双(4-(乙烯基硫基)苯基)硫烷 | 152419-78-8

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 中文名称: 双(4-(乙烯基硫基)苯基)硫烷
• 英文名称: bis(4-vinylthiophenyl)sulfide
• 英文别名: 4,4'-bis(vinylthio)diphenyl sulfide；1-ethenylsulfanyl-4-(4-ethenylsulfanylphenyl)sulfanylbenzene
• CAS: 152419-78-8
• 化学式: C₁₆H₁₄S₃
• 分子量: 302.485
• InChiKey: WQUQHXQTTKKFGY-UHFFFAOYSA-N

物化性质

• 沸点：
  465.3±45.0 °C(Predicted)
• 密度：
  1.22±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  75.9
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 包装等级：
  III
• 危险类别：
  9
• 危险性防范说明：
  P501,P273,P260,P270,P264,P280,P391,P314,P337+P313,P305+P351+P338,P301+P312+P330
• 危险品运输编号：
  3077
• 危险性描述：
  H302,H319,H372,H410

反应信息

• 作为反应物：
  描述：

  双(4-(乙烯基硫基)苯基)硫烷 在 双氧水 、 溶剂黄146 作用下， 以 水 为溶剂， 以92%的产率得到1-ethenylsulfonyl-4-(4-ethenylsulfonylphenyl)sulfanylbenzene
  参考文献：
  名称：

  Moskvichev; Tarasov; Timoshenko, Russian Journal of Organic Chemistry, 1996, vol. 32, # 12, p. 1791 - 1794

  摘要：

  DOI：
• 作为产物：
  描述：

  4'4-二巯基二苯硫醚 在 氢氧化钾 、 四丁基溴化铵 作用下， 以 二甲基亚砜 为溶剂， 反应 1.83h， 生成 双(4-(乙烯基硫基)苯基)硫烷
  参考文献：
  名称：

  Nesterov, V. V.; Tarasov, A. V.; Afonin, A. V., Journal of Organic Chemistry USSR (English Translation), 1992, vol. 28, # 9.2, p. 1526 - 1530

  摘要：

  DOI：

文献信息

• Dental Materials Based On Low-Viscosity Radically Polymerizable Monomers With A High Refractive Index
  申请人：Ivoclar Vivadent AG

  公开号：US20190015301A1

  公开（公告）日：2019-01-17

  Radically polymerizable, difunctional phenylene sulfide according to Formula I in which X, Y independently of each other in each case are absent or are O or NR 6 , R 1 , R 2 independently of each other in each case are H, a linear or branched C 1 to C 10 alkyl radical, —OR 7 , —SR 8 , Cl or Br, R 3 is absent or is a C 1 -C 10 alkylene radical which can be interrupted by O or S, R 4 is absent or is a C 1 -C 10 alkylene radical which can be interrupted by O or S, wherein R 3 and R 4 cannot be absent at the same time, R 5 is H or a C 1 -C 5 alkyl radical, R 6 , R 7 , R 8 independently of each other in each case are H or a linear or branched C 1 to C 10 alkyl radical, a, b, c, d independently of each other in each case are 0 or 1 and e is 1 or 2.

  根据以下公式I，根据以下公式I，根据以下公式I，根据以下公式I，可进行根本聚合的二官能苯基硫化物，其中X、Y在每种情况下独立地不存在或为O或NR6，R1、R2在每种情况下独立地为H、线性或支链的C1至C10烷基基团，-OR7，-SR8，Cl或Br，R3不存在或为可以被O或S中断的C1-C10烷基基团，R4不存在或为可以被O或S中断的C1-C10烷基基团，其中R3和R4不能同时不存在，R5为H或C1-C5烷基基团，R6、R7、R8在每种情况下独立地为H或线性或支链的C1至C10烷基基团，a、b、c、d在每种情况下独立地为0或1，e为1或2。
• Coating composition for optical parts, thin film layer made of it and optical part comprising it
  申请人：HOYA CORPORATION

  公开号：EP0964019A1

  公开（公告）日：1999-12-15

  The invention provides optical parts having good impact resistance, good adhesiveness between the substrate and a thin film layer formed thereon, good scratch resistance and good antireflection capabilities. A coating composition comprising at least one selected from dithian ring skeleton-having sulfur compounds of a general formula (1):    wherein n is an integer of from 1 to 3, and benzene ring-having sulfur compounds of a general formula (2):    wherein m is 0 or 1, and a polyfunctional thiol is applied onto the surface of a plastic substrate to form thereon a thin film layer.

  本发明提供的光学部件具有良好的抗冲击性、基底与在其上形成的薄膜层之间良好的粘合性、良好的抗划伤性和抗反射能力。一种涂层组合物，包含至少一种选自通式（1）的二噻环骨架含硫化合物： 其中 n 为 1 至 3 的整数、 和通式（2）的苯环含硫化合物： 其中 m 为 0 或 1、 将多官能团硫醇涂覆在塑料基材表面，在其上形成薄膜层。
• Organic-inorganic composite resin composition, organic-inorganic composite resin material, optical element, and stacked diffraction optical element
  申请人：CANON KABUSHIKI KAISHA

  公开号：EP2484721A1

  公开（公告）日：2012-08-08

  Provided are an organic-inorganic composite resin composition and an organic-inorganic composite resin material made of a cured product thereof, containing at least an organic compound having a polymerizable functional group, metal oxide fine particles, and a polymerization initiator. The cured product obtained by curing the organic-inorganic composite resin composition through application of an active energy has a refractive index nd of 1.61 or more and 1.65 or less, Abbe's number νd of 13 or more and 20 or less, and an anomalous dispersion characteristic θg, F of 0.42 or more and 0.54 or less. Further provided is an optical element comprising a transparent substrate and the organic-inorganic composite resin material formed on the transparent substrate.

  本发明提供了一种有机-无机复合树脂组合物及其固化产物制成的有机-无机复合树脂材料，其中至少含有一种具有可聚合官能团的有机化合物、金属氧化物微粒和一种聚合引发剂。通过应用活性能量固化有机-无机复合树脂组合物而获得的固化产物具有 1.61 或以上和 1.65 或以下的折射率 nd，13 或以上和 20 或以下的阿贝数 νd，以及 0.42 或以上和 0.54 或以下的反常分散特性 θg, F。进一步提供的光学元件包括透明基板和在透明基板上形成的有机-无机复合树脂材料。
• ANTIREFLECTIVE COATING COMPOSITION, ANTIREFLECTIVE FILM, AND PREPARATION METHOD THEREOF
  申请人：LG Chem, Ltd.

  公开号：EP2557130A2

  公开（公告）日：2013-02-13

  This disclosure relates to an anti-reflective coating composition that is divided into at least two layers through phase separation after monolayer coating, more particularly an anti-reflective coating composition comprising hollow particles coated with a fluorine-based compound having refractive index of 1.3~1.4 and surface tension of 10-25 mN/m on the surface, an anti-reflection film manufactured therefrom, and a method of manufacturing the same. In the anti-reflective coating composition of the present invention, at least two layers may be spontaneously formed only by single coating due to smooth phase separation in the coating layer. Particularly, since an interface of each layer formed by phase separation is substantially chemically bonded or crosslinked, delamination of each layer may be minimized. And, a film with excellent scratch resistance and anti-reflection may be manufactured by a more simplified method using the anti-reflective coating composition of the present invention.

  本发明涉及一种在单层涂布后通过相分离至少分为两层的减反射性涂层组合物，特别是一种减反射性涂层组合物，该组合物包括表面涂布有折射率为 1.3~1.4 和表面张力为 10-25 mN/m 的氟基化合物的空心颗粒、由此制造的减反射膜以及制造方法。 在本发明的减反射涂层组合物中，由于涂层中的相分离平滑，因此仅通过一次涂敷就可自发形成至少两层涂层。特别是，由于相分离形成的各层界面基本上是化学键合或交联的，因此可以最大限度地减少各层的分层。而且，使用本发明的减反射涂层组合物，可以通过更简化的方法制造出具有优异抗划伤性和抗反射性的薄膜。
• ANTIREFLECTIVE AND ANTIGLARE COATING COMPOSITION, ANTIREFLECTIVE AND ANTIGLARE FILM, AND METHOD FOR PRODUCING SAME
  申请人：LG Chem, Ltd.

  公开号：EP2594614A2

  公开（公告）日：2013-05-22

  An exemplary embodiment of the present invention provides an antireflective and antiglare coating composition, comprising: a low refractive substance having a refractive index of 1.2 to 1.45, a high refractive substance having a refractive index of 1.46 to 2, a fluorine-based compound and a particulates having an average particle diameter of 1 to 10 µm, wherein a surface energy difference between the low refractive substance and the high refractive substance is 5 mN/m or more, an antireflective and antiglare film manufactured by using the same, and a method for manufacturing the same. According to the exemplary embodiment of the present invention, an antireflective and antiglare film having excellent wear resistance and antireflection function may be manufactured by a single coating process using the single composition, such that a manufacturing cost may be decreased.

  本发明的一个示例性实施例提供了一种防反射和防眩光涂层组合物，包括：折射率为 1.2 至 1.45 的低折射率物质、折射率为 1.46 至 2 的高折射率物质、氟基化合物和平均粒径为 1 至 10 µm 的微粒，其中低折射率物质和高折射率物质之间的表面能差为 5 mN/m 或更多，使用该组合物制造防反射和防眩膜，以及制造该组合物的方法。根据本发明的示例性实施例，可通过使用单一成分的单一涂布工艺制造出具有优异耐磨性和防反射功能的防反射和防眩光薄膜，从而降低制造成本。

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