-dione 1441023-34-2 C21H24N4O3S
    6-cyclohexyl-9-(tetrahydro-2H-pyran-2-yl)pyridazino[4,5-b]pyrido[3,2-f][1,4]thiazepine-5,10(6H,9H)-dione
    —— 6-(3,5-dimethylphenyl)-9-(tetrahydro-2H-pyran-2-yl)pyridazino[4,5-b]pyrido[3,2-f][1,4]thiazepine-5,10(6H,9H)-dione 1441045-76-6 C23H22N4O3S
    6-(3,5-dimethylphenyl)-9-(tetrahydro-2H-pyran-2-yl)pyridazino[4,5-b]pyrido[3,2-f][1,4]thiazepine-5,10(6H,9H)-dione
    —— 1-(phenylthio)-4-methoxybutan-2-one 35737-56-5 C11H14O2S
    1-(phenylthio)-4-methoxybutan-2-one
    —— 2,5-Dimethyl-3,4-bis(1,3-benzodithiol-2-yl)pyrrol 67370-48-3 C20H17NS4
    2,5-Dimethyl-3,4-bis(1,3-benzodithiol-2-yl)pyrrol
    —— 2,6-bis<(p-methoxyphenyl)thio>benzonitrile 111324-51-7 C21H17NO2S2
    2,6-bis<(p-methoxyphenyl)thio>benzonitrile
    —— tert-Butyl-glyoxylsaeurethioamid 4602-28-2 C6H11NOS
    tert-Butyl-glyoxylsaeurethioamid