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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [2-(2,5-dimethyl-1-propylpyrrol-3-yl)-2-oxoethyl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate —— C20H23N3O4S
    [2-(2,5-dimethyl-1-propylpyrrol-3-yl)-2-oxoethyl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate
    —— [2-[2-(4-fluorophenyl)ethylamino]-2-oxoethyl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate —— C19H18FN3O4S
    [2-[2-(4-fluorophenyl)ethylamino]-2-oxoethyl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate
    —— (2R)-N-ethyl-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C14H18N4OS2
    (2R)-N-ethyl-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— 2-Ethanimidoyl-4-[[5-(3-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-oxobutanenitrile —— C14H12FN5OS2
    2-Ethanimidoyl-4-[[5-(3-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-oxobutanenitrile
    —— N-(2-methylphenyl)-5-[[(2R)-oxolan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C14H17N3OS2
    N-(2-methylphenyl)-5-[[(2R)-oxolan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N-(2,4-dimethylphenyl)-5-[[(2R)-oxolan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C15H19N3OS2
    N-(2,4-dimethylphenyl)-5-[[(2R)-oxolan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N-[(1S)-3-methyl-1-phenylbutyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C17H21N3O2S
    N-[(1S)-3-methyl-1-phenylbutyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— (2S)-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-ethylpropanamide —— C15H20N4OS2
    (2S)-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-ethylpropanamide
    —— (2S)-2-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-ethylpropanamide —— C15H20N4OS2
    (2S)-2-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-ethylpropanamide
    —— (2R)-N,N-dimethyl-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C14H18N4OS2
    (2R)-N,N-dimethyl-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-2-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]propanenitrile —— C14H16N4OS2
    (2S)-2-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]propanenitrile
    —— 1-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-3-pentylthiourea —— C14H21N3S2
    1-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-3-pentylthiourea
    —— ethyl (2S)-2-phenyl-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetate —— C17H21N3O2S
    ethyl (2S)-2-phenyl-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetate
    —— 2-methyl-4-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3-thiazole —— C16H18N4OS3
    2-methyl-4-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3-thiazole
    —— (4R)-N-[2-(4-chlorophenyl)sulfanylethyl]-4-ethyl-1,3-thiazolidin-2-imine —— C13H17ClN2S2
    (4R)-N-[2-(4-chlorophenyl)sulfanylethyl]-4-ethyl-1,3-thiazolidin-2-imine
    —— 2-[[4-amino-5-[(2S)-2-phenylpropyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C13H16N4O2S
    2-[[4-amino-5-[(2S)-2-phenylpropyl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— (2S)-2-ethanimidoyl-3-oxo-4-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanenitrile —— C11H15N5OS2
    (2S)-2-ethanimidoyl-3-oxo-4-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanenitrile
    —— (2S)-4-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-2-(4-methyl-1,3-thiazol-2-yl)-3-oxobutanenitrile —— C17H15N5OS3
    (2S)-4-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-2-(4-methyl-1,3-thiazol-2-yl)-3-oxobutanenitrile
    —— 2-[(1R)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-4-propyl-1H-pyrimidin-6-one —— C17H17FN4O2S
    2-[(1R)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-4-propyl-1H-pyrimidin-6-one
    —— [2-[(1-Cyanocyclohexyl)amino]-2-oxoethyl] 2-phenylsulfanylacetate —— C17H20N2O3S
    [2-[(1-Cyanocyclohexyl)amino]-2-oxoethyl] 2-phenylsulfanylacetate
    —— N-cyclopentyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C18H27N3O4S2
    N-cyclopentyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— [(2R)-1-[[(1S,2S)-2-methylcyclohexyl]amino]-1-oxopropan-2-yl] 2-phenylsulfanylacetate —— C18H25NO3S
    [(2R)-1-[[(1S,2S)-2-methylcyclohexyl]amino]-1-oxopropan-2-yl] 2-phenylsulfanylacetate
    —— [(2R)-1-(1-adamantylamino)-1-oxopropan-2-yl] 2-phenylsulfanylacetate —— C21H27NO3S
    [(2R)-1-(1-adamantylamino)-1-oxopropan-2-yl] 2-phenylsulfanylacetate
    —— [(2R)-1-[(1-cyanocyclohexyl)amino]-1-oxopropan-2-yl] 2-phenylsulfanylacetate —— C18H22N2O3S
    [(2R)-1-[(1-cyanocyclohexyl)amino]-1-oxopropan-2-yl] 2-phenylsulfanylacetate
    —— (2S)-2-(2,4-dimethylphenyl)sulfanyl-N-[2-(4-fluorophenyl)ethyl]propanamide —— C19H22FNOS
    (2S)-2-(2,4-dimethylphenyl)sulfanyl-N-[2-(4-fluorophenyl)ethyl]propanamide
    —— [2-[2,5-Dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]-2-oxoethyl] 2-phenylsulfanylacetate —— C19H18N2O3S2
    [2-[2,5-Dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]-2-oxoethyl] 2-phenylsulfanylacetate
    —— [2-[2-(2,4-Dioxo-1,3-thiazolidin-3-yl)ethylamino]-2-oxoethyl] 2-phenylsulfanylacetate —— C15H16N2O5S2
    [2-[2-(2,4-Dioxo-1,3-thiazolidin-3-yl)ethylamino]-2-oxoethyl] 2-phenylsulfanylacetate
    —— [(2R)-1-[[(1S,2R)-2-methylcyclohexyl]amino]-1-oxopropan-2-yl] 2-phenylsulfanylacetate —— C18H25NO3S
    [(2R)-1-[[(1S,2R)-2-methylcyclohexyl]amino]-1-oxopropan-2-yl] 2-phenylsulfanylacetate
    —— 2-[(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-4-propyl-1H-pyrimidin-6-one —— C18H20N4O2S
    2-[(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-4-propyl-1H-pyrimidin-6-one
    —— 2-(2,4-dimethylphenyl)sulfanyl-N-[(2S)-2-phenylpropyl]acetamide —— C19H23NOS
    2-(2,4-dimethylphenyl)sulfanyl-N-[(2S)-2-phenylpropyl]acetamide
    —— 2-(2,4-dimethylphenyl)sulfanyl-N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]acetamide —— C15H21NO3S2
    2-(2,4-dimethylphenyl)sulfanyl-N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]acetamide
    —— 2-(2,4-dimethylphenyl)sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C15H21NO2S
    2-(2,4-dimethylphenyl)sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— N-[2-(4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide —— C11H12N4O2S3
    N-[2-(4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide
    —— (2R)-2-(2,5-dimethylphenyl)sulfanyl-N-[2-(4-fluorophenyl)ethyl]propanamide —— C19H22FNOS
    (2R)-2-(2,5-dimethylphenyl)sulfanyl-N-[2-(4-fluorophenyl)ethyl]propanamide
    —— 2-(2,4-dimethylphenyl)sulfanyl-1-[1-[(3S)-1,1-dioxothiolan-3-yl]-2,5-dimethylpyrrol-3-yl]ethanone —— C20H25NO3S2
    2-(2,4-dimethylphenyl)sulfanyl-1-[1-[(3S)-1,1-dioxothiolan-3-yl]-2,5-dimethylpyrrol-3-yl]ethanone
    —— (2S)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-pyrimidin-2-ylsulfanylpropanamide —— C15H16FN3OS
    (2S)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-pyrimidin-2-ylsulfanylpropanamide
    —— N-[(1S)-1-cyano-1-cyclopropylethyl]-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C18H21N5OS2
    N-[(1S)-1-cyano-1-cyclopropylethyl]-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (2R)-1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-pyrimidin-2-ylsulfanylpropan-1-one —— C20H17ClN4O2S
    (2R)-1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-pyrimidin-2-ylsulfanylpropan-1-one
    —— (2R)-1-[1-(furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]-2-pyrimidin-2-ylsulfanylpropan-1-one —— C18H19N3O2S
    (2R)-1-[1-(furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]-2-pyrimidin-2-ylsulfanylpropan-1-one
    —— N-[2-(4-fluorophenyl)ethyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H19FN4OS
    N-[2-(4-fluorophenyl)ethyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (2R)-N-(1-adamantyl)-2-pyrimidin-2-ylsulfanylpropanamide —— C17H23N3OS
    (2R)-N-(1-adamantyl)-2-pyrimidin-2-ylsulfanylpropanamide
    —— 2-[[5-(2-Methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetonitrile —— C12H12N4OS
    2-[[5-(2-Methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetonitrile
    —— N-tert-butyl-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C16H22N4O2S
    N-tert-butyl-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-benzyl-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C19H20N4O2S
    N-benzyl-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 6-Amino-5-[2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1-propylpyrimidine-2,4-dione —— C15H20N6O3S
    6-Amino-5-[2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1-propylpyrimidine-2,4-dione
    —— 2-(Furan-2-yl)-5-(pyrimidin-2-ylsulfanylmethyl)-1,3,4-oxadiazole —— C11H8N4O2S
    2-(Furan-2-yl)-5-(pyrimidin-2-ylsulfanylmethyl)-1,3,4-oxadiazole
    —— 1-[1-(Furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C19H22N4O2S
    1-[1-(Furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— N-[(4-fluorophenyl)methyl]-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C19H19FN4O2S
    N-[(4-fluorophenyl)methyl]-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— (2R)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-pyrimidin-2-ylsulfanylpropanamide —— C15H16FN3OS
    (2R)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-pyrimidin-2-ylsulfanylpropanamide
    —— 2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methylacetamide —— C16H20N4O3S3
    2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methylacetamide