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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-hydroxy-2-(phenylthio)cyclohex-2-en-1-one —— C12H12O2S
    3-hydroxy-2-(phenylthio)cyclohex-2-en-1-one
    —— 3-[(4-methylphenyl)sulfanyl]cyclohex-2-en-1-one —— C13H14OS
    3-[(4-methylphenyl)sulfanyl]cyclohex-2-en-1-one
    —— 3-(4-chlorophenylthio) cyclohex-2-enone —— C12H11ClOS
    3-(4-chlorophenylthio) cyclohex-2-enone
    —— methyl 3-oxo-2-[(1H-1,2,4-triazol-3-yl)thio]butanoate —— C7H9N3O3S
    methyl 3-oxo-2-[(1H-1,2,4-triazol-3-yl)thio]butanoate
    —— methyl 3-oxo-4-(pyridin-2-ylthio)butanoate —— C10H11NO3S
    methyl 3-oxo-4-(pyridin-2-ylthio)butanoate
    —— N-[1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]benzenesulfonamide —— C22H23N5O2S2
    N-[1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]benzenesulfonamide
    —— N-[1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]-N'-methylsulfamide —— C17H22N6O2S2
    N-[1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]-N'-methylsulfamide
    —— N-[2-[1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]ethyl]methanesulfonamide —— C19H25N5O2S2
    N-[2-[1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]ethyl]methanesulfonamide
    —— N-[1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]-N',N'-dimethylsulfamide —— C18H24N6O2S2
    N-[1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]-N',N'-dimethylsulfamide
    —— N-[1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]-N',N'-pentamethylenesulfamide —— C21H28N6O2S2
    N-[1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]-N',N'-pentamethylenesulfamide
    —— N,N-[3-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)-3-azapentamethylene]sulfamide —— C15H18N6O2S2
    N,N-[3-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)-3-azapentamethylene]sulfamide
    —— 1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidine-3-carboxamide —— C17H19N5OS
    1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidine-3-carboxamide
    —— 8-[(4-methylpiperazin-1-yl)methyl]-10H-pyrazino[2,3-b][1,4]benzothiazine —— C16H19N5S
    8-[(4-methylpiperazin-1-yl)methyl]-10H-pyrazino[2,3-b][1,4]benzothiazine
    —— 1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidine-4-carboxamide —— C17H19N5OS
    1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidine-4-carboxamide
    —— N-[1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]trifluoromethanesulfonamide —— C17H18F3N5O2S2
    N-[1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]trifluoromethanesulfonamide
    —— N-[[1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]methyl]methanesulfonamide —— C18H23N5O2S2
    N-[[1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]methyl]methanesulfonamide
    —— N-[1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]-N',N'-(3-oxapentamethylene)sulfamide —— C20H26N6O3S2
    N-[1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]-N',N'-(3-oxapentamethylene)sulfamide
    —— 8-(piperidin-1-ylmethyl)-10H-pyrazino[2,3-b][1,4]benzothiazine —— C16H18N4S
    8-(piperidin-1-ylmethyl)-10H-pyrazino[2,3-b][1,4]benzothiazine
    —— N-[1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]methanesulfonamide —— C17H21N5O2S2
    N-[1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]methanesulfonamide
    —— 8-[(morpholin-4-yl)methyl]-10H-pyrazino[2,3-b][1,4]benzothiazine —— C15H16N4OS
    8-[(morpholin-4-yl)methyl]-10H-pyrazino[2,3-b][1,4]benzothiazine
    —— N,N-[3-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)-3-azapentamethylene]methanesulfonamide —— C16H19N5O2S2
    N,N-[3-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)-3-azapentamethylene]methanesulfonamide
    —— N,N-[3-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)-3-azapentamethylene]acetamide —— C17H19N5OS
    N,N-[3-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)-3-azapentamethylene]acetamide
    —— N-[1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]acetamide —— C18H21N5OS
    N-[1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]acetamide
    —— 8-(heptamethyleniminomethyl)-10H-pyrazino[2,3-b][1,4]benzothiazine —— C18H22N4S
    8-(heptamethyleniminomethyl)-10H-pyrazino[2,3-b][1,4]benzothiazine
    —— N,N-[3-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)-3-azapentamethylene]-N',N'-dimethylsulfamide —— C17H22N6O2S2
    N,N-[3-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)-3-azapentamethylene]-N',N'-dimethylsulfamide
    —— 8-(azetidin-1-ylmethyl)-10H-pyrazino[2,3-b][1,4]benzothiazine —— C14H14N4S
    8-(azetidin-1-ylmethyl)-10H-pyrazino[2,3-b][1,4]benzothiazine
    —— 2-((chloromethyl)thio)thiazole —— C4H4ClNS2
    2-((chloromethyl)thio)thiazole
    —— 5-(N-isopropyl-N-methylsulfamoyl)-2-((4-methoxyphenyl)thio)benzoic acid —— C18H21NO5S2
    5-(N-isopropyl-N-methylsulfamoyl)-2-((4-methoxyphenyl)thio)benzoic acid
    —— (1-phenylethyl)(o-tolyl)sulfane —— C15H16S
    (1-phenylethyl)(o-tolyl)sulfane
    —— (4-fluorophenyl)(1-phenylethyl)sulfane —— C14H13FS
    (4-fluorophenyl)(1-phenylethyl)sulfane
    —— mesityl propargyl sulfide —— C12H14S
    mesityl propargyl sulfide
    —— trimethylsilyl-(13)C-methyl-phenylsulfide —— C10H16SSi
    trimethylsilyl-(13)C-methyl-phenylsulfide
    —— N-(7-bromo-6-oxoheptyl)-2-(4-fluorophenylthio)acetamide —— C15H19BrFNO2S
    N-(7-bromo-6-oxoheptyl)-2-(4-fluorophenylthio)acetamide
    —— 2-(Ethylthio)-3,6-dihydro-6-oxo-1,3,5-triphenyl-1-pyrimidinium-4-olat —— C24H20N2O2S
    2-(Ethylthio)-3,6-dihydro-6-oxo-1,3,5-triphenyl-1-pyrimidinium-4-olat
    —— 6-(2-azidomethyl-phenylsulfanyl)-3-isoprolyl-[1,2,4]triazolo[4,3-a]pyridine —— C16H16N6S
    6-(2-azidomethyl-phenylsulfanyl)-3-isoprolyl-[1,2,4]triazolo[4,3-a]pyridine
    —— hydroxyethyl octyl sulfide —— C10H22OS
    hydroxyethyl octyl sulfide
    —— (4R,5S,6R)-3,4,5,6-tetrahydro-3-[(2S,3S)-3-hydroxy-3-phenyl-2-((phenylthio)methyl)propionyl]-4-isopropyl-5-methyl-6-phenyl-2H-1,3,4-oxadiazin-2-one —— C29H32N2O4S
    (4R,5S,6R)-3,4,5,6-tetrahydro-3-[(2S,3S)-3-hydroxy-3-phenyl-2-((phenylthio)methyl)propionyl]-4-isopropyl-5-methyl-6-phenyl-2H-1,3,4-oxadiazin-2-one
    —— 2,4-dimethylthiopyrimidine-5-boronic acid —— C6H9BN2O2S2
    2,4-dimethylthiopyrimidine-5-boronic acid
    —— 2-(3-benzyloxypropyl)-5-(3,5-dichlorophenylthio)-4-isopropyl-1H-imidazole —— C22H24Cl2N2OS
    2-(3-benzyloxypropyl)-5-(3,5-dichlorophenylthio)-4-isopropyl-1H-imidazole
    —— 2-(3-benzyloxypropyl)-5-(3,5-dichlorophenylthio)-4-isopropyl-1-ethyl-1H-imidazole —— C24H28Cl2N2OS
    2-(3-benzyloxypropyl)-5-(3,5-dichlorophenylthio)-4-isopropyl-1-ethyl-1H-imidazole
    —— (4S,5S)-4-methyl-2-(2-methyl-1,3-dithian-2-yl)-5-phenyl-4,5-dihydro-1,3-oxazole —— C15H19NOS2
    (4S,5S)-4-methyl-2-(2-methyl-1,3-dithian-2-yl)-5-phenyl-4,5-dihydro-1,3-oxazole
    —— 2-methylthio-4-(4'-aminophenylarsonic acid)aminopyrimidine 296235-31-9 C11H12AsN3O3S
    2-methylthio-4-(4'-aminophenylarsonic acid)aminopyrimidine
    —— 1,1-dioxo-2-methyl-2,3-dihydrobenzo[e][1,4,2]dithiazine-3-thione —— C8H7NO2S3
    1,1-dioxo-2-methyl-2,3-dihydrobenzo[e][1,4,2]dithiazine-3-thione
    —— 1,1-dioxo-2-methyl-2,3-dihydrobenzo[e][1,4,2]dithiazine-3-one —— C8H7NO3S2
    1,1-dioxo-2-methyl-2,3-dihydrobenzo[e][1,4,2]dithiazine-3-one
    —— 5-(2-hydroxyethyl)-6-methyl-2-[(1-methyl-2-oxopropyl)thio]-4(3H)-pyrimidinone —— C11H16N2O3S
    5-(2-hydroxyethyl)-6-methyl-2-[(1-methyl-2-oxopropyl)thio]-4(3H)-pyrimidinone
    —— (E)-2-[(methylamino)phenylmethylene]-benzo[b]thiophen-3(2H)-one —— C16H13NOS
    (E)-2-[(methylamino)phenylmethylene]-benzo[b]thiophen-3(2H)-one
    —— (4 hydroxyphenylthio)nitromethane —— C7H7NO3S
    (4 hydroxyphenylthio)nitromethane
    —— N-(2-[(2,3-difluorobenzyl)thio]-6-{[(1R)-2-hydroxy-1-methylethyl]amino}pyrimidin-4-yl)piperidine-1-sulfonamide —— C19H25F2N5O3S2
    N-(2-[(2,3-difluorobenzyl)thio]-6-{[(1R)-2-hydroxy-1-methylethyl]amino}pyrimidin-4-yl)piperidine-1-sulfonamide
    —— N-{6-chloro-2-[(3-chloro-2-fluorobenzyl)thio]pyrimidin-4-yl}-2-(dimethylamino)ethanesulfonamide —— C15H17Cl2FN4O2S2
    N-{6-chloro-2-[(3-chloro-2-fluorobenzyl)thio]pyrimidin-4-yl}-2-(dimethylamino)ethanesulfonamide
    —— N-(2-[(3-chloro-2-fluorobenzyl)thio]-6-{[(1R)-2-hydroxy-1-methylethyl]amino}pyrimidin-4-yl)-2-(dimethylamino)ethanesulfonamide —— C18H25ClFN5O3S2
    N-(2-[(3-chloro-2-fluorobenzyl)thio]-6-{[(1R)-2-hydroxy-1-methylethyl]amino}pyrimidin-4-yl)-2-(dimethylamino)ethanesulfonamide