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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methyl-N-[(1R)-1-phenylethyl]acetamide —— C21H24N4OS2
    2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methyl-N-[(1R)-1-phenylethyl]acetamide
    —— (3S,6S)-N-methyltricyclo[4.3.1.13,8]undecane-1-carbothioamide —— C13H21NS
    (3S,6S)-N-methyltricyclo[4.3.1.13,8]undecane-1-carbothioamide
    —— 2-[(2R)-1-methyl-4-[(2-methylsulfanylpyrimidin-5-yl)methyl]piperazin-2-yl]ethanol —— C13H22N4OS
    2-[(2R)-1-methyl-4-[(2-methylsulfanylpyrimidin-5-yl)methyl]piperazin-2-yl]ethanol
    —— 3-benzylsulfanyl-4-[(Z)-(2,5-dimethyl-1-propan-2-ylpyrrol-3-yl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C19H23N5S2
    3-benzylsulfanyl-4-[(Z)-(2,5-dimethyl-1-propan-2-ylpyrrol-3-yl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— N-[(Z)-(2,5-dimethyl-1-propan-2-ylpyrrol-3-yl)methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide —— C18H22FN3OS
    N-[(Z)-(2,5-dimethyl-1-propan-2-ylpyrrol-3-yl)methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide
    —— N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-2-[(1R,2R,6S,7R)-3,5-dioxo-4-azatricyclo[5.2.1.02,6]dec-8-en-4-yl]acetamide —— C25H24N2O3S
    N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-2-[(1R,2R,6S,7R)-3,5-dioxo-4-azatricyclo[5.2.1.02,6]dec-8-en-4-yl]acetamide
    —— N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-2-[(1R,2S,6S,7R)-3,5-dioxo-4-azatricyclo[5.2.1.02,6]dec-8-en-4-yl]acetamide —— C25H24N2O3S
    N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-2-[(1R,2S,6S,7R)-3,5-dioxo-4-azatricyclo[5.2.1.02,6]dec-8-en-4-yl]acetamide
    —— (1S)-N-ethyl-1-[(1S,2R)-2-ethylcyclohexyl]-2-methylsulfonylethanamine —— C13H27NO2S
    (1S)-N-ethyl-1-[(1S,2R)-2-ethylcyclohexyl]-2-methylsulfonylethanamine
    —— (1S)-N-ethyl-1-[(1R,2R)-2-ethylcyclohexyl]-2-methylsulfonylethanamine —— C13H27NO2S
    (1S)-N-ethyl-1-[(1R,2R)-2-ethylcyclohexyl]-2-methylsulfonylethanamine
    —— (1S)-N-ethyl-1-[(1S,2S)-2-ethylcyclohexyl]-2-methylsulfonylethanamine —— C13H27NO2S
    (1S)-N-ethyl-1-[(1S,2S)-2-ethylcyclohexyl]-2-methylsulfonylethanamine
    —— N-[4-(2,4-dimethylphenyl)sulfanylphenyl]-2-[(1R,2S,6S,7R)-3,5-dioxo-4-azatricyclo[5.2.1.02,6]dec-8-en-4-yl]acetamide —— C25H24N2O3S
    N-[4-(2,4-dimethylphenyl)sulfanylphenyl]-2-[(1R,2S,6S,7R)-3,5-dioxo-4-azatricyclo[5.2.1.02,6]dec-8-en-4-yl]acetamide
    —— N-[4-(2,4-dimethylphenyl)sulfanylphenyl]-2-[(1R,2R,6S,7R)-3,5-dioxo-4-azatricyclo[5.2.1.02,6]dec-8-en-4-yl]acetamide —— C25H24N2O3S
    N-[4-(2,4-dimethylphenyl)sulfanylphenyl]-2-[(1R,2R,6S,7R)-3,5-dioxo-4-azatricyclo[5.2.1.02,6]dec-8-en-4-yl]acetamide
    —— (1S)-N-ethyl-1-[(1R,2S)-2-ethylcyclohexyl]-2-methylsulfonylethanamine —— C13H27NO2S
    (1S)-N-ethyl-1-[(1R,2S)-2-ethylcyclohexyl]-2-methylsulfonylethanamine
    —— 1-[(S)-2-(2-chloroethoxy)ethylsulfinyl]octane —— C12H25ClO2S
    1-[(S)-2-(2-chloroethoxy)ethylsulfinyl]octane
    —— N-[4-(4-bromophenyl)sulfanylphenyl]-2-[(1R,2R,6S,7R)-3,5-dioxo-4-azatricyclo[5.2.1.02,6]dec-8-en-4-yl]acetamide —— C23H19BrN2O3S
    N-[4-(4-bromophenyl)sulfanylphenyl]-2-[(1R,2R,6S,7R)-3,5-dioxo-4-azatricyclo[5.2.1.02,6]dec-8-en-4-yl]acetamide
    —— N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-[(1R,2R,6S,7R)-3,5-dioxo-4-azatricyclo[5.2.1.02,6]dec-8-en-4-yl]acetamide —— C25H24N2O3S
    N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-[(1R,2R,6S,7R)-3,5-dioxo-4-azatricyclo[5.2.1.02,6]dec-8-en-4-yl]acetamide
    —— (2S)-1-[4-[(3,5-dimethyl-1,2-oxazol-4-yl)sulfonyl]piperazin-1-yl]-2-phenylsulfanylpropan-1-one —— C18H23N3O4S2
    (2S)-1-[4-[(3,5-dimethyl-1,2-oxazol-4-yl)sulfonyl]piperazin-1-yl]-2-phenylsulfanylpropan-1-one
    —— 1-[(R)-2-(2-chloroethoxy)ethylsulfinyl]octane —— C12H25ClO2S
    1-[(R)-2-(2-chloroethoxy)ethylsulfinyl]octane
    —— N-[4-(4-bromophenyl)sulfanylphenyl]-2-[(1R,2S,6S,7R)-3,5-dioxo-4-azatricyclo[5.2.1.02,6]dec-8-en-4-yl]acetamide —— C23H19BrN2O3S
    N-[4-(4-bromophenyl)sulfanylphenyl]-2-[(1R,2S,6S,7R)-3,5-dioxo-4-azatricyclo[5.2.1.02,6]dec-8-en-4-yl]acetamide
    —— N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-[(1R,2S,6S,7R)-3,5-dioxo-4-azatricyclo[5.2.1.02,6]dec-8-en-4-yl]acetamide —— C25H24N2O3S
    N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-[(1R,2S,6S,7R)-3,5-dioxo-4-azatricyclo[5.2.1.02,6]dec-8-en-4-yl]acetamide
    —— 2-(2,5-difluorophenyl)sulfanyl-N-[(1S)-2-morpholin-4-yl-1-phenylethyl]acetamide —— C20H22F2N2O2S
    2-(2,5-difluorophenyl)sulfanyl-N-[(1S)-2-morpholin-4-yl-1-phenylethyl]acetamide
    —— 5-bromo-2-[(1R,3S)-3-methylcyclohexyl]sulfanylpyrimidine —— C11H15BrN2S
    5-bromo-2-[(1R,3S)-3-methylcyclohexyl]sulfanylpyrimidine
    —— N-[(1R)-2-morpholin-4-ium-4-yl-1-phenylethyl]-2-phenylsulfanylacetamide —— C20H25N2O2S+
    N-[(1R)-2-morpholin-4-ium-4-yl-1-phenylethyl]-2-phenylsulfanylacetamide
    —— [5-[(1S,2R)-2-ethylcyclohexyl]sulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl]methanamine —— C14H26N4S
    [5-[(1S,2R)-2-ethylcyclohexyl]sulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl]methanamine
    —— 5-bromo-2-[(1S,3S)-3-methylcyclohexyl]sulfanylpyrimidine —— C11H15BrN2S
    5-bromo-2-[(1S,3S)-3-methylcyclohexyl]sulfanylpyrimidine
    —— [5-[(1R,2R)-2-ethylcyclohexyl]sulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl]methanamine —— C14H26N4S
    [5-[(1R,2R)-2-ethylcyclohexyl]sulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl]methanamine
    —— 2-(3,4-dimethylphenyl)sulfanyl-N-[(1S)-2-morpholin-4-yl-1-phenylethyl]acetamide —— C22H28N2O2S
    2-(3,4-dimethylphenyl)sulfanyl-N-[(1S)-2-morpholin-4-yl-1-phenylethyl]acetamide
    —— 3-(4-chlorophenyl)sulfanyl-N-[(1R)-2-morpholin-4-yl-1-phenylethyl]propanamide —— C21H25ClN2O2S
    3-(4-chlorophenyl)sulfanyl-N-[(1R)-2-morpholin-4-yl-1-phenylethyl]propanamide
    —— [5-[(1S,2S)-2-ethylcyclohexyl]sulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl]methanamine —— C14H26N4S
    [5-[(1S,2S)-2-ethylcyclohexyl]sulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl]methanamine
    —— [5-[(1R,2S)-2-ethylcyclohexyl]sulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl]methanamine —— C14H26N4S
    [5-[(1R,2S)-2-ethylcyclohexyl]sulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl]methanamine
    —— 4-[(2-Benzylsulfanyl-6-methylpyrimidin-4-yl)amino]phenol —— C18H17N3OS
    4-[(2-Benzylsulfanyl-6-methylpyrimidin-4-yl)amino]phenol
    —— 5-bromo-2-[(1R,3R)-3-methylcyclohexyl]sulfanylpyrimidine —— C11H15BrN2S
    5-bromo-2-[(1R,3R)-3-methylcyclohexyl]sulfanylpyrimidine
    —— N-[(1R)-2-morpholin-4-yl-1-phenylethyl]-2-phenylsulfanylacetamide —— C20H24N2O2S
    N-[(1R)-2-morpholin-4-yl-1-phenylethyl]-2-phenylsulfanylacetamide
    —— 2-[(1R,2S)-2-ethylcyclohexyl]sulfanyl-5-fluoroaniline —— C14H20FNS
    2-[(1R,2S)-2-ethylcyclohexyl]sulfanyl-5-fluoroaniline
    —— 5-bromo-2-[(1S,3R)-3-methylcyclohexyl]sulfanylpyrimidine —— C11H15BrN2S
    5-bromo-2-[(1S,3R)-3-methylcyclohexyl]sulfanylpyrimidine
    —— 2-[(1S,2S)-2-ethylcyclohexyl]sulfanyl-5-fluoroaniline —— C14H20FNS
    2-[(1S,2S)-2-ethylcyclohexyl]sulfanyl-5-fluoroaniline
    —— 2-[(1S,2R)-2-ethylcyclohexyl]sulfanylpyrimidine-4,6-diamine —— C12H20N4S
    2-[(1S,2R)-2-ethylcyclohexyl]sulfanylpyrimidine-4,6-diamine
    —— 2-[(1R,2R)-2-ethylcyclohexyl]sulfanyl-5-fluoroaniline —— C14H20FNS
    2-[(1R,2R)-2-ethylcyclohexyl]sulfanyl-5-fluoroaniline
    —— 2-[(1S,2R)-2-ethylcyclohexyl]sulfanyl-5-fluoroaniline —— C14H20FNS
    2-[(1S,2R)-2-ethylcyclohexyl]sulfanyl-5-fluoroaniline
    —— (2R)-3-octadecylsulfonylpropane-1,2-diol —— C21H44O4S
    (2R)-3-octadecylsulfonylpropane-1,2-diol
    —— 6-amino-2-[(1R,2S)-2-ethylcyclohexyl]sulfanyl-1H-pyrimidin-4-one —— C12H19N3OS
    6-amino-2-[(1R,2S)-2-ethylcyclohexyl]sulfanyl-1H-pyrimidin-4-one
    —— 2-[(1R,2S)-2-ethylcyclohexyl]sulfanylpyrimidine-4,6-diamine —— C12H20N4S
    2-[(1R,2S)-2-ethylcyclohexyl]sulfanylpyrimidine-4,6-diamine
    —— 6-amino-2-[(1S,2R)-2-ethylcyclohexyl]sulfanyl-1H-pyrimidin-4-one —— C12H19N3OS
    6-amino-2-[(1S,2R)-2-ethylcyclohexyl]sulfanyl-1H-pyrimidin-4-one
    —— 2-[(1S,2S)-2-ethylcyclohexyl]sulfanylpyrimidine-4,6-diamine —— C12H20N4S
    2-[(1S,2S)-2-ethylcyclohexyl]sulfanylpyrimidine-4,6-diamine
    —— 6-amino-2-[(1R,2R)-2-ethylcyclohexyl]sulfanyl-1H-pyrimidin-4-one —— C12H19N3OS
    6-amino-2-[(1R,2R)-2-ethylcyclohexyl]sulfanyl-1H-pyrimidin-4-one
    —— 6-amino-2-[(1S,2S)-2-ethylcyclohexyl]sulfanyl-1H-pyrimidin-4-one —— C12H19N3OS
    6-amino-2-[(1S,2S)-2-ethylcyclohexyl]sulfanyl-1H-pyrimidin-4-one
    —— Ethyl 2-[(5-amino-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]acetate —— C8H14N4O2S
    Ethyl 2-[(5-amino-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]acetate
    —— 2-[3-Amino-5-(cyanomethylsulfanyl)-1,2,4-triazol-4-yl]acetamide —— C6H8N6OS
    2-[3-Amino-5-(cyanomethylsulfanyl)-1,2,4-triazol-4-yl]acetamide
    —— (2Z,5Z)-2-(2-methylpropylidene)-5-[(4-methylsulfanylphenyl)methylidene]cyclopentan-1-one —— C17H20OS
    (2Z,5Z)-2-(2-methylpropylidene)-5-[(4-methylsulfanylphenyl)methylidene]cyclopentan-1-one
    —— 5-Benzylsulfanyl-4-[(2-chlorophenyl)methyl]-1,2,4-triazol-3-amine —— C16H15ClN4S
    5-Benzylsulfanyl-4-[(2-chlorophenyl)methyl]-1,2,4-triazol-3-amine