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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(4-fluorophenyl)sulfanyl-N'-(1,3,5-trimethylpyrazol-4-yl)sulfonylpropanehydrazide —— C15H19FN4O3S2
    3-(4-fluorophenyl)sulfanyl-N'-(1,3,5-trimethylpyrazol-4-yl)sulfonylpropanehydrazide
    —— N-[(2R)-2-(3,4-dimethylphenyl)sulfanylpropyl]pentan-1-amine —— C16H27NS
    N-[(2R)-2-(3,4-dimethylphenyl)sulfanylpropyl]pentan-1-amine
    —— N-[(2S)-2-(3-bromophenyl)sulfanylpropyl]pentan-1-amine —— C14H22BrNS
    N-[(2S)-2-(3-bromophenyl)sulfanylpropyl]pentan-1-amine
    —— N-[(2R)-2-(3-bromophenyl)sulfanylpropyl]pentan-1-amine —— C14H22BrNS
    N-[(2R)-2-(3-bromophenyl)sulfanylpropyl]pentan-1-amine
    —— (2R)-5-methyl-N-[2-(2-methylphenyl)sulfanylethyl]hexan-2-amine —— C16H27NS
    (2R)-5-methyl-N-[2-(2-methylphenyl)sulfanylethyl]hexan-2-amine
    —— [(2S)-1-(1-adamantylamino)-1-oxopropan-2-yl] 3-phenylsulfanylpropanoate —— C22H29NO3S
    [(2S)-1-(1-adamantylamino)-1-oxopropan-2-yl] 3-phenylsulfanylpropanoate
    —— [5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]methyl 3-(3,4-difluorophenyl)sulfanylpropanoate —— C16H12F2N2O4S
    [5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]methyl 3-(3,4-difluorophenyl)sulfanylpropanoate
    —— [2-[[(1R)-1-(3-chlorophenyl)ethyl]amino]-2-oxoethyl] 3-(3,4-difluorophenyl)sulfanylpropanoate —— C19H18ClF2NO3S
    [2-[[(1R)-1-(3-chlorophenyl)ethyl]amino]-2-oxoethyl] 3-(3,4-difluorophenyl)sulfanylpropanoate
    —— [2-[[(3S)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 3-(3,4-difluorophenyl)sulfanylpropanoate —— C15H17F2NO5S2
    [2-[[(3S)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 3-(3,4-difluorophenyl)sulfanylpropanoate
    —— [2-oxo-2-[[(1S)-1-phenylethyl]amino]ethyl] 3-(3,4-difluorophenyl)sulfanylpropanoate —— C19H19F2NO3S
    [2-oxo-2-[[(1S)-1-phenylethyl]amino]ethyl] 3-(3,4-difluorophenyl)sulfanylpropanoate
    —— [2-(Benzylamino)-2-oxoethyl] 3-(3,4-difluorophenyl)sulfanylpropanoate —— C18H17F2NO3S
    [2-(Benzylamino)-2-oxoethyl] 3-(3,4-difluorophenyl)sulfanylpropanoate
    —— [2-[[(3S)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] (2S)-2-phenyl-2-phenylsulfanylacetate —— C20H21NO5S2
    [2-[[(3S)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] (2S)-2-phenyl-2-phenylsulfanylacetate
    —— [2-[(1-cyanocyclohexyl)amino]-2-oxoethyl] (2R)-2-phenyl-2-phenylsulfanylacetate —— C23H24N2O3S
    [2-[(1-cyanocyclohexyl)amino]-2-oxoethyl] (2R)-2-phenyl-2-phenylsulfanylacetate
    —— [2-[(1-cyanocyclopentyl)amino]-2-oxoethyl] (2S)-2-phenyl-2-phenylsulfanylacetate —— C22H22N2O3S
    [2-[(1-cyanocyclopentyl)amino]-2-oxoethyl] (2S)-2-phenyl-2-phenylsulfanylacetate
    —— [2-(tert-butylamino)-2-oxoethyl] (2R)-2-phenyl-2-phenylsulfanylacetate —— C20H23NO3S
    [2-(tert-butylamino)-2-oxoethyl] (2R)-2-phenyl-2-phenylsulfanylacetate
    —— [2-(benzylamino)-2-oxoethyl] (2R)-2-phenyl-2-phenylsulfanylacetate —— C23H21NO3S
    [2-(benzylamino)-2-oxoethyl] (2R)-2-phenyl-2-phenylsulfanylacetate
    —— (2-Amino-2-oxoethyl) 3-(3,4-difluorophenyl)sulfanylpropanoate —— C11H11F2NO3S
    (2-Amino-2-oxoethyl) 3-(3,4-difluorophenyl)sulfanylpropanoate
    —— N-[(2S)-2-(3,4-dimethylphenyl)sulfanylpropyl]aniline —— C17H21NS
    N-[(2S)-2-(3,4-dimethylphenyl)sulfanylpropyl]aniline
    —— [2-[benzyl(methyl)amino]-2-oxoethyl] (2R)-2-phenyl-2-phenylsulfanylacetate —— C24H23NO3S
    [2-[benzyl(methyl)amino]-2-oxoethyl] (2R)-2-phenyl-2-phenylsulfanylacetate
    —— [2-[[(3R)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] (2R)-2-phenyl-2-phenylsulfanylacetate —— C20H21NO5S2
    [2-[[(3R)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] (2R)-2-phenyl-2-phenylsulfanylacetate
    —— N-[(2R)-2-(3,4-dimethylphenyl)sulfanylpropyl]aniline —— C17H21NS
    N-[(2R)-2-(3,4-dimethylphenyl)sulfanylpropyl]aniline
    —— N-[(2R)-2-(2-bromophenyl)sulfanylpropyl]pentan-3-amine —— C14H22BrNS
    N-[(2R)-2-(2-bromophenyl)sulfanylpropyl]pentan-3-amine
    —— 2-ethylsulfanyl-N-[(2R)-5-methylhexan-2-yl]aniline —— C15H25NS
    2-ethylsulfanyl-N-[(2R)-5-methylhexan-2-yl]aniline
    —— N-[(2S)-2-(2-bromophenyl)sulfanylpropyl]pentan-3-amine —— C14H22BrNS
    N-[(2S)-2-(2-bromophenyl)sulfanylpropyl]pentan-3-amine
    —— (2R)-N-(2-phenylsulfanylethyl)octan-2-amine —— C16H27NS
    (2R)-N-(2-phenylsulfanylethyl)octan-2-amine
    —— (2S)-N-(2-phenylsulfanylethyl)octan-2-amine —— C16H27NS
    (2S)-N-(2-phenylsulfanylethyl)octan-2-amine
    —— N-[(1R)-1-cyclohexylethyl]-2-ethylsulfanylaniline —— C16H25NS
    N-[(1R)-1-cyclohexylethyl]-2-ethylsulfanylaniline
    —— N-[(1S)-1-cyclohexylethyl]-2-ethylsulfanylaniline —— C16H25NS
    N-[(1S)-1-cyclohexylethyl]-2-ethylsulfanylaniline
    —— 2-ethylsulfanyl-N-[(2S)-5-methylhexan-2-yl]aniline —— C15H25NS
    2-ethylsulfanyl-N-[(2S)-5-methylhexan-2-yl]aniline
    —— (2R)-2-(7-tert-butyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N-[(1R,2S,3S)-2,3-dimethylcyclohexyl]propanamide —— C23H35N5O3S
    (2R)-2-(7-tert-butyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N-[(1R,2S,3S)-2,3-dimethylcyclohexyl]propanamide
    —— (2S)-2-(7-tert-butyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]propanamide —— C23H35N5O3S
    (2S)-2-(7-tert-butyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]propanamide
    —— (2R)-2-(7-tert-butyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]propanamide —— C23H35N5O3S
    (2R)-2-(7-tert-butyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]propanamide
    —— (2S)-2-(7-tert-butyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N-[(1R,2S,3S)-2,3-dimethylcyclohexyl]propanamide —— C23H35N5O3S
    (2S)-2-(7-tert-butyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-N-[(1R,2S,3S)-2,3-dimethylcyclohexyl]propanamide
    —— N-[(1S)-1-cyclopentylethyl]-2-ethylsulfanylaniline —— C15H23NS
    N-[(1S)-1-cyclopentylethyl]-2-ethylsulfanylaniline
    —— N-[(1R)-1-cyclopentylethyl]-2-ethylsulfanylaniline —— C15H23NS
    N-[(1R)-1-cyclopentylethyl]-2-ethylsulfanylaniline
    —— 1-[(3S)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-pyridin-2-ylsulfanylethanone —— C20H16ClN3O2S
    1-[(3S)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-pyridin-2-ylsulfanylethanone
    —— N-[[(2S)-oxolan-2-yl]methyl]-2-pyridin-2-ylsulfanylacetamide —— C12H16N2O2S
    N-[[(2S)-oxolan-2-yl]methyl]-2-pyridin-2-ylsulfanylacetamide
    —— N-[(1S)-1-cyano-1-cyclopropylethyl]-2-pyridin-2-ylsulfanylacetamide —— C13H15N3OS
    N-[(1S)-1-cyano-1-cyclopropylethyl]-2-pyridin-2-ylsulfanylacetamide
    —— (2S)-N-cyclopropyl-2-pyridin-2-ylsulfanylpropanamide —— C11H14N2OS
    (2S)-N-cyclopropyl-2-pyridin-2-ylsulfanylpropanamide
    —— ethyl 2,4-dimethyl-5-[(2S)-2-pyridin-2-ylsulfanylpropanoyl]-1H-pyrrole-3-carboxylate —— C17H20N2O3S
    ethyl 2,4-dimethyl-5-[(2S)-2-pyridin-2-ylsulfanylpropanoyl]-1H-pyrrole-3-carboxylate
    —— N-[2-(4-fluorophenyl)ethyl]-2-pyridin-2-ylsulfanylacetamide —— C15H15FN2OS
    N-[2-(4-fluorophenyl)ethyl]-2-pyridin-2-ylsulfanylacetamide
    —— N-[(2R)-2-phenylpropyl]-2-pyridin-2-ylsulfanylacetamide —— C16H18N2OS
    N-[(2R)-2-phenylpropyl]-2-pyridin-2-ylsulfanylacetamide
    —— 1-[(3R)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-pyridin-2-ylsulfanylethanone —— C18H15N3OS3
    1-[(3R)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-pyridin-2-ylsulfanylethanone
    —— (E)-3-[[3-[(4-chlorophenyl)methylsulfanyl]-1H-1,2,4-triazol-5-yl]amino]-2-(4-methyl-1,3-thiazol-2-yl)prop-2-enenitrile —— C16H13ClN6S2
    (E)-3-[[3-[(4-chlorophenyl)methylsulfanyl]-1H-1,2,4-triazol-5-yl]amino]-2-(4-methyl-1,3-thiazol-2-yl)prop-2-enenitrile
    —— ethyl (2S)-2-cyano-3-(3-phenylsulfanylpropylimino)propanoate —— C15H18N2O2S
    ethyl (2S)-2-cyano-3-(3-phenylsulfanylpropylimino)propanoate
    —— (2R)-3-[2-(4-chlorophenyl)sulfanylethylimino]-2-(4-methyl-1,3-thiazol-2-yl)propanenitrile —— C15H14ClN3S2
    (2R)-3-[2-(4-chlorophenyl)sulfanylethylimino]-2-(4-methyl-1,3-thiazol-2-yl)propanenitrile
    —— ethyl (E)-2-cyano-3-[2-[2-(2-fluorophenyl)sulfanylacetyl]hydrazinyl]prop-2-enoate —— C14H14FN3O3S
    ethyl (E)-2-cyano-3-[2-[2-(2-fluorophenyl)sulfanylacetyl]hydrazinyl]prop-2-enoate
    —— (E)-3-[4-(1H-benzimidazol-2-ylsulfanyl)anilino]-2-(4-methyl-1,3-thiazol-2-yl)prop-2-enenitrile —— C20H15N5S2
    (E)-3-[4-(1H-benzimidazol-2-ylsulfanyl)anilino]-2-(4-methyl-1,3-thiazol-2-yl)prop-2-enenitrile
    —— [4-[[(E)-2-cyano-2-(4-methyl-1,3-thiazol-2-yl)ethenyl]amino]-3-fluorophenyl] thiocyanate —— C14H9FN4S2
    [4-[[(E)-2-cyano-2-(4-methyl-1,3-thiazol-2-yl)ethenyl]amino]-3-fluorophenyl] thiocyanate
    —— (2R)-5-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-2-methyl-2-(propylamino)pentanenitrile —— C13H23N5S
    (2R)-5-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-2-methyl-2-(propylamino)pentanenitrile