双(4-甲基丙烯酰基硫代苯基)硫醚 | 129283-82-5

• 物质功能分类: 化学试剂 - 有机试剂 - 酯类
• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 中文名称: 双(4-甲基丙烯酰基硫代苯基)硫醚
• 中文别名: 4,4'-二巯基二苯硫醚双甲基丙烯酸甲酯
• 英文名称: bis(4-methacryloylthiophenyl)sulfide
• 英文别名: Bis(4-methacryloylthiophenyl) Sulfide；S-[4-[4-(2-methylprop-2-enoylsulfanyl)phenyl]sulfanylphenyl] 2-methylprop-2-enethioate
• CAS: 129283-82-5
• 化学式: C₂₀H₁₈O₂S₃
• 分子量: 386.56
• InChiKey: SPNAQSNLZHHUIJ-UHFFFAOYSA-N

物化性质

• 熔点：
  64 °C
• 沸点：
  527.8±50.0 °C(Predicted)
• 密度：
  1.26±0.1 g/cm3(Predicted)
• 溶解度：
  溶于甲苯

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  25
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  110
• 氢给体数：
  0
• 氢受体数：
  5

安全信息

• 海关编码：
  2934999090

反应信息

• 作为产物：
  描述：

  4'4-二巯基二苯硫醚 、 甲基丙烯酰氯 、 四乙基溴化铵 生成 双(4-甲基丙烯酰基硫代苯基)硫醚
  参考文献：
  名称：

  ARAKAVA, TSUTOMU;MIXOSEHN, NAOKI;MARUYAMA, SATOSI;JOSIDA, XARUO

  摘要：

  DOI：

文献信息

• [EN] HIGH REFRACTIVE INDEX POLYMERIZABLE MONOMERS AND APPLICATIONS THEREOF<br/>[FR] MONOMÈRES POLYMÉRISABLES À INDICE DE RÉFRACTION ÉLEVÉ ET LEURS APPLICATIONS
  申请人：CORNING INC

  公开号：WO2018075848A1

  公开（公告）日：2018-04-26

  Provided herein are sulfated compounds that are useful as high refractive index monomers for optical and other applications and methods for producing the same. The sulfated compounds are liquid at room temperature and exhibit good miscibility with other monomers. They are branched and can act as crosslinking agents, increasing the rigidity of the resulting polymers. They have low molecular weights and are useful in combinations with higher viscosity oligomers or crystalline monomers and to generate curable compositions. Also provided herein are high refractive index curable compositions produced from the sulfated compounds suitable for the production optical articles, including for coatings, gratings, and other surface features. Further provided are high refractive index nanocomposite materials made from the sulfated compounds and curable compositions. Also provided herein are articles and optical devices incorporating the curable compositions and nanocomposites described herein.

  本文提供的是硫酸化合物，可用作光学和其他应用中的高折射率单体，并提供制备这些化合物的方法。这些硫酸化合物在室温下为液体，与其他单体具有良好的混溶性。它们是分支的，并可作为交联剂，增加所得聚合物的刚度。它们具有较低的分子量，可与较高粘度的寡聚物或结晶单体组合使用，生成可固化的混合物。本文还提供了由这些硫酸化合物制备的适用于生产光学制品的高折射率可固化组合物，包括用于涂层、光栅和其他表面特征。此外，还提供了由这些硫酸化合物和可固化组合物制成的高折射率纳米复合材料。本文还提供了包含所述可固化组合物和纳米复合材料的制品和光学器件。
• Optical product having a high refractive index microreplication resin
  申请人：3M Innovative Properties Company

  公开号：US20030100693A1

  公开（公告）日：2003-05-29

  A polymerizable composition that includes a monomer of the formula 1 wherein X is hydrogen or one or more of methyl, chlorine, bromine or iodine, R 1 is a straight or branched alkyl linking group of 2 to 12 carbon atoms, R 2 is hydrogen or methyl, and n is 1 to 3; and a monomer of the formula 2 wherein X 1 and X 2 are each independently hydrogen or one or more of methyl, chlorine, bromine or iodine, and R 2 is hydrogen or methyl is described having a high index of refraction and being suitable for use in forming an optical product.

  一种可聚合的组合物，包括下式1的单体，其中X是氢或一个或多个甲基、氯、溴或碘，R1是2到12个碳原子的直链或支链烷基连接基，R2是氢或甲基，n为1到3；以及下式2的单体，其中X1和X2各自独立地是氢或一个或多个甲基、氯、溴或碘，R2是氢或甲基，具有高折射率并适用于形成光学产品。
• High refractive index microreplication resin
  申请人：3M Innovative Properties Company

  公开号：US20020123589A1

  公开（公告）日：2002-09-05

  A polymerizable composition that includes a monomer of the formula 1 wherein X is hydrogen or one or more of methyl, chlorine, bromine or iodine, R 1 is a straight or branched alkyl linking group of 2 to 12 carbon atoms, R 2 is hydrogen or methyl, and n is 1 to 3; and a monomer of the formula 2 wherein X 1 and X 2 are each independently hydrogen or one or more of methyl, chlorine, bromine or iodine, and R 2 is hydrogen or methyl is described having a high index of refraction and being suitable for use in forming an optical product.

  一种可聚合的组合物，包括式1的单体，其中X是氢或一个或多个甲基、氯、溴或碘，R1是2到12个碳原子的直链或支链烷基连接基，R2是氢或甲基，n为1到3；以及式2的单体，其中X1和X2各自独立地是氢或一个或多个甲基、氯、溴或碘，R2是氢或甲基，具有高折射率，适用于制造光学产品。
• Antireflection film, production process of the same, polarizing plate and image displaying apparatus
  申请人：Ikeda Akira

  公开号：US20050208230A1

  公开（公告）日：2005-09-22

  An antireflection film comprising: a transparent support; and a low refractive index layer as an outermost layer, wherein the low refractive index layer comprises a crosslinkable compound capable of forming a cured film having a universal hardness of 75 N/mm 2 or more. A polarizing plate has the antireflection film as a surface protective film. An image displaying apparatus has the antireflection film or the polarizing plate.

  一种防反射膜，包括：透明支撑；以及作为最外层的低折射率层，其中低折射率层包括一种能够形成硬度为75 N/mm2或更高的固化膜的交联化合物。极化板具有防反射膜作为表面保护膜。图像显示装置具有防反射膜或极化板。
• Antireflection film, polarized plate and image display device
  申请人：Matsunaga Naohiro

  公开号：US20060057307A1

  公开（公告）日：2006-03-16

  The present invention can provide an antireflection film improved in the scratch resistance while having a sufficiently high antireflection property, and a polarizing plate and a display device using the antireflection film, the antireflection film antireflection film comprising: a transparent support; and as an outermost layer, a low refractive index layer containing a fluorine-containing polymer, wherein the low refractive index layer comprises at least one inorganic fine particle having an average particle size of 30 to 100% of the thickness of the low refractive index layer; the polarizing plate using the antireflection film for one of two protective films of a polarizer in the polarizing plate; and the image display device using the antireflection film or polarizing plate for the outermost surface of the display.

  本发明提供了一种抗反射膜，该抗反射膜在具有足够高的抗反射性能的同时，提高了抗划伤性能。还提供了使用该抗反射膜的偏振板和显示设备。该抗反射膜包括：透明支撑体；以及作为最外层的低折射率层，该低折射率层包含含有氟含量的聚合物，其中，该低折射率层包括至少一种平均粒径为低折射率层厚度的30%至100%的无机细粒子；使用该抗反射膜的偏振板用于偏振板的两个保护膜之一；以及使用该抗反射膜或偏振板用于显示器的最外表面的图像显示设备。

表征谱图