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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-N-cyclopropyl-2-[[5-[(1R)-1-(dimethylamino)propyl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C13H22N4O2S
    (2R)-N-cyclopropyl-2-[[5-[(1R)-1-(dimethylamino)propyl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— N-[(1S)-1-(furan-2-yl)ethyl]-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C13H16N4O2S
    N-[(1S)-1-(furan-2-yl)ethyl]-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-[[5-[(1R)-1-(dimethylamino)propyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methoxyethyl)acetamide —— C12H22N4O3S
    2-[[5-[(1R)-1-(dimethylamino)propyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methoxyethyl)acetamide
    —— 2-[[5-[(1S)-1-(dimethylamino)propyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C13H22N4O4S2
    2-[[5-[(1S)-1-(dimethylamino)propyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— [(1S)-1-[5-[(2S)-1-amino-1-oxopropan-2-yl]sulfanyl-1,3,4-oxadiazol-2-yl]propyl]-dimethylazanium —— C10H19N4O2S+
    [(1S)-1-[5-[(2S)-1-amino-1-oxopropan-2-yl]sulfanyl-1,3,4-oxadiazol-2-yl]propyl]-dimethylazanium
    —— 2-[[5-[(1R)-1-(dimethylamino)propyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylacetamide —— C10H18N4O2S
    2-[[5-[(1R)-1-(dimethylamino)propyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylacetamide
    —— (2R)-N-cyclopropyl-2-[[5-(piperidin-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C14H22N4O2S
    (2R)-N-cyclopropyl-2-[[5-(piperidin-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-2-[[5-[(1S)-1-(dimethylamino)propyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylpropanamide —— C11H20N4O2S
    (2S)-2-[[5-[(1S)-1-(dimethylamino)propyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylpropanamide
    —— N-acetyl-2-[[5-(piperidin-1-ium-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C12H19N4O3S+
    N-acetyl-2-[[5-(piperidin-1-ium-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-(piperidin-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-prop-2-ynylacetamide —— C13H18N4O2S
    2-[[5-(piperidin-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-prop-2-ynylacetamide
    —— (2R)-N-methyl-2-[[5-(piperidin-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C12H20N4O2S
    (2R)-N-methyl-2-[[5-(piperidin-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-2-[[5-(piperidin-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propan-2-ylpropanamide —— C14H24N4O2S
    (2S)-2-[[5-(piperidin-1-ylmethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propan-2-ylpropanamide
    —— [(1R)-1-[5-[(2R)-1-amino-1-oxopropan-2-yl]sulfanyl-1,3,4-oxadiazol-2-yl]propyl]-dimethylazanium —— C10H19N4O2S+
    [(1R)-1-[5-[(2R)-1-amino-1-oxopropan-2-yl]sulfanyl-1,3,4-oxadiazol-2-yl]propyl]-dimethylazanium
    —— N-methyl-2-[[5-(3-morpholin-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C12H21N5O2S2
    N-methyl-2-[[5-(3-morpholin-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (2S)-N-(2-cyanoethyl)-N-methyl-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C10H14N4O2S
    (2S)-N-(2-cyanoethyl)-N-methyl-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N-ethyl-2-[[5-(3-morpholin-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C14H25N5O2S2
    (2R)-N-ethyl-2-[[5-(3-morpholin-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— N-tert-butyl-2-[[5-(3-morpholin-4-ium-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H28N5O2S2+
    N-tert-butyl-2-[[5-(3-morpholin-4-ium-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (2R)-N-cyclopropyl-2-[[5-(3-morpholin-4-ium-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C15H26N5O2S2+
    (2R)-N-cyclopropyl-2-[[5-(3-morpholin-4-ium-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— N-[[(2S)-oxolan-2-yl]methyl]-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C12H18N4O2S
    N-[[(2S)-oxolan-2-yl]methyl]-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (2R)-N,N-dimethyl-2-[[5-(3-morpholin-4-ium-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C14H26N5O2S2+
    (2R)-N,N-dimethyl-2-[[5-(3-morpholin-4-ium-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-N,N-dimethyl-2-[[5-(3-morpholin-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C14H25N5O2S2
    (2R)-N,N-dimethyl-2-[[5-(3-morpholin-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-N-(2-cyanoethyl)-2-[(5-cyclopropyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-methylpropanamide —— C12H16N4O2S
    (2S)-N-(2-cyanoethyl)-2-[(5-cyclopropyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-methylpropanamide
    —— (2R)-2-[(5-cyclopropyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-prop-2-enylpropanamide —— C11H15N3O2S
    (2R)-2-[(5-cyclopropyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-prop-2-enylpropanamide
    —— N-tert-butyl-2-[[5-(3-morpholin-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H27N5O2S2
    N-tert-butyl-2-[[5-(3-morpholin-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 1-[1-[(3R)-1,1-dioxothiolan-3-yl]-2,5-dimethylpyrrol-3-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanone —— C15H19N3O4S2
    1-[1-[(3R)-1,1-dioxothiolan-3-yl]-2,5-dimethylpyrrol-3-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanone
    —— (2R)-N-methyl-2-[[5-(3-morpholin-4-ium-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C13H24N5O2S2+
    (2R)-N-methyl-2-[[5-(3-morpholin-4-ium-4-ylpropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— 2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C10H15N3O3S
    2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— 2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-1-[1-[(3R)-1,1-dioxothiolan-3-yl]-2,5-dimethylpyrrol-3-yl]ethanone —— C16H22N4O3S2
    2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-1-[1-[(3R)-1,1-dioxothiolan-3-yl]-2,5-dimethylpyrrol-3-yl]ethanone
    —— N-[(3R)-3-methyl-1,1-dioxothiolan-3-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C10H15N3O4S2
    N-[(3R)-3-methyl-1,1-dioxothiolan-3-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— 2-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]-1-(4-methylpiperazin-4-ium-1-yl)ethanone —— C11H20N5OS+
    2-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanyl]-1-(4-methylpiperazin-4-ium-1-yl)ethanone
    —— 1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C12H20N4O2S
    1-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— (2R)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-methylpropanamide —— C8H14N4OS
    (2R)-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-methylpropanamide
    —— 2-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-methyl-1,3,4-oxadiazole —— C8H11N5OS
    2-[(4,5-Dimethyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-methyl-1,3,4-oxadiazole
    —— (3R)-1-[(2R)-1-methoxypropan-2-yl]-5-oxo-N-(2-phenylsulfanylphenyl)pyrrolidine-3-carboxamide —— C21H24N2O3S
    (3R)-1-[(2R)-1-methoxypropan-2-yl]-5-oxo-N-(2-phenylsulfanylphenyl)pyrrolidine-3-carboxamide
    —— ethyl N-[2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetyl]carbamate —— C8H11N3O4S
    ethyl N-[2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetyl]carbamate
    —— (2S)-N-cyclopropyl-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C10H16N4OS
    (2S)-N-cyclopropyl-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2R)-2-[(5-cyclopropyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-(methylcarbamoyl)propanamide —— C10H14N4O3S
    (2R)-2-[(5-cyclopropyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-(methylcarbamoyl)propanamide
    —— N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C10H15N3O4S2
    N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]-2-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— N-benzyl-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C17H22N4O3S2
    N-benzyl-2-[(4,5-dimethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— 2-[(Z)-(2-bromophenyl)methylideneamino]oxy-N-[2-(4-methylphenyl)sulfanylethyl]acetamide —— C18H19BrN2O2S
    2-[(Z)-(2-bromophenyl)methylideneamino]oxy-N-[2-(4-methylphenyl)sulfanylethyl]acetamide
    —— 2-[(Z)-benzylideneamino]oxy-N-[2-(4-methylphenyl)sulfanylethyl]acetamide —— C18H20N2O2S
    2-[(Z)-benzylideneamino]oxy-N-[2-(4-methylphenyl)sulfanylethyl]acetamide
    —— N-[(1S)-1-cyclopropylethyl]-2-[[5-[4-(difluoromethylsulfanyl)anilino]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C16H18F2N4OS3
    N-[(1S)-1-cyclopropylethyl]-2-[[5-[4-(difluoromethylsulfanyl)anilino]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[(1R)-1-cyclopropylethyl]-2-[[5-[4-(difluoromethylsulfanyl)anilino]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C16H18F2N4OS3
    N-[(1R)-1-cyclopropylethyl]-2-[[5-[4-(difluoromethylsulfanyl)anilino]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-benzyl-N-[(1R)-1-cyclopropylethyl]-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide —— C23H27NO3S
    N-benzyl-N-[(1R)-1-cyclopropylethyl]-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide
    —— N-benzyl-N-[(1S)-1-cyclopropylethyl]-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide —— C23H27NO3S
    N-benzyl-N-[(1S)-1-cyclopropylethyl]-2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)acetamide
    —— N-[[4-(dimethylamino)phenyl]methyl]-N-[[(2R)-oxolan-2-yl]methyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C21H31N5O2S
    N-[[4-(dimethylamino)phenyl]methyl]-N-[[(2R)-oxolan-2-yl]methyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[[4-(dimethylamino)phenyl]methyl]-N-[[(2S)-oxolan-2-yl]methyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C21H31N5O2S
    N-[[4-(dimethylamino)phenyl]methyl]-N-[[(2S)-oxolan-2-yl]methyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 1-[[2-(2,5-difluorophenyl)sulfanylacetyl]amino]-3-[(2R)-1-methoxypropan-2-yl]thiourea —— C13H17F2N3O2S2
    1-[[2-(2,5-difluorophenyl)sulfanylacetyl]amino]-3-[(2R)-1-methoxypropan-2-yl]thiourea
    —— N-benzyl-N-[(1S)-1-cyclopropylethyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C22H31N5O2S
    N-benzyl-N-[(1S)-1-cyclopropylethyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-benzyl-N-[(1R)-1-cyclopropylethyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C22H31N5O2S
    N-benzyl-N-[(1R)-1-cyclopropylethyl]-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide