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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(5-{5-[(4-chlorophenyl)sulfanyl]-2-(tetrahydro-2H-pyran-4-yl)-1,3-oxazol-4-yl}pyridin-2-yl)propan-2-ol —— C22H23ClN2O3S
    2-(5-{5-[(4-chlorophenyl)sulfanyl]-2-(tetrahydro-2H-pyran-4-yl)-1,3-oxazol-4-yl}pyridin-2-yl)propan-2-ol
    —— methyl 4-({2-[(4-chlorophenyl)sulfanyl]ethyl}carbamoyl)cyclohexanecarboxylate —— C17H22ClNO3S
    methyl 4-({2-[(4-chlorophenyl)sulfanyl]ethyl}carbamoyl)cyclohexanecarboxylate
    —— N-{2-[(4-chlorophenyl)sulfanyl]ethyl}tetrahydro-2H-pyran-4-carboxamide —— C14H18ClNO2S
    N-{2-[(4-chlorophenyl)sulfanyl]ethyl}tetrahydro-2H-pyran-4-carboxamide
    —— 2-((4-chlorophenyl)thio)pyrazine —— C10H7ClN2S
    2-((4-chlorophenyl)thio)pyrazine
    —— 5-chloro-4-[(4-chlorophenylthio)-(2,5-difluorophenyl)methyl]-2-(4'-hydroxypiperidine-1'-yl)pyridine —— C23H20Cl2F2N2OS
    5-chloro-4-[(4-chlorophenylthio)-(2,5-difluorophenyl)methyl]-2-(4'-hydroxypiperidine-1'-yl)pyridine
    —— (2-ethanesulfonyl-ethyl)-diethyl-amine —— C8H19NO2S
    (2-ethanesulfonyl-ethyl)-diethyl-amine
    —— 3-phenylsulfanyl-9-oxa-1,9a-diazacyclopenta[b]naphthalen-4-one —— C16H10N2O2S
    3-phenylsulfanyl-9-oxa-1,9a-diazacyclopenta[b]naphthalen-4-one
    —— N,N-dimethyl-3-(t-butyldimethylsilyl)-3-ethylsulfonylpropanamide —— C13H29NO3SSi
    N,N-dimethyl-3-(t-butyldimethylsilyl)-3-ethylsulfonylpropanamide
    —— ethyl hept-6-enyl sulfone —— C9H18O2S
    ethyl hept-6-enyl sulfone
    —— ethyl 4,4-dimethylpentyl sulfone —— C9H20O2S
    ethyl 4,4-dimethylpentyl sulfone
    —— 2-(ethylsulfonyl)propanal —— C5H10O3S
    2-(ethylsulfonyl)propanal
    —— 2-(benzylthio)-6-oxo-4-(pyridin-4-yl)-1,6-dihydropyrimidine-5-carbonitrile —— C17H12N4OS
    2-(benzylthio)-6-oxo-4-(pyridin-4-yl)-1,6-dihydropyrimidine-5-carbonitrile
    —— 6-cyano-7-(4-pyridyl)-2,3-dihydrothiazolo[3,2-a]pyrimidin-5(H)-one —— C12H8N4OS
    6-cyano-7-(4-pyridyl)-2,3-dihydrothiazolo[3,2-a]pyrimidin-5(H)-one
    —— 3-methyl-2-methylthio-4-oxo-6-(4-pyridyl)-3,4-dihydropyrimidine-5-carbonitrile —— C12H10N4OS
    3-methyl-2-methylthio-4-oxo-6-(4-pyridyl)-3,4-dihydropyrimidine-5-carbonitrile
    —— 2-ethylthio-4-oxo-6-(4-pyridyl)-3,4-dihydropyrimidine-5-carbonitrile —— C12H10N4OS
    2-ethylthio-4-oxo-6-(4-pyridyl)-3,4-dihydropyrimidine-5-carbonitrile
    —— 2-(3,4-dimethylbenzylthio)-4-oxo-6-(4-pyridyl)-3,4-dihydropyrimidine-5-carbonitrile —— C19H16N4OS
    2-(3,4-dimethylbenzylthio)-4-oxo-6-(4-pyridyl)-3,4-dihydropyrimidine-5-carbonitrile
    —— 2-(4-chlorobenzylthio)-4-oxo-6-(4-pyridyl)-3,4-dihydropyrimidine-5-carbonitrile —— C17H11ClN4OS
    2-(4-chlorobenzylthio)-4-oxo-6-(4-pyridyl)-3,4-dihydropyrimidine-5-carbonitrile
    —— 3-benzylthio-5-(6-chloropyrazin-2-yl)[1,3,4]thiadiazole —— C13H9ClN4S2
    3-benzylthio-5-(6-chloropyrazin-2-yl)[1,3,4]thiadiazole
    —— 5-chloro-2-ethylthio-4-pyridinecarbonitrile —— C8H7ClN2S
    5-chloro-2-ethylthio-4-pyridinecarbonitrile
    —— 5-Chloro-2-methylthio-4-pyridinecarbonitrile —— C7H5ClN2S
    5-Chloro-2-methylthio-4-pyridinecarbonitrile
    —— 6-chloro-3-propylthio-2-pyridinecarbonitrile —— C9H9ClN2S
    6-chloro-3-propylthio-2-pyridinecarbonitrile
    —— 3-chloro-6-propylthio-2-pyridinecarbonitrile —— C9H9ClN2S
    3-chloro-6-propylthio-2-pyridinecarbonitrile
    —— 1,2,4,5-tetrakis[(4-pyridylsulfanyl)methyl]benzene —— C30H26N4S4
    1,2,4,5-tetrakis[(4-pyridylsulfanyl)methyl]benzene
    —— 6,6-dimethyl-3-<(phenylthio)methyl>-2-cyclohexen-1-one —— C15H18OS
    6,6-dimethyl-3-<(phenylthio)methyl>-2-cyclohexen-1-one
    —— 1-(3-hydroxy-2-butyl-azetidin-1-yl)-2,2-dimethylpropane-1-thione —— C12H23NOS
    1-(3-hydroxy-2-butyl-azetidin-1-yl)-2,2-dimethylpropane-1-thione
    —— 1-(2-allyl-3-hydroxyazetidin-1-yl)-2,2-dimethylpropane-1-thione —— C11H19NOS
    1-(2-allyl-3-hydroxyazetidin-1-yl)-2,2-dimethylpropane-1-thione
    —— 1-(2,4-dideutero-3-hydroxyazetidin-1-yl)-2,2-dimethylpropane-1-thione —— C8H15NOS
    1-(2,4-dideutero-3-hydroxyazetidin-1-yl)-2,2-dimethylpropane-1-thione
    —— 1-(3-hydroxy-2-methyl-azetidin-1-yl)-2,2-dimethylpropane-1-thione —— C9H17NOS
    1-(3-hydroxy-2-methyl-azetidin-1-yl)-2,2-dimethylpropane-1-thione
    —— 1-(3-hydroxy-2-(tributylstannyl)azetidin-1-yl)-2,2-dimethylpropane-1-thione —— C20H41NOSSn
    1-(3-hydroxy-2-(tributylstannyl)azetidin-1-yl)-2,2-dimethylpropane-1-thione
    —— 1-(2-deutero-3-(hydroxy)-azetidin-1-yl)-2,2-dimethylpropane-1-thione —— C8H15NOS
    1-(2-deutero-3-(hydroxy)-azetidin-1-yl)-2,2-dimethylpropane-1-thione
    —— ethyl 9-(4-dimethylaminophenyl)-4-oxo-7-methyl-9H-3,4-dihydrothiazolo[a-2,3:b-4,5]dipyrimidine-8-carboxylate —— C20H21N5O3S
    ethyl 9-(4-dimethylaminophenyl)-4-oxo-7-methyl-9H-3,4-dihydrothiazolo[a-2,3:b-4,5]dipyrimidine-8-carboxylate
    —— 1-(2,3-dihydro[1,4]benzoxathiin-5-yl)piperid-4-one —— C13H15NO2S
    1-(2,3-dihydro[1,4]benzoxathiin-5-yl)piperid-4-one
    —— 2,3-dihydro-3-hydroxymethylenethiopyrano[2,3-b]pyridin-4(4H)-one —— C9H7NO2S
    2,3-dihydro-3-hydroxymethylenethiopyrano[2,3-b]pyridin-4(4H)-one
    —— 3-(1,1,3,3-tetramethyl-butylmercapto)-thiophene —— C12H20S2
    3-(1,1,3,3-tetramethyl-butylmercapto)-thiophene
    —— bis(4-((trimethylsilyl)thio)phenyl)sulfane —— C18H26S3Si2
    bis(4-((trimethylsilyl)thio)phenyl)sulfane
    —— S,S'-(thiobis(4,1-phenylene)) dibenzothioate —— C26H18O2S3
    S,S'-(thiobis(4,1-phenylene)) dibenzothioate
    —— 5-amino-2-chloro-4-methylthiopyrimidine —— C5H6ClN3S
    5-amino-2-chloro-4-methylthiopyrimidine
    —— (3R)-3-{-2-[2-(tetrahydropyran-2-yloxy)ethyl]-[1,3]dithian-2-yl}butan-2-one —— C15H26O3S2
    (3R)-3-{-2-[2-(tetrahydropyran-2-yloxy)ethyl]-[1,3]dithian-2-yl}butan-2-one
    —— methyl 2-[2-formyl-6-(trifluoromethyl)phenyl]sulfanylpyridine-3-carboxylate —— C15H10F3NO3S
    methyl 2-[2-formyl-6-(trifluoromethyl)phenyl]sulfanylpyridine-3-carboxylate
    —— 2-({5-anilino-2-[(1,3-dimethylbutyl)amino]phenyl}sulfanyl)nicotinic acid —— C24H27N3O2S
    2-({5-anilino-2-[(1,3-dimethylbutyl)amino]phenyl}sulfanyl)nicotinic acid
    —— ethyl 4-{[4-(phenylthio)phenyl]sulfonyl}piperidine-4-carboxylate trifluoroacetate —— C2HF3O2*C20H23NO4S2
    ethyl 4-{[4-(phenylthio)phenyl]sulfonyl}piperidine-4-carboxylate trifluoroacetate
    —— ethyl 4-{[4-(phenylthio)phenyl]sulfonyl}piperidine-4-carboxylate hydrochloride —— C20H23NO4S2*ClH
    ethyl 4-{[4-(phenylthio)phenyl]sulfonyl}piperidine-4-carboxylate hydrochloride
    —— N-hydroxy-1-(methylsulfonyl)-4-{[4-(phenylthio)phenyl]sulfonyl}piperidine-4-carboxamide —— C19H22N2O6S3
    N-hydroxy-1-(methylsulfonyl)-4-{[4-(phenylthio)phenyl]sulfonyl}piperidine-4-carboxamide
    —— (4-(methylsulfonyl)cyclohexyl)methanamine —— C8H17NO2S
    (4-(methylsulfonyl)cyclohexyl)methanamine
    —— 1-isothiocyanato-2-yne —— C5H5NS
    1-isothiocyanato-2-yne
    —— 3-chloro-1-(4-chloro-5H-1,2,3-dithiazol-5-ylidene)-3-[2-(2-methylsulfanyl-1,3,4-thiadiazol-5-yl)-1,3,4-thiadiazol-5-yl]-1,2-diazaprop-2-ene —— C8H3Cl2N7S5
    3-chloro-1-(4-chloro-5H-1,2,3-dithiazol-5-ylidene)-3-[2-(2-methylsulfanyl-1,3,4-thiadiazol-5-yl)-1,3,4-thiadiazol-5-yl]-1,2-diazaprop-2-ene
    —— N-<2-(p-Tolylthio)aethyl>cyclopropylamin —— C12H17NS
    N-<2-(p-Tolylthio)aethyl>cyclopropylamin
    —— 3-((4-aminophenyl)thio)acrylic acid —— C9H9NO2S
    3-((4-aminophenyl)thio)acrylic acid
    —— (Z)-3-n-Butyl-1-(phenylthio)hept-3-ene-1-yne —— C17H22S
    (Z)-3-n-Butyl-1-(phenylthio)hept-3-ene-1-yne
    —— 94B11 —— C20H19NO3S
    94B11