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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [2-[2-(2-Fluorophenyl)ethylamino]-2-oxoethyl] 3-phenylsulfanylpropanoate —— C19H20FNO3S
    [2-[2-(2-Fluorophenyl)ethylamino]-2-oxoethyl] 3-phenylsulfanylpropanoate
    —— 3-[2-(2-amino-2-oxoethyl)sulfanyl-4,6-dimethylpyrimidin-5-yl]-N-[(2R)-2-phenylpropyl]propanamide —— C20H26N4O2S
    3-[2-(2-amino-2-oxoethyl)sulfanyl-4,6-dimethylpyrimidin-5-yl]-N-[(2R)-2-phenylpropyl]propanamide
    —— 2-(3-cyano-4,6-dimethylpyridin-2-yl)sulfanyl-N-[(1S)-1-phenylbutyl]acetamide —— C20H23N3OS
    2-(3-cyano-4,6-dimethylpyridin-2-yl)sulfanyl-N-[(1S)-1-phenylbutyl]acetamide
    —— (2S)-2-(3-cyano-4,6-dimethylpyridin-2-yl)sulfanyl-N-propan-2-ylpropanamide —— C14H19N3OS
    (2S)-2-(3-cyano-4,6-dimethylpyridin-2-yl)sulfanyl-N-propan-2-ylpropanamide
    —— N-[(1S)-1-phenylbutyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C17H22N4OS2
    N-[(1S)-1-phenylbutyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[(1R)-1-phenylbutyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C17H22N4OS2
    N-[(1R)-1-phenylbutyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-(3-cyano-4,6-dimethylpyridin-2-yl)sulfanyl-N-[(1R)-1-phenylbutyl]acetamide —— C20H23N3OS
    2-(3-cyano-4,6-dimethylpyridin-2-yl)sulfanyl-N-[(1R)-1-phenylbutyl]acetamide
    —— N-methyl-N-[(1S)-1-phenylethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C16H20N4OS2
    N-methyl-N-[(1S)-1-phenylethyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (2R)-N-[(1R)-1-phenylbutyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C18H24N4OS2
    (2R)-N-[(1R)-1-phenylbutyl]-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (5E)-3-ethyl-2-(2-methylphenyl)imino-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one —— C20H20N2OS2
    (5E)-3-ethyl-2-(2-methylphenyl)imino-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one
    —— (5E)-2-(2,4-difluorophenyl)imino-3-ethyl-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one —— C19H16F2N2OS2
    (5E)-2-(2,4-difluorophenyl)imino-3-ethyl-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one
    —— (5Z)-3-methyl-2-(2-methylphenyl)imino-5-[(5-phenylsulfanylfuran-2-yl)methylidene]-1,3-thiazolidin-4-one —— C22H18N2O2S2
    (5Z)-3-methyl-2-(2-methylphenyl)imino-5-[(5-phenylsulfanylfuran-2-yl)methylidene]-1,3-thiazolidin-4-one
    —— (5E)-2-(4-chlorophenyl)imino-3-methyl-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one —— C18H15ClN2OS2
    (5E)-2-(4-chlorophenyl)imino-3-methyl-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one
    —— (5E)-2-(4-chlorophenyl)imino-3-ethyl-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one —— C19H17ClN2OS2
    (5E)-2-(4-chlorophenyl)imino-3-ethyl-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one
    —— (5E)-5-[(2-hydroxyphenyl)methylidene]-3-methyl-2-(3-methylsulfanylphenyl)imino-1,3-thiazolidin-4-one —— C18H16N2O2S2
    (5E)-5-[(2-hydroxyphenyl)methylidene]-3-methyl-2-(3-methylsulfanylphenyl)imino-1,3-thiazolidin-4-one
    —— (5E)-5-[(2-chlorophenyl)methylidene]-3-methyl-2-(3-methylsulfanylphenyl)imino-1,3-thiazolidin-4-one —— C18H15ClN2OS2
    (5E)-5-[(2-chlorophenyl)methylidene]-3-methyl-2-(3-methylsulfanylphenyl)imino-1,3-thiazolidin-4-one
    —— (5E)-3-methyl-2-(3-methylsulfanylphenyl)imino-5-[(5-piperidin-1-ylfuran-2-yl)methylidene]-1,3-thiazolidin-4-one —— C21H23N3O2S2
    (5E)-3-methyl-2-(3-methylsulfanylphenyl)imino-5-[(5-piperidin-1-ylfuran-2-yl)methylidene]-1,3-thiazolidin-4-one
    —— (5E)-3-methyl-2-(3-methylsulfanylphenyl)imino-5-[(5-pyrrolidin-1-ylfuran-2-yl)methylidene]-1,3-thiazolidin-4-one —— C20H21N3O2S2
    (5E)-3-methyl-2-(3-methylsulfanylphenyl)imino-5-[(5-pyrrolidin-1-ylfuran-2-yl)methylidene]-1,3-thiazolidin-4-one
    —— (5E)-2-(4-ethylphenyl)imino-3-methyl-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one —— C20H20N2OS2
    (5E)-2-(4-ethylphenyl)imino-3-methyl-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one
    —— (5E)-5-[(4-methylsulfanylphenyl)methylidene]-2-phenylimino-3-propyl-1,3-thiazolidin-4-one —— C20H20N2OS2
    (5E)-5-[(4-methylsulfanylphenyl)methylidene]-2-phenylimino-3-propyl-1,3-thiazolidin-4-one
    —— 3-[(4-Phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanoic acid —— C11H10N2O2S3
    3-[(4-Phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanoic acid
    —— (2R)-2-pyrimidin-2-ylsulfanylpropanoate —— C7H7N2O2S-
    (2R)-2-pyrimidin-2-ylsulfanylpropanoate
    —— (5E)-3-methyl-2-(4-methylphenyl)imino-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one —— C19H18N2OS2
    (5E)-3-methyl-2-(4-methylphenyl)imino-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one
    —— [2-oxo-2-[[(1S)-1-phenylbutyl]amino]ethyl] 2-(2-fluorophenyl)sulfanylacetate —— C20H22FNO3S
    [2-oxo-2-[[(1S)-1-phenylbutyl]amino]ethyl] 2-(2-fluorophenyl)sulfanylacetate
    —— 3-[(4-Methyl-1,3-thiazol-2-yl)sulfanyl]propanoate —— C7H8NO2S2-
    3-[(4-Methyl-1,3-thiazol-2-yl)sulfanyl]propanoate
    —— (2R)-2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanoate —— C12H11N2O3S-
    (2R)-2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanoate
    —— 3-[(3-Methylsulfanyl-1,2,4-thiadiazol-5-yl)sulfanyl]propanoic acid —— C6H8N2O2S3
    3-[(3-Methylsulfanyl-1,2,4-thiadiazol-5-yl)sulfanyl]propanoic acid
    —— (2S)-2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]propanoate —— C5H7N4O2S-
    (2S)-2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]propanoate
    —— {[3-(Methylsulfanyl)-1,2,4-thiadiazol-5-yl]sulfanyl}acetic acid —— C5H6N2O2S3
    {[3-(Methylsulfanyl)-1,2,4-thiadiazol-5-yl]sulfanyl}acetic acid
    —— (2R)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanoate —— C11H9N2O2S3-
    (2R)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanoate
    —— (2R)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanoic acid —— C7H9NO2S2
    (2R)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanoic acid
    —— (2R)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoic acid —— C11H9FN2O3S
    (2R)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoic acid
    —— (2R)-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]propanoic acid —— C12H11NO2S2
    (2R)-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]propanoic acid
    —— (2R)-2-[[5-(5-methyl-1,2-oxazol-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate —— C9H8N3O4S-
    (2R)-2-[[5-(5-methyl-1,2-oxazol-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate
    —— 2-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S)-1-(furan-2-yl)ethyl]acetamide —— C18H20N4O2S2
    2-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S)-1-(furan-2-yl)ethyl]acetamide
    —— 3-{[5-(4-Bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}propanoic acid —— C11H9BrN2O3S
    3-{[5-(4-Bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}propanoic acid
    —— (2S)-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanoic acid —— C10H9N3O3S
    (2S)-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanoic acid
    —— 3-[[5-(2-Fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate —— C11H8FN2O3S-
    3-[[5-(2-Fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate
    —— 3-{[5-(4-Fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}propanoic acid —— C11H9FN2O3S
    3-{[5-(4-Fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}propanoic acid
    —— (2R)-2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanoic acid —— C12H12N2O3S
    (2R)-2-[(5-benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanoic acid
    —— 3-[(3-Methylsulfanyl-1,2,4-thiadiazol-5-yl)sulfanyl]propanoate —— C6H7N2O2S3-
    3-[(3-Methylsulfanyl-1,2,4-thiadiazol-5-yl)sulfanyl]propanoate
    —— (2R)-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]propanoate —— C12H10NO2S2-
    (2R)-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]propanoate
    —— 2-[[5-(5-Methyl-1,2-oxazol-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetic acid —— C8H7N3O4S
    2-[[5-(5-Methyl-1,2-oxazol-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetic acid
    —— (2R)-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoic acid —— C9H8N2O4S
    (2R)-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoic acid
    —— (2R)-2-[[5-(3-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate —— C11H8FN2O3S-
    (2R)-2-[[5-(3-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate
    —— (2R)-2-pyrimidin-2-ylsulfanylpropanoic acid —— C7H8N2O2S
    (2R)-2-pyrimidin-2-ylsulfanylpropanoic acid
    —— (2S)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanoate —— C7H8NO2S2-
    (2S)-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanoate
    —— 3-Pyrimidin-2-ylsulfanylpropanoate —— C7H7N2O2S-
    3-Pyrimidin-2-ylsulfanylpropanoate
    —— [2-[[4-(Dimethylamino)phenyl]methylamino]-2-oxoethyl] 3-phenylsulfanylpropanoate —— C20H24N2O3S
    [2-[[4-(Dimethylamino)phenyl]methylamino]-2-oxoethyl] 3-phenylsulfanylpropanoate
    —— (2R)-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanoic acid —— C7H10N2O3S
    (2R)-2-[(5-ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanoic acid