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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— α-(phenylthio)maleic anhydride 84649-32-1 C10H6O3S
    α-(phenylthio)maleic anhydride
    —— <i>N</i>-(5-methylsulfanyl-[1,2,4]dithiazol-3-ylidene)-acetamide 40229-43-4 C5H6N2OS3
    <i>N</i>-(5-methylsulfanyl-[1,2,4]dithiazol-3-ylidene)-acetamide
    —— anti-S-Ethyl-O-<N-methylcarbamoyl>-thiopropion-hydroximat 19145-21-2 C7H14N2O2S
    anti-S-Ethyl-O-<N-methylcarbamoyl>-thiopropion-hydroximat
    —— (E)-2-[(amino)-phenylmethylene]-benzo[b]thiophen-3(2H)-one 77946-49-7 C15H11NOS
    (E)-2-[(amino)-phenylmethylene]-benzo[b]thiophen-3(2H)-one
    —— anti(alkylthio)-S-Methyl-thiopropion-hydroximat 19145-18-7 C4H9NOS
    anti(alkylthio)-S-Methyl-thiopropion-hydroximat
    —— anti-S-Methyl-O-<N-methyl-carbamoyl>-thiopropion-hydroximat 19145-19-8 C6H12N2O2S
    anti-S-Methyl-O-<N-methyl-carbamoyl>-thiopropion-hydroximat
    —— 5-<p-(phenylthio)phenyl>-1-ethyl-5-methyldihydro-<1H,7H>-5H-pyrano<3,2-d>oxazole-2,6-dione 145371-52-4 C21H21NO4S
    5-<p-(phenylthio)phenyl>-1-ethyl-5-methyldihydro-<1H,7H>-5H-pyrano<3,2-d>oxazole-2,6-dione
    —— isooctylmercaptan 110502-71-1 C8H18S
    isooctylmercaptan
    —— 2-(6,7-Dimethoxyquinolin-4-ylsulfanyl)thiazol-5-ylamine 417722-27-1 C14H13N3O2S2
    2-(6,7-Dimethoxyquinolin-4-ylsulfanyl)thiazol-5-ylamine
    —— 2-<p-(phenylthio)phenyl>-2-methyl-6-<<(ethylamino)carbonyl>oxy>-3-oxo-3,6-dihydro-2H-pyran 145371-48-8 C21H21NO4S
    2-<p-(phenylthio)phenyl>-2-methyl-6-<<(ethylamino)carbonyl>oxy>-3-oxo-3,6-dihydro-2H-pyran
    —— 5-ethyl-1-methyl-5-<4-(phenylthio)phenyl>-6-hydroxyperhydropyrano<3,2-d>oxazole-2-one 145371-64-8 C21H23NO4S
    5-ethyl-1-methyl-5-<4-(phenylthio)phenyl>-6-hydroxyperhydropyrano<3,2-d>oxazole-2-one
    —— lead(II) thiocyanate —— C2N2PbS2
    lead(II) thiocyanate
    —— 1-phenyl-4-phenylthio-3-dodecene 93242-58-1 C24H32S
    1-phenyl-4-phenylthio-3-dodecene
    —— 1-{5-[6-Cyano-7-(2-methoxyethoxy)quinolin-4-ylsulfanyl]-thiophen-2-yl}-3-(3-cyanophenyl)-urea 417715-70-9 C25H19N5O3S2
    1-{5-[6-Cyano-7-(2-methoxyethoxy)quinolin-4-ylsulfanyl]-thiophen-2-yl}-3-(3-cyanophenyl)-urea
    —— N-(3-Cyanophenyl)-N'-(5-(6,7-dimethoxyquinolin-4-ylsulfanyl)thiophen-2-yl)urea 417715-25-4 C23H18N4O3S2
    N-(3-Cyanophenyl)-N'-(5-(6,7-dimethoxyquinolin-4-ylsulfanyl)thiophen-2-yl)urea
    —— 5-(6,7-Dimethoxyquinolin-4-ylsulfanyl)thiophen-2-ylamine 417722-24-8 C15H14N2O2S2
    5-(6,7-Dimethoxyquinolin-4-ylsulfanyl)thiophen-2-ylamine
    —— N-(3-Cyanophenyl)-N'-(2-(6,7-dimethoxyquinolin-4-ylsulfanyl)thiazol-5-yl)urea 417715-35-6 C22H17N5O3S2
    N-(3-Cyanophenyl)-N'-(2-(6,7-dimethoxyquinolin-4-ylsulfanyl)thiazol-5-yl)urea
    —— 4-(5-aminothiophen-2-ylsulfanyl)-7-(2-methoxyethoxy)-quinoline-6-carbonitrile 417722-45-3 C17H15N3O2S2
    4-(5-aminothiophen-2-ylsulfanyl)-7-(2-methoxyethoxy)-quinoline-6-carbonitrile
    —— 2-<p-(phenylthio)phenyl>-2-methyl-6-<<(methylamino)carbonyl>oxy>-2H-pyran-3(6H)-one —— C20H19NO4S
    2-<p-(phenylthio)phenyl>-2-methyl-6-<<(methylamino)carbonyl>oxy>-2H-pyran-3(6H)-one
    —— cis-6-Methoxy-2-<p-(phenylthio)phenyl>-2-methyl-2H-pyran-3(6H)-one 102285-72-3 C19H18O3S
    cis-6-Methoxy-2-<p-(phenylthio)phenyl>-2-methyl-2H-pyran-3(6H)-one
    —— 1,5-dimethyl-5<4-(phenylthio)phenyl>-6-hydroxyperhydropyrano<3,2-d>oxazole-2-one 133150-05-7 C20H21NO4S
    1,5-dimethyl-5<4-(phenylthio)phenyl>-6-hydroxyperhydropyrano<3,2-d>oxazole-2-one
    —— 1,5-dimethyl-5-<4-(phenylthio)phenyl>-dihydro<1H,7H>-5H-pyrano<3,2-d>oxazole-2,6-dione 133150-03-5 C20H19NO4S
    1,5-dimethyl-5-<4-(phenylthio)phenyl>-dihydro<1H,7H>-5H-pyrano<3,2-d>oxazole-2,6-dione
    —— 6-hydroxy-2-<p-(phenylthio)phenyl>-2-methyl-2H-pyran-3(6H)-one 102285-67-6 C18H16O3S
    6-hydroxy-2-<p-(phenylthio)phenyl>-2-methyl-2H-pyran-3(6H)-one
    —— 5-<(4-Nitro-2-aminophenyl)-thio>-4-chlor-3(2H)-pyridazinon 62688-70-4 C10H7ClN4O3S
    5-<(4-Nitro-2-aminophenyl)-thio>-4-chlor-3(2H)-pyridazinon
    —— 11-(ω-mercapto)-undecanylamine 155638-19-0 C11H25NS
    11-(ω-mercapto)-undecanylamine
    —— (S)-5-methyl-3-(phenylthio)-3-(10-undecenyl)dihydrofuran-2(3H)-one 862603-45-0 C22H32O2S
    (S)-5-methyl-3-(phenylthio)-3-(10-undecenyl)dihydrofuran-2(3H)-one
    —— 3-ethyl-5a,6,7,8,9,9a-hexahydro-5<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 66933-22-0 C10H16N4S
    3-ethyl-5a,6,7,8,9,9a-hexahydro-5<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— 1-[(E)-2-methoxy-vinyl]-pentylsulfanyl-benzene 63109-51-3 C14H20OS
    1-[(E)-2-methoxy-vinyl]-pentylsulfanyl-benzene
    —— {[(ethylsulfanyl)carbonyl]oxy}methyl acetate 133217-53-5 C6H10O4S
    {[(ethylsulfanyl)carbonyl]oxy}methyl acetate
    —— Phenyl(5-ethylthio-1,2,3-thiadiazolyl)carbinol 64837-40-7 C11H12N2OS2
    Phenyl(5-ethylthio-1,2,3-thiadiazolyl)carbinol
    —— 4-Aza-phenothiazin-10-carbonsaeure-N-methyl-piperidyl-(3)-ester 98471-15-9 C18H19N3O2S
    4-Aza-phenothiazin-10-carbonsaeure-N-methyl-piperidyl-(3)-ester
    —— 4-chloro-2-<3-hydroxy-2-(phenylthio)propyl>phenol 126708-16-5 C15H15ClO2S
    4-chloro-2-<3-hydroxy-2-(phenylthio)propyl>phenol
    —— N,N-Dimethyl(methylsulfanyl)methaniminium 59259-49-3 C4H10NS+
    N,N-Dimethyl(methylsulfanyl)methaniminium
    —— 4-chloro-2-<2-hydroxy-3-(phenylthio)propyl>phenol 126708-06-3 C15H15ClO2S
    4-chloro-2-<2-hydroxy-3-(phenylthio)propyl>phenol
    —— trihydryl-1,1,2 phenylthio-1 F-octanol-2 89807-96-5 C14H9F13OS
    trihydryl-1,1,2 phenylthio-1 F-octanol-2
    —— 1-Phenyl-2-phenylthio-non-2-en 61173-93-1 C21H26S
    1-Phenyl-2-phenylthio-non-2-en
    —— (1R,2R)-2-(4-tolylthio)-1-cyclohexanol 102834-18-4 C13H18OS
    (1R,2R)-2-(4-tolylthio)-1-cyclohexanol
    —— bis(3-nitropyridin-2-yl)sulfane 52597-34-9 C10H6N4O4S
    bis(3-nitropyridin-2-yl)sulfane
    —— 1,2-dichloro-1-phenylthiophenyl phosphine oxide 113107-95-2 C20H17Cl2OPS
    1,2-dichloro-1-phenylthiophenyl phosphine oxide
    —— 1-phenylthiopropyldiphenylphosphine oxide 61173-97-5 C21H21OPS
    1-phenylthiopropyldiphenylphosphine oxide
    —— (5-ethylsulfanyl-[1,3,4]thiadiazol-2-yl)-phenyl-methanol 64837-42-9 C11H12N2OS2
    (5-ethylsulfanyl-[1,3,4]thiadiazol-2-yl)-phenyl-methanol
    —— 7-furan-2-yl-2-oxo-3,5,6,7-tetrahydro-2<i>H</i>-thiopyrano[2,3-<i>d</i>]thiazole-6-carboxylic acid ethyl ester 63670-90-6 C13H13NO4S2
    7-furan-2-yl-2-oxo-3,5,6,7-tetrahydro-2<i>H</i>-thiopyrano[2,3-<i>d</i>]thiazole-6-carboxylic acid ethyl ester
    —— [(7-bromo-1-phenylheptyl)thio]benzene 167159-84-4 C19H23BrS
    [(7-bromo-1-phenylheptyl)thio]benzene
    —— 5-(2-diethylamino-ethyl)-2-ethylsulfanyl-thiophene-3-carbaldehyde 63785-97-7 C13H21NOS2
    5-(2-diethylamino-ethyl)-2-ethylsulfanyl-thiophene-3-carbaldehyde
    —— 4-methoxy-5-amino-6-methylthiopyrimidine 57705-51-8 C6H9N3OS
    4-methoxy-5-amino-6-methylthiopyrimidine
    —— 1-[7-Bromo-1-(4-fluorophenyl)heptyl]sulfanyl-4-methylbenzene 234080-54-7 C20H24BrFS
    1-[7-Bromo-1-(4-fluorophenyl)heptyl]sulfanyl-4-methylbenzene
    —— 1lambda~6~-Thiecane-1,1-dione 62738-03-8 C9H18O2S
    1lambda~6~-Thiecane-1,1-dione
    —— (2-bromophenyl)(5-methyl-2-nitrophenyl)sulfane 1332939-38-4 C13H10BrNO2S
    (2-bromophenyl)(5-methyl-2-nitrophenyl)sulfane
    —— 2-pentafluorosulfanylpentanal 1122591-47-2 C5H9F5OS
    2-pentafluorosulfanylpentanal
    —— (Z)-butanethial S-oxide 32157-32-7 C4H8OS
    (Z)-butanethial S-oxide