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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-[[2-(4-Bromo-2-methylphenyl)sulfanylacetyl]amino]-3-tert-butylthiourea —— C14H20BrN3OS2
    1-[[2-(4-Bromo-2-methylphenyl)sulfanylacetyl]amino]-3-tert-butylthiourea
    —— 1-Tert-butyl-3-[[2-(2,5-dimethylphenyl)sulfanylacetyl]amino]thiourea —— C15H23N3OS2
    1-Tert-butyl-3-[[2-(2,5-dimethylphenyl)sulfanylacetyl]amino]thiourea
    —— N'-[2-(3,5-dimethyl-1H-pyrazol-1-yl)acetyl]-3-[4,6-dimethyl-2-(methylsulfanyl)pyrimidin-5-yl]propanehydrazide —— C17H24N6O2S
    N'-[2-(3,5-dimethyl-1H-pyrazol-1-yl)acetyl]-3-[4,6-dimethyl-2-(methylsulfanyl)pyrimidin-5-yl]propanehydrazide
    —— N'-[2-(2,5-difluorophenyl)sulfanylacetyl]-2-(3,5-dimethylpyrazol-1-yl)acetohydrazide —— C15H16F2N4O2S
    N'-[2-(2,5-difluorophenyl)sulfanylacetyl]-2-(3,5-dimethylpyrazol-1-yl)acetohydrazide
    —— 5-[(1S)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C12H10FN5OS2
    5-[(1S)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— N'-[2-(4-methylphenyl)sulfanylacetyl]-3-(5-phenylfuran-2-yl)propanehydrazide —— C22H22N2O3S
    N'-[2-(4-methylphenyl)sulfanylacetyl]-3-(5-phenylfuran-2-yl)propanehydrazide
    —— N'-[2-(4-methylphenyl)sulfanylacetyl]-4-morpholin-4-yl-4-oxobutanehydrazide —— C17H23N3O4S
    N'-[2-(4-methylphenyl)sulfanylacetyl]-4-morpholin-4-yl-4-oxobutanehydrazide
    —— (E)-N'-[2-(4-methylphenyl)sulfanylacetyl]-3-thiophen-2-ylprop-2-enehydrazide —— C16H16N2O2S2
    (E)-N'-[2-(4-methylphenyl)sulfanylacetyl]-3-thiophen-2-ylprop-2-enehydrazide
    —— 2,5-dimethyl-N'-[2-(4-methylphenyl)sulfanylacetyl]-1-propan-2-ylpyrrole-3-carbohydrazide —— C19H25N3O2S
    2,5-dimethyl-N'-[2-(4-methylphenyl)sulfanylacetyl]-1-propan-2-ylpyrrole-3-carbohydrazide
    —— 4-cyclohexyl-N'-[2-(2-fluorophenyl)sulfanylacetyl]butanehydrazide —— C18H25FN2O2S
    4-cyclohexyl-N'-[2-(2-fluorophenyl)sulfanylacetyl]butanehydrazide
    —— 2-benzylsulfanyl-N'-[2-(4-methylphenyl)sulfanylacetyl]acetohydrazide —— C18H20N2O2S2
    2-benzylsulfanyl-N'-[2-(4-methylphenyl)sulfanylacetyl]acetohydrazide
    —— (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N,N-dimethylpropanamide —— C7H12N4OS2
    (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N,N-dimethylpropanamide
    —— N'-[2-(2-fluorophenyl)sulfanylacetyl]-4-thiophen-2-ylbutanehydrazide —— C16H17FN2O2S2
    N'-[2-(2-fluorophenyl)sulfanylacetyl]-4-thiophen-2-ylbutanehydrazide
    —— N'-[2-(2-fluorophenyl)sulfanylacetyl]-4-morpholin-4-yl-4-oxobutanehydrazide —— C16H20FN3O4S
    N'-[2-(2-fluorophenyl)sulfanylacetyl]-4-morpholin-4-yl-4-oxobutanehydrazide
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-cyclopropyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C11H16N4O3S3
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-cyclopropyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— N'-[2-(2-fluorophenyl)sulfanylacetyl]-2,5-dimethyl-1-propan-2-ylpyrrole-3-carbohydrazide —— C18H22FN3O2S
    N'-[2-(2-fluorophenyl)sulfanylacetyl]-2,5-dimethyl-1-propan-2-ylpyrrole-3-carbohydrazide
    —— N'-[2-(2-fluorophenyl)sulfanylacetyl]-2-[3-(trifluoromethyl)pyrazol-1-yl]acetohydrazide —— C14H12F4N4O2S
    N'-[2-(2-fluorophenyl)sulfanylacetyl]-2-[3-(trifluoromethyl)pyrazol-1-yl]acetohydrazide
    —— N'-[2-(2,5-dimethylphenyl)sulfanylacetyl]-2-(2-fluorophenyl)sulfanylacetohydrazide —— C18H19FN2O2S2
    N'-[2-(2,5-dimethylphenyl)sulfanylacetyl]-2-(2-fluorophenyl)sulfanylacetohydrazide
    —— N'-[2-(3,5-dimethylpyrazol-1-yl)acetyl]-3-phenylsulfanylpropanehydrazide —— C16H20N4O2S
    N'-[2-(3,5-dimethylpyrazol-1-yl)acetyl]-3-phenylsulfanylpropanehydrazide
    —— 3-[(1S)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1H-1,2,4-triazol-5-amine —— C13H14N6OS
    3-[(1S)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1H-1,2,4-triazol-5-amine
    —— 3-(4-chlorophenyl)sulfanyl-N'-[2-(3,5-dimethylpyrazol-1-yl)acetyl]propanehydrazide —— C16H19ClN4O2S
    3-(4-chlorophenyl)sulfanyl-N'-[2-(3,5-dimethylpyrazol-1-yl)acetyl]propanehydrazide
    —— 2-(2-methylphenyl)sulfanyl-N-(pyridin-2-ylmethyl)acetamide —— C15H16N2OS
    2-(2-methylphenyl)sulfanyl-N-(pyridin-2-ylmethyl)acetamide
    —— 2-(4-bromo-2-methylphenyl)sulfanyl-N-(pyridin-2-ylmethyl)acetamide —— C15H15BrN2OS
    2-(4-bromo-2-methylphenyl)sulfanyl-N-(pyridin-2-ylmethyl)acetamide
    —— 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-(pyridin-2-ylmethyl)acetamide —— C16H17N5O2S
    2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-(pyridin-2-ylmethyl)acetamide
    —— 2-(4-bromophenyl)sulfanyl-N-(pyridin-2-ylmethyl)acetamide —— C14H13BrN2OS
    2-(4-bromophenyl)sulfanyl-N-(pyridin-2-ylmethyl)acetamide
    —— [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] pyridine-3-carboxylate —— C20H16N2O3S
    [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] pyridine-3-carboxylate
    —— [2-[2-(4-Chlorophenyl)sulfanylanilino]-2-oxoethyl] pyridine-3-carboxylate —— C20H15ClN2O3S
    [2-[2-(4-Chlorophenyl)sulfanylanilino]-2-oxoethyl] pyridine-3-carboxylate
    —— [(2R)-1-(ethylamino)-1-oxopropan-2-yl] 2-(2,5-dimethylphenyl)sulfanylacetate —— C15H21NO3S
    [(2R)-1-(ethylamino)-1-oxopropan-2-yl] 2-(2,5-dimethylphenyl)sulfanylacetate
    —— [(2S)-1-(ethylamino)-1-oxopropan-2-yl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate —— C15H20BrNO3S
    [(2S)-1-(ethylamino)-1-oxopropan-2-yl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate
    —— [(2R)-1-(ethylamino)-1-oxopropan-2-yl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate —— C15H20BrNO3S
    [(2R)-1-(ethylamino)-1-oxopropan-2-yl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate
    —— 3-tert-butyl-4-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C14H18N4S2
    3-tert-butyl-4-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— N-[(1R)-1-(4-fluorophenyl)ethyl]-3-(4-fluorophenyl)sulfanylpropanamide —— C17H17F2NOS
    N-[(1R)-1-(4-fluorophenyl)ethyl]-3-(4-fluorophenyl)sulfanylpropanamide
    —— 3-(4-chlorophenyl)sulfanyl-N-[(1S)-1-(4-fluorophenyl)ethyl]propanamide —— C17H17ClFNOS
    3-(4-chlorophenyl)sulfanyl-N-[(1S)-1-(4-fluorophenyl)ethyl]propanamide
    —— 3-(4-chlorophenyl)sulfanyl-N-[(1R)-1-(4-fluorophenyl)ethyl]propanamide —— C17H17ClFNOS
    3-(4-chlorophenyl)sulfanyl-N-[(1R)-1-(4-fluorophenyl)ethyl]propanamide
    —— N-butyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C18H23N3O4S2
    N-butyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— 1-(5-Bromothiophen-2-yl)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanone —— C14H9BrN2O2S2
    1-(5-Bromothiophen-2-yl)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanone
    —— (2S)-N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C17H20N4O2S
    (2S)-N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— 2-[[2-(4-Fluorophenyl)-1,3-thiazol-4-yl]methylsulfanyl]-5-phenyl-1,3,4-oxadiazole —— C18H12FN3OS2
    2-[[2-(4-Fluorophenyl)-1,3-thiazol-4-yl]methylsulfanyl]-5-phenyl-1,3,4-oxadiazole
    —— (2S)-1-(4-ethylpiperazin-1-yl)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-1-one —— C17H22N4O2S
    (2S)-1-(4-ethylpiperazin-1-yl)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-1-one
    —— 1-(5-Chlorothiophen-2-yl)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanone —— C14H9ClN2O2S2
    1-(5-Chlorothiophen-2-yl)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanone
    —— N-[(3-fluorophenyl)methyl]-N-methyl-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C18H16FN3O2S
    N-[(3-fluorophenyl)methyl]-N-methyl-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— (2R)-1-[1-(furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-1-one —— C22H21N3O3S
    (2R)-1-[1-(furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-1-one
    —— N-[(1S)-1-cyano-1-cyclopropylethyl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C16H16N4O2S
    N-[(1S)-1-cyano-1-cyclopropylethyl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— (2R)-1-(4-ethylpiperazin-1-yl)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-1-one —— C17H22N4O2S
    (2R)-1-(4-ethylpiperazin-1-yl)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-1-one
    —— (2S)-N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C17H20N4O2S
    (2S)-N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-1-(4-ethylpiperazin-4-ium-1-yl)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-1-one —— C17H23N4O2S+
    (2R)-1-(4-ethylpiperazin-4-ium-1-yl)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-1-one
    —— N-[(6-chloro-3,4-dihydro-2H-1,5-benzodioxepin-8-yl)methyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide —— C20H24ClN3O3S
    N-[(6-chloro-3,4-dihydro-2H-1,5-benzodioxepin-8-yl)methyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide
    —— N-[(6-chloro-3,4-dihydro-2H-1,5-benzodioxepin-8-yl)methyl]-2-(4-fluorophenyl)sulfanylacetamide —— C18H17ClFNO3S
    N-[(6-chloro-3,4-dihydro-2H-1,5-benzodioxepin-8-yl)methyl]-2-(4-fluorophenyl)sulfanylacetamide
    —— N-[(6-chloro-3,4-dihydro-2H-1,5-benzodioxepin-8-yl)methyl]-2-(3,4-dimethylphenyl)sulfanylacetamide —— C20H22ClNO3S
    N-[(6-chloro-3,4-dihydro-2H-1,5-benzodioxepin-8-yl)methyl]-2-(3,4-dimethylphenyl)sulfanylacetamide
    —— N-[(6-chloro-3,4-dihydro-2H-1,5-benzodioxepin-8-yl)methyl]-2-phenylsulfanylacetamide —— C18H18ClNO3S
    N-[(6-chloro-3,4-dihydro-2H-1,5-benzodioxepin-8-yl)methyl]-2-phenylsulfanylacetamide