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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(ethylsulfanyl)-6,6-dimethyl-1-(1H-pyrazol-3-yl)-6,7-dihydro-2-benzothiophen-4(5H)-one —— C15H18N2OS2
    3-(ethylsulfanyl)-6,6-dimethyl-1-(1H-pyrazol-3-yl)-6,7-dihydro-2-benzothiophen-4(5H)-one
    —— [2-(ethylthio)-4-fluorophenyl]amine —— C8H10FNS
    [2-(ethylthio)-4-fluorophenyl]amine
    —— 1-(7-ethanethioheptyl)-cyclopropene —— C12H22S
    1-(7-ethanethioheptyl)-cyclopropene
    —— 4-chloro-6-(ethylthio)pyrimidin-5-amine —— C6H8ClN3S
    4-chloro-6-(ethylthio)pyrimidin-5-amine
    —— 4-(2-aminopyrid-6-ylthio)butyronitrile —— C9H11N3S
    4-(2-aminopyrid-6-ylthio)butyronitrile
    —— 2-amino-6-benzylthiopyridine hydrochloride —— C12H12N2S*ClH
    2-amino-6-benzylthiopyridine hydrochloride
    —— 4-ethylsulfanylpyridine-3-carbonitrile —— C8H8N2S
    4-ethylsulfanylpyridine-3-carbonitrile
    —— 5-bromo-3-(ethylthio)pyrazin-2-amine —— C6H8BrN3S
    5-bromo-3-(ethylthio)pyrazin-2-amine
    —— 4-(6-amino-8-((3,5-dichlorophenyl)thio)-9H-purin-9-yl)-butanenitrile —— C15H12Cl2N6S
    4-(6-amino-8-((3,5-dichlorophenyl)thio)-9H-purin-9-yl)-butanenitrile
    —— 1-phenylthio-1-buten-3-ol —— C10H12OS
    1-phenylthio-1-buten-3-ol
    —— 2-amino-5-((3-cyanopropyl)mercapto)-1,3,4-thiadiazole —— C6H8N4S2
    2-amino-5-((3-cyanopropyl)mercapto)-1,3,4-thiadiazole
    —— O,O-dimethyl S-[3-methyl-4-(methylthio)phenyl]phosphorothioate —— C10H15O3PS2
    O,O-dimethyl S-[3-methyl-4-(methylthio)phenyl]phosphorothioate
    —— 2-cyclopenlythio-6-(2,6-diflurophenymethyl)-3,4-dihydro-5-methylpyrimidin-4-(3H)-one —— C17H18F2N2OS
    2-cyclopenlythio-6-(2,6-diflurophenymethyl)-3,4-dihydro-5-methylpyrimidin-4-(3H)-one
    —— 2-(cyclopentylthio)-5,6-dibenzylpyrimidin-4(3H)-one —— C23H24N2OS
    2-(cyclopentylthio)-5,6-dibenzylpyrimidin-4(3H)-one
    —— diethyl butyl<1-(bispentyloxyphosphinyl)-2-methyl-2-(phenylthio)propyl>amidophosphate —— C28H53NO6P2S
    diethyl butyl<1-(bispentyloxyphosphinyl)-2-methyl-2-(phenylthio)propyl>amidophosphate
    —— diethyl butyl<1-(diethoxyphosphinyl)-2-methyl-2-(phenylthio)propyl>amidophosphate —— C22H41NO6P2S
    diethyl butyl<1-(diethoxyphosphinyl)-2-methyl-2-(phenylthio)propyl>amidophosphate
    —— diethyl butyl<1-(dimethoxyphosphinyl)-2-methyl-2-(phenylthio)propyl>amidophosphate —— C20H37NO6P2S
    diethyl butyl<1-(dimethoxyphosphinyl)-2-methyl-2-(phenylthio)propyl>amidophosphate
    —— diethyl methyl-N-<1-(butoxythiocarbonylthio)-2-methyl-2-(phenylthio)propyl>amidophosphate —— C20H34NO4PS3
    diethyl methyl-N-<1-(butoxythiocarbonylthio)-2-methyl-2-(phenylthio)propyl>amidophosphate
    —— 1-methyl-5-(3-cyclopentylthiopropyl)thio-1,2,3,4-tetrazole —— C10H18N4S2
    1-methyl-5-(3-cyclopentylthiopropyl)thio-1,2,3,4-tetrazole
    —— (pyridylthio)cyclopentane —— C10H13NS
    (pyridylthio)cyclopentane
    —— 2-cyclopentylthio-6-[1-(2,6-difluorophenyl)ethyl]-3,4-dihydro-5-methylpyrimidin-4(3H)-one —— C18H20F2N2OS
    2-cyclopentylthio-6-[1-(2,6-difluorophenyl)ethyl]-3,4-dihydro-5-methylpyrimidin-4(3H)-one
    —— methyl-2-((3-bromopyridin-4-yl)thio)-2-methylpropanoate —— C10H12BrNO2S
    methyl-2-((3-bromopyridin-4-yl)thio)-2-methylpropanoate
    —— 5-chloro-1-(3-phenylpropyl)-3-(phenylsulfanyl)pyrazin-2(1H)-one —— C19H17ClN2OS
    5-chloro-1-(3-phenylpropyl)-3-(phenylsulfanyl)pyrazin-2(1H)-one
    —— (2-bromophenyl)(3-bromopropyl)sulfane —— C9H10Br2S
    (2-bromophenyl)(3-bromopropyl)sulfane
    —— (3-bromopropyl)(2-fluorophenyl)sulfane —— C9H10BrFS
    (3-bromopropyl)(2-fluorophenyl)sulfane
    —— 2-((3-bromopropyl)thio)-5-methyl-1,3,4-thiadiazole —— C6H9BrN2S2
    2-((3-bromopropyl)thio)-5-methyl-1,3,4-thiadiazole
    —— 2-[p-(phenylthio)phenoxy]ethylamine —— C14H15NOS
    2-[p-(phenylthio)phenoxy]ethylamine
    —— 6a,11a-dihydro-4-(1,1-dimethylethyl)-7H-cyclohepta[b]benz-1,4-oxathiin —— C17H20OS
    6a,11a-dihydro-4-(1,1-dimethylethyl)-7H-cyclohepta[b]benz-1,4-oxathiin
    —— 6a,11a-dihydro-4-methyl-7H-cyclohepta[b]benz-1,4-oxathiin —— C14H14OS
    6a,11a-dihydro-4-methyl-7H-cyclohepta[b]benz-1,4-oxathiin
    —— 6a,11a-dihydro-3,5-bis(1,1-dimethylethyl)-11H-cyclohepta[b]benz-1,4-oxathiin —— C21H28OS
    6a,11a-dihydro-3,5-bis(1,1-dimethylethyl)-11H-cyclohepta[b]benz-1,4-oxathiin
    —— 6a,11a-dihydro-4-(1,1-dimethylethyl)-11H-cyclohepta[b]benz-1,4-oxathiin —— C17H20OS
    6a,11a-dihydro-4-(1,1-dimethylethyl)-11H-cyclohepta[b]benz-1,4-oxathiin
    —— 6a,11a-dihydro-3,5-bis(1,1-dimethylethyl)-7H-cyclohepta[b]benz-1,4-oxathiin —— C21H28OS
    6a,11a-dihydro-3,5-bis(1,1-dimethylethyl)-7H-cyclohepta[b]benz-1,4-oxathiin
    —— 1-(methylsulfonyl)cyclobutanecarbonitrile —— C6H9NO2S
    1-(methylsulfonyl)cyclobutanecarbonitrile
    —— N-(Dimethylphosphito)-N,N'-dimethylthioharnstoff —— C5H13N2O2PS
    N-(Dimethylphosphito)-N,N'-dimethylthioharnstoff
    —— <i>N</i>,<i>N</i>-diethyl-4-trichloromethylsulfanyl-aniline —— C11H14Cl3NS
    <i>N</i>,<i>N</i>-diethyl-4-trichloromethylsulfanyl-aniline
    —— bis (4-hydroxy-3,5-dimethoxyphenyl)sulfure —— C16H18O6S
    bis (4-hydroxy-3,5-dimethoxyphenyl)sulfure
    —— trichloromethyldithioacetic acid —— C3H3Cl3S2
    trichloromethyldithioacetic acid
    —— (3-bromo-4-fluorophenyl)(methyl)sulfane 1511032-71-5 C7H6BrFS
    (3-bromo-4-fluorophenyl)(methyl)sulfane
    —— 1-Phenyl-8-methyl-1.6-dithianonane —— C14H22S2
    1-Phenyl-8-methyl-1.6-dithianonane
    —— 2-(2-(phenylthio)phenyl)-1-(pyrrolidin-1-yl)pentan-1-one —— C21H25NOS
    2-(2-(phenylthio)phenyl)-1-(pyrrolidin-1-yl)pentan-1-one
    —— 2-[2-(4-fluorophenyl)ethylsulfanyl]-4-hydroxy-1H-pyrimidin-6-one —— C12H11FN2O2S
    2-[2-(4-fluorophenyl)ethylsulfanyl]-4-hydroxy-1H-pyrimidin-6-one
    —— 2-(2-(phenylthio)phenyl)-1-(thiophen-3-yl)ethan-1-one —— C18H14OS2
    2-(2-(phenylthio)phenyl)-1-(thiophen-3-yl)ethan-1-one
    —— (2-(hept-2-ynyl)phenyl)(phenyl)sulfide —— C19H20S
    (2-(hept-2-ynyl)phenyl)(phenyl)sulfide
    —— (2E)-3-phenyl-2-[(phenylsulfanyl)methyl]prop-2-enenitrile —— C16H13NS
    (2E)-3-phenyl-2-[(phenylsulfanyl)methyl]prop-2-enenitrile
    —— dioctyl sulfide —— C16H34S
    dioctyl sulfide
    —— 5-methyl-4-propyl-2-[4-({3-[4-(4-propyl-4H-1,2,4-triazol-3-yl)tetrahydro-2H-pyran-4-yl]phenyl}thio)phenyl]-2,4-dihydro-3H-1,2,4-triazol-3-one —— C28H34N6O2S
    5-methyl-4-propyl-2-[4-({3-[4-(4-propyl-4H-1,2,4-triazol-3-yl)tetrahydro-2H-pyran-4-yl]phenyl}thio)phenyl]-2,4-dihydro-3H-1,2,4-triazol-3-one
    —— 5-[(2,4-dimethylphenyl)methyl]-6-methyl-2-(propylsulfanyl)pyrimidin-4(3H)-one —— C17H22N2OS
    5-[(2,4-dimethylphenyl)methyl]-6-methyl-2-(propylsulfanyl)pyrimidin-4(3H)-one
    —— 5,6-dimethyl-2-(propylsulfanyl)pyrimidin-4(3H)-one —— C9H14N2OS
    5,6-dimethyl-2-(propylsulfanyl)pyrimidin-4(3H)-one
    —— 5-benzyl-6-methyl-2-(propylsulfanyl)pyrimidin-4(3H)-one —— C15H18N2OS
    5-benzyl-6-methyl-2-(propylsulfanyl)pyrimidin-4(3H)-one
    —— 2-Fluoro-6-trifluoromethyl-n-propylthiobenzene —— C10H10F4S
    2-Fluoro-6-trifluoromethyl-n-propylthiobenzene