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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[[5-(cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C12H18N4O2S2
    2-[[5-(cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— 2-[(4-Chlorophenyl)methylsulfanyl]-5-piperidin-4-yl-1,3,4-oxadiazole —— C14H16ClN3OS
    2-[(4-Chlorophenyl)methylsulfanyl]-5-piperidin-4-yl-1,3,4-oxadiazole
    —— 2-[[5-(Cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(2,5-dimethylthiophen-3-yl)ethanone —— C13H15N3OS3
    2-[[5-(Cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(2,5-dimethylthiophen-3-yl)ethanone
    —— N-(cyclohexen-1-yl)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-methoxyethyl)acetamide —— C20H26N4O2S2
    N-(cyclohexen-1-yl)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-methoxyethyl)acetamide
    —— c-(5-Benzylsulfanyl-[1,3,4]oxadiazol-2-yl)-methylamine —— C10H11N3OS
    c-(5-Benzylsulfanyl-[1,3,4]oxadiazol-2-yl)-methylamine
    —— [5-[(4-Fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]methylazanium —— C10H11FN3OS+
    [5-[(4-Fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]methylazanium
    —— (1S,2S)-1-(5-benzylsulfanyl-1,3,4-oxadiazol-2-yl)-2-methylbutan-1-amine —— C14H19N3OS
    (1S,2S)-1-(5-benzylsulfanyl-1,3,4-oxadiazol-2-yl)-2-methylbutan-1-amine
    —— (5-Propan-2-ylsulfanyl-1,3,4-oxadiazol-2-yl)methanamine —— C6H11N3OS
    (5-Propan-2-ylsulfanyl-1,3,4-oxadiazol-2-yl)methanamine
    —— [(1S,2S)-2-methyl-1-[5-[(2-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butyl]azanium —— C15H22N3OS+
    [(1S,2S)-2-methyl-1-[5-[(2-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butyl]azanium
    —— 2-Ethylsulfanyl-5-piperidin-4-yl-1,3,4-oxadiazole —— C9H15N3OS
    2-Ethylsulfanyl-5-piperidin-4-yl-1,3,4-oxadiazole
    —— [(1S)-3-methyl-1-(5-propylsulfanyl-1,3,4-oxadiazol-2-yl)butyl]azanium —— C10H20N3OS+
    [(1S)-3-methyl-1-(5-propylsulfanyl-1,3,4-oxadiazol-2-yl)butyl]azanium
    —— (1S,2S)-1-[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutan-1-amine —— C14H18ClN3OS
    (1S,2S)-1-[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutan-1-amine
    —— [(1S,2S)-1-[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutyl]azanium —— C14H19ClN3OS+
    [(1S,2S)-1-[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutyl]azanium
    —— 3-(5-Benzylsulfanyl-1,3,4-oxadiazol-2-yl)propylazanium —— C12H16N3OS+
    3-(5-Benzylsulfanyl-1,3,4-oxadiazol-2-yl)propylazanium
    —— [5-[(4-Chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]methanamine —— C10H10ClN3OS
    [5-[(4-Chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]methanamine
    —— (5-Propylsulfanyl-1,3,4-oxadiazol-2-yl)methanamine —— C6H11N3OS
    (5-Propylsulfanyl-1,3,4-oxadiazol-2-yl)methanamine
    —— 4-[5-(Benzylsulfanyl)-1,3,4-oxadiazol-2-YL]piperidine —— C14H17N3OS
    4-[5-(Benzylsulfanyl)-1,3,4-oxadiazol-2-YL]piperidine
    —— 3-[5-[(4-Fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propylazanium —— C12H15FN3OS+
    3-[5-[(4-Fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propylazanium
    —— (1S,2S)-2-methyl-1-[5-[(3-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butan-1-amine —— C15H21N3OS
    (1S,2S)-2-methyl-1-[5-[(3-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butan-1-amine
    —— (1S,2S)-1-[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutan-1-amine —— C14H18ClN3OS
    (1S,2S)-1-[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutan-1-amine
    —— 2-Methylsulfanyl-5-piperidin-4-yl-1,3,4-oxadiazole —— C8H13N3OS
    2-Methylsulfanyl-5-piperidin-4-yl-1,3,4-oxadiazole
    —— (1S,2S)-2-methyl-1-[5-[(2-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butan-1-amine —— C15H21N3OS
    (1S,2S)-2-methyl-1-[5-[(2-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butan-1-amine
    —— 2-(5-Propylsulfanyl-1,3,4-oxadiazol-2-yl)ethylazanium —— C7H14N3OS+
    2-(5-Propylsulfanyl-1,3,4-oxadiazol-2-yl)ethylazanium
    —— 2-[[5-(Cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-[1-[(4-fluorophenyl)methyl]-2,5-dimethylpyrrol-3-yl]ethanone —— C20H21FN4OS2
    2-[[5-(Cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-[1-[(4-fluorophenyl)methyl]-2,5-dimethylpyrrol-3-yl]ethanone
    —— 2-[(4,5-dicyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-1-(1H-pyrrol-2-yl)ethanone —— C14H16N4OS
    2-[(4,5-dicyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-1-(1H-pyrrol-2-yl)ethanone
    —— (3S,5R)-3-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-5-methyloxolan-2-one —— C14H15N3O2S2
    (3S,5R)-3-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-5-methyloxolan-2-one
    —— (3R,5R)-3-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-5-methyloxolan-2-one —— C14H15N3O2S2
    (3R,5R)-3-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-5-methyloxolan-2-one
    —— (2S)-2-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-(4-fluorophenyl)ethyl]propanamide —— C15H19FN4O2S
    (2S)-2-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-(4-fluorophenyl)ethyl]propanamide
    —— 2-Cyclopropyl-5-[2-(trifluoromethyl)quinazolin-4-yl]sulfanyl-1,3,4-oxadiazole —— C14H9F3N4OS
    2-Cyclopropyl-5-[2-(trifluoromethyl)quinazolin-4-yl]sulfanyl-1,3,4-oxadiazole
    —— N-[(3-chlorophenyl)methyl]-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C17H17ClN4O2S
    N-[(3-chlorophenyl)methyl]-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[(1R)-1-(3-chlorophenyl)ethyl]-3-(4-fluorophenyl)sulfanylpropanamide —— C17H17ClFNOS
    N-[(1R)-1-(3-chlorophenyl)ethyl]-3-(4-fluorophenyl)sulfanylpropanamide
    —— 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N',N'-dimethylacetohydrazide —— C12H13ClN4O2S
    2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N',N'-dimethylacetohydrazide
    —— 2-(4-bromophenyl)sulfanyl-N',N'-dimethylacetohydrazide —— C10H13BrN2OS
    2-(4-bromophenyl)sulfanyl-N',N'-dimethylacetohydrazide
    —— 1-(4-Butylphenyl)-3-[(2-phenylsulfanylacetyl)amino]thiourea —— C19H23N3OS2
    1-(4-Butylphenyl)-3-[(2-phenylsulfanylacetyl)amino]thiourea
    —— 2-[1-[(2S)-3-ethylpentan-2-yl]-4-oxopyrimidin-2-yl]sulfanylacetic acid —— C13H20N2O3S
    2-[1-[(2S)-3-ethylpentan-2-yl]-4-oxopyrimidin-2-yl]sulfanylacetic acid
    —— (E)-3-[5-chloro-3-methyl-1-(2-methylpropyl)pyrazol-4-yl]-N'-[2-(4-methylphenyl)sulfanylacetyl]prop-2-enehydrazide —— C20H25ClN4O2S
    (E)-3-[5-chloro-3-methyl-1-(2-methylpropyl)pyrazol-4-yl]-N'-[2-(4-methylphenyl)sulfanylacetyl]prop-2-enehydrazide
    —— N'-[2-(2-fluorophenyl)sulfanylacetyl]-5-methyl-3-phenyl-1,2-oxazole-4-carbohydrazide —— C19H16FN3O3S
    N'-[2-(2-fluorophenyl)sulfanylacetyl]-5-methyl-3-phenyl-1,2-oxazole-4-carbohydrazide
    —— 2-[1-[(2R)-3-ethylpentan-2-yl]-4-oxopyrimidin-2-yl]sulfanylacetic acid —— C13H20N2O3S
    2-[1-[(2R)-3-ethylpentan-2-yl]-4-oxopyrimidin-2-yl]sulfanylacetic acid
    —— 3-methyl-N'-[2-(4-methylphenyl)sulfanylacetyl]-5-propan-2-yl-1,2-oxazole-4-carbohydrazide —— C17H21N3O3S
    3-methyl-N'-[2-(4-methylphenyl)sulfanylacetyl]-5-propan-2-yl-1,2-oxazole-4-carbohydrazide
    —— 3-ethyl-5-methyl-N'-[2-(4-methylphenyl)sulfanylacetyl]-1,2-oxazole-4-carbohydrazide —— C16H19N3O3S
    3-ethyl-5-methyl-N'-[2-(4-methylphenyl)sulfanylacetyl]-1,2-oxazole-4-carbohydrazide
    —— 2-[(3S)-1,1-dioxothiolan-3-yl]-N'-[2-(2-fluorophenyl)sulfanylacetyl]acetohydrazide —— C14H17FN2O4S2
    2-[(3S)-1,1-dioxothiolan-3-yl]-N'-[2-(2-fluorophenyl)sulfanylacetyl]acetohydrazide
    —— 3-(2-chlorophenyl)-5-methyl-N'-[2-(4-methylphenyl)sulfanylacetyl]-1,2-oxazole-4-carbohydrazide —— C20H18ClN3O3S
    3-(2-chlorophenyl)-5-methyl-N'-[2-(4-methylphenyl)sulfanylacetyl]-1,2-oxazole-4-carbohydrazide
    —— 2-[(2-chlorophenyl)methylsulfanyl]-N'-[2-(4-methylphenyl)sulfanylacetyl]acetohydrazide —— C18H19ClN2O2S2
    2-[(2-chlorophenyl)methylsulfanyl]-N'-[2-(4-methylphenyl)sulfanylacetyl]acetohydrazide
    —— (Z)-3-amino-2-[2-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanylacetyl]but-2-enenitrile —— C12H9ClF3N3OS
    (Z)-3-amino-2-[2-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanylacetyl]but-2-enenitrile
    —— [(Z)-1-methylsulfonylethylideneamino] N-methylcarbamate —— C5H10N2O4S
    [(Z)-1-methylsulfonylethylideneamino] N-methylcarbamate
    —— [(Z)-1-[(S)-methylsulfinyl]ethylideneamino] N-methylcarbamate —— C5H10N2O3S
    [(Z)-1-[(S)-methylsulfinyl]ethylideneamino] N-methylcarbamate
    —— [(Z)-1-[(R)-methylsulfinyl]ethylideneamino] N-methylcarbamate —— C5H10N2O3S
    [(Z)-1-[(R)-methylsulfinyl]ethylideneamino] N-methylcarbamate
    —— (Z)-3-amino-2-[2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]but-2-enenitrile —— C14H11FN4O2S
    (Z)-3-amino-2-[2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]but-2-enenitrile
    —— 2-[(2R)-1-(2,2-dimethylpropyl)-4-[(2-methylsulfanylpyrimidin-5-yl)methyl]piperazin-2-yl]ethanol —— C17H30N4OS
    2-[(2R)-1-(2,2-dimethylpropyl)-4-[(2-methylsulfanylpyrimidin-5-yl)methyl]piperazin-2-yl]ethanol
    —— N-(4-methylphenyl)-4-[[1-(thiophen-2-ylmethyl)tetrazol-5-yl]sulfanylmethyl]-1,3-thiazol-2-amine —— C17H16N6S3
    N-(4-methylphenyl)-4-[[1-(thiophen-2-ylmethyl)tetrazol-5-yl]sulfanylmethyl]-1,3-thiazol-2-amine